Search Results (1,115)

In the present work, the optimization of ceramic-based composite WC(Co,Ni) welds by laser cladding was carried out using response surface methodology based on finite element analysis. The heat distribution and temperature field of laser-melted WC(Co,Ni) ceramic coatings were simulated using ANSYS software, which allowed the computation of the distribution of residual stresses. The results show that the isotherms in the simulation of the temperature field are elliptical in shape, and that the isotherms in front of the moving heat source are dense with a larger temperature gradient, while the isotherms behind the heat source are sparse with a smaller temperature gradient. In addition, the observed microstructural evolution shows that the melting zone domains of WC(Co,Ni) are mainly composed of unmelted carbides. These carbides are dendritic, rod-like, leaf-like, or net-like, and are agglomerated into smaller groups. The W content of these unmelted carbides exceeds 80%, while the C content is around 1.5–3.0%. The grey areas are composed of WC, Co and Ni compounds. Based on the regression model, a quadratic model was successfully constructed. A three-dimensional profile model of the residual stress behaviour was further explored. The estimated values of the RSM-based FEA model for residual stress are very similar to the actual results, which shows that the model is effective in reducing residual stress by laser cladding. Full article

This paper presents a comprehensive review of the environmentally friendly management and reutilization of electronic waste (e-waste) plastics in flexible pavement construction. The discussion begins with an overview of e-waste management challenges and outlines key recycling approaches for converting plastic waste into asphalt-compatible materials. This review then discusses the types of e-waste plastics used for asphalt modification, their incorporation methods, and compatibility challenges. Physical and chemical treatment techniques, including the use of free radical initiators, are then explored for improving dispersion and performance. Additionally, in situations where advanced pretreatment methods are not applicable due to cost, safety, or technical constraints, the application of alternative approaches, such as the use of low-cost complementary additives, is discussed as a practical solution to enhance compatibility and performance. Finally, the influence of e-waste plastics on the conventional and rheological properties of asphalt binders, as well as the performance of asphalt mixtures, is also evaluated. Findings indicate that e-waste plastics, when combined with appropriate pretreatment methods and complementary additives, can enhance workability, cold-weather cracking resistance, high-temperature anti-rutting performance, and resistance against moisture-induced damage while also offering environmental and economic benefits. This review highlights the potential of e-waste plastics as sustainable asphalt modifiers and provides insights across the full utilization pathway, from recovery to in-field performance. Full article

Cultivated land quality is a key factor in ensuring sustainable agricultural development. Exploring differences in cultivated land quality under distinct cropping systems is essential for developing targeted improvement strategies. This study takes place in Shenyang City—located in the typical black soil region of Northeast China—as a case area to construct a cultivated land quality evaluation system comprising 13 indicators, including organic matter, effective soil layer thickness, and texture configuration. A minimum data set (MDS) was separately extracted for paddy and upland fields using principal component analysis (PCA) to conduct a comprehensive evaluation of cultivated land quality. Additionally, an obstacle degree model was employed to identify the limiting factors and quantify their impact. The results indicated the following. (1) Both MDSs consisted of seven indicators, among which five were common: ≥10 °C accumulated temperature, available phosphorus, arable layer thickness, irrigation capacity, and organic matter. Parent material and effective soil layer thickness were unique to paddy fields, while landform type and soil texture were unique to upland fields. (2) The cultivated land quality index (CQI) values at the sampling point level showed no significant difference between paddy (0.603) and upland (0.608) fields. However, their spatial distributions diverged significantly; paddy fields were dominated by high-grade land (Grades I and II) clustered in southern areas, whereas uplands were primarily of medium quality (Grades III and IV), with broader spatial coverage. (3) Major constraint factors for paddy fields were effective soil layer thickness (21.07%) and arable layer thickness (22.29%). For upland fields, the dominant constraints were arable layer thickness (27.57%), organic matter (25.40%), and ≥10 °C accumulated temperature (23.28%). Available phosphorus and ≥10 °C accumulated temperature were identified as shared constraint factors affecting quality classification in both systems. In summary, cultivated land quality under different cropping systems is influenced by distinct limiting factors. The construction of cropping-system-specific MDSs effectively improves the efficiency and accuracy of cultivated land quality assessment, offering theoretical and methodological support for land resource management in the black soil regions of China. Full article

Maintaining the required relative humidity values in the vehicle cabin is an important HVAC task, along with considerations related to the temperature, velocity, air pressure and noise. Deviation from the optimal values worsens the psycho-physiological state of the driver and affects the energy efficiency of the train. In this study, a model of liquid film formation on and removal from various cabin surfaces was constructed using the fundamental Navier–Stokes hydrodynamic equations. A special transport model based on the liquid vapor diffusion equation was used to simulate the air environment inside the cabin. The evaporation and condensation of surface films were simulated using the Euler film model, which directly considers liquid–gas and gas–liquid transitions. Numerical results were obtained using the RANS equations and a turbulence model by means of the finite volume method in Ansys CFD. Conjugate fields of temperature, velocity and moisture concentration were constructed for various time intervals, and the dependence values for the film thicknesses on various surfaces relative to time were determined. The verification was conducted in comparison with the experimental data, based on the protocol for measuring the microclimate indicators in workplaces, as applied to the train cabin: the average ranges encompassed temperature changes from 11% to 18%, and relative humidity ranges from 16% to 26%. Comparison with the results of other studies, without considering the phase transition and condensation, shows that, for the warm mode, the average air temperature in the cabin with condensation is 12.5% lower than without condensation, which is related to the process of liquid evaporation from the heated walls. The difference in temperature values for the model with and without condensation ranged from −12.5% to +4.9%. We demonstrate that, with an effective mode of removing condensate film from the window surface, including recirculation modes, the energy consumption of the climate control system improves significantly, but this requires a more accurate consideration of thermodynamic parameters and relative humidity. Thus, considering the moisture condensation model reveals that this variable can significantly affect other parameters of the microclimate in cabins: in particular, the temperature. This means that it should be considered in the numerical modeling, along with the basic heat transfer equations. Full article

Sustainable building design is significantly impacted by the local climate response knowledge ingrained in traditional architecture. However, its integration and dissemination with contemporary green technologies are limited by the absence of a comprehensive quantitative analysis of the regulation of its humid and temperature environment. The Ganzhou Wei family compound from China’s wind–heat environmental regulation systems are examined in this study. We statistically evaluate the synergy between spatial morphology, material qualities, and microclimate using field data with Thsware and Ecotect software in a multiscale simulation framework. The findings indicate that the compound’s special design greatly controls the thermal and wind conditions. Cold alleyways and courtyards work together to maximize thermal environment regulation and encourage natural ventilation. According to quantitative studies, courtyards with particular depths (1–4 m) and height-to-width ratios (e.g., 1:1) reduce wind speed loss. A cool alley (5:1 height–width ratio) creates a dynamic wind–speed–temperature–humidity balance by lowering summer daytime temperatures by 2.5 °C. It also serves as a “cold source area” that moderates temperatures in the surrounding area by up to 2.1 °C. This study suggests a quantitative correlation model based on “spatial morphology–material performance–microclimate response,” which offers a technical route for historic building conservation renovation and green renewal, as well as a scientific foundation for traditional buildings to maintain thermal comfort under low energy consumption. Although based on a specific geographical case, the innovative analytical methods and strategies of this study are of great theoretical and practical significance for promoting the modernization and transformation of traditional architecture, low-carbon city construction, and sustainable building design. Full article

Downhole kick is one of the most severe safety hazards in deep and ultra-deep well drilling operations. Traditional monitoring methods, which rely on surface flow rate and fluid level changes, are limited by their delayed response and insufficient sensitivity, making them inadequate for early warning. This study proposes a real-time monitoring technique for gas content in drilling fluid based on the attenuation principle of Ba-133 γ-rays. By integrating laboratory static/dynamic experiments and Geant4-11.2 Monte Carlo simulations, the influence mechanism of gas–liquid two-phase media on γ-ray transmission characteristics is systematically elucidated. Firstly, through a comparative analysis of radioactive source parameters such as Am-241 and Cs-137, Ba-133 (main peak at 356 keV, half-life of 10.6 years) is identified as the optimal downhole nuclear measurement source based on a comparative analysis of penetration capability, detection efficiency, and regulatory compliance. Compared to alternative sources, Ba-133 provides an optimal energy range for detecting drilling fluid density variations, while also meeting exemption activity limits (1 × 10⁶ Bq) for field deployment. Subsequently, an experimental setup with drilling fluids of varying densities (1.2–1.8 g/cm³) is constructed to quantify the inverse square attenuation relationship between source-to-detector distance and counting rate, and to acquire counting data over the full gas content range (0–100%). The Monte Carlo simulation results exhibit a mean relative error of 5.01% compared to the experimental data, validating the physical correctness of the model. On this basis, a nonlinear inversion model coupling a first-order density term with a cubic gas content term is proposed, achieving a mean absolute percentage error of 2.3% across the full range and R² = 0.999. Geant4-based simulation validation demonstrates that this technique can achieve a measurement accuracy of ±2.5% for gas content within the range of 0–100% (at a 95% confidence interval). The anticipated field accuracy of ±5% is estimated by accounting for additional uncertainties due to temperature effects, vibration, and mud composition variations under downhole conditions, significantly outperforming current surface monitoring methods. This enables the high-frequency, high-precision early detection of kick events during the shut-in period. The present study provides both theoretical and technical support for the engineering application of nuclear measurement techniques in well control safety. Full article

Creating a comfortable microclimate in the premises of buildings is currently becoming one of the priorities in the field of architecture, construction and engineering systems. The increased attention from the scientific community to this topic is due not only to the desire to ensure healthy and favorable conditions for human life but also to the need for the rational use of energy resources. This area is becoming particularly relevant in the context of global challenges related to climate change, rising energy costs and increased environmental requirements. Practice shows that any technical solutions to ensure comfortable temperature, humidity and air exchange in rooms should be closely linked to the concept of energy efficiency. This allows one not only to reduce operating costs but also to significantly reduce greenhouse gas emissions, thereby contributing to sustainable development and environmental safety. In this connection, this study presents a parametric assessment of the influence of climatic and geometric factors on the aerodynamic characteristics of the air cavity, which affect the heat exchange process in the ventilated layer of curtain wall systems. The assessment was carried out using a combined analytical calculation method that provides averaged thermophysical parameters, such as mean air velocity ($V_s$), average internal surface temperature ($t_{in.s}^{av}$), and convective heat transfer coefficient (${\alpha }_s$) within the air cavity. This study resulted in empirical average values, demonstrating that the air velocity within the cavity significantly depends on atmospheric pressure and façade height difference. For instance, a 10-fold increase in façade height leads to a 4.4-fold increase in air velocity. Furthermore, a three-fold variation in local resistance coefficients results in up to a two-fold change in airflow velocity. The cavity thickness, depending on atmospheric pressure, was also found to affect airflow velocity by up to 25%. Similar patterns were observed under ambient temperatures of +20 °C, +30 °C, and +40 °C. The analysis confirmed that airflow velocity is directly affected by cavity height, while the impact of solar radiation is negligible. However, based on the outcomes of the analytical model, it was concluded that the method does not adequately account for the effects of solar radiation and vertical temperature gradients on airflow within ventilated façades. This highlights the need for further full-scale experimental investigations under hot climate conditions in South Kazakhstan. The findings are expected to be applicable internationally to regions with comparable climatic characteristics. Ultimately, a correct understanding of thermophysical processes in such structures will support the advancement of trends such as Lightweight Design, Functionally Graded Design, and Value Engineering in the development of curtain wall systems, through the optimized selection of façade configurations, accounting for temperature loads under specific climatic and design conditions. Full article

An altermagnet, characterized by its distinctive magnetic properties, may hold potential applications in diverse fields such as magnetic materials, spintronics, data storage, and quantum computing. As a prototypical altermagnet, RuO₂ exhibits spin polarization and demonstrates the advantageous characteristics of high electrical conductivity and low thermal conductivity. These exceptional properties endow it with considerable promise in the emerging field of thermal spintronics. We studied the electronic structure and thermoelectric properties of RuO₂; the constructed RuO₂/TiO₂/RuO₂ all-antiferromagnetic tunnel junction (AFMTJ) exhibited thermally induced magnetoresistance (TIMR), reaching a maximum TIMR of 1756% at a temperature gradient of 5 K. Compared with prior studies on RuO₂-based antiferromagnetic tunnel junctions, the novelty of this work lies in the thermally induced magnetoresistance based on its superior thermoelectric properties. In parallel structures, the spin-down current dominates the transmission spectrum, whereas in antiparallel structures, the spin-up current governs the transmission spectrum, underscoring the spin-polarized thermal transport. In addition, thermoelectric efficiency emphasizes the potential of RuO₂ to link antiferromagnetic robustness with ferromagnetic spin functionality. These findings promote the development of efficient spintronic devices and spin-based storage technology for waste heat recovery and emphasize the role of spin splitting in zero-magnetization systems. Full article

We investigate magnetic instabilities toward multiple-Q states in centrosymmetric bilayer triangular-lattice systems. By focusing on the interplay between the layer-dependent Dzyaloshinskii–Moriya interaction and layer-independent bond-dependent anisotropic interaction, both of which originate from the relativistic spin-orbit coupling, we construct a low-temperature phase diagram based on an effective spin model that also includes frustrated isotropic exchange interactions. Employing simulated annealing, we reveal the stabilization of three distinct double-Q phases in the absence of an external magnetic field, each characterized by noncoplanar spin textures with spatially modulated local scalar spin chirality. Under applied magnetic fields, we identify field-induced phase transitions among single-Q, double-Q, and triple-Q states, some of which exhibit a finite net scalar spin chirality indicative of topologically nontrivial order. These findings highlight centrosymmetric systems with sublattice-dependent Dzyaloshinskii–Moriya interactions as promising platforms for realizing a variety of multiple-Q spin textures. Full article

High-resolution numerical weather prediction requires accurate cloud microphysical initial conditions to enhance forecasting capabilities for high-impact severe weather events such as convective storms. This study integrated Fengyun-2 (FY-2) geostationary satellite data (equivalent blackbody temperature and total cloud cover) and next-generation 3D weather radar reflectivity from the China Meteorological Administration (CMA) to construct cloud microphysical initial fields and evaluate their impact on the CMA-MESO 3 km regional model. An analysis of the catastrophic rainfall event in Henan on 20 July 2021, and a 92-day continuous experiment (May–July 2024) revealed that assimilating cloud microphysical variables significantly improved precipitation forecasting: the equitable threat scores (ETSs) for 1 h forecasts of light, moderate, and heavy rain increased from 0.083, 0.043, and 0.007 to 0.41, 0.36, and 0.217, respectively, with average hourly ETS improvements of 21–71% for 2–6 h forecasts and increases in ETSs for light, moderate, and heavy rain of 7.5%, 9.8%, and 24.9% at 7–12 h, with limited improvement beyond 12 h. Furthermore, the root mean square error (RMSE) of the 2 m temperature forecasts decreased across all 1–72 h lead times, with a 4.2% reduction during the 1–9 h period, while the geopotential height RMSE reductions reached 5.8%, 3.3%, and 2.0% at 24, 48, and 72 h, respectively. Additionally, synchronized enhancements were observed in 10 m wind prediction accuracy. These findings underscore the critical role of cloud microphysical initialization in advancing mesoscale numerical weather prediction systems. Full article

We numerically investigate the effect of multi-spin interactions on the stability of skyrmion crystals and other multiple-Q magnetic states, with a particular emphasis on the momentum-resolved bicubic interaction. By performing simulated annealing for an effective spin model that incorporates bilinear, biquadratic, and bicubic interactions on a two-dimensional triangular lattice, we construct the corresponding low-temperature phase diagram. Our results reveal that a positive bicubic interaction stabilizes a skyrmion crystal with a skyrmion number of two, whereas a negative bicubic interaction favors a single-Q spiral state. Moreover, we demonstrate that the stability region of the field-induced skyrmion crystal with the skyrmion number of one is largely enlarged in the presence of a positive bicubic interaction. Full article

Background/Objectives: Tegoprazan (TPZ) is a potassium-competitive acid blocker (P-CAB) used to treat conditions such as gastroesophageal reflux disease, peptic ulcer, and Helicobacter pylori infection. It exists in three solid forms: amorphous, Polymorph A, and Polymorph B. This study investigates the molecular basis of polymorph selection, focusing on conformational bias and solvent-mediated phase transformations (SMPTs). Methods: The conformational energy landscapes of two TPZ tautomers were constructed using relaxed torsion scans with the OPLS4 force field and validated by nuclear Overhauser effect (NOE)-based nuclear magnetic resonance (NMR). Hydrogen-bonded dimers were analyzed using DFT-D. Powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC), solubility, and slurry tests were conducted using methanol, acetone, and water. Kinetic profiles were modeled with the Kolmogorov–Johnson–Mehl–Avrami (KJMA) equation. Results: Polymorph A was thermodynamically stable across all analyses. Both amorphous TPZ and Polymorph B converted to A in a solvent-dependent manner. Methanol induced direct A formation, while acetone showed a B → A transition. Crystallization was guided by solution conformers and hydrogen bonding. Conclusions: TPZ polymorph selection is governed by solution-phase conformational preferences, tautomerism, and solvent-mediated hydrogen bonding. DFT-D and NMR analyses showed that protic solvents favor the direct crystallization of stable Polymorph A, while aprotic solvents promote the transient formation of metastable Polymorph B. Elevated temperatures and humidity accelerate polymorphic transitions. This crystal structure prediction (CSP)-independent strategy offers a practical framework for rational polymorph control and the mitigation of disappearing polymorph risks in tautomeric drugs. Full article

We present a formal framework for modeling neural network dynamics using Category Theory, specifically through Markov categories. In this setting, neural states are represented as objects and state transitions as Markov kernels, i.e., morphisms in the category. This categorical perspective offers an algebraic alternative to traditional approaches based on stochastic differential equations, enabling a rigorous and structured approach to studying neural dynamics as a stochastic process with topological insights. By abstracting neural states as submeasurable spaces and transitions as kernels, our framework bridges biological complexity with formal mathematical structure, providing a foundation for analyzing emergent behavior. As part of this approach, we incorporate concepts from Interacting Particle Systems and employ mean-field approximations to construct Markov kernels, which are then used to simulate neural dynamics via the Ising model. Our simulations reveal a shift from unimodal to multimodal transition distributions near critical temperatures, reinforcing the connection between emergent behavior and abrupt changes in system dynamics. Full article

Measuring the small tree trunk variations during the day–night cycle, seasonal cycles, as well as those caused by the plant’s growth and health regime is a very important action in horticulture or forestry because by analyzing the collected data, assessments can be made on the health of the trees, but also on the climatic conditions and changes in a certain region. This can be performed with devices called dendrometers. This paper presents a new type of approach to these measurement types in which the trunk volume changes are highly sensitively converted into the axial stress on sensitive elements made of magnetic materials in wire form in which the giant stress impedance effect occurs. Finally, by electronic processing of the signals provided by the sensitive elements, digital words with a decimal value proportional to the diameter variations are obtained. This paper presents the operating principle, the constructive details and the experimental results obtained by testing the device in the laboratory and in-field. The proposed dendrometer, compared to those available commercially, has the advantage of good resolution and sensitivity, good immunity to temperature variations, the possibility of transmitting the result remotely, robustness and low price. Some metrological parameters obtained from the experimental testing are the following: resolution 1.6 µm, linearity 1.4%, measurement range 0 to 5 mm, temperature coefficient 0.012%/°C. Full article

The construction sector presently consumes about 40% of global energy and generates 36% of CO₂ emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding and the insulated structure, address that challenge. First, the paper categorises VFs by structural configuration, ventilation strategy and functional control into four principal families: double-skin, rainscreen, hybrid/adaptive and active–passive systems, with further extensions such as BIPV, PCM and green-wall integrations that couple energy generation or storage with envelope performance. Heat-transfer analysis shows that the cavity interrupts conductive paths, promotes buoyancy- or wind-driven convection, and curtails radiative exchange. Key design parameters, including cavity depth, vent-area ratio, airflow velocity and surface emissivity, govern this balance, while hybrid ventilation offers the most excellent peak-load mitigation with modest energy input. A synthesis of simulation and field studies indicates that properly detailed VFs reduce envelope cooling loads by 20–55% across diverse climates and cut winter heating demand by 10–20% when vents are seasonally managed or coupled with heat-recovery devices. These thermal benefits translate into steadier interior surface temperatures, lower radiant asymmetry and fewer drafts, thereby expanding the hours occupants remain within comfort bands without mechanical conditioning. Climate-responsive guidance emerges in tropical and arid regions, favouring highly ventilated, low-absorptance cladding; temperate and continental zones gain from adaptive vents, movable insulation or PCM layers; multi-skin adaptive facades promise balanced year-round savings by re-configuring in real time. Overall, the review demonstrates that VFs constitute a versatile, passive-plus platform for low-carbon buildings, simultaneously enhancing energy efficiency, durability and indoor comfort. Future advances in smart controls, bio-based materials and integrated energy-recovery systems are poised to unlock further performance gains and accelerate the sector’s transition to net-zero. Emerging multifunctional materials such as phase-change composites, nanostructured coatings, and perovskite-integrated systems also show promise in enhancing facade adaptability and energy responsiveness. Full article