Search Results (210)

This study presents the first application of an automatic ultrasonic mapping system for the assessment of natural consolidants applied to replicas of painted wall surfaces. In Cultural Heritage conservation, evaluating consolidation efficiency remains a critical issue, particularly for substrates characterized by high porosity, heterogeneity, and mechanical fragility. Ultrasonic testing offers a fully non-contact diagnostic approach capable of detecting variations in cohesion, stiffness, and internal discontinuities, thus overcoming the limitations of semi-invasive mechanical procedures. Three polysaccharide-based consolidants—Arabic gum, Funori, and Opuntia ficus-indica mucilage—were applied to wall-painting replicas prepared according to historically documented techniques. Their performance was investigated through a comparative methodology combining a peeling test with non-contact air-coupled ultrasonic probes. Results indicate that Opuntia mucilage, although still at an experimental stage, provides significant improvements in cohesion, confirming its potential as a sustainable and substrate-compatible alternative to conventional consolidants. By demonstrating the complementary nature of ultrasonic mapping and peeling tests, this work contributes to the development of reproducible, non-invasive diagnostic strategies for evaluating consolidation treatments, particularly on fragile surfaces where conventional mechanical testing is unsuitable. Full article

The color design of architectural interior display spaces directly affects the effectiveness of cultural information communication and the visual cognitive experience of viewers. However, there is currently a lack of combined subjective and objective evaluation regarding how to scientifically translate and apply traditional color systems in modern contexts. This study takes the virtual display space of traditional Chinese floral arrangements as a case, aiming to construct an evaluation framework integrating the Semantic Differential Method and eye-tracking technology, to empirically examine how color schemes based on the translation of traditional aesthetics affect the subjective perception and objective visual attention behavior of modern viewers. Firstly, colors were extracted and translated from Song Dynasty paintings and literature, constructing five sets of culturally representative color combination samples, which were then applied to standardized virtual exhibition booths. Eye tracking data of 49 participants during free viewing were recorded via an eye-tracker, and their subjective ratings on four dimensions—cultural color atmosphere perception, color matching comfort level, artwork form clarity, and explanatory text clarity—were collected. Data analysis comprehensively employed linear mixed models, non-parametric tests, and Spearman’s rank correlation analysis. The results show that, regarding subjective perception, different color schemes exhibited significant differences in traditional feel, comfort, and text clarity, with Sample 4 and Sample 5 performing better on multiple indicators; a moderate-strength, significant positive correlation was found between traditional cultural atmosphere perception and color matching comfort. Regarding objective eye-tracking behavior, color significantly influenced the overall visual engagement duration and the processing depth of the text area. Among them, the color scheme of Sample 5 better promoted sustained reading of auxiliary textual information, while the total fixation duration obtained for Sample 4 was significantly shorter than that of other schemes. No direct correlation was found between subjective ratings and spontaneous eye-tracking behavior under the experimental conditions of this study; the depth of processing textual information was a key factor driving overall visual engagement. The research provides empirical evidence and design insights for the scientific application of color in spaces such as cultural heritage displays to optimize visual experience. Full article

This article provides a comprehensive review of the literature on the use of graphene-based nanomaterials (graphene oxide, reduced graphene oxide, and graphene nanoplatelets) and nanosilica (SiO₂) in architectural paint and coatings. The aim was to quantitatively assess their effect on dirt pickup resistance, hydrophobicity, and mechanical properties. In a systematic search across ScienceDirect, Scopus, and Web of Science (2010–2025), 20 studies that met the set inclusion criteria were identified. We extracted and generalized data with random-effects models (REML) based on standardized mean differences, conducting subgroup and meta-regression analyses to assess filler type, loading, and binder system impact. The results reveal that graphene-based fillers and SiO₂ improve coating performance at the same time, and hybrid graphene-SiO₂ systems may provide a synergistic improvement depending on the binder matrix. Our results present the first quantitative evidence of graphene-SiO₂ interaction in the coating formulations, identify remaining research gaps, and indicate methods for designing next-generation facade paints with better dirt repellence, durability, and sustainability. Full article

The escalating global heatwave crisis demands urgent advancements in high-efficiency, energy-saving cooling technologies. Radiative cooling (RC) paints, capable of passively dissipating heat through the atmospheric transparent window (ATW, 8–13 μm) without external energy input, have emerged as a groundbreaking solution for sustainable thermal management. This perspective advocates for a paradigm shift in the field from solely focusing on optical performance optimization to comprehensive system design that simultaneously achieves high cooling power, industrial-scale manufacturability, long-term environmental durability, and customizable aesthetics. We systematically analyzed the fundamental design principles of RC paints, reviewed the construction strategy of the state-of-the-art RC paints, advanced multi-band spectral engineering, synergistic integration with complementary cooling technologies, and robust structural configurations for large-scale deployment. Addressing critical challenges for commercialization, we also proposed targeted solutions, including enhanced application-specific durability, cost-effective production scaling, and multifunctional system integration. This work provides a strategic roadmap to accelerate the transition of RC paints from laboratory prototypes to ubiquitous real-world applications, ultimately contributing to a sustainable future with improved thermal comfort. Full article

The recycling and reuse of wood have gained importance as strategies for reducing construction waste, lowering costs, and promoting circular practices in the built environment. This study evaluates the performance of recycled wood particle/epoxy composites (WPECs) for façade applications by prototyping panels produced from granulated degraded wood bonded with epoxy resin and coated with intumescent fire-retardant paint. The panels were design to meet standards for ventilated façade applications in accordance with EN 310-93 and ASTM D1037-06a and relevant building codes for facade cladding. Three replicates of each panel type were tested under controlled laboratory conditions to assess water absorption, equilibrium moisture content, capillarity, fire resistance, and mechanical performance. Moisture measurements were performed at immersion and drying intervals of 12, 24, 36, 72, and 120 h for four WPEC types manufactured with pine, beech, oak, and olive fibers. Statistical evaluation using SPSS (one-way and two-way ANOVA) confirmed significant species effects across most parameters. Results indicated that olive and oak WPECs provided the highest dimensional stability under moisture exposure, with olive additionally demonstrating superior compressive strength (35.45 MPa) and hardness (˂10,000 N). Pine and beech WPECs exhibited intermediate bending strength (≈10 MPa) and elasticity, while oak contributed stable swelling values despite lower strength. Fire resistance tests suggested relative improvements, although further standardized evaluation is needed. Collectively, olive and oak WPECs emerged as the most promising façade materials, combining durability, mechanical strength, and sustainability. Full article

The environmental sustainability of cleaning materials used in heritage conservation remains poorly quantified despite growing attention to the replacement of hazardous petroleum-based solvents with bio-based alternatives. This study applies a comprehensive Life Cycle Assessment (LCIA) to compare conventional solvents with innovative bio-based formulations, including Fatty Acid Methyl Esters (FAMEs), Deep Eutectic Solvents (DES), and aqueous or organogel systems used for cleaning painted surfaces. Following ISO 14040/14044 standards and using the Ecoinvent v3.8 database with the EF 3.1 impact method, three functional units were adopted to reflect material and system-level scales. Results demonstrate that water-rich systems, such as agar gels and emulsified organogels, yield significantly lower climate and toxicity impacts (up to 85–90% reduction) compared with petroleum-based benchmarks, while FAME and DES exhibit outcomes highly dependent on allocation rules and baseline datasets. When including application materials, cotton wipes dominate total environmental burdens, emphasizing that system design outweighs solvent substitution in improving sustainability. The study provides reproducible data and methodological insights for integrating LCIA into conservation decision-making, contributing to the transition toward evidence-based and environmentally responsible heritage practices. Full article

Rapid urban growth in South Indian coastal cities such as Chennai has intensified the Urban Heat Island (UHI) effect, with paved parking lots, walkways, and open spaces acting as major heat reservoirs. This study specifically compares conventional construction materials with natural and low-thermal-inertia alternatives to evaluate their relative ability to mitigate Surface Urban Heat Island (SUHI) effects. Unlike previous studies that examine isolated materials or single seasons, this pilot provides a unified, multi-season comparison of nine urban surfaces, offering new evidence on their comparative cooling performance. To assess practical mitigation strategies, a field pilot was conducted using nine surface types commonly employed in the region—concrete, interlocking tiles, parking tiles, white cooling tiles, white-painted concrete, natural grass, synthetic turf, barren soil, and a novel 10% coconut-shell biochar concrete. The rationale of this comparison is to evaluate how conventional, reflective, vegetated, and low-thermal-inertia surfaces differ in their capacity to reduce surface heating, thereby identifying practical, material-based strategies for SUHI mitigation in tropical cities. Surface temperatures were measured at four times of day (pre-dawn, noon, sunset, night) across three months (winter, transition, summer). Results revealed sharp noon-time contrasts: synthetic turf and barren soil peaked above 45–70 °C in summer, while reflective coatings and natural grass remained 25–35 °C cooler. High thermal-mass materials such as concrete and interlocked tiles retained heat into the evening, whereas grass and reflective tiles cooled rapidly, lowering late-day and nocturnal heat loads. Biochar concrete performed thermally similarly to conventional concrete but offered co-benefits of ~10% cement reduction, carbon sequestration, and sustainable reuse of locally abundant coconut shell waste. Full article

The focus of this paper is on the large-format wooden panel painting Maundy Thursday Altarpiece from Southern Germany. Its wooden support and paint layer were severely damaged due to high climatic fluctuations, above all dryness. The aim of the research project was to develop a low-risk, conservatively acceptable procedure for controlled in situ humidification. In an interdisciplinary approach, a practical monitoring concept on-site was linked to art technology analyses, surface monitoring, hygrothermal simulations, and climate chamber tests. Based on the results, an individual climate corridor for controlled humidification of the case study was developed with the help of an enclosure and implemented in two gradual moistening phases. The combination of conservative support, measurement technology, and digital assessment allowed a controlled approach to a conservation optimum without other active interventions in the original material. The results highlight the need for object-specific strategies and humidity corridors at the interface between conservation, climate adaptation, and sustainability. A deviation from museum standard recommendations (depending on the guidelines 40–60% rH) shows the special challenges of monument preservation. Full article

Alumina nanoparticles have broad applications in catalysis, electronics, and the construction sector, and are widely incorporated as additives in coating formulations to enhance mechanical durability and functional performance. This work focuses on the green synthesis of aluminum oxide (Al₂O₃) nanoparticles using lemongrass (Cymbopogon citratus) extract. Aluminum nitrate [Al(NO₃)₃] and aluminum chloride (AlCl₃) were used with extract. The reaction was carried out at 70 °C for 1 h at 250 rpm and then thermal treatments at 700 °C and 900 °C were applied. The results showed that nanoparticles synthesized from the AlCl₃ and calcined at 700 °C exhibited a smaller particle size (36 ± 14 nm) as compared with those synthesized from the [Al(NO₃)₃] and calcined at 700 °C (49 ± 25 nm). Despite both precursors yielding nanoparticles, the peaks related to the γ-Al₂O₃ crystal phase were observed in the AlCl₃ at 700 °C calcination. Conversely, the nanoparticles synthesized from the [Al(NO₃)₃] required a high temperature treatment at 900 °C to display this stable crystal phase. This study reports an easy and cost-effective green chemistry route to obtain γ-Al₂O₃ nanoparticles, highlighting the importance of the selection of precursors as a critical step to achieve a sustainable and low-energy process, suggesting the potential applications in paints with multifunctional properties. Full article

The search for sustainable alternatives to synthetic composites has become increasingly relevant in aerospace engineering education and student rocketry. Fiberglass is widely used for rocket fuselages due to its favorable balance of performance and cost, but it is energy-intensive, non-biodegradable, and environmentally burdensome. This study provides the first demonstration of natural fiber composites applied to student rocket fuselages, evaluating bamboo and jute as sustainable alternatives to fiberglass. Fiberglass, bamboo, and jute laminates were fabricated following the procedures of the RocketWolf team at CEFET/RJ. The fuselages were characterized by parachute ejection tests, surface roughness analysis, and flight simulations using OpenRocket software. Additional data such as laminate mass, wall thickness, fiber–resin ratio, and cost analysis were incorporated to provide a comprehensive assessment. Results revealed contrasting behaviors: untreated bamboo composites showed poor resin impregnation, brittle behavior, and lack of structural stability, confirming their unsuitability without chemical treatment. Jute composites, in contrast, achieved adequate impregnation, cylindrical geometry, and superior surface roughness (Ra = 37 µm) compared to fiberglass with paint (62 µm) or envelopes (52 µm). Both fiberglass and jute fuselages successfully passed parachute ejection tests, while simulations indicated apogees close to 1 km, fulfilling competition requirements. The jute fuselage also presented slightly improved stability margins. Economically, jute was ~492% cheaper than fiberglass in fiber-only comparison but absorbed more resin; nevertheless, real purchase prices favored jute. These findings confirm that jute composites are a technically feasible, cost-effective, and sustainable substitute for fiberglass in student rocket fuselages. Beyond technical validation, this work demonstrates the educational and environmental benefits of integrating natural fibers into academic rocketry, bridging sustainability, performance, and innovation. Full article

The imperative for sustainable water management strategies is driven by challenges, such as limited water availability, economic development, population growth, and escalating environmental concerns. A viable strategy involves water collection and reuse. This study assessed the quality of wastewater produced by paint manufacturing companies, which is characterised by high chemical oxygen demand and turbidity, as well as the presence of organic materials, suspended particles, and heavy metals. Such wastewater requires treatment prior to environmental discharge. After analysing the current methods of wastewater treatment in the paint industry, this study seeks to establish a conceptual framework for developing a methodology for the collection of wastewater from rinsing machines and containers within the paint manufacturing sector while identifying optimal practices in raw wastewater management. It examines various strategies for minimising the waste generated in the paint manufacturing industry, drawing upon the waste management practices of a specific plant. Utilising data from 190 samples, the quality of the generated wastewater was estimated using probabilistic methods, including the Monte Carlo simulations, distribution fitting, and Student’s t-test. Based on the results, a wastewater management strategy was formulated for the company. By implementing water treatment and recycling systems, paint manufacturers can reduce their reliance on freshwater resources, lower the costs associated with wastewater disposal, and mitigate their environmental impact. Effective management in this domain can significantly enhance the treatment of industrial wastewater and facilitate the development of strategies for the reuse of rinse wastewater, thereby supporting the principles of a circular economy. Full article

In recent years, the automotive industry has experienced increasing demand for advanced paint protection solutions aimed at improving vehicle durability, preserving aesthetic appeal, and promoting environmental sustainability. This paper critically examines the main categories of paint protection coatings on wax, ceramic, graphene, and hybrid formulations by focusing on their chemical composition, application methods, protective performance, and limitations. Wax coatings remain widely adopted due to their affordability and ease of use, though they offer limited longevity. Ceramic coatings, in contrast, provide superior hardness, hydrophobicity, and resistance to scratches, corrosion, and ultraviolet (UV) degradation, albeit with higher costs and complex application procedures. Emerging graphene-based coatings demonstrate exceptional hydrophobicity, thermal stability, and durability, positioning them as potential next-generation solutions, though their environmental and economic feasibility remains under exploration. Hybrid and self-healing coatings further highlight the trend toward multifunctional, intelligent protection systems. This work also emphasizes the critical role of surface preparation in determining coating performance. Future research directions are outlined, including the development of biodegradable, zero-VOC, and intelligent self-aligning coatings, which could significantly advance sustainable automotive surface protection. Overall, this work provides a comprehensive synthesis of current technologies and identifies pathways for innovation in automotive paint protection materials. Full article

This paper presents an overview of a research line developed at the Istituto Centrale per il Restauro within the CHANGES (Cultural Heritage Active Innovation for Next-Gen Sustainable Society) project, funded under the Italian National Recovery and Resilience Plan. The research was developed in different phases: a first one dedicated to the study of the deep background and the state of the art in the ICR background: history, methodologies and research in the field; a second phase was dedicated to the selection of a specific urban art mural, as a key study with conservation problems connected to some of the principal preservation treatments related to the outdoor context; the mural was also identified as a beloved icon in the public space with a profound socio-cultural meaning for the community. Nido di Vespe, created in 2014 by the artist Lucamaleonte is part of a broader artistic project called M.U.Ro-Museum of Urban Art of Rome, an open-air public art museum located in the Quadraro district in Rome, designed by the artist Diavù. A third phase focused on the research in ICR laboratories, specifically addressing: cleaning, reintegration, and protection strategies adapted to dynamic outdoor environments. A multi-step cleaning system based on polyvinyl alcohol-borax semi-interpenetrated hydrogels loaded with nanostructured fluids was developed to selectively remove spray-paint vandalism while preserving the chemically similar original pictorial layers. The reintegration phase investigated acrylic and urea-aldehyde resins as binders to produce compatible, reversible, and UV-traceable retouching and infilling materials. For surface protection, multilayer coating systems incorporating nanoparticles with antimicrobial, photocatalytic, and UV-stabilizing properties were formulated to enhance durability and chromatic stability. Laboratory tests on mock-ups simulating typical street and urban art materials and morphologies showed satisfactory results, while diagnostic investigations on Nido di Vespe provided the reference data to calibrate the experiments with real mural conditions. Cleaning tests demonstrated promising removal efficiency, influenced by the chemical composition, thickness of the overpainted layers, and surface roughness. The reintegration system met the expected performance requirements, as the tested binders provided good results and allowed the development of compatible, reversible, and distinguishable solutions. Protective coatings showed good results in terms of chromatic stability and surface integrity; however, the long-term behavior of both reintegration, cleaning, and protection systems requires further evaluation. The results achieved so far support the development of sustainable and flexible conservation strategies for the conservation of contemporary street and urban murals and will guide the future application of the selected materials and methodologies in pilot conservation interventions on the mural chosen as a meaningful case study within the broader research. Full article

The use of preservatives such as diuron and isoproturon in the paint industry is essential to protect products against microbial attack. However, these compounds are subject to strict regulation due to the harmful effects they have on the environment and human health. Therefore, analytical strategies to control the production process at paint plants are fundamental to ensure suitable products. In the present work, a low-cost portable square-wave voltammetry device with commercial screen-printed electrodes was proposed to control the starting products and to determine isoproturon and diuron levels in manufactured paint products. Under the optimized conditions (electrolyte HClO₄ 0.18 M, nickel oxide-doped carbon electrodes, E_SW = 0.02 V, E_step = 0.0015 V, and ƒ = 15 Hz), the results indicated satisfactory analytical performance, with detection limits of 3.5 and 3.0 mg L⁻¹ for isoproturon and diuron, respectively, and precision lower than 7.5% for both biocides. The analytical strategy employed to achieve satisfactory selectivity involved taking advantage of the specific interaction of cysteine with 1,2-benzisothiazol-3(2H)-one (BIT) as a potential interferent in some commercial products and the use of matrix match calibration. A recovery study provided values in the range of 92–104% for accuracy validation. A sample pretreatment step was needed due to the paint composition, and a miniaturized method was proposed here. The novelty of this method lies in the use of a portable voltammetry device in real-world industrial applications to control the paint production process using a cost-effective, time-saving, sustainable, and green protocol. The HEXAGON tool is used for assessing greenness and sustainability. The choice of reagents like HClO₄ and the minimization of waste from the small volumes used align with the principles of using safer solvents, a key concern in green and sustainable chemistry. Full article

CIE recommendations for architectural exterior illumination provide general guidelines for highlighting building forms, with emphasis on edges, curvature, and spatial layering. However, they do not explicitly address luminance contrast disposition—specifically, whether elements further from the viewer should appear brighter or if those closer should be more intensely lit. Inspiration for addressing this problem can be drawn from the principles of Renaissance and Baroque paintings, where techniques of working with light evolved from dramatic contrasts to more rational and balanced approaches, offering valuable models for contemporary illumination design. This study compares the principles of painting from that period with eye-tracking and survey-based methods to investigate whether the arrangement of luminance contrasts of illuminated building facades significantly influences viewers’ visual attention, aesthetic judgment, and perception of depth. The verification was conducted in two stages using three lighting variants of a selected architectural object. These variants differed in the luminance contrast distribution between surfaces closer to and farther from the observer, while maintaining a constant average luminance level across the entire façade of 10 cd/m². The first stage analysed visual reactions of 116 (out of 178) participants to luminance changes across the multi-segmented façade, presented in a darkened room on a luminance-calibrated display. The second stage involved a survey in which 358 participants were asked about their lighting preferences. Participants—including both design professionals and laypeople—exhibited consistent perceptions regarding how different lighting configurations affected their impression of the building. The results revealed that luminance disposition significantly influenced the perceived volume of the structure, particularly the sense of depth. Eye-tracking data also indicated a strong positive correlation between subjective aesthetic assessments and patterns of visual attention. Full article