Search Results (44)

Per- and polyfluoroalkyl substances (PFAS) have been reported to contaminate soil as a result of improper management of waste, wastewater, landfill leachate, biosolids, and a large and indiscriminate use of aqueous film-forming foams (AFFF), posing potential risks to human health. However, their high chemical and thermal stability pose a great challenge for remediation. As a result, there is an increasing interest in identifying and optimizing very effective and sustainable technologies for PFAS removal. This review summarizes both traditional and innovative remediation strategies and technologies for PFAS-contaminated soils. Unlike existing literature, which primarily focuses on the effectiveness of PFAS remediation, this review critically discusses several techniques (based on PFAS immobilization, mobilization and extraction, and destruction) with a deep focus on their sustainability and scalability. PFAS destruction technologies demonstrate the highest removal efficiencies; however, thermal treatments face sustainability challenges due to high energy demands and potential formation of harmful by-products, while mechanical treatments have rarely been explored at full scale. PFAS immobilization techniques are less costly than destruction methods, but issues related to the regeneration/disposal of spent sorbents should be still addressed and more long-term studies conducted. PFAS mobilization techniques such as soil washing/flushing are hindered by the generation of PFAS-laden wastewater requiring further treatments, while phytoremediation is limited to small- or medium-scale experiments. Finally, bioremediation would be the cheapest and least impactful alternative, though its efficacy remains uncertain and demonstrated under simplified lab-scale conditions. Future research should prioritize pilot- and full-scale studies under realistic conditions, alongside comprehensive assessments of environmental impacts and economic feasibility. Full article

Soil salinization presents a significant challenge, driven by factors such as inadequate drainage, shallow aquifers, and high evaporation rates, threatening global food security. The sunflower emerges as a key cash crop in such areas, providing the opportunity to convert its straw into biochar, which offers additional agronomic and environmental benefits. This study investigates the effectiveness of biochar interlayers in enhancing salt leaching and suppressing upward salt migration through integrated laboratory and field experiments. The effectiveness of varying biochar interlayer application rates was assessed in promoting salt leaching, decreasing soil electrical conductivity (EC), and enhancing crop performance in saline soils through a systematic approach that combines laboratory and field experiments. The biochar treatments included a control (CK) and different applications of 20 (BL20), 40 (BL40), 60 (BL60), and 80 (BL80) tons of biochar per hectare, all applied below a depth of 20 cm, with each treatment replicated three times. The laboratory and field experimental setups maintained consistency in terms of biochar treatments and interlayer placement methodology. During the laboratory column experiments, the soil columns were treated with deionized water, and their leachates were analyzed for EC and major ionic components. The results showed that columns with biochar interlayers exhibited significantly higher efflux rates compared to those of the control and notably accelerated the time required for the effluent EC to decrease to 2 dS m⁻¹. The CK required 43 days for full discharge and 38 days for EC stabilization below 2 dS m⁻¹. In contrast, biochar treatments notably reduced these times, with BL80 achieving discharge in just 7 days and EC stabilization in 10 days. Elution events occurred 20–36 days earlier in the biochar-treated columns, confirming biochar’s effectiveness in enhancing leaching efficiency in saline soils. The field experiment results supported the laboratory findings, indicating that increased biochar application rates significantly reduced soil EC and ion concentrations at depths of 0–20 cm and 20–40 cm, lowering the EC from 7.12 to 2.25 dS m⁻¹ and from 6.30 to 2.41 dS m⁻¹ in their respective layers. The application of biochar interlayers resulted in significant reductions in Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻, SO₄²⁻, and HCO₃⁻ concentrations across both soil layers. In the 0–20 cm layer, Na⁺ decreased from 3.44 to 2.75 mg·g⁻¹, K⁺ from 0.24 to 0.11 mg·g⁻¹, Ca²⁺ from 0.35 to 0.20 mg·g⁻¹, Mg²⁺ from 0.31 to 0.24 mg·g⁻¹, Cl⁻ from 1.22 to 0.88 mg·g⁻¹, SO₄²⁻ from 1.91 to 1.30 mg·g⁻¹ and HCO₃⁻ from 0.39 to 0.18 mg·g⁻¹, respectively. Similarly, in the 20–40 cm layer, Na⁺ declined from 3.62 to 3.05 mg·g⁻¹, K⁺ from 0.28 to 0.12 mg·g⁻¹, Ca²⁺ from 0.39 to 0.26 mg·g⁻¹, Mg²⁺ from 0.36 to 0.27 mg·g⁻¹, Cl⁻ from 1.18 to 0.80 mg·g⁻¹, SO₄²⁻ from 1.95 to 1.33 mg·g⁻¹ and HCO₃⁻ from 0.42 to 0.21 mg·g⁻¹ under increasing biochar rates. Moreover, the use of biochar interlayers significantly improved the physiological traits of sunflowers, including their photosynthesis rates, stomatal conductance, and transpiration efficiency, thereby boosting biomass and achene yield. These results highlight the potential of biochar interlayers as a sustainable strategy for soil desalination, water conservation, and enhanced crop productivity. This approach is especially promising for managing salt-affected soils in regions like California, where soil salinization represents a considerable threat to agricultural sustainability. Full article

To investigate the changes in the composition and structure of the dissolved organic matter (DOM) of the lysate solutions of different types of soil after green manure tilling treatment, we set up two types of soil materials (fluvo-aquic soil; coastal saline soil) and three green manure tilling treatments (T1: CK—without green manure, T2: tilling Dongmu70 rye, and T3: tilling rapeseed green manure); then, the soil leachate was obtained with a soil column simulation test and its DOM spectral properties were determined. The rapeseed green manure leachate demonstrated a significantly higher humic macromolecule content and aromaticity compared to Dongmu70 rye leachate. Fluorescence Index (FI) values (1.5–2.2) suggest a mixed origin of dissolved organic matter (DOM) from both terrestrial and microbial-derived sources. All Humification Index (HIX) values remained below 1, indicating low humification levels and limited stabilization of DOM within the leachate system, and Biological Index (BIX) values exceeding 1 across all soil layers highlight the predominance of a recent biological metabolism in shaping DOM autochthonous origins. The SUVA₂₆₀ values in Dongmu70 rye–moist soils and rapeseed green manure–coastal saline soil exhibited reductions of 0.020–2.573 L·(mg·m)⁻¹ relative to pre-drenching levels. After tilling rapeseed green manure, the SUVA₂₅₄ value of coastal saline soil at the 60–90 cm layer decreased by 1.941 L·(mg·m)⁻¹. This study shows that differences in green manure and soil type affect DOM sources and composition, reducing DOM leaching, with coastal saline soil + rapeseed green manure and fluvo-aquic soil + Dongmu70 rye being the advantageous combinations. The study results provide theoretical guidance for applying green manure coupled with freshwater leaching technology in the context of saline and alkaline land with multiple soil types. Full article

Landfill leachate, a complex wastewater generated from municipal solid waste (MSW) landfills, presents significant environmental challenges due to its high organic content and toxic pollutants. This study proposes a sustainable solution by employing the green synthesis of copper oxide nanoparticles (CuO NPs) using durian (Durio zibethinus) husk extract, which serves as a natural reducing and stabilizing agent. This approach transforms agricultural waste into a valuable resource for environmental remediation. The synthesis was carried out under mild conditions, avoiding harmful chemicals and reducing energy consumption. The CuO NPs were characterized by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), Fourier-transform infrared spectroscopy (FTIR), and UV-Vis spectroscopy to examine their morphology, crystallinity, purity, and optical properties. SEM and HR-TEM analyses revealed mainly spherical nanoparticles with an average size of 35–50 nm and minimal aggregation. XRD analysis confirmed the presence of a highly crystalline monoclinic phase of CuO, while the EDX spectrum showed distinct peaks corresponding to copper (72%) and oxygen (28%) by weight, confirming the high purity of the material. Preliminary tests demonstrated the photocatalytic efficiency of the CuO NPs, achieving up to a 79% reduction in chemical oxygen demand (COD) in landfill leachate. These findings underscore the potential of green-synthesized CuO NPs for environmental applications, offering an innovative, sustainable method for wastewater treatment and supporting the advancement of solid waste management practices. Full article

Water pollution caused by landfill leachate, which contains high concentrations of heavy metals and organic contaminants, poses a serious environmental threat. Among the potential remediation strategies, phytoremediation using Miscanthus x giganteus (giant miscanthus) has gained attention due to its strong resistance to harsh conditions and its capacity to accumulate heavy metals. This study evaluates the effectiveness of Miscanthus x giganteus in treating landfill leachate, with a focus on removing key pollutants such as zinc (Zn), nickel (Ni), and copper (Cu) by simulating wetland conditions. A pilot-scale experiment conducted at the Grebača landfill site assessed the plant’s ability to enhance metal bioavailability, stabilize contaminants, and limit their mobility within the leachate system. The results demonstrated that Miscanthus x giganteus effectively mobilized Zn and Ni through rhizospheric activity, whereas Cu remained largely immobile, indicating potential for phytostabilization. Sequential extraction analysis further confirmed that the plant significantly reduced the mobile fractions of Zn and Ni in the soil, highlighting its dual role in both phytoremediation and phytostabilization. These findings suggest that Miscanthus x giganteus offers a sustainable and cost-effective approach to landfill leachate treatment, serving as a viable alternative to conventional methods. By integrating this nature-based solution into industrial and municipal waste management, it promotes environmental sustainability while enhancing remediation efficiency. Full article

This study evaluated the efficiency of catalytic ozonation with magnetite (Fe₃O₄) in degrading recalcitrant organic compounds in leachates from two sanitary landfills in Colombia. The optimum treatment conditions were also analyzed by means of a response surface design, resulting in 6 g O₃/h, 2.5 g/L Fe₃O₄, and pH 9, which resulted in COD removal rates of 85.3% in El Guayabal and 75.8% in La Madera. Moreover, the BOD₅/COD ratio increased from 0.26 to 0.38 and from 0.23 to 0.32, respectively, suggesting increased effluent biodegradability. The most efficient ozone consumption (2.7 g O₃ per gram of COD removed) was obtained under alkaline conditions with a high catalyst concentration. Magnetite demonstrated structural stability, although its catalytic efficiency progressively decreased after three cycles of use, with COD removal decreasing from 85.3% to 73.6%. These findings validate catalytic ozonation with magnetite as an efficient alternative for advanced leachate treatment, with the potential to optimize contaminant removal in industrial effluents and strengthen environmental remediation strategies. Full article

Waste-to-energy (WtE) is a key part of modern waste management. In the European Union, approximately 500 WtE plants process more than 100 million tons of waste yearly, while globally, more than 2700 plants handle over 500 million tons. Roughly 20% of the waste processed is bottom ash (BA). However, this ash can contain heavy metals in concentrations that may render it hazardous. This paper presents a study focusing on stabilizing municipal solid waste incineration BA using simple and industrially viable treatments. The Slovenian WtE plant operator wishes to install the stabilization process; thus, the samples obtained from the plant were treated (1) with a CO₂ gas flow, (2) with water spraying, and (3) with a combination of water spraying and a CO₂ gas flow under laboratory conditions. Thermodynamic calculations were applied to define potential reactions during the treatment processes in the temperature range from 0 to 100 °C and to define the equilibrium composition of the treated ash with additions of CO₂ and water. The standard leaching test EN 12457-4 of treated ash shows a reduction of over 40% in barium concentration and over 30% in lead concentration in leachates. Full article

This study investigates the potential of microbial-induced calcium carbonate precipitation (MICP) for soil stabilization and heavy metal immobilization, utilizing landfill leachate-derived ureolytic consortium. Experimental conditions identified yeast extract-based media as most effective for bacterial growth, urease activity, and calcite formation compared to nutrient broth and brown sugar media. Optimal MICP conditions, at pH 8–9 and 30 °C, supported the most efficient biomineralization. The process facilitated the removal of Cd²⁺ (99.10%) and Ni²⁺ (78.33%) while producing stable calcite crystals that enhanced soil strength. Thermal analyses (thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC)) confirmed the successful production of CaCO₃ and its role in improving soil stability. DSC analysis revealed endothermic and exothermic peaks, including a significant exothermic peak at 444 °C, corresponding to the thermal decomposition of CaCO₃ into CO₂ and CaO, confirming calcite formation. TGA results showed steady weight loss, consistent with the breakdown of CaCO₃, supporting the formation of stable carbonates. The MICP treatment significantly increased soil strength, with the highest surface strength observed at 440 psi, correlating with the highest CaCO₃ content (18.83%). These findings underscore the effectiveness of MICP in soil stabilization, pollutant removal, and improving geotechnical properties. Full article

The process of purifying agricultural products, at various food processing plants, generates waste materials that consist of precipitated calcium carbonate, organic debris, and trace amounts of soil and agricultural contaminants. A specific food-processing waste, hereafter referred to as a food industry byproduct, FIBP, is typically stockpiled on land adjacent to the corresponding food processing facilities due to its large volume and chemical composition. The FIBP also contains commercially available unspent lime products, which makes its reuse viable in various applications. An example is construction applications where an organic content of up to 5% by weight is allowed, such as treating expansive clays. Traditionally, lime stabilization has been used for improving the properties of expansive clays, where ground improvement methods are necessary for a large area. However, the process of producing lime is resource- and energy-intensive as it includes crushing and heating limestone in kilns to extract lime. Therefore, one specific doubly sustainable application is the treatment of expansive clays using the FIBP instead of lime. The main application tested here is the treatment of expansive clayey soils underneath a stretch of State Highway 95 near Marsing, ID. Other potential applications are in road and embankment construction. To evaluate the potential of expansive clay stabilization utilizing the FIBP, a series of geotechnical and environmental laboratory testing were conducted to measure the engineering properties (e.g., swell potential, permeability, and strength properties) of expansive clay amended with FIBP. Preliminary testing on blends with an expansive clay suggests benefits such as decreased swelling potential, increased density, and leachate immobilization. Full article

This study investigated the influence of green manure planting on the spectroscopic properties of dissolved organic matter (DOM) in saline–alkali soil under freshwater leaching conditions at different soil depths. The UV₂₅₄, UV₂₅₃/UV₂₀₃, α₃₀₀, α₃₅₅, SUVA₂₅₄, SUVA₂₆₀, and S_R ultraviolet parameters indicated reductions in the content of large molecular substances, benzene ring substitution degree, colored dissolved organic matter, aromaticity, and hydrophobic components in the soil leachate DOM with an increasing soil depth. Compared with the non-green manure treatment control, green manure planting mitigated the leaching of dissolved organic matter in soil during saline irrigation, with rape green manure demonstrating superior effectiveness. Utilizing three-dimensional fluorescence combined with parallel factor analysis, this study analyzed three fluorescent components of soil leachate DOM: C1 (visible-light fulvic acid), C2 (humic acid), and C3 (tyrosine-like protein). The combined contribution of the two humic substance components (C1 + C2) was approximately 70%, indicating the dominance of humic substances in leachate DOM. The fluorescence parameters of soil leachate DOM included an average of the fluorescence index (FI) values between 1.4 and 1.9, low humification index (HIX) values consistently below 4, and biological index (BIX) values ranging from 0.8 to 1.0, suggesting a mixed source, low humification degree, poor stability, and moderate self-source characteristics. Compared with the non-green manure treatment control, both the green manure treatments exhibited a relatively higher proportion of biogenic sources and humification degree in soil leachate DOM. This suggests that planting green manure can reduce the relative DOM content under freshwater leaching conditions, increase the proportion of biogenic sources in soil leachate DOM, and enhance soil humification. Planting rapeseed green manure can diminish the leaching of DOM from land sources and augment soil humification. Full article

To assess the long-term stability of lead-contaminated loess treated with calcium-free Enzyme-Induced Carbonate Precipitation (EICP) technology while avoiding significant soil strength increases, various parameters such as the pH value, heavy metal ion leaching rate, and soil heavy metal speciation were evaluated. This study investigated the remediated soil’s stability under complex environmental conditions, including dry–wet cycles and acid rain leaching. The intrinsic mechanisms were elucidated through the Zeta potential, scanning electron microscopy (SEM), and X-ray diffraction (XRD) analyses. The results showed that compared to the untreated lead-contaminated loess, the surface strength of the loess treated with EICP technology increased by 3.86 times, with a 1.47-fold increase observed with the calcium-free EICP treatment. Carbonate precipitation improved the erosion resistance by adsorbing or coating fine particles and forming bridging connections with coarse particles. As the number of dry–wet cycles increased, the soil pH gradually decreased but remained above 8.25. The heavy metal leaching rate increased with the leaching cycles until reaching a plateau. The acid rain influence showed a decrease in the Pb²⁺ content in the leachate as the acid rain solution pH increased, meeting hazardous waste disposal regulations. These findings offer new insights for improving heavy metal-contaminated loess site remediation and understanding the underlying geochemical mechanisms. Full article

In the past, due to improper sludge treatment technology and the absence of treatment standards, some municipal sludge was simply dewatered and then sent to landfills, occupying a significant amount of land and posing a serious threat of secondary pollution. To free up land in the landfill area for the expansion of a large-scale wastewater treatment plant (WWTP) in Shanghai, in this study, we conducted comprehensive pilot research on the entire chain of landfill sludge reprocessing and resource utilization. Both the combination of polyferric silicate sulfate (PFSS) and polyetheramine (PEA) and the combination of polyaluminum silicate (PAS) and polyetheramine (PEA) were used for sludge conditioning before dewatering, resulting in dewatered sludge with approximately 60% moisture content. The combined process involved coagulation and sedimentation, flocculation, and oxidation to treat the leachate generated during dewatering. The treatment process successfully met the specified water pollutant discharge concentration limits for the leachate, with the concentration of ammonia nitrogen in the effluent as low as 15.6 mg/L. Co-incineration in a power plant and modification were applied to stabilize and harmlessly dispose of the dewatered sludge. The coal-generating system ran stably, and no obvious problems were observed in the blending process. In the modification experiment, adding 5% to 7% of the solidifying agent increased the sludge bearing ratio by 53% and 57%, respectively. This process effectively reduced levels of fecal coliforms and heavy metals in the sludge but had a less noticeable effect on organic matter content. The modified sludge proved suitable for use as backfill material in construction areas without requirements for organic matter. The results of this study provide valuable insights for a completed full-scale landfill sludge reclamation and land resource release project. Full article

The treatment of stabilized leachates with high refractory organic matter content, which are over 10 years old, presents a challenge. This study explored the potential of electro-coagulation (EC) and electro-oxidation (EO) treatment systems to address this issue. The objective of this study was to investigate the phytotoxicity of the proposed treatment system on seed growth and examine possible relationships between phytotoxicity results and the characterization of leachates, effluents, soil, and radicles. Phytotoxicity tests were conducted on seeds of Lactuca sativa, Cucumis sativus, and Phaseolus vulgaris, using Inductively Coupled Plasma-Optical analysis. The evolution of organic matter was monitored by fractionating the chemical oxygen demand (COD) and humic substances. The biodegradability index increased from 0.094 in raw leachate to 0.26 and 0.48 with EC and EO, respectively. Removal rates of 82%, 86%, 99%, and 81% were achieved for COD, dissolved organic carbon, color, and ammoniacal nitrogen, respectively. The biodegradable COD increased from 26% in raw leachate to 39% in the EC process and 58% in the EO process effluent. The proposed treatment system successfully broke the aromatic structures of the humic substances present in the raw leachate, thereby increasing the content of biodegradable material. Phytotoxicity tests revealed that the proposed treatment system significantly reduced the phytotoxicity of the generated effluents. Full article

For arsenic decontamination from groundwater, arsenic crystallization is becoming adopted due to its sustainability and economic benefits. However, arsenic crystallization technology is a two-step process, which makes it complex and generates hazardous waste. Successful efforts toward making it a single-step process are presented here. The addition of nanorods and ball-milled zinc sulfide nanoparticles to arsenic-contaminated water result in highly monodispersed and high-arsenic-containing mineralized nanowaste with a crystalline structure similar to the mineral Tooeleite ((Fe³⁺₆(As³⁺O₃)₄SO₄(OH)₄·4H₂O)). This study reports the results of a short-term stability test based on a toxicity characteristic leaching procedure and a long-term stability test of the mineralized synthetic nanowaste produced from water treatment. The Tooeleite-like mineralized nanowaste passed short-term stability tests. Arsenic in the leachate were found to be 1.1 ± 0.2 mg L⁻¹ and 4.8 ± 0.3 mg L⁻¹ from waste generated by the nanorod and ball-milled nanoparticles, respectively. The crystallinity was well preserved, as observed from the post-stability-test diffraction patterns, consequently proving that the waste product can be non-hazardous and therefore would not require any secondary treatment before final disposal. Full article

High-strength wastewaters from a variety of sources, including the food industry, domestic septage, and landfill leachate, are often hauled to municipal wastewater treatment plants (WWTPs) for co-treatment. Due to their high organic loadings, these wastewaters can cause process upsets in both a WWTP’s liquid and solids treatment trains and consume organic treatment capacity, leaving less capacity available to service customers in the catchment area. A novel pre-treatment method, the Waste Activated Sludge-High Rate (WASHR) process, is proposed to optimize the co-treatment of high-strength wastewaters. The WASHR process combines the contact stabilization and sequencing batch reactor processes. It utilizes waste activated sludge from a municipal WWTP as its biomass source, allowing for a rapid start-up. Bench-scale treatment trials of winery wastewater confirm the WASHR process can reduce loadings on the downstream WWTP’s liquid and solids treatment trains. A case study approach is used to confirm the economic viability and environmental sustainability of the WASHR process compared to direct co-treatment, using life-cycle cost analyses and greenhouse gas emissions estimates. Full article