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Search Results (1,212)

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Keywords = soft magnets

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25 pages, 19715 KiB  
Article
Microstructure, Mechanical Properties, and Magnetic Properties of 430 Stainless Steel: Effect of Critical Cold Working Rate and Heat Treatment Atmosphere
by Che-Wei Lu, Fei-Yi Hung and Tsung-Wei Chang
Metals 2025, 15(8), 868; https://doi.org/10.3390/met15080868 (registering DOI) - 2 Aug 2025
Viewed by 157
Abstract
430 stainless steel exhibits soft magnetic properties, excellent formability, and corrosion resistance, making it widely used in industrial applications. This study investigates the effects of different cold working rates on the properties of 430 stainless steel subjected to various magnetic annealing atmospheres (F-1.5Si, [...] Read more.
430 stainless steel exhibits soft magnetic properties, excellent formability, and corrosion resistance, making it widely used in industrial applications. This study investigates the effects of different cold working rates on the properties of 430 stainless steel subjected to various magnetic annealing atmospheres (F-1.5Si, F-1.5Si-10%, F-1.5Si-40%, F-1.5Si-10% (MA), F-1.5Si-40% (MA), F-1.5Si-10% (H2), and F-1.5Si-40% (H2)). The results indicate that increasing the cold working rate improves the material’s mechanical properties; however, it negatively impacts its magnetic and corrosion resistance properties. Additionally, the magnetic annealing process improves the mechanical properties, while atmospheric magnetic annealing optimizes the overall magnetic performance. In contrast, magnetic annealing in a hydrogen atmosphere does not enhance the magnetic properties as effectively as atmospheric magnetic annealing. Still, it promotes the formation of a protective layer, preserving the mechanical properties and providing better corrosion resistance. Furthermore, regardless of whether magnetic annealing is conducted in an atmospheric or hydrogen environment, materials with 10% cold work rate (F-1.5Si-10% (MA) and F-1.5Si-10% (H2)) exhibit the lowest coercive force (286 and 293 A/m in the 10 Hz test condition), making them ideal for electromagnetic applications. Full article
(This article belongs to the Special Issue Heat Treatment and Mechanical Behavior of Steels and Alloys)
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25 pages, 8721 KiB  
Article
Experiments in 3D Printing Electric Motors
by Alex Ellery, Abdurr Elaskri, Mariappan Parans Paranthaman and Fabrice Bernier
Machines 2025, 13(8), 679; https://doi.org/10.3390/machines13080679 - 1 Aug 2025
Viewed by 71
Abstract
This paper catalogues a series of experiments we conducted to explore how to 3D print a DC electric motor. The individual parts of the electric motor were 3D printed but assembled by hand. First, we focused on a rotor with soft magnetic properties, [...] Read more.
This paper catalogues a series of experiments we conducted to explore how to 3D print a DC electric motor. The individual parts of the electric motor were 3D printed but assembled by hand. First, we focused on a rotor with soft magnetic properties, for which we adopted ProtoPastaTM, which is a commercial off-the-shelf PLA filament incorporating iron particles. Second, we focused on the stator permanent magnets, which were 3D printed through binder jetting. Third, we focused on the wire coils, for which we adopted a form of laminated object manufacture of copper wire. The chief challenge was in 3D printing the coils, because the winding density is crucial to the performance of the motor. We have demonstrated that DC electric motors can be 3D printed and assembled into a functional system. Although the performance was poor due to the wiring problem, we showed that the other 3D printing processes were consistent with high performance. Nevertheless, we demonstrated the principle of 3D printing electric motors. Full article
(This article belongs to the Special Issue Additive Manufacturing of Electrical Machines)
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31 pages, 5480 KiB  
Review
Solid Core Magnetic Gear Systems: A Comprehensive Review of Topologies, Core Materials, and Emerging Applications
by Serkan Sezen, Kadir Yilmaz, Serkan Aktas, Murat Ayaz and Taner Dindar
Appl. Sci. 2025, 15(15), 8560; https://doi.org/10.3390/app15158560 (registering DOI) - 1 Aug 2025
Viewed by 234
Abstract
Magnetic gears (MGs) are attracting increasing attention in power transmission systems due to their contactless operation principles, low frictional losses, and high efficiency. However, the broad application potential of these technologies requires a comprehensive evaluation of engineering parameters, such as material selection, energy [...] Read more.
Magnetic gears (MGs) are attracting increasing attention in power transmission systems due to their contactless operation principles, low frictional losses, and high efficiency. However, the broad application potential of these technologies requires a comprehensive evaluation of engineering parameters, such as material selection, energy efficiency, and structural design. This review focuses solely on solid-core magnetic gear systems designed using laminated electrical steels, soft magnetic composites (SMCs), and high-saturation alloys. This review systematically examines the topological diversity, torque transmission principles, and the impact of various core materials, such as electrical steels, soft magnetic composites (SMCs), and cobalt-based alloys, on the performance of magnetic gear systems. Literature-based comparative analyses are structured around topological classifications, evaluation of material properties, and performance analyses based on losses. Additionally, the study highlights that aligning material properties with appropriate manufacturing methods, such as powder metallurgy, wire electrical discharge machining (EDM), and precision casting, is essential for the practical scalability of magnetic gear systems. The findings reveal that coaxial magnetic gears (CMGs) offer a favorable balance between high torque density and compactness, while soft magnetic composites provide significant advantages in loss reduction, particularly at high frequencies. Additionally, application trends in fields such as renewable energy, electric vehicles (EVs), aerospace, and robotics are highlighted. Full article
(This article belongs to the Section Electrical, Electronics and Communications Engineering)
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25 pages, 2023 KiB  
Article
Geographical Origin Authentication of Leaves and Drupes from Olea europaea via 1H NMR and Excitation–Emission Fluorescence Spectroscopy: A Data Fusion Approach
by Duccio Tatini, Flavia Bisozzi, Sara Costantini, Giacomo Fattori, Amedeo Boldrini, Michele Baglioni, Claudia Bonechi, Alessandro Donati, Cristiana Tozzi, Angelo Riccaboni, Gabriella Tamasi and Claudio Rossi
Molecules 2025, 30(15), 3208; https://doi.org/10.3390/molecules30153208 - 30 Jul 2025
Viewed by 198
Abstract
Geographical origin authentication of agrifood products is essential for ensuring their quality, preventing fraud, and maintaining consumers’ trust. In this study, we used proton nuclear magnetic resonance (1H NMR) and excitation–emission matrix (EEM) fluorescence spectroscopy combined with chemometric methods for the [...] Read more.
Geographical origin authentication of agrifood products is essential for ensuring their quality, preventing fraud, and maintaining consumers’ trust. In this study, we used proton nuclear magnetic resonance (1H NMR) and excitation–emission matrix (EEM) fluorescence spectroscopy combined with chemometric methods for the geographical origin characterization of olive drupes and leaves from different Tuscany subregions, where olive oil production is relevant. Single-block approaches were implemented for individual datasets, using principal component analysis (PCA) for data visualization and Soft Independent Modeling of Class Analogy (SIMCA) for sample classification. 1H NMR spectroscopy provided detailed metabolomic profiles, identifying key compounds such as polyphenols and organic acids that contribute to geographical differentiation. EEM fluorescence spectroscopy, in combination with Parallel Factor Analysis (PARAFAC), revealed distinctive fluorescence signatures associated with polyphenolic content. A mid-level data fusion strategy, integrating the common dimensions (ComDim) method, was explored to improve the models’ performance. The results demonstrated that both spectroscopic techniques independently provided valuable insights in terms of geographical characterization, while data fusion further improved the model performances, particularly for olive drupes. Notably, this study represents the first attempt to apply EEM fluorescence for the geographical classification of olive drupes and leaves, highlighting its potential as a complementary tool in geographic origin authentication. The integration of advanced spectroscopic and chemometric methods offers a reliable approach for the differentiation of samples from closely related areas at a subregional level. Full article
(This article belongs to the Section Food Chemistry)
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20 pages, 4182 KiB  
Article
A Soft Reconfigurable Inverted Climbing Robot Based on Magneto-Elastica-Reinforced Elastomer
by Fuwen Hu, Bingyu Zhao and Wenyu Jiang
Micromachines 2025, 16(8), 855; https://doi.org/10.3390/mi16080855 - 25 Jul 2025
Viewed by 326
Abstract
This work presents a novel type of soft reconfigurable mobile robot with multimodal locomotion, which is created using a controllable magneto-elastica-reinforced composite elastomer. The rope motor-driven method is employed to modulate magnetics–mechanics coupling effects and enable the magneto-elastica-reinforced elastomer actuator to produce controllable [...] Read more.
This work presents a novel type of soft reconfigurable mobile robot with multimodal locomotion, which is created using a controllable magneto-elastica-reinforced composite elastomer. The rope motor-driven method is employed to modulate magnetics–mechanics coupling effects and enable the magneto-elastica-reinforced elastomer actuator to produce controllable deformations. Furthermore, the 3D-printed magneto-elastica-reinforced elastomer actuators are assembled into several typical robotic patterns: linear configuration, parallel configuration, and triangular configuration. As a proof of concept, a few of the basic locomotive modes are demonstrated including squirming-type crawling at a speed of 1.11 mm/s, crawling with turning functions at a speed of 1.11 mm/s, and omnidirectional crawling at a speed of 1.25 mm/s. Notably, the embedded magnetic balls produce magnetic adhesion on the ferromagnetic surfaces, which enables the soft mobile robot to climb upside-down on ferromagnetic curved surfaces. In the experiment, the inverted ceiling-based inverted crawling speed is 2.17 mm/s, and the inverted freeform surface-based inverted crawling speed is 3.40 mm/s. As indicated by the experimental results, the proposed robot has the advantages of a simple structure, low cost, reconfigurable multimodal motion ability, and so on, and has potential application in the inspection of high-value assets and operations in confined environments. Full article
(This article belongs to the Special Issue Development and Applications of Small-Scale Soft Robotics)
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29 pages, 4447 KiB  
Article
Cooling Systems for High-Speed Machines—Review and Design Considerations
by Matthew Meier and Elias G. Strangas
Energies 2025, 18(15), 3954; https://doi.org/10.3390/en18153954 - 24 Jul 2025
Viewed by 470
Abstract
High-speed machines are attractive to many industries due to their small size and light weight, but present unique cooling challenges due to their increased loss and reduced surface area. Cooling system advancements are central to the development of faster, smaller machines, and as [...] Read more.
High-speed machines are attractive to many industries due to their small size and light weight, but present unique cooling challenges due to their increased loss and reduced surface area. Cooling system advancements are central to the development of faster, smaller machines, and as such, are constantly evolving. This paper presents a review of classical and state-of-the-art cooling systems. Each cooling method—air cooling, indirect liquid cooling, and direct liquid cooling—has potential use in cooling high-speed machines, but each comes with unique considerations, which are discussed. An example design process highlights the interdependence of the electromagnetic and thermal design choices, illustrating the necessity of integrating the electromagnetic and thermal designs in a holistic approach. Full article
(This article belongs to the Special Issue Advances in Permanent Magnet Synchronous Generator)
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24 pages, 5864 KiB  
Article
A High-Efficiency Bi-Directional CLLLC Converter with Auxiliary LC Network for Fixed-Frequency Operation in V2G Systems
by Tran Duc Hung, Zeeshan Waheed, Manh Tuan Tran and Woojin Choi
Energies 2025, 18(14), 3815; https://doi.org/10.3390/en18143815 - 17 Jul 2025
Viewed by 255
Abstract
This paper introduces an enhanced bi-directional full-bridge resonant converter designed for Vehicle-to-Grid (V2G) systems. A key innovation lies in the incorporation of an auxiliary LC resonant circuit connected via a tertiary transformer winding. This circuit dynamically modifies the magnetizing inductance based on operating [...] Read more.
This paper introduces an enhanced bi-directional full-bridge resonant converter designed for Vehicle-to-Grid (V2G) systems. A key innovation lies in the incorporation of an auxiliary LC resonant circuit connected via a tertiary transformer winding. This circuit dynamically modifies the magnetizing inductance based on operating frequency, enabling soft-switching across all primary switches, specifically, Zero-Voltage Switching (ZVS) at turn-on and near Zero-Current Switching (ZCS) at turn-off across the entire load spectrum. Additionally, the converter supports both Constant Current (CC) and Constant Voltage (CV) charging modes at distinct, fixed operating frequencies, thus avoiding wide frequency variations. A 3.3 kW prototype developed for onboard electric vehicle charging applications demonstrates the effectiveness of the proposed topology. Experimental results confirm high efficiency in both charging and discharging operations, achieving up to 98.13% efficiency in charge mode and 98% in discharge mode. Full article
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22 pages, 4482 KiB  
Article
Cu-Doping Induced Structural Transformation and Magnetocaloric Enhancement in CoCr2O4 Nanoparticles
by Ming-Kang Ho, Yun-Tai Yu, Hsin-Hao Chiu, K. Manjunatha, Shih-Lung Yu, Bing-Li Lyu, Tsu-En Hsu, Heng-Chih Kuo, Shuan-Wei Yu, Wen-Chi Tu, Chiung-Yu Chang, Chia-Liang Cheng, H. Nagabhushana, Tsung-Te Lin, Yi-Ru Hsu, Meng-Chu Chen, Yue-Lin Huang and Sheng Yun Wu
Nanomaterials 2025, 15(14), 1093; https://doi.org/10.3390/nano15141093 - 14 Jul 2025
Viewed by 328
Abstract
This study systematically investigates the impact of Cu2+ doping on the structural, magnetic, and magnetocaloric properties of CuxCo1−xCr2O4 nanoparticles synthesized via a solution combustion method. Cu incorporation up to x = 20% induces a [...] Read more.
This study systematically investigates the impact of Cu2+ doping on the structural, magnetic, and magnetocaloric properties of CuxCo1−xCr2O4 nanoparticles synthesized via a solution combustion method. Cu incorporation up to x = 20% induces a progressive structural transformation from a cubic spinel to a trigonal corundum phase, as confirmed by X-ray diffraction and Raman spectroscopy. The doping process also leads to increased particle size, improved crystallinity, and reduced agglomeration. Magnetic measurements reveal a transition from hard to soft ferrimagnetic behavior with increasing Cu content, accompanied by a notable rise in the Curie temperature from 97.7 K (x = 0) to 140.2 K (x = 20%). The magnetocaloric effect (MCE) is significantly enhanced at higher doping levels, with the 20% Cu-doped sample exhibiting a maximum magnetic entropy change (−ΔSM) of 2.015 J/kg-K and a relative cooling power (RCP) of 58.87 J/kg under a 60 kOe field. Arrott plot analysis confirms that the magnetic phase transitions remain second-order in nature across all compositions. These results demonstrate that Cu doping is an effective strategy for tuning the magnetostructural response of CoCr2O4 nanoparticles, making them promising candidates for low-temperature magnetic refrigeration applications. Full article
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17 pages, 1208 KiB  
Article
Structural Features of the Temporomandibular Joint Evaluated by MRI and Their Association with Oral Function and Craniofacial Morphology in Female Patients with Malocclusion: A Cross-Sectional Study
by Mari Kaneda, Yudai Shimpo, Kana Yoshida, Rintaro Kubo, Fumitaka Kobayashi, Akira Mishima, Chinami Igarashi and Hiroshi Tomonari
J. Clin. Med. 2025, 14(14), 4921; https://doi.org/10.3390/jcm14144921 - 11 Jul 2025
Viewed by 370
Abstract
Background/Objectives: Temporomandibular disorders (TMDs) are a group of musculoskeletal and neuromuscular conditions involving the temporomandibular joint (TMJ), masticatory muscles, and related anatomical structures. Although magnetic resonance imaging (MRI) is considered a noninvasive and highly informative imaging modality for assessing TMJ soft tissues, [...] Read more.
Background/Objectives: Temporomandibular disorders (TMDs) are a group of musculoskeletal and neuromuscular conditions involving the temporomandibular joint (TMJ), masticatory muscles, and related anatomical structures. Although magnetic resonance imaging (MRI) is considered a noninvasive and highly informative imaging modality for assessing TMJ soft tissues, few studies have examined how TMJ structural features observed on MRI findings relate to oral function and craniofacial morphology in female patients with malocclusion. To investigate the associations among TMJ structural features, oral function, and craniofacial morphology in female patients with malocclusion, using MRI findings interpreted in conjunction with a preliminary assessment based on selected components of the DC/TMDs Axis I protocol. Methods: A total of 120 female patients (mean age: 27.3 ± 10.9 years) underwent clinical examination based on DC/TMDs Axis I and MRI-based structural characterization of the TMJ. Based on the structural features identified by MRI, patients were classified into four groups for comparison: osteoarthritis (OA), bilateral disk displacement (BDD), unilateral disk displacement (UDD), and a group with Osseous Change/Disk Displacement negative (OC/DD (−)). Occlusal contact area, occlusal force, masticatory efficiency, tongue pressure, and lip pressure were measured. Lateral cephalometric analysis assessed skeletal and dental patterns. Results: OA group exhibited significantly reduced occlusal contact area (p < 0.0083, η2 = 0.12) and occlusal force (p < 0.0083, η2 = 0.14) compared to the OC/DD (−) group. Cephalometric analysis revealed that both OA and BDD groups had significantly larger ANB angles (OA: 5.7°, BDD: 5.2°, OC/DD (−): 3.7°; p < 0.0083, η2 = 0.21) and FMA angles (OA: 32.4°, BDD: 31.8°, OC/DD (−): 29.0°; p < 0.0083, η2 = 0.17) compared to the OC/DD (−) group. No significant differences were observed in masticatory efficiency, tongue pressure, or lip pressure. Conclusions: TMJ structural abnormalities detected via MRI, especially osteoarthritis, are associated with diminished oral function and skeletal Class II and high-angle features in female patients with malocclusion. Although orthodontic treatment is not intended to manage TMDs, MRI-based structural characterization—when clinically appropriate—may aid in treatment planning by identifying underlying joint conditions. Full article
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15 pages, 4616 KiB  
Article
A Novel Wide-Gain-Range Variable-Structure DC/DC Converter Based on an LLC Resonant Converter
by Qingqing He, Shun Tang, Dan Ren, Zhaoyang Tang, Qisheng Zhu, Chao Tang and Keliang Zhou
Energies 2025, 18(14), 3664; https://doi.org/10.3390/en18143664 - 10 Jul 2025
Viewed by 380
Abstract
The LLC resonant converter, as an isolated DC-DC conversion topology, has been widely adopted in industrial applications. However, when operating under wide input/output voltage ranges, a broad switching frequency range is required to achieve the desired voltage gain. This wide frequency variation complicates [...] Read more.
The LLC resonant converter, as an isolated DC-DC conversion topology, has been widely adopted in industrial applications. However, when operating under wide input/output voltage ranges, a broad switching frequency range is required to achieve the desired voltage gain. This wide frequency variation complicates the design of magnetic components, causes loss of soft-switching characteristics, and deteriorates electromagnetic interference (EMI) performance. To address these challenges, this paper presents a detailed analysis of the L-LCLC resonant converter. By controlling the connection/disconnection of additional inductors and capacitors through switching devices, the topology achieves structural reconfiguration to enhance the voltage gain range. Optimal mode transition points are selected to ensure stable operation during mode transitions, thereby reducing design complexity, minimizing transition losses, and suppressing voltage/current stress. The parameter design methodology for the additional reactive components is systematically developed. The converter’s performance is validated with Simulink, and the experimental prototype is established with 100 W. Both simulation and experimental results confirm that the L-LCLC resonant converter achieves a wide voltage gain range within a narrow frequency band while maintaining stable mode transitions. Full article
(This article belongs to the Special Issue Reliability of Power Electronics Devices and Converter Systems)
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15 pages, 5712 KiB  
Article
Synthesis of Magnetic Nanoparticle/Polymer Matrix Nanocomposites with Induced Magnetic Performance
by Anastasios C. Patsidis, Aikaterini Sanida, Georgia C. Manika, Sevasti Gioti, Georgios N. Mathioudakis, Nicholas Petropoulos, Athanasios Kanapitsas, Christos Tsonos, Thanassis Speliotis and Georgios C. Psarras
Polymers 2025, 17(14), 1913; https://doi.org/10.3390/polym17141913 - 10 Jul 2025
Viewed by 420
Abstract
In this work magnetic nanoparticles (Fe3O4, or ZnFe2O4, or SrFe12O19) and BaTiO3 microparticles were embedded in an epoxy resin for the synthesis of three series of hybrid magnetic polymer nanocomposites. [...] Read more.
In this work magnetic nanoparticles (Fe3O4, or ZnFe2O4, or SrFe12O19) and BaTiO3 microparticles were embedded in an epoxy resin for the synthesis of three series of hybrid magnetic polymer nanocomposites. Barium titanate content was kept constant, while magnetic phase content was varied. Fabricated specimens were structurally and morphologically characterized by employing scanning electron microscopy images and X-ray diffraction patterns. Results implied successful synthesis of the hybrid nanocomposites. The magnetic behavior of the pure magnetic nanoparticles and the fabricated nanocomposites was investigated via a Vibrating Sample Magnetometer. The magnetic performance of each type of magnetic phase (i.e., soft and hard) was induced in the nanocomposites, and magnetic performance is strengthened with the increase in magnetic phase content. Initial magnetization curves were used for the determination of mass magnetic susceptibility of all nanocomposites. Magnetic saturation and magnetic remanence have been found to follow a linear relationship with magnetic phase content, giving the opportunity to predict the system’s response in advance. Full article
(This article belongs to the Special Issue Polymers in Inorganic Chemistry: Synthesis and Applications)
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62 pages, 4192 KiB  
Review
Advancements in Magnetorheological Foams: Composition, Fabrication, AI-Driven Enhancements and Emerging Applications
by Hesamodin Khodaverdi and Ramin Sedaghati
Polymers 2025, 17(14), 1898; https://doi.org/10.3390/polym17141898 - 9 Jul 2025
Viewed by 577
Abstract
Magnetorheological (MR) foams represent a class of smart materials with unique tunable viscoelastic properties when subjected to external magnetic fields. Combining porous structures with embedded magnetic particles, these materials address challenges such as leakage and sedimentation, typically encountered in conventional MR fluids while [...] Read more.
Magnetorheological (MR) foams represent a class of smart materials with unique tunable viscoelastic properties when subjected to external magnetic fields. Combining porous structures with embedded magnetic particles, these materials address challenges such as leakage and sedimentation, typically encountered in conventional MR fluids while offering advantages like lightweight design, acoustic absorption, high energy harvesting capability, and tailored mechanical responses. Despite their potential, challenges such as non-uniform particle dispersion, limited durability under cyclic loads, and suboptimal magneto-mechanical coupling continue to hinder their broader adoption. This review systematically addresses these issues by evaluating the synthesis methods (ex situ vs. in situ), microstructural design strategies, and the role of magnetic particle alignment under varying curing conditions. Special attention is given to the influence of material composition—including matrix types, magnetic fillers, and additives—on the mechanical and magnetorheological behaviors. While the primary focus of this review is on MR foams, relevant studies on MR elastomers, which share fundamental principles, are also considered to provide a broader context. Recent advancements are also discussed, including the growing use of artificial intelligence (AI) to predict the rheological and magneto-mechanical behavior of MR materials, model complex device responses, and optimize material composition and processing conditions. AI applications in MR systems range from estimating shear stress, viscosity, and storage/loss moduli to analyzing nonlinear hysteresis, magnetostriction, and mixed-mode loading behavior. These data-driven approaches offer powerful new capabilities for material design and performance optimization, helping overcome long-standing limitations in conventional modeling techniques. Despite significant progress in MR foams, several challenges remain to be addressed, including achieving uniform particle dispersion, enhancing viscoelastic performance (storage modulus and MR effect), and improving durability under cyclic loading. Addressing these issues is essential for unlocking the full potential of MR foams in demanding applications where consistent performance, mechanical reliability, and long-term stability are crucial for safety, effectiveness, and operational longevity. By bridging experimental methods, theoretical modeling, and AI-driven design, this work identifies pathways toward enhancing the functionality and reliability of MR foams for applications in vibration damping, energy harvesting, biomedical devices, and soft robotics. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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16 pages, 1455 KiB  
Article
Comparison of Magnetic Resonance Imaging Scales for Assessment of Interval Changes of Arthropathy in Boys with Severe Hemophilia
by Ningning Zhang, Manuel Carcao, Danial M. Ignas, Brian M. Feldman, Pamela Hilliard, Rahim Moineddin, Ann Marie Stain, Paul Babyn, Victor S. Blanchette and Andrea S. Doria
J. Clin. Med. 2025, 14(13), 4792; https://doi.org/10.3390/jcm14134792 - 7 Jul 2025
Viewed by 420
Abstract
Background/Objectives: The variety of magnetic resonance imaging (MRI) scales available to measure soft tissue and osteochondral changes in joints of persons with hemophilia poses challenges in evaluating published clinical/research studies. To evaluate the value of four MRI scales [(i) the 17-point International Prophylaxis [...] Read more.
Background/Objectives: The variety of magnetic resonance imaging (MRI) scales available to measure soft tissue and osteochondral changes in joints of persons with hemophilia poses challenges in evaluating published clinical/research studies. To evaluate the value of four MRI scales [(i) the 17-point International Prophylaxis Study Group [IPSG] additive scale; (ii) and (iii) the compatible IPSG progressive (P) and additive (A) scales; and (iv) the Denver progressive scale] to assess joint change in boys with hemophilia participating in a prospective two-year prophylaxis study. Methods: Boys with severe hemophilia A (ages, 7–16 years) followed at the Hospital for Sick Children, Toronto, Canada had MRI evaluations of six index joints (ankles, knees, elbows) at study entry and exit. Musculoskeletal (MSK) outcomes included in the study were the Colorado Child Physical Examination (PE) scale; the Pettersson (X-ray) scale; and the aforementioned 4 MRI scales. Results: Very strong (r ≥ 0.80) correlations were observed between the IPSG 17-point, the IPSG progressive (P) and the Denver MRI scales, and moderate (r = 0.40–0.59) to strong (r = 0.60–0.79) correlations for the IPSG 17 point and the IPSG additive (A) MRI scales. Very weak (r = 0.20–0.39) or no correlations were observed between soft tissue MRI scores and the swelling item of the Child PE scale. Conclusions: All four MRI scales demonstrated relative comparability of their construct validities for assessing mild/moderate hemophilic arthropathy. The 17-point IPSG additive scale is recommended as a reference standard in future long-term studies of young boys with hemophilia receiving factor and non-factor-based preventive therapies. Full article
(This article belongs to the Section Hematology)
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18 pages, 2880 KiB  
Article
Novel Magnetically Charged Grafts for Vascular Repair: Process Optimization, Mechanical Characterization and In Vitro Validation
by Iriczalli Cruz-Maya, Roberto De Santis, Luciano Lanotte and Vincenzo Guarino
Polymers 2025, 17(13), 1877; https://doi.org/10.3390/polym17131877 - 5 Jul 2025
Viewed by 488
Abstract
In the last decade, magnetic nanoparticles (MNPs) have attracted much attention for the implementation of non-invasive approaches suitable for the diagnosis and treatment of vascular diseases. In this work, the optimization of novel vascular grafts loaded with Nickel-based nanoparticles via electrospinning is proposed. [...] Read more.
In the last decade, magnetic nanoparticles (MNPs) have attracted much attention for the implementation of non-invasive approaches suitable for the diagnosis and treatment of vascular diseases. In this work, the optimization of novel vascular grafts loaded with Nickel-based nanoparticles via electrospinning is proposed. Two different polycarbonate urethanes—i.e., Corethane A80 (COT) and Chronoflex AL80 (CHF)—were used to fabricate 3D electrospun nanocomposite grafts. SEM analysis showed a homogeneous distribution of fibers, with slight differences in terms of average diameters as a function of the polymer used—(1.14 ± 0.18) µm for COT, and (1.33 ± 0.23) µm for CHF—that tend to disappear in the presence of MNPs—(1.26 ± 0.19) µm and (1.26 ± 0.213) µm for COT/NPs and CHF/NPs, respectively. TGA analyses confirmed the higher ability of CHF to entrap MNPs in the fibers—18.25% with respect to 14.63% for COT—while DSC analyses suggested an effect of MNPs on short-range rearrangements of hard/soft micro-domains of CHF. Accordingly, mechanical tests confirmed a decay of mechanical strength in the presence of MNPs with some differences depending on the matrix—from (6.16 ± 0.33) MPa to (4.55 ± 0.2) MPa (COT), and from (3.67 ± 0.18) MPa to (2.97 ± 0.22) MPa (CNF). The in vitro response revealed that the presence of MNPs did not negatively affect cell viability after 7 days in in vitro culture, suggesting a promising use of these materials as smart vascular grafts able to support the actuation function of vessel wall muscles. Full article
(This article belongs to the Section Polymer Applications)
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12 pages, 3806 KiB  
Article
Effects of Annealing Processes on Microstructure and Properties of FeNi-Based Amorphous Alloy
by Chenglong Sun, Mengen Shi, Xinyu Wang, Daying Deng and Weihuo Li
Materials 2025, 18(13), 3172; https://doi.org/10.3390/ma18133172 - 4 Jul 2025
Viewed by 375
Abstract
The present experiment is aimed at investigating the changes in the properties of an FeNiCBCo amorphous alloy after different stress relief annealing. It was established that, under equivalent temperature and time conditions, the strip that underwent no magnetic field annealing exhibited the maximum [...] Read more.
The present experiment is aimed at investigating the changes in the properties of an FeNiCBCo amorphous alloy after different stress relief annealing. It was established that, under equivalent temperature and time conditions, the strip that underwent no magnetic field annealing exhibited the maximum Bs of 1.09 T. The soft magnetic properties were found to be marginally enhanced by the transverse magnetic treatment, and the coercivity was notably reduced from 10.15 to 0.27 A/m after the longitudinal magnetic treatment. Furthermore, it was determined that, subsequent to the longitudinal magnetic treatment and the annealing treatment with no magnetic field, the strip exhibited enhanced mechanical properties due to the precipitation of the second phase A1 FeNi nanoparticles within the strip. In contrast, the transverse magnetic treatment significantly improved the strength of the alloy. Additionally, the strip demonstrated superior mechanical properties, while the strength of the alloys with the transverse magnetic treatment was significantly increased. This study demonstrates that transverse magnetic treatment can evidently enhance the strength, and magnetic field-free and longitudinal magnetic annealing treatments improve the soft magnetic properties, of amorphous alloys while maintaining good mechanical properties. Full article
(This article belongs to the Special Issue Characterization, Properties, and Applications of New Metallic Alloys)
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