Search Results (72)

End-of-life thermoset composite coatings removed from fuel storage infrastructure represent a difficult waste stream because they combine a cross-linked polymer matrix, glass fibre reinforcement, functional layers and possible contamination from long-term contact with petroleum products. This study presents a preliminary assessment of an epoxy-glass laminate removed from the internal surface of a large vertical diesel fuel storage tank. The work combined a simplified numerical analysis of the technical role of the coating with thermogravimetric analysis and microscopic examination of solid residues after thermal conversion. The numerical results confirmed that the coating had a real reinforcing function, reducing the maximum equivalent stress in the corroded steel shell from 228.80 MPa to 191.85 MPa. TG/DTG analysis showed that the main mass loss of the laminate occurred below 500–600 °C, while the residual mass depended strongly on the process atmosphere. The highest residue was obtained after pyrolysis (28.75%), followed by CO₂-assisted conversion (26.17%) and combustion (20.87%). Microscopic observations showed that pyrolysis favoured morphological preservation of the fibrous/mineral fraction, but the glass fibres remained partly associated with carbonised epoxy resin and graphite-containing particles. Combustion removed the organic fraction more completely, but the remaining fibres showed signs of degradation. The results indicate that pyrolysis should be treated as a promising preliminary pretreatment route when morphological preservation of the fibrous/mineral fraction is prioritised, although the retained mechanical performance and phase composition of the fibres were not assessed. The study should be regarded as a thermogravimetric and microscopic screening of a real post-service epoxy-glass coating, supporting preliminary selection of end-of-life management pathways rather than a complete recycling or environmental assessment. By linking the thermal behaviour of a real post-service composite coating with feasible end-of-life pathways, the study contributes to sustainable waste management by supporting more informed decisions on material preservation, energy recovery, industrial co-processing and avoidance of landfilling for difficult thermoset composite wastes. Full article

This paper presents research on reinforced concrete beams strengthened with non-pretensioned and pretensioned near-surface-mounted (NSM) carbon fibre-reinforced polymer (CFRP) strips under self-weight and external preloading. The first part of this paper briefly describes and discusses the results of experimental tests performed on six beams with different reinforcing steel ratios, preloading levels, and strengthening-system configurations. Next, three-dimensional (3D) numerical models of the tested specimens were developed. The models consider the nonlinear behavior of concrete (both in tension and compression), steel bars, and the interface between concrete and CFRP laminates. For these models, the material parameters were established based on experiments and recommendations from the literature. Furthermore, a sensitivity analysis was conducted with respect to the material parameters of the model that were not directly obtained from experimental measurements. The analyses validated the applicability of the numerical model in predicting the flexural behavior of reinforced concrete (RC) members strengthened with near-surface-mounted (NSM) CFRP materials over the full loading range. Furthermore, the developed models were employed to assess the effectiveness of active strengthening relative to passive strengthening methods (i.e., without pretensioning of the laminate). A comparison study of actively and passively strengthened elements indicates that prestressing does not affect the ultimate limit state but enhances serviceability limit states. The presented computational model, together with the adopted computational strategy, demonstrates its effectiveness for analyzing realistic scenarios involving RC beams that are damaged and subjected to loading during the strengthening process. Full article

Metal packaging materials remain fundamental across food, beverage, pharmaceutical, cosmetic, and technical sectors owing to their combination of mechanical robustness, total light and gas barrier performance, thermal resistance, and established recyclability. Aluminum alloys, tinplate, tin-free steel (TFS/ECCS), stainless steels, metal–matrix composites (MMCs), and metal–polymer or metal–paper laminates define distinct metal-based packaging architectures whose metallurgical and interfacial design governs forming behaviour, corrosion and migration pathways, coating integrity, and mechanical reliability. In this review, these architectures are examined from a materials- and systems-oriented perspective, linking composition, microstructure, processing routes, and surface engineering to functional performance across rigid, semi-rigid, and flexible formats. The analysis also considers the ongoing transition from bisphenol A (BPA)-based epoxy linings to BPA-free and hybrid coating chemistries, the use of nano-structured metallic and metal-oxide surfaces, and the role of composite laminates in which thin metallic foils are combined with polymeric or paper-based structural layers. These material and architectural aspects are discussed together with safety, regulatory, and circularity considerations that increasingly influence the design and selection of metal-based packaging. Ion migration, coating degradation, and corrosion under realistic storage environments are considered in relation to EU, FDA, ISO, and sector-specific requirements, while attention is also paid to the contrast between well-established closed-loop recycling infrastructures for aluminum and steel and the more complex end-of-life management of coated metals and multilayer laminates. The review provides a unified framework connecting materials selection, metallurgical design, processing, performance, regulatory compliance, and sustainability in metal-based packaging systems. Applications spanning consumer goods, pharmaceuticals, cosmetics, and advanced electronics are integrated to support an overall understanding of how metallic and hybrid metal-based architectures underpin functional reliability and life-cycle sustainability. Full article

This study investigates the dynamic behavior and structural optimization of hydraulic water well drilling rig masts through a comparative finite element analysis (FEA) of metallic and composite configurations. The reference model, manufactured from structural steel (S355J2/E315), was compared with two optimized lightweight alternatives made of carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer (GFRP) laminates. Simulations were performed in MSC Visual Nastran using identical geometric and loading conditions, including the critical dynamic event of drill string pull-out. The results demonstrate that substituting steel with composite materials significantly decreases the overall mass by up to 55%, while increasing the first natural frequency by 20–25% and reducing dynamic stress amplification by approximately 15–20%. Furthermore, the maximum tip displacement of the mast was reduced by 35–45% for the composite variants, indicating improved stiffness and vibration damping capability. These findings confirm that polymer composite structures offer superior dynamic performance, lower inertial loads, and enhanced operational safety, providing a viable route for next-generation lightweight drilling rig designs integrating advanced macromolecular materials. Full article

Industrial conveyor systems commonly use steel flight bars, which can account for nearly 50% of the total system mass and significantly affect energy consumption. This study investigates epoxy matrix composites reinforced with glass, carbon, and Kevlar fibers as lightweight alternatives to steel flight bars. A multiscale analytical approach combining micromechanics, Classical Laminate Theory (CLT), and ply-level failure criteria is applied to evaluate the structural response under an industrial bending moment of 342.02 N·m. Tensile tests on vacuum-infused woven glass/epoxy laminates are used to validate micromechanical assumptions and calibrate elastic properties. Ply-wise analysis shows that carbon/epoxy laminates exhibit the lowest longitudinal stresses (≈43 MPa), followed by Kevlar/epoxy (≈53 MPa) and glass/epoxy (≈95 MPa), all well below their respective strength limits. Replacing steel flight bars (4.64 t) with composite alternatives reduces the moving mass to 0.68–0.82 t, corresponding to an 82–85% reduction. This mass reduction significantly lowers the required mechanical power, resulting in an estimated annual energy saving of R$ 8812.80 under continuous operation. Overall, the results demonstrate that polymer-matrix composite flight bars are structurally safe and energetically advantageous, with carbon/epoxy providing the highest mechanical efficiency. Full article

Externally bonded carbon-fiber-reinforced polymer (CFRP) can increase the flexural capacity of steel beams, but the benefit is often limited by the performance of the adhesive interface. This study develops and validates a three-dimensional finite-element model (FEM) with an explicit cohesive-zone representation of the adhesive layer. It reproduced benchmark four-point bending tests in terms of peak load, corresponding mid-span deflection, and the transition from end/intermediate debonding to laminate rupture. A one-factor-at-a-time parametric analysis is carried out to examine the influence of (i) member geometry (beam depth; flange and web thickness), (ii) CFRP configuration (bonded length; laminate thickness), and (iii) bond quality (cohesive normal strength). Within the ranges studied, cohesive strength and bonded length are the primary variables controlling both capacity and failure mode: strengths below about 25 MPa and short plates lead to debonding-governed response. Increasing strength to around 27 MPa and bonded length to 650–700 mm delays debonding, promotes CFRP rupture, and produces the largest incremental gains in peak load, while further increases in length give smaller additional gains. Increasing laminate thickness and steel depth or flange/web thickness always raises peak load, but under baseline bond conditions failure remains debonding and the added material is only partially mobilized. When cohesive strength is increased above the threshold, additional CFRP thickness becomes more effective. A linear regression model is fitted to the FEM dataset to express peak load as a function of bonded length, cohesive strength, laminate thickness, and steel dimensions, and is complemented by a failure-mode map and a cost–capacity chart based on material quantities. Together, these results provide quantitative trends and simple relations that can support preliminary design of CFRP-strengthened steel beams for similar configurations. Full article

This study quantifies how pressurized water immersion alters the reciprocating sliding behavior of glass and Kevlar woven fabric-reinforced polymer hybrid composite laminates. Specimens were immersed in deionized water at 10 bar and 25 °C for 0, 7, 14, and 21 days, then tested against a 6 mm 100Cr6 steel ball at 20 N under four regimes that combine 1 or 2 Hz with 10 m or 20 m total sliding. Water uptake rose from 0 to 8.54% by day 21 and followed a short-time Fickian square root of time trend, indicating diffusion-controlled sorption. The coefficient of friction exhibited a robust nonmonotonic response with a pronounced minimum at 14 days that was typically 20 to 40% lower than the unaged reference across frequencies and distances, while 7 days produced a partial decrease and 21 days trended upward. Three-dimensional profilometry showed progressive widening and deepening of wear tracks with immersion, for example, at 1 Hz and 10 m width increased from about 1596 to about 2050 to 2101 μm and depth from about 128 to about 184 to 185 μm, with a transient narrowing at 2 Hz after 7 days. Scanning electron microscopy corroborated a transition from mild plowing to matrix plasticization with fiber–matrix debonding and debris compaction. Beyond geometric wear metrics, this study re-processed the existing profilometry and COF records to derive a moisture-dependent mechanistic approach. Moisture uptake up to 8.54% reorganizes the third body at the interface so that friction drops markedly at 14 days (typically 20–40% below the unaged state), while concurrent matrix plasticization and interface weakening enlarge the wear cross-section extracted from the same 3D maps, decoupling friction from damage width/depth under wet conditioning. Factorial analysis ranked immersion time as the dominant driver of damage for width and depth with frequency as a secondary factor and sliding distance as a minor factor, highlighting immersion-controlled tribological design windows for marine and humid service. Full article

Brushless DC (BLDC) motors are increasingly used in industrial applications due to their high efficiency, reliability, and low weight. However, their performance strongly depends on the electromagnetic properties of stator and rotor core materials. This study evaluates six BLDC motor configurations, employing materials such as M19 electrical steel, 1010 low-carbon steel, magnetic PLA, and ABS, and analyzes their impact using FEMM 4.2 finite element simulations. Key electromagnetic characteristics—including flux linkage, Back-EMF, torque, and torque ripple—were compared across configurations. The reference motor with M19 steel stator and 1010 steel rotor achieved ~7 mWb flux linkage, ~39 V pk–pk Back-EMF, and 1.44 Nm torque with ~49% ripple, confirming the suitability of laminated steels for high-power-density designs. Substituting M19 with 1010 steel in the stator reduced torque by less than 10%, indicating material interchangeability with minimal performance loss. By contrast, polymer-based designs exhibited drastic degradation: magnetic PLA yielded only 3.5% of the baseline torque with sixfold ripple increase, while ABS delivered nearly zero torque and >700% ripple. Hybrid configurations improved PLA-based results by 15–20%, though they remained far below ferromagnetic cores. Overall, results demonstrate a nearly linear relationship between material permeability and both flux linkage and Back-EMF, alongside a sharp rise in torque ripple at low permeability. The findings highlight the advantages of ferromagnetic and laminated steel cores for efficiency and stability, while polymer and hybrid cores are limited to lightweight demonstrator applications. Full article

Polymeric nanocomposites have been extensively investigated due to their potential for enhancing the mechanical and tribological properties of polymer composites. In this study, the mechanical performance of carbon fiber-reinforced epoxy composites modified with nano-sized ferrochrome slag particles, an industrial by-product from stainless steel manufacturing, was evaluated. Composite laminates were fabricated using a vacuum-assisted hand lay-up process, with consistent carbon fiber reinforcement and uniformly dispersed nanofillers in the epoxy matrix. Mechanical properties such as tensile, flexural, impact, and Shore D hardness were evaluated as per ASTM and ISO standards. At 2 wt.% nanofiller loading, enhanced tensile strength and hardness by 33.02% and 8.92%, respectively, were achieved, while flexural strength and impact strength increased by 3.70% and 3.62% at 1 wt.% compared to the neat composite. Higher filler contents (>3 wt.%) resulted in reduced performance due to particle agglomeration and microstructural inhomogeneity. A scanning electron microscope was used to determine the uniform dispersion and agglomeration of nanofillers. The results demonstrated the potential of ferrochrome slag as a sustainable and cost-effective nanofiller for advanced composite applications. Full article

To replicate delaminations at the coupon and substructural scales, simulated defects are often introduced into test specimens; therefore, understanding their behaviour within the laminate is essential. Full-field imaging is employed to investigate the effects of artificial defects in Carbon Fibre-Reinforced Polymer (CFRP) composites. Centre Crack Ply (CCP) specimens are used to evaluate the Mode II fracture toughness of laminated composites from a simple tensile test. Two batches of specimens are manufactured using IM7/8552. Artificial defects are introduced using a steel film insert of 5 µm thickness. For the first type of samples, the inserts were coated with Frekote release agent, while for the second type, the steel inserts were incorporated into the laminate without coating. Additionally, a third batch of specimens with a [0₄, 90]s layup is manufactured. Thermoelastic Stress Analysis (TSA) and Digital Image Correlation (DIC) are employed to obtain full-field temperature and displacement data from the tested samples. The inclusion of 90-degree plies enhances thermal contrast exploiting, their anisotropic mechanical and thermal properties. First, the specimens are tested under monotonic loading to failure, with DIC used to capture strain distributions at damage initiation and failure. In addition, acoustic emission is employed to evaluate damage initiation. Load drops provide an indirect evaluation of fracture toughness. Results show that full-field imaging is capable of establishing how the release agent and the layup configuration influence damage initiation and propagation. The non-adiabatic thermoelastic response is shown to be effective in observing subsurface damage. Finally, a novel approach to evaluate fracture toughness from the temperature increase at the failure event is proposed. Full article

Drilling-induced damage in fiber-reinforced polymer composite materials was measured excavating four laminates, basalt (B₁₄), glass (G₁₄) and their two sandwich type hybrids (B₄G₆B₄, G₄B₆G₄), with 6 mm twist drills at 1520 revolutions per minute and 0.10 mm rev⁻¹ under dry running with an uncoated high-speed steel (HSS-R), grind-coated high-speed steel (HSS-G) or physical vapor deposition-coated (high-speed steel coated with Titanium Nitride (TiN) and Titanium Aluminum Nitride (TiAlN)) drill bits. The hybrid sheets were deliberately incorporated to clarify how alternating basalt–glass architectures redistribute interlaminar stresses during drilling, while the hard, low-friction TiN and TiAlN ceramic coatings enhance cutting performance by forming a heat-resistant tribological barrier that lowers tool–workpiece adhesion, reduces interface temperature, and thereby suppresses thrust-induced delamination. Replacement of an uncoated, grind-coated, high-speed-steel drill (HSS-G) with the latter coats lowered the mechanical and thermal loads substantially: mean thrust fell from 79–94 N to 24–30 N, and peak workpiece temperatures from 112 °C to 74 °C. Accordingly, entry/exit oversize fell from 2.5–4.7% to under 0.6% and, from the surface, the SEM image displayed clean fiber severance rather than pull-out and matrix smear. By analysis of variance (ANOVA), 92.7% of the variance of thrust and 86.6% of that of temperature could be accounted for by the drill-bit factor, thus confirming that the coatings overwhelm the laminate structure and hybrid stacking simply redistribute, but cannot overcome, the former influence. Regression models and an artificial neural network optimized via meta-heuristic optimization foretold thrust, temperature and delamination with an R² value of 0.94 or higher, providing an instant-screening device with which to explore industrial application. The work reveals TiAlN- and TiN-coated drills as financially competitive alternatives with which to achieve ±1% dimensional accuracy and minimum subsurface damage during multi-material composite machining. Full article

Carbon fiber-reinforced polymer (CFRP) laminates have been widely coated on aged and damaged structures for recovering or enhancing their structural performance. The health conditions of the coated composite structures have been given high attention, as they are critically important for assessing operational safety and residual service life. However, the current problem is the lack of an efficient, long-term, and stable monitoring technique to characterize the structural behavior of coated composite structures in the whole life cycle. For this reason, bare and packaged fiber Bragg grating (FBG) sensors have been specially developed and designed in sensing networks to monitor the structural performance of CFRP-coated composite beams under different loads. Some optical fibers have also been inserted in the CFRP laminates to configure the smart CFRP component. Detailed data interpretation has been conducted to declare the strengthening process and effect. Finite element simulation and simplified theoretical analysis have been conducted to validate the experimental testing results and the deformation profiles of steel beams before and after the CFRP coating has been carefully checked. Results indicate that the proposed FBG sensors and sensing layout can accurately reflect the structural performance of the composite beam structure, and the CFRP coating can share partial loads, which finally leads to the downward shift in the centroidal axis, with a value of about 10 mm. The externally bonded sensors generally show good stability and high sensitivity to the applied load and temperature-induced inner stress variation. The study provides a straightforward instruction for the establishment of a structural health monitoring system for CFRP-coated composite structures in the whole life cycle. Full article

Cross-laminated timber (CLT) is a high-performance engineered timber that is very widely adopted. In several conditions, such as strength improvement at vulnerable connection points, local stress concentrations, existing structure retrofitting, and others, it is desirable to enhance the mechanical performance of CLT by applying additional reinforcement systems. This paper reports on an experimental campaign aimed at assessing the mechanical behavior of CLT panels reinforced with steel-reinforced polymers (SRPs). Twenty Sardinian Maritime Pine CLT panels, including unreinforced, SRP single- and double-layer reinforced panels, have been subjected to bending tests to determine the bending strength, stiffness, failure mechanism and enhancement of the reinforced panels compared to the unreinforced ones. In addition, an analytical model has been proposed to understand the mechanical behavior of SRP-reinforced CLT panels. The results show that SRP reinforcement significantly increases the strength and stiffness and influences the failure mechanism of CLT panels. The strength improvement induced by the reinforcement, however, is not proportional to its amount, since the increase due to the SRP double layer is only slightly higher than that due to the SRP single layer. The stiffness enhancement is less relevant, as expected. Attention has been paid to the possible shear failures of reinforced panels. Full article

Polyester-glass laminates are widely used to reinforce underground steel fuel tanks due to their excellent corrosion resistance and mechanical performance. However, the management of these composites at the end of their service life poses significant challenges, particularly in terms of material recovery and environmental impact. This study investigates both the structural benefits and recyclability of polyester-glass laminates. Numerical simulations confirmed that reinforcing corroded steel tank shells with a 5 mm GFRP (Glass Fiber Reinforced Polymer) coating reduced the maximum equivalent stress by nearly 50%, significantly improving mechanical integrity. In parallel, thermogravimetric and microscopic analyses were conducted on waste GFRP samples subjected to pyrolysis, gasification, and combustion. Among the methods tested, pyrolysis proved to be the most favorable, allowing substantial organic degradation while preserving the structural integrity of the glass fiber fraction. However, microscopy revealed that the fibers were embedded in a dense char matrix, requiring additional separation processes. Although combustion leaves the fibers physically loose, pyrolysis is favored due to better preservation of fiber mechanical properties. Combustion resulted in loose and morphologically intact fibers but exposed them to high temperatures, which, according to the literature, may reduce their mechanical strength. Gasification showed intermediate performance in terms of energy recovery and fiber preservation. The findings suggest that pyrolysis offers the best trade-off between environmental performance and fiber recovery potential, provided that appropriate post-treatment is applied. This work supports the use of pyrolysis as a technically and environmentally viable strategy for recycling polyester-glass laminates and encourages further development of closed-loop composite waste management. Full article

This study introduces a method for predicting the tensile properties of high-strength steel/carbon fiber-reinforced polymer (CFRP) composite laminates using Metal Volume Fraction (MVF) theory. DP590 and DP980 high-strength steels (thickness ~0.8 mm) were selected as substrates, and composite laminates were fabricated by compression molding with CFRP prepreg. Tensile tests were performed on an MTS universal testing machine, and fracture morphology was analyzed using scanning electron microscopy (SEM). The results demonstrated a typical mixed failure mode: necking and fracture in the metal layer, and neat fiber fracture in the CFRP layer. Comparisons of experimental tensile strength with theoretical predictions revealed that the model based on the metal strength at fracture significantly outperformed the model using tensile strength for predictions, with narrower error ranges. For example, the error for DP590/CFRP laminates ranged from 2.31% to 12.89%, whereas for DP980/CFRP laminates, it was –6.12%. Additionally, the study showed that using metals with higher plasticity in fiber metal laminates could underutilize the metal layer’s potential at peak stress, leading to significant deviations when predictions rely on tensile strength. Therefore, it is recommended to use the metal strength corresponding to peak stress for more accurate MVF-based tensile property predictions. This method provides a robust theoretical foundation for predicting the tensile performance of high-strength steel/CFRP laminates, aiding in optimizing structural designs for automotive and aerospace applications. Future research could explore the effects of different metal and fiber combinations, as well as more complex stacking designs. Full article