Search Results (320)

Titanium alloys exhibit exceptional strength-to-density ratios, high hardness, and outstanding resistance to elevated temperatures, making them indispensable structural materials in aerospace engineering, marine construction, and biomedical applications. In aerospace systems specifically, fatigue failure represents the predominant failure mode for titanium alloy components. This review systematically examines prevalent surface treatment techniques for titanium alloys—including shot peening, ultrasonic rolling treatment, hot isostatic pressing (HIP), physical vapor deposition (PVD), micro-arc oxidation (MAO), and thermal spray processes—and critically evaluates their respective effects on fatigue performance. The underlying mechanisms of each technique are concisely outlined, with emphasis on stress state evolution, near-surface microstructural refinement, and interfacial integrity. Building upon the characteristic surface-dominated fatigue fracture behavior of titanium alloys, this work focuses on how coating composition, architecture (e.g., graded, multilayer, or nanocomposite designs), and interfacial bonding strength govern fatigue resistance. A unified analysis is presented on the distinct yet complementary roles of substrate deformation strengthening (e.g., residual compression, grain refinement) and coating-mediated protection (e.g., barrier function, crack deflection, stress redistribution) during fatigue crack initiation and propagation. Key determinants of fatigue performance, including residual stress distribution, coating/substrate adhesion, thermal mismatch, and environmental degradation susceptibility, are rigorously assessed. Finally, emerging research frontiers are identified, including intelligent process–structure–property mapping, in situ monitoring of fatigue damage at coated interfaces, and design of multifunctional gradient coatings that synergistically enhance strength, wear resistance, and fatigue endurance of titanium alloy components. Full article

Viral and fungal diseases of greenhouse strawberries lead to significant crop losses, while traditional uniform spraying schemes do not account for the actual distribution of infection foci or changes in the microclimate. This paper proposes an integrated system for greenhouse farms that combines a stochastic SIRS model of the epidemic process with a microclimate-dependent infection coefficient β_eff(t), a computer vision module based on a lightweight YOLOv10n detector, and a mobile sprayer robot. For three sets of parameters corresponding to moderate infection, outbreak, and suppression scenarios, ensemble simulations are performed (100 realizations per scenario). The results show that the maximum number of infected plants reaches approximately 690 out of 1000 in the outbreak scenario and only about 28 out of 1000 in the suppression scenario, reflecting the effect of timely microclimate correction and local spraying. The YOLOv10n detector is used as a sensor to determine the proportion of affected plants I(0)/N and provides automatic formation of the initial conditions of the population model. The resulting forecasts then serve as the basis for selecting one of three operating modes for the spraying robot (observation, microclimate correction, local treatment). Unlike existing works that consider disease detection, epidemiological models, or robotic spraying separately, this paper proposes a unified closed-loop scheme of “computer vision—stochastic model—mobile robot,” linking detection quality with epidemic process forecasting and treatment strategy. In this study, the feasibility of the proposed system was examined through numerical simulations, detector-level performance evaluation, and offline image-based integrated validation of the detector-to-decision workflow. Full closed-loop experiments in a real greenhouse environment are planned for future work. Full article

Unmanned aerial vehicles (UAVs) are an alternative to traditional pesticide applications in orchards. Particularly, drones are an example of UAVs that have increased in popularity in recent years; however, relatively few studies have evaluated how spraying operation modes interact with other drone parameters within a single experimental framework. This study evaluated the effects of operation mode, application volume, flight height, and droplet size on spray coverage, droplet density, droplet spectra, and droplet size uniformity using the spraying drone DJI Agras T40 under a simulated canopy structure. A four-factorial experimental design was used; treatments included three operation modes (i.e., standard mode, fruit-tree mode, and spinning mode), two application volumes (i.e., 37.4 L/ha and 74.8 L/ha), two flight heights (i.e., 3 m and 5 m), and two droplet sizes (i.e., 150 μm and 300 μm). Operation mode was among the most influential factors affecting spray deposition quality. The spinning mode achieved the highest overall spray coverage (20.81%) and droplet density (172.44 drops/cm²), while the standard mode provided the most uniform spatial distribution. Results from the interaction analyses indicated that the parameter combination that produced the highest spray coverage within the tested ranges was an application volume of 74.8 L/ha, a flight height of 3 m, and a droplet size of 150 μm in the standard mode. For the fruit-tree mode, the highest spray coverage was observed at an application volume of 74.8 L/ha, a flight height of 5 m, and a droplet size of 300 μm. For the spinning mode, the combination associated with the highest spray coverage was 74.8 L/ha, 3 m, and 300 μm. In conclusion, the results provide data-driven guidance on how drone operational parameters influence spray deposition and can support future validation under commercial orchard conditions. Full article

Ensuring the required microclimate parameters is the most critical task in hot climates. In pig farms, air cooling is provided by means of steam-compression chillers or evaporative cooling, which is the simplest way to cool the air. The implementation of evaporative cooling depends largely on the interaction of the media involved in this process. This paper considers the process of interaction of cooling water with the surface of a cellular polycarbonate heat exchanger. A mathematical model describing the process of wetting the sprayed surface of the heat exchanger is obtained. The authors determined the theoretical water flow rate required to provide air cooling for a given operation mode. Experimental trials of a recuperative heat recovery unit with a heat exchanger made of cellular polycarbonate equipped with a water evaporative cooling system were carried out. The authors conducted a comparative assessment to evaluate the effectiveness of evaporative cooling in a heat recovery unit equipped with a polycarbonate heat exchanger versus panel evaporative systems using wetted paper pads at pig farms in the Vladimir and Tambov regions of Russia. The panel evaporative coolers provided a temperature reduction of 11.3 °C without any splashing effect. Under the same operating conditions, the heat recovery unit achieved an inlet air temperature reduction of 10.5 °C, accompanied by splashing. When the water flow rate supplied for evaporation was reduced until the splashing ceased, the cooling temperature drop decreased to 10.1 °C, which is 11% lower, compared with the paper pads. The study revealed characteristic operating modes for the unit that ensure effective air cooling, depending on the cooling water flow rate. Since the prevailing temperature during the system’s main operating time is significantly lower than the design temperature (the absolute temperature maximum), to achieve effective cooling of the supply air without splashing or excessive water waste, the cooling circuit water should circulate at a flow rate within 40 to 63% of the maximum design value. Alternatively, an automated control system should be employed to regulate the water supply based on outdoor air temperature and humidity. Full article

This study evaluates the effectiveness of laser cleaning techniques for the non-contact removal of unwanted deposits from the surface of contemporary urban mural paintings. Two sets of mock-up samples, painted with popular graffiti spray paints on lime-based plaster, and artificially contaminated, were subjected to various cleaning procedures using Nd:YAG lasers operated in Q-switched (QS), long Q-switched (LQS) or short free-running mode (SFR). A multi-analytical approach—including X-ray fluorescence spectroscopy (XRF), Fourier-transform infrared spectroscopy (FTIR), colorimetry, and hyperspectral imaging (HSI)—was used to identify pigments and binders, and to evaluate cleaning efficiency and pigment preservation. XRF and FTIR were useful in understanding the composition of the sprays, while colorimetric ΔE values quantified cleaning efficiency and potential damage, and hyperspectral reflectance and LSU (linear spectral unmixing) abundance maps provided spatial distribution insights into contaminant removal and pigment preservation. The results demonstrate that laser cleaning effectiveness and selectivity are strongly dependent on the operational regime and fluence. In particular, long Q-switched laser irradiation at moderate fluence levels achieved effective contaminant removal with minimal chromatic and chemical alteration of the original paint layers. These findings support the development of tailored, sustainable, and non-contact laser cleaning protocols for the conservation of contemporary urban murals and contribute to the establishment of objective, multi-parameter criteria for evaluating cleaning outcomes in street art conservation. Full article

New insecticides for indoor residual spraying (IRS) are being developed to manage resistance. Chlorfenapyr (Sylando^® 240SC), a pro-insecticide, is metabolized by active mosquitoes into the toxic metabolite tralopyril. This mode of action requires adapted “free flying” bioassays (because chlorfenapyr is converted to its toxic metabolite tralopyril when mosquitoes are metabolically active). A miniature-experimental hut (MEH) assay was developed within the Ifakara Ambient Chamber Test (I-ACT) with a rabbit as a host to measure residual efficacy under controlled conditions. Sylando^® 240SC was compared with SumiShield^® 50WG (clothianidin) for 12-month residual efficacy against malaria and arbovirus vectors. Residual activity was assessed on mud, wood and concrete with two huts per substrate treated with Sylando^® 240SC, one with SumiShield^® 50WG, and one with untreated control. Five replicates of 20 mosquitoes per strain (malaria vectors: pyrethroid-susceptible Anopheles gambiae and -resistant An. arabiensis and An. funestus; culicines Aedes aegypti and Culex quinquefasciatus) were exposed overnight at one-week post spraying and monthly thereafter. Multivariable mixed-effect logistic regression with binomial errors and log link function assessed non-inferiority with a 7% margin on mosquito mortality as the primary outcome for malaria vectors. Both products induced delayed mortality, with higher effects on malaria vectors than culicines. Across all substrates and malaria species combined over the full 12 months of observation, Sylando^® 240SC was non-inferior to SumiShield^® 50WG on mortality measured at 72 h (76% vs. 67%, OR = 0.86, 95% CI: 0.77–0.97) and 168 h (89% vs. 82%, OR = 0.74, 95% CI: 0.63–0.87). Sylando^® 240SC performed comparably to SumiShield^® 50WG, supporting its use as an IRS additional option. The new I-ACT mini-experimental-hut assay provides a practical tool for evaluating pro-insecticides. The importance of free-flight evaluation methods for pro-insecticides is discussed. Full article

The performance of flux-cored Zn-Al filler metal is susceptible to corrosion-induced degradation, thereby impairing its brazability. In this study, flux-cored Zn-2Al filler metals are prepared, and the salt spray test is subsequently carried out on the prepared filler metals. Scanning transmission electron microscope is used to identify the phases in filler metals. An electrochemical workstation was employed to test the electrochemical performance of the filler metals. The corrosion pathways and evolution patterns of filler metals are analyzed. The findings demonstrate that the corrosion type of the filler metals is electrochemical corrosion, characterized primarily by the corrosion modes of pitting corrosion and intergranular corrosion. The cathode is the α-Al phase, which undergoes an oxygen-absorption corrosion reaction, while the anode is the η-Zn phase, which experiences corrosion and subsequent dissolution. The continuously distributed α-Al phase bands and discontinuously distributed large-sized rod-like α-Al phases accelerate the corrosion rate, and the corrosion propagation rate along the extrusion direction is higher than that in the radially inward direction. After 15 days of salt spray corrosion, the tensile strength of filler metals decreases by 16.2%, and the elongation rate decreases to 3.73%. Full article

Phytic acid (PA), owing to its strong acidity and multidentate metal-chelating properties, readily forms multiple adduct/complex ions in mass spectrometry and is prone to pronounced matrix effects, resulting in complicated spectra and compromised sensitivity and quantitative robustness, which poses a major challenge for rapid and accurate PA quantification. Herein, we developed a rapid quantitative method for PA based on trimethylsilyldiazomethane (TMSD) methyl-ester derivatization coupled with paper spray mass spectrometry (PS–MS). PA was derivatized with TMSD to yield the methylated product (PA-Me), and the derivative solution was purified via “post-derivatization nitrogen blow-down followed by water reconstitution”, thereby markedly reducing background interference. In positive-ion mode, the stable sodium adduct ion [PA-Me+Na]⁺ (m/z 851.04) was used as the quantifier, enabling fast quantification with selected ion monitoring (SIM). PS–MS was performed with a 15 μL spotting volume and methanol/water (90/10, v/v, containing 0.1% formic acid) as the spray solvent, allowing rapid analysis without chromatographic separation. The method exhibited good linearity over 0.125–30 μg/mL (R² ≥ 0.9965), with a limit of detection (LOD, S/N = 3) of 0.080 μg/mL and a limit of quantification (LOQ, S/N = 10) of 0.270 μg/mL. The intra-day and inter-day precision values were both < 10% (RSD), and recoveries ranged from 87.2% to 122.4%. This LC-free strategy features low solvent consumption and high analytical throughput, and was validated using rice bran protein and rice bran polysaccharide samples, providing technical support for rapid screening and quality control of PA in complex food/plant matrices. Full article

Wire-arc coatings have received substantial attention for corrosion protection; however, poor bonding often leads to delamination, corrosion initiation, and costly re-coating of structural components. This review combines bibliometric mapping with a focused technical synthesis to clarify how bonding performance has been studied in wire-arc coatings. Specifically, publication trends, keyword co-occurrence networks, and country-level co-authorship maps are used to map the evolution of the field and position adhesion-related studies within the broader literature. The analysis of 762 wire-arc coating publications from Web of Science (among 13,314 thermal spray coating records) reveals that research is centered on microstructure, mechanical properties, and corrosion resistance, with growing links to wire-based additive manufacturing. Keyword co-occurrence networks demonstrate clear process–structure–property relationships, while country-level collaboration maps highlight the leadership of China, the USA, and Germany. Critical to note, only eight publications systematically investigate the combined effects of substrate roughness, coating thickness, and Zn-Al coating composition on bond strength—representing less than 0.01% of the thermal spray literature. This pronounced research gap underscores the novelty of the present review, which synthesizes existing knowledge on adhesion mechanisms, identifies key process parameters, and establishes a research agenda to optimize wire-arc coatings for infrastructure corrosion protection. The technical synthesis highlights that adhesion is governed by the coupled effects of surface preparation (roughness and topography), coating build-up (thickness), and spray conditions (e.g., standoff distance and substrate preheating), which together influence coating microstructure and failure modes. These findings provide a structured framework to guide parameter selection for durable coatings. Full article

This research examines how atmospheric plasma spraying torch power and coating thickness jointly affect the adhesion strength, microstructure, porosity, and flexural behavior of $A{l}_2{O}_3$ coatings on 100Cr6 steel substrates. Optical microscopy, SEM and EDS mapping, 3D surface-roughness analysis, Vickers hardness testing (HV2) on polished cross-sections, and three-point bending of extracted beams were employed to develop a processing–structure–property map. This multi-technique approach enables the cross-validation of processing–structure–property relationships and supports a robust identification of the optimal power–thickness condition by jointly considering porosity (densification), adhesion strength, flexural response and failure mode. All conditions resulted in an average surface roughness Ra of approximately 1.0 µm. Increasing torch power to 45 kW generally reduced cross-sectional porosity, except at 500 µm, where globular pores appeared. Hardness (HV2) increased with power and peaked at the intermediate thickness (500 µm); adhesion up to 63 MPa was recorded for the 300 µm/45 kW coating. Flexural strength was highest at 500 µm and was consistently greater at 45 kW than at 39 kW. Fractography showed a shift in failure mode from interface-driven delamination at 39 kW to more cohesive, tortuous intra-coating cracks at 45 kW, aligned with improved splat bonding and crack-path deflection. An intermediate thickness of 500 µm deposited at 45 kW is thus identified as an optimal condition to balance densification and crack-path tortuosity, leading to enhanced hardness and flexural performance. Full article

Hexoses, particularly glucose, are one of the most essential molecules for sustaining life; therefore, reliable methods for their analysis are very important. In our study, we present a qualitative and quantitative approach for analysing hexoses using MALDI IMS (Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry Imaging) with betaine aldehyde derivatisation and a CHCA (α-Cyano-4-hydroxycinnamic acid) matrix in positive ionisation mode. In this study, we demonstrated betaine aldehyde derivatisation of glucose from dried droplets and explored the analysis of hexoses in brain and liver tissue slices. We assessed whether our method could distinguish between mannose, galactose, glucose, and fructose and optimised the preparation of a biomimetic calibration curve using stable-isotope labelled glucose for hexose analysis. For this purpose, we investigated the number of betaine aldehyde layers required to obtain a proper calibration curve; examined whether changes in the spray nozzle position during CHCA matrix deposition could facilitate analysis and investigated how storage conditions influenced the calibration curve analysis. Finally, we optimised the technique for liver and brain analysis and assessed variations in hexose levels between brain, liver, kidney, and spinal cord tissues from control and morphine-addicted animals. We hope that our biomimetic approach to creating the calibration curve will be helpful for quantitative analysis and aid in developing various quantitative methods for assessing endogenous substances. Full article

Needle-free injection (NFI) technology is a promising alternative to conventional syringe injection, as it mitigates needle-related complications and enhances patient compliance. However, achieving the controlled and efficient dispersion of larger-volume formulations (>1 mL) within tissues remains a significant challenge. This study presents a novel pneumatic NFI system that uses a two-phase driving mode to regulate driving pressure and duration with an ejection volume of 1.0–2.0 mL. The integrated pressure stabilization unit significantly reduces pressure fluctuations during the initial injection phase, generating a more stable and uniform spray distribution. It is designed to produce an ideal elliptical dispersion effect while eliminating splatter, enabling controlled large-volume delivery. Jet impact experiments were conducted to investigate the dynamic characteristics of microjets generated by conventional single-phase and novel two-phase driving modes. Furthermore, the influence of the driving mode on the dispersion behaviors of microjets in agarose gels was explored through high-speed imaging of gel injections. The results demonstrate that the two-phase driving mode produces a distinct two-phase jet pressure profile. Compared to the single-phase mode, the two-phase mode produced a significantly larger dispersion width at equivalent initial driving pressures. This promotes more uniform lateral drug distribution and achieves a higher percentage of liquid drug delivery in gels. Furthermore, favorable driving pressure combinations were identified for different volumes: (1.25–0.25) MPa for 1.0 mL, (1.25–0.50) MPa for 1.5 mL, and (1.50–0.50) MPa for 2.0 mL. This provides a practical basis for optimizing clinical parameters and advancing the development of controllable NFI systems. Full article

The transplanted cotton–wheat rotation enables dual cropping but alters root system architecture, typically suppressing taproot growth and promoting shallow lateral and fibrous roots, with unclear implications for irrigation response and water use efficiency (WUE). Field experiments were conducted in 2021 and 2022 to investigate root growth, spatial distribution, and water uptake sources, using a minirhizotron system and stable hydrogen and oxygen isotopes. The study examined the effects of two cultivation modes (direct seeding and transplanting) and three irrigation methods (border irrigation, micro-spray tape irrigation, and surface drip irrigation) on cotton root traits and WUE. Results showed that transplanted cotton roots were predominantly concentrated in the 0–30 cm soil layer (75.35–77.13% of total root length), significantly higher than those of direct-seeded cotton (63.10–74.71%). Under micro-spray tape and drip irrigation, the root length density (RLD) of transplanted cotton was 18.55% and 23.46% higher, respectively, than that of direct-seeded cotton, whereas under border irrigation it was 5.09% lower. Transplanted cotton mainly extracted water from the 0–40 cm soil layer (utilization rate: 65.49%), while direct-seeded cotton primarily relied on water from the 20–60 cm layer (53.20%). Although no statistically significant difference in yield was observed between the two cultivation modes, transplanted cotton exhibited a 15.37% higher WUE than direct-seeded cotton. Moreover, surface drip irrigation substantially enhanced WUE, exceeding that under border irrigation and micro-spray tape irrigation by 37.35% and 14.07%, respectively. This study enhances understanding of root traits in transplanted cotton and demonstrates that irrigation methods regulate WUE by modifying root distribution and water uptake patterns. Full article

This study examined whether short water rinsing after hydrofluoric acid (HF) etching achieves comparable total bond strength (TBS) to more advanced cleaning protocols. Ninety-six lithium disilicate specimens were etched with 5% HF and then assigned to one of six post-etch cleaning methods: a 15 s water spray, 60 s water spray, brushing with a toothbrush, an ultrasonic bath with distilled water, an ultrasonic bath with 99% isopropanol, or a 37% phosphoric acid followed by an ultrasonic bath. The specimens were then bonded to acrylic tubes filled with composite resin. Half of the specimens were stored in water at 37 °C for three days, and the other half were stored for 150 days with 37,500 thermal cycles (5 °C/55 °C). TBS testing, failure mode evaluation, and microleakage testing were performed. Two-way ANOVA and Tukey’s test were used for statistical evaluation. Aging for 150 days significantly reduced TBS in all groups. Cleaning with a 60 s water spray resulted in significantly higher TBS than phosphoric acid plus ultrasonic cleaning, regardless of storage time. No significant differences were found among the other cleaning methods. There was no change in microleakage among the different groups; the failure was predominantly cohesive. A 15 s water spray after HF etching was as effective as more complex cleaning protocols in terms of TBS and SEM-observed surface characteristics. Full article

Cheese whey, the major by-product of the dairy industry, poses an environmental challenge due to its high organic load but simultaneously represents a nutrient-dense matrix suitable for biotechnological valorization. This review synthesizes recent advances positioning whey as (i) a fermentation substrate for lactic acid bacteria, yeasts/fungi, and microalgae, enabling the production of functional biomass, organic acids, bioethanol, exopolysaccharides, enzymes, and wastewater bioremediation; (ii) a platform for postbiotic generation, supporting cell-free preparations with functional activities; and (iii) a food-grade encapsulating material, particularly through whey proteins (β-lactoglobulin, α-lactalbumin), which can form emulsions, gels, and films that protect biotics and bioactive compounds during processing, storage, and gastrointestinal transit. We analyze key operational variables (whey type and pretreatment, supplementation strategies, batch and continuous cultivation modes), encapsulation routes (spray drying, freeze-drying, and hybrid protein–polysaccharide systems), and performance trade-offs relevant to industrial scale-up. Finally, we outline future directions, including precision fermentation, mixed-culture processes with in situ lactase activity, microfluidics-enabled encapsulation, and life-cycle assessment, to integrate product yields with environmental performance. Collectively, these strategies reframe whey from a high-impact waste into a circular bioeconomy resource for the food, nutraceutical, and environmental sectors. Full article