Search Results (188)

Using solid particulates as a heat transfer medium for concentrated solar power (CSP) systems has many advantages, positioning them as a superior option compared with conventional heat transfer media such as steam, oil, air, and molten salt. However, a critical imperative lies in the comprehensive evaluation of the properties of potential solid particulates intended for utilization under such extreme thermal conditions. This paper undertakes an exhaustive examination of both ambient and high-temperature thermophysical properties of four naturally occurring particulate materials, Riyadh white sand, Riyadh red sand, Saudi olivine sand, and US olivine sand, and one well-known engineered particulate material. The parameters under scrutiny encompass loose bulk density, tapped bulk density, real density, sintering temperature, and thermal conductivity. The results reveal that the theoretical density decreases with the increase in temperature. The bulk density of solid particulates depends strongly on the particulate size distribution, as well as on the compaction. The tapped bulk density was found to be larger than the loose density for all particulates, as expected. The sintering test proved that Riyadh white sand is sintered at the highest temperature and pressure, 1300 °C and 50 MPa, respectively. US olivine sand was solidified at 800 °C and melted at higher temperatures. This proves that US olivine sand is not suitable to be used as a thermal energy storage and heat transfer medium in high-temperature particle-based CSP systems. The experimental results of thermal diffusivity/conductivity reveal that, for all particulates, both properties decrease with the increase in temperature, and results up to 475.5 °C are reported. Full article

In order to reduce gas consumption and increase the renewable energy proportion, this paper proposes a poly-generation system that couples geothermal, solar, and liquid natural gas (LNG) cold energy to produce steam, gaseous natural gas, and low-temperature nitrogen. The high-temperature flue gas is used to heat LNG; low-temperature flue gas, mainly nitrogen, can be used for cold storage cooling, enabling the staged utilization of the energy. Solar shortwave is used for power generation, and longwave is used to heat the working medium, which realizes the full spectrum utilization of solar energy. The influence of different equipment and operating parameters on the performance of a steam generation system is studied, and the multi-objective model of the multi-generation system is established and optimized. The results show that for every 100 W/m² increase in solar radiation, the renewable energy ratio of the system increases by 1.5%. For every 10% increase in partial load rate of gas boiler, the proportion of renewable energy decreases by 1.27%. The system’s energy efficiency, cooling output, and the LNG vaporization flow rate are negatively correlated with the scale of solar energy utilization equipment. The decision variables determined by the TOPSIS (technique for order of preference by similarity to ideal solution) method have better economic performance. Its investment cost is 18.14 × 10 CNY, which is 7.83% lower than that of the LINMAP (linear programming technique for multidimensional analysis of preference). Meanwhile, the proportion of renewable energy is only 0.29% lower than that of LINMAP. Full article

The suitability of 347H stainless steel (SS347H) for chloride salt environments is critical in selecting materials for next-generation concentrated solar power (CSP) systems. This study investigated the corrosion behavior of SS347H in a ton-scale purification system with continuously flowing chloride salt under three conditions: exposure to NaCl-KCl-MgCl₂ molten salt vapor, immersion in molten salt, and at the molten salt surface interface. Results revealed that corrosion was most severe in the molten salt vapor, where HCl steam facilitated Cl⁻ reactions with Fe and Cr in the metal, causing dissolution and forming deep corrosion pits. At the interface, liquid Mg triggered displacement reactions with Fe²⁺/Cr²⁺ ions in the salt, depositing Fe and Cr onto the surface, which reduced corrosion intensity. Within the molten salt, Mg’s purification effect minimized impurity-induced corrosion, resulting in the least damage. In all cases, the primary corrosion mechanism involves the dissolution of Fe and Cr, with the formation of minor MgO. These insights provide valuable guidance for applying 347H stainless steel in chloride salt environments. Full article

Water scarcity is a growing global challenge, intensified by climate change, seawater intrusion, and pollution. While conventional desalination methods are energy-intensive, solar-driven interfacial evaporators offer a promising low-energy solution by leveraging solar energy for water evaporation, with the resulting steam condensed into purified water. Despite advancements, challenges persist, particularly in addressing volatile contaminants and biofouling, which can compromise long-term performance. The integration of photocatalysts into solar-driven interfacial evaporators has been proposed as a solution, enabling pollutant degradation and microbial inactivation while enhancing water transport and self-cleaning properties. This review critically assesses testing methodologies for solar-driven interfacial evaporators incorporating both photothermal and photocatalytic functions. While previous studies have examined materials and system design, the added complexity of photocatalysis necessitates new testing approaches. First, solar still setups are analyzed, particularly concentrating on the selection of materials and geometry for the transparent cover and water-collecting surfaces. Then, performance evaluation tests are discussed, with focus on the types of tested pollutants and analytical techniques. Finally, key challenges are presented, providing insights for future advancements in sustainable water purification. Full article

The innovation in thermal storage systems for solar thermal power generation is crucial for achieving efficient utilization of new energy sources. Molten salt has been extensively studied as a phase change material (PCM) for latent heat thermal energy storage systems. In this study, a two-dimensional model of a vertical shell-and-tube heat exchanger is developed, utilizing water-steam as the heat transfer fluid (HTF) and phase change material for heat transfer analysis. Through numerical simulations, we explore the interplay between PCM solidification and HTF boiling. The transient results show that tube length affects water boiling duration and PCM solidification thickness. Higher heat transfer fluid flow rates lower solidified PCM temperatures, while lower heat transfer fluid inlet temperatures delay boiling and shorten durations, forming thicker PCM solidification layers. Adding fins to the tube wall boosts heat transfer efficiency by increasing contact area with the phase change material. This extension of boiling time facilitates greater PCM solidification, although it may not always optimize the alignment of bundles within the thermal energy storage system. Full article

This review thoroughly evaluates gasification as a transformative alternative to conventional methods for managing municipal solid waste (MSW), highlighting its potential to convert carbonaceous materials into syngas for energy and chemical synthesis. A comparative evaluation of more than 350 papers and documents demonstrated that gasification is superior to incineration and pyrolysis, resulting in lower harmful emissions and improved energy efficiency, which aligns with sustainability goals. Key operational findings indicate that adjusting the temperature to 800–900 °C leads to the consumption of CO₂ and the production of CO via the Boudouard reaction. Air gasification produces syngas yields of up to 76.99 wt% at 703 °C, while oxygen gasification demonstrates a carbon conversion efficiency of 80.2%. Steam and CO₂ gasification prove to be effective for producing H₂ and CO, respectively. Catalysts, especially nickel-based ones, are effective in reducing tar and enhancing syngas quality. Innovative approaches, such as co-gasification, plasma and solar-assisted gasification, chemical looping, and integration with carbon capture, artificial intelligence (AI), and the Internet of Things (IoT), show promise in improving process performance and reducing technical and economic hurdles. The review identifies research gaps in catalyst development, feedstock variability, and system integration, emphasizing the need for integrated research, policy, and investment to fully realize the potential of gasification in the clean energy transition and sustainable MSW management. Full article

Steam is widely used in industry as a heat carrier for thermal processes and is primarily generated by gas-fired steam boilers. The decarbonization of industrial thermal demand relies on the capability of clean and renewable technologies to provide steam through reliable and cost-effective systems. Concentrating solar thermal technologies are attracting attention as a heat source for industrial steam generation. In addition, electricity-driven high-temperature heat pumps can provide heat using either renewable or grid electricity by upgrading ambient or waste heat to the required temperature level. In this study, linear Fresnel solar collectors and high-temperature heat pumps driven by photovoltaics are considered heat sources for steam generation in industrial processes. Energetic and economic analyses are performed across the European countries to assess and compare their performances. The results demonstrate that for a given available area for the solar field, solar thermal systems provide a higher annual energy yield in southern countries and at lower costs than heat pumps. On the other hand, heat pumps driven by photovoltaics provide higher annual energy for decreasing solar radiation conditions (central and northern Europe), although it leads to higher costs than solar thermal systems. A hybrid scheme combining the two technologies is the favorable option in central Europe, allowing a trade-off between the costs and the energy yield per unit area. Full article

This paper aims to evaluate the feasibility and performances of a novel hybrid solar–gas system, which provides electric power and cooling. By using Ebsilon (V15.0) software, the operation, advanced exergic and economic analyses of this hybrid system are conducted. The analysis results show that the total electric power and energy efficiency of the hybrid system are 96.0 MW and 45.8%. The solar energy system contributes an electric power of 9.0 MW. The maximum cooling load is 69.66 MW. The exergic loss and exergic efficiency of the whole hybrid system are 119.1 MW and 44.6%. The combustion chamber (CC) has the maximum exergic loss (56.5 MW). The exergic loss and exergic efficiency of the solar direct steam generator (SDSG) are 28.5 MW and 36.2%. For the air compressor (AC), CC, heat recovery steam generator (HRSG) and refrigeration system (CSS), a considerable part of the exergic loss is exogenous. The avoidable exergic loss of the CC is 11.69 MW. For the SDSG, there is almost no avoidable exergic loss. Economic analysis shows that for the hybrid system, the levelized cost of energy is 0.08125 USD/kWh, and the dynamic recycling cycle is 5.8 years, revealing certain economic feasibility. The results of this paper will contribute to the future research and development of solar–gas hybrid utilization technology to a certain extent. Full article

The industrial sector accounts for approximately 65% of global energy consumption, with projections indicating a steady annual increase of 1.2% in energy demand. In the context of growing concerns about climate change and the need for sustainable energy solutions, solar thermal energy has emerged as a promising technology for reducing reliance on fossil fuels. With its ability to provide high-efficiency heat for industrial processes at temperatures ranging from 150 °C to over 500 °C, solar thermal power generation offers significant potential for decarbonizing energy-intensive industries. This review provides a comprehensive analysis of various solar thermal technologies, including parabolic troughs, solar towers, and linear Fresnel reflectors, comparing their effectiveness across different industrial applications such as process heating, desalination, and combined heat and power (CHP) systems. For instance, parabolic trough systems have demonstrated optimal performance in high-temperature applications, achieving efficiency levels up to 80% for steam generation, while solar towers are particularly suitable for large-scale, high-temperature operations, reaching temperatures above 1000 °C. The paper also evaluates the economic feasibility of these technologies, showing that solar thermal systems can achieve a levelized cost of energy (LCOE) of USD 60–100 per MWh, making them competitive with conventional energy sources in many regions. However, challenges such as high initial investment, intermittency of solar resource, and integration into existing industrial infrastructure remain significant barriers. This review not only discusses the technical principles and economic aspects of solar thermal power generation but also outlines specific recommendations for enhancing the scalability and industrial applicability of these technologies in the near future. Full article

Relative to other renewable energy technologies, concentrated solar power (CSP) is only in the beginning phases of large-scale deployment. Its incorporation into national grids is steadily growing, with anticipation of its substantial contribution to the energy mix. A number of emerging economies are situated in areas that receive abundant amounts of direct normal irradiance (DNI), which translates into expectations of significant effectiveness for CSP. However, any assessment related to the planning of CSP facilities is challenging because of the complexity of the associated criteria and the number of stakeholders. Additional complications are the differing concepts and configurations for CSP plants available, a dearth of related experience, and inadequate amounts of data in some developing countries. The goal of the work presented in this paper was to evaluate the practical CSP implementation options for such parts of the world. Ambiguity and imprecision issues were addressed through the application of multi-criteria decision-making (MCDM) in a fuzzy environment. Six technology combinations, involving dry cooling and varied installed capacity levels, were examined: three parabolic trough collectors with and without thermal storage, two solar towers with differing storage levels, and a linear Fresnel with direct steam generation. The in-depth performance analysis was based on 4 main criteria and 29 sub-criteria. Quantitative and qualitative data, plus input from 44 stakeholders, were incorporated into the proposed fuzzy analytic hierarchy process (AHP) model. In addition to demonstrating the advantages and drawbacks of each scenario relative to the local energy sector requirements, the model’s results also provide accurate recommendation guidelines for integrating CSP technology into national grids while respecting stakeholders’ priorities. Full article

Biogas (primarily biomethane), as a carbon-neutral renewable energy source, holds great potential to replace fossil fuels for sustainable hydrogen production. Conventional biogas reforming systems adopt strategies similar to industrial natural gas reforming, posing challenges such as high temperatures, high energy consumption, and high system complexity. In this study, we propose a novel multi-product sequential separation-enhanced reforming method for biogas-derived hydrogen production, which achieves high H₂ yield and CO₂ capture under mid-temperature conditions. The effects of reaction temperature, steam-to-methane ratio, and CO₂/CH₄ molar ratio on key performance metrics including biomethane conversion and hydrogen production are investigated. At a moderate reforming temperature of 425 °C and pressure of 0.1 MPa, the conversion rate of CH₄ in biogas reaches 97.1%, the high-purity hydrogen production attains 2.15 mol-H₂/mol-feed, and the hydrogen yield is 90.1%. Additionally, the first-law energy conversion efficiency from biogas to hydrogen reaches 65.6%, which is 11 percentage points higher than that of conventional biogas reforming methods. The yield of captured CO₂ reaches 1.88 kg-CO₂/m³-feed, effectively achieving near-complete recovery of green CO₂ from biogas. The mild reaction conditions allow for a flexible integration with industrial waste heat or a wide selection of other renewable energy sources (e.g., solar heat), facilitating distributed and carbon-negative hydrogen production. Full article

The global shortage of freshwater resources and the energy crisis have propelled solar-driven interfacial evaporation (SDIE) coupled with photocatalytic technology to become a research focus in efficient and low-carbon water treatment. Graphene-based materials demonstrate unique advantages in SDIE–photocatalysis integrated systems, owing to their broadband light absorption, ultrafast thermal carrier dynamics, tunable electronic structure, and low evaporation enthalpy characteristics. This review systematically investigates the enhancement mechanisms of graphene photothermal conversion on photocatalytic processes, including (1) improving light absorption through surface morphology modulation, defect engineering, and plasmonic material compositing; (2) reducing water evaporation enthalpy via hydrophilic functional group modification and porous structure design; (3) suppressing heat loss through thermal insulation layers and 3D structural optimization; and (4) enhancing water transport efficiency via fluid channel engineering and wettability control. Furthermore, salt resistance strategies and structural optimization significantly improve system practicality and stability. In water treatment applications, graphene-based SDIE systems achieve synergistic “adsorption–catalysis–evaporation” effects, enabling efficient the degradation of organic pollutants, reduction in/fixation of heavy metal ions, and microbial inactivation. However, practical implementation still faces challenges including low steam condensation efficiency, insufficient long-term material durability, and high scaling-up costs. Future research should prioritize enhancing heat and mass transfer in condensation systems, optimizing material environmental adaptability, and developing low-cost manufacturing processes to promote widespread application of graphene-based SDIE–photocatalysis integrated systems. Full article

Solar steam generation (SSG) has garnered significant attention for its potential in water purification applications. While composites with physically combined structures based on semiconductors or biomass have been developed for SSG, there remains a critical need for low-cost, high-efficiency devices. In this study, TiO₂ composites exhibiting excellent stability, high solar absorption, porous microstructure, and hydrophilic surfaces were identified as effective materials for SSG and water purification for the first time. A novel SSG device was designed by decorating TiO₂ onto three-dimensional carbonized Osmanthus fragrans leaves (TiO₂/carbonized OFL). Compared to directly carbonized OFL (without TiO₂) and Osmanthus fragrans leaves with templated TiO₂ (OFL-templated TiO₂), the TiO₂/carbonized OFL carbon composites demonstrated enhanced solar absorption, achieving over 99% in the visible region and more than 80% in the near-infrared region. Under solar illumination of 1 kW·m⁻², the TiO₂/carbonized OFL device achieved a high water evaporation rate of 2.31 kg·m⁻²·h⁻¹, which is 1.6 times higher than that of carbonized OFL and 3.45 times higher than OFL-templated TiO₂. Additionally, the TiO₂/carbonized OFL system exhibited remarkable efficiency in treating pharmaceutical wastewater, with a chemical oxygen demand (COD) removal efficiency of 98.9% and an ammonia nitrogen removal efficiency of 90.8% under solar radiation. Full article

Growing interest in sustainable energy has gathered significant attention for alternative technologies, with hydrogen-based solutions emerging as a crucial component in the transition to cleaner and more resilient energy systems. Following that, hydrogen-based microgrids, integrated with renewable energy sources including wind and solar, have gained substantial attention as an upcoming pathway toward long-term energy sustainability. Hydrogen, produced through processes such as electrolysis and steam methane reforming, can be stored in various forms including compressed gas, liquid, or solid-state hydrides, and later utilized for electricity generation through fuel cells and gas turbines. This dynamic energy system offers highly flexible, scalable, and resilient solutions for various applications. Specifically, hydrogen-based microgrids are particularly suitable for offshore and islanded applications, with geographical factors, adverse environmental conditions, and limited access to conventional energy solutions. This is critical for energy independence, long-term storage capacity, and grid stability. This review explores topological and functional-based classifications of microgrids, advancements in hydrogen generation, storage, and utilization technologies, and their integration with microgrid systems. It also critically evaluates the key challenges of each technology, including cost, efficiency, and scalability, which impact the feasibility of hydrogen microgrids. Full article

Direct steam generation (DSG) is a promising technology for introducing solar energy into industrial applications, yet it still faces significant challenges. This work analyzes two critical issues associated with DSG: temperature gradients on the receiver tube wall caused by direct and concentrated radiation and flow instability resulting from the phase transition of the working fluid from liquid–vapor to vapor. These phenomena can reduce the mechanical strength of the receiver tube and lead to sudden pressure increases, deformation, or rupture, which hinder the implementation of DSG in solar thermal plants. To address these challenges, the behavior of a receiver tube composed of copper on the inside and an Al₂O₃ envelope is studied. A 50 MWe hybrid solar thermal plant is proposed for Mulegé, Baja California Sur, Mexico, including a solar field designed to analyze the production of superheated steam during peak solar irradiance hours. The effect of the Cu-Al₂O₃ ratio on the receiver tube is evaluated, with Al₂O₃ serving as a thermal regulator to reduce temperature gradients and mitigate flow instability. This combination of materials improves the receiver tube’s performance, ensuring mechanical stability and enhancing the viability of DSG systems. By reducing temperature gradients and flow instability, DSG-based plants can double thermal efficiency and significantly lower environmental impact by eliminating the need for thermal oils, which require frequent replacement. These findings demonstrate the potential for hybrid solar thermal plants to provide sustainable and efficient solutions for industrial energy needs. Full article