Search Results (41)

Although coconut water is recognized for its desirable sensory appeal and nutritional composition, its broader industrial use is constrained by the rapid deterioration that occurs after extraction. In this study, crossflow microfiltration of coconut water with a silicon carbide membrane was optimized by investigating pressure and temperature through a face-centered design (FCD) and artificial neural network modeling coupled with a genetic algorithm (ANN–GA). Permeate flux and fouling index were used as process responses, and the optimized condition was further examined in terms of hydraulic resistance, fouling behavior, and retention of minerals and primary metabolites. Pressure and temperature affected the process differently: permeate flux showed marked nonlinear behavior, whereas fouling index was governed mainly by pressure. At the sample level, ANN described permeate flux more accurately than FCD (R² = 0.99 vs. 0.96), whereas FCD showed better grouped cross-validated predictivity across unseen pressure–temperature conditions (Q² = 0.85 vs. 0.57). For the fouling index, FCD outperformed ANN in both sample-level fit and grouped validation (R² = 0.95 vs. 0.60; Q² = 0.70 vs. 0.61). Both approaches converged on the same favorable operating window, and experimental validation at 60 kPa and 35 °C yielded 1085.23 ± 23.12 L h⁻¹ m⁻² and 83.56 ± 1.56%. During concentration mode, flux decline was severe but predominantly reversible, with high clean-water permeance recovery after chemical cleaning. Resistance partition and fouling modeling indicated that the main hydraulic limitation was associated with concentration polarization and external cake-layer buildup rather than irreversible membrane damage. The clarified fraction also preserved high transmission of major minerals and relevant primary metabolites, indicating that the selected condition combined high productivity, manageable fouling, and satisfactory nutritional retention. Full article

The growing problem of antibiotic resistance poses a serious threat to public health and ecosystems. New disinfection methods could help address this global issue. In this study, ultraviolet-C light-emitting diodes (UV-C LEDs) were used to inactivate Escherichia coli isolates resistant to antibiotics. These isolates were obtained from various real water sources, including seawater, surface water, and treated wastewater. Inactivation assays were performed using two wavelengths (255 nm and 265 nm), applying UV fluences ranging from 1 to 7 mJ/cm² to a phosphate-buffered saline solution inoculated with a mixture of 10 E. coli strains. Using an UV fluence of 2 mJ/cm², a log reduction of about 5 was achieved with both UV-C wavelengths tested. SEM imaging revealed no observable alterations in cell morphology after UV-C exposure. Pyrimidine dimer formation was quantified, yielding approximately 40 ng/mL of cyclobutane pyrimidine dimers after 2 mJ/cm² of exposure to both wavelengths. Additionally, water treatment was tested using ceramic silicon carbide membranes. High average rejection efficiencies (99.9%) were obtained for both total coliforms and E. coli using uncut flat sheet membranes. The combination with UV-C LEDs led to treatment of the concentrated membrane retentate (99.985% or higher), highlighting the potential of this treatment approach for effective water disinfection. Full article

Silicon carbide (SiC) detectors continue to emerge as a promising technology for applications requiring radiation hardness, fast response times, and stable operation in harsh environments. In this work, the charge-collection dynamics of ultra-thin membrane SiC detectors are investigated through time-dependent TCAD simulations, consistent with previously reported measurements. The study analyzes the transient response following the localized generation of electron–hole pairs induced by ions, comparing bulk and membrane detector geometries with identical active-layer thicknesses. Two-dimensional simulations provide a time-resolved characterization of the electron and hole current-density distributions within the active region of the device. The results show that both device architectures present a transient current signal featuring two main components. Despite similarities in the prompt drift-driven signal component, the SiC membrane response is characterized by a short secondary component returning to zero within 3.5 × 10^–10 s at zero external bias, making it well-suited for reliable single-ion detection. In contrast, bulk devices exhibit a markedly different response, characterized by a significantly more intense and prolonged secondary component followed by a long tail that does not return to zero within the simulation time window for all investigated reverse biases. This tail is the result of the collection of carriers generated in the substrate that reach the depletion region through diffusion-driven processes. These findings contribute to the optimization of SiC-based solid-state detectors for quantum-technology device fabrication, demonstrating that the removal of the substrate drastically reduces the diffusion-dominated current component, thereby ensuring precise timing and minimal charge loss. Full article

The coconut water market continues to expand, but industrial supply is constrained by the high perishability of fresh coconut water and the need for stabilization routes that preserve quality. This study optimized crossflow microfiltration of coconut water using a silicon carbide (SiC) ceramic membrane, high permeability, chemical/thermal robustness, and cleanability, and assessed the techno-economic feasibility of a green coconut biorefinery producing microfiltered coconut water and coconut pulp. Pressure and temperature were modeled and optimized using a face-centered design (FCD) and artificial neural networks coupled with a genetic algorithm (ANN–GA), considering permeate flux and fouling index (p < 0.05). Both approaches converged to the same operating point, and experimental validation at 75 kPa and 30 °C achieved 605.32 ± 15.34 L h⁻¹ m⁻² and 82.79 ± 1.35% at VRR = 1. Sample-level fit statistics favored ANN (higher R² and lower sample-level errors), whereas condition-wise grouped cross-validation (leave-one-condition-out) indicated higher predictivity and lower RMSE_CV for the quadratic FCD/RSM models across experimental conditions, highlighting response-dependent generalization within the investigated domain. Fouling analysis indicated concentration polarization as the main resistance contribution and a flux-decline behavior best described by the intermediate blocking mechanism. A SuperPro Designer^® simulation over a 20-year project life indicated economic feasibility under baseline assumptions (Internal rate of return—IRR = 23.80%, Net present value—NPV = US$733,761, payback = 2.96 years), with profitability remaining attractive under ±10% selling-price variation. Overall, the process optimization and modeling outcomes align with the economic case, reinforcing the potential of this biorefinery concept for industrial deployment. Full article

Important advancements in the development of novel materials and designs have led to the creation of advanced mineral membranes with high packing densities and enhanced competitiveness in relation to polymeric and classic mineral membranes. Olive juice represents an underutilised source of phenolic and secoiridoid antioxidants, in which industrial valorisation is hindered by some technical limitations, particularly the effective removal of suspended solids during processing. The efficiency of two recrystallized silicon carbide-based microfiltration membranes with an equivalent industrial filtration packing density of 782 m²/m³ was evaluated. One of them had nominal pore sizes of 500 nm and was made of mixed oxides and the other had nominal pore sizes of 200 nm and was made of α-Al₂O₃. The 500 nm membrane demonstrated superior filtration flux and faster processing compared to the 200 nm membrane, though both achieved complete removal of suspended solids. A greater workload of the 500 nm membrane resulted in a progressive irreversible fouling, caused by the smallest-sized suspended particles and macromolecular colloids. Particle size had a greater impact on fouling than particle load. Both membrane treatments induced a spontaneous increase in the concentrations of up to 24 phenolic, secoiridoid and secoiridoidyl phenylethanoid conjugates. This effect can be considered as an additional benefit of the thus clarified olive juices. Further investigations are warranted to elucidate the underlying mechanisms driving these transformations. Full article

In radiofrequency filters, there is an increasing demand for high-frequency, wide-bandwidth operation. Recently, laterally excited A₁-mode Lamb wave resonators (XBARs) have attracted significant attention; however, freestanding structures are mechanically fragile, limiting their practical implementation. To address this challenge, a novel bonded membrane structure consisting of a lithium niobate (LiNbO₃; LN) thin plate supported by a silicon carbide (SiC) layer is proposed to realize high-frequency, high-performance, and thermally robust acoustic resonators. Finite element simulations were performed to analyze the excitation and propagation of A₁-mode Lamb waves in the LN/SiC membrane, clarifying the distinct behavior compared with XBARs. The influence of the bonded SiC thin layer on A₁-mode Lamb waves was systematically evaluated in terms of coupling coefficient and phase velocity, and design guidelines were established based on these insights. A fabricated LN/SiC resonator with an interdigital electrode pitch of 12 µm exhibited a clear A₁-mode response near 1.2 GHz, showing an effective electromechanical coupling coefficient of 24% and a phase velocity exceeding 14,000 m/s. These results demonstrate the feasibility of the bonded LN/SiC membrane as a promising platform for high electromechanical coupling, high-speed, and thermally stable acoustic devices. Full article

Membrane fouling poses a significant challenge in the widespread adoption and cost-effective operation of membrane technology. Among different strategies to mitigate fouling, dynamic membrane (DM) technology has emerged as a promising one for effective control and mitigation of membrane fouling. Silicon carbide (SiC) membranes have attracted considerable attention as membrane materials due to their remarkable advantages, yet membrane fouling is still inevitable in challenging separation tasks, such as oil-in-water (O/W) emulsion separation, and thus effective mitigation of membrane fouling is essential to maximize their economic viability. This study investigates the use of pre-deposited oxide DMs to mitigate the fouling of SiC membranes during the separation of O/W emulsions. Among five screened oxides (Fe₂O₃, SiO₂, TiO₂, ZrO₂, Al₂O₃), SiO₂ emerged as the most effective DM material due to its favorable combination of particle size, negative surface charge, hydrophilicity, and underwater oleophobicity, leading to minimized oil droplet adhesion via electrostatic repulsion to DM surfaces and enhanced antifouling performance. Parameter optimization in dead-end mode revealed a DM deposition amount of 300 g/m², a transmembrane pressure (TMP) of 0.25 bar, and a backwashing pressure of 2 bar as ideal conditions, achieving stable oil rejection (~93%) and high pure water flux recovery ratios (FRR, >90%). Cross-flow filtration outperformed dead-end mode, maintaining normalized permeate fluxes of ~0.4–0.5 (cf. ~0.2 in dead-end) and slower FRR decline, attributed to reduced concentration polarization and enhanced DM stability under tangential flow. Optimal cross-flow conditions included a DM preparation time of 20 min, a TMP of 0.25 bar, and a flow velocity of 0.34 m/s. The results establish SiO₂-based DMs as a cost-effective strategy to enhance SiC membrane longevity and efficiency in O/W emulsion separation. Full article

The proper usage of a bandwidth-limited imaging bolometer for the measurement of the lateral temperature profile of microstructures in Silicon-Carbide (SiC) is analyzed. The SiC spectral emissivity, ${ϵ}_{SiC}\left(\lambda \right)$, has a dip at $\lambda \sim 12$$\mathsf{\mu }$m, which is in the band of a typical commercially available instrument and complicates the selection of the value of the equivalent emissivity, ${ϵ}_{eq,SiC}$, in the instrument settings. The impact is analyzed by deduction using simulation, and by experimental validation. Membranes of 3C-SiC of 1000 $\mathsf{\mu }$m diameter and 3 $\mathsf{\mu }$m thickness have been fabricated on Si wafers, with integrated poly-SiC resistors for both membrane heating and on-membrane temperature measurement for calibration purposes. The optimum setting was found as ${ϵ}_{eq,SiC}$ = 0.705 ± 0.025 by deduction and as ${ϵ}_{eq,SiC}$ = 0.66 ± 0.06 by experimental validation in the temperature range 120 °C to 400 °C. The apparent temperature coefficient of emissivity, $TCE<$ 2 × 10⁻⁴ °C⁻¹ is due to the shift of the Wien peak wavelength relative to the instrument’s sensitivity band. Full article

Novel catalytic silicon carbide membrane filters (SCMFs) are synthesized with Co/Al–layered double hydroxide (Co/Al-LDH)-coated silicon carbide powder. After capsuled in a self-designed membrane shell, the SCMFs are utilized in activating persulphate for aniline degradation. Thermal analysis conducted via TG/DTG/DSC examination shows that the heating treatment is beneficial in elevating the activating ability of SCMFs, and the derived Co₃O₄ displays superior catalytical efficiency than Co/Al-LDHs precursor. The XRD patterns and SEM images indicate the sheet-like Co/Al-LDHs are uniformly coprecipitated throughout the surface of SCMFs. Within 20 min, around 95% of aniline is eliminated under 0.7 m of flow velocity and 8:1 of persulphate to aniline ratio. Three-dimensional fluorescence and GC chromatography reveal that distinct by-products exist in the early stage of the aniline degradation process between the sintered and non-sintered Co/Al-LDH-coated SCMFs. The integration strategy of Co/Al-LDH coatings and heating treatment endows traditional SCMFs with robust catalytic properties for engineering-oriented applications in wastewater treatment. Full article

A huge variety of chemical commodities are built from propylene molecules, and its conventional production technologies (naphtha steam cracking and fluid catalytic cracking) are unable to satisfy C₃H₆’s increasing requirements. In this scenario, Direct Propane Dehydrogenation (PDH) provides a practical and reliable route for supplying this short demand due to the economic availability of the raw material (C₃H₈) and the high propylene selectivities. The main challenges of propane dehydrogenation technology are related to the design of very active catalysts with negligible byproduct formation. In particular, the issue of catalyst deactivation by coke deposition still requires further development. In addition, PDH is a considerable endothermic reaction, and the efficiency of this technology is strictly related to heat transfer management. Thus, this current review specifically discusses the recent advances in highly dispersed bimetallic and trimetallic catalysts proposed for the PDH reaction in both conventional-heated and microwave-heated reactors. From the point of view of catalyst development, the recent research is mainly addressed to obtain nanometric and single-atom catalysts and core–shell alloys: atomically dispersed metal atoms promote the desorption of surface-bonded propylene and inhibit its further dehydrogenation. The discussion is focused on the alternative formulations proposed in the last few years, employing active species and supports different from the classical Pt-Sn/Al₂O₃ catalyst. Concerning the conventional route of energy-supply to the catalytic bed, the advantage of using a membrane as well as fluidized bed reactors is highlighted. Recent developments in alternative microwave-assisted dehydrogenation (PDH) employing innovative catalytic systems based on silicon carbide (SiC) facilitate selective heating of the catalyst. This advancement leads to improved catalytic activity and propylene selectivity while effectively reducing coke formation. Additionally, it promotes environmental sustainability in the ongoing electrification of chemical processes. Full article

Rivers are not only a vital part of the Earth’s water cycle but also sources and sinks for greenhouse gases (GHGs), exerting a significant influence on the global carbon budget. Rapid urbanization and intense human activities lead to water pollution and river habitat degradation, thereby affecting riverine greenhouse gas (GHG) emissions indirectly. Artificial management and restoration measures taken for rivers further increase the uncertainty of GHG emissions from rivers. In the context of carbon neutrality goals, research on GHG emissions from rivers has gradually become a hot topic. However, there is a scarcity of collective and comparative studies on the spatiotemporal patterns and mechanisms of riverine GHG emissions, especially a lack of summaries exploring the impacts of pollution and restoration on GHG emissions from rivers. This work systematically reviews recent studies concerning the emissions of CO₂, CH₄, and N₂O from rivers, with a particular focus on the characteristics and driving factors. Results have shown that riverine GHG emissions exhibit significant spatiotemporal heterogeneity. Besides hydrological factors such as wind speed, flow velocity, rainfall, and water level, large amounts of pollutants entering rivers strongly affect the production and emission of GHGs, since nutrients, organic matter, heavy metals, microplastics, and antibiotics can alter the biogeochemical processes in river ecosystems. Remediation measures can reduce water pollution levels, but some measures may further increase the emission of GHGs from rivers. This work emphasizes the need for conducting in-depth research on the synergies between treating river pollution and reducing riverine GHG emissions. It also proposes to reinforce the monitoring of GHGs and construct emission databases of rivers for sustainable watershed management. Full article

Sodium hypochlorite (NaClO) is widely used for the chemical cleaning of fouled ultrafiltration (UF) membranes. Various studies performed on polymeric membranes demonstrate that long-term (>100 h) exposure to NaClO deteriorates the physicochemical properties of the membranes, leading to reduced performance and service life. However, the effect of NaClO cleaning on ceramic membranes, particularly the number of cleaning cycles they can undergo to alleviate irreversible fouling, remains poorly understood. Silicon carbide (SiC) membranes have garnered widespread attention for water and wastewater treatment, but their chemical stability in NaClO has not been studied. Low-pressure chemical vapor deposition (LP-CVD) provides a simple and economical route to prepare/modify ceramic membranes. As such, LP-CVD facilitates the preparation of SiC membranes: (a) in a single step; and (b) at much lower temperatures (700–900 °C) in comparison with sol-gel methods (ca. 2000 °C). In this work, SiC ultrafiltration (UF) membranes were prepared via LP-CVD at two different deposition temperatures and pressures. Subsequently, their chemical stability in NaClO was investigated over 200 h of aging. Afterward, the properties and performance of as-prepared SiC UF membranes were evaluated before and after aging to determine the optimal deposition conditions. Our results indicate that the SiC UF membrane prepared via LP-CVD at 860 °C and 100 mTorr exhibited excellent resistance to NaClO aging, while the membrane prepared at 750 °C and 600 mTorr significantly deteriorated. These findings not only highlight a novel preparation route for SiC membranes in a single step via LP-CVD, but also provide new insights about the careful selection of LP-CVD conditions for SiC membranes to ensure their long-term performance and robustness under harsh chemical cleaning conditions. Full article

In recent times, ion implantation has received increasing interest for novel applications related to deterministic material doping on the nanoscale, primarily for the fabrication of solid-state quantum devices. For such applications, precise information concerning the number of implanted ions and their final position within the implanted sample is crucial. In this work, we present an innovative method for the detection of single ions of MeV energy by using a sub-micrometer ultra-thin silicon carbide sensor operated as an in-beam counter of transmitted ions. The SiC sensor signals, when compared to a Passivated Implanted Planar Silicon detector signal, exhibited a 96.5% ion-detection confidence, demonstrating that the membrane sensors can be utilized for high-fidelity ion counting. Furthermore, we assessed the angular straggling of transmitted ions due to the interaction with the SiC sensor, employing the scanning knife-edge method of a focused ion microbeam. The lateral dimension of the ion beam with and without the membrane sensor was compared to the SRIM calculations. The results were used to discuss the potential of such experimental geometry in deterministic ion-implantation schemes as well as other applications. Full article

Silicon carbide (SiC) membrane has emerged as a promising class of inorganic ceramic membranes with many advantageous attributes and has been used for a variety of industrial microfiltration (MF) processes. The state-of-the-art industrial manufacturing of SiC membranes based on the particle sintering method can only achieve an average pore size that ranges from 40 nm to a few micrometers, which is still unsatisfactory for ultrafiltration (UF) applications. Thus, the pore size control of SiC membranes remains a focus of continuing study. Herein, we provide an in situ sol–gel modification strategy to tailor the pore size of SiC membranes by a superficial deposition of SiO₂ onto the membrane surface and membrane pore channels. Our in situ sol–gel modification method is simple and effective. Furthermore, the physical characteristics and the filtration performance of the membrane can easily be controlled by the in situ reaction time. With an optimal in situ reaction time of 30 min, the average pore size of the membrane can be reduced from macropores (400 nm) to mesopores (below 20 nm), and the retention ability for 20 nm fluorescent PS microspheres can be improved from 5% to 93%; the resultant SiC/SiO₂ composite membranes are imparted with water permeance of 77 L·m⁻²·h⁻¹·bar⁻¹, improved anti-protein-fouling properties, excellent performance, and anti-acid stabilities. Therefore, modified SiC/SiO₂ membranes based on the in situ sol–gel process have great potential as UF membranes for a variety of industrial processes. Full article

Tissue engineering (TE) and nanomedicine require devices with hydrophilic surfaces to better interact with the biological environment. This work presents a study on the wettability of cubic silicon-carbide-based (SiC) surfaces. We developed four cubic silicon-carbide-based epitaxial layers and three nanowire (NW) substrates. Sample morphologies were analyzed, and their wettabilities were quantified before and after a hydrogen plasma treatment to remove impurities due to growth residues and enhance hydrophilicity. Moreover, sample biocompatibility has been assessed with regard to L929 cells. Our results showed that core–shell nanowires (SiO₂/SiC NWs), with and without hydrogen plasma treatment, are the most suitable candidate material for biological applications due to their high wettability that is not influenced by specific treatments. Biological tests underlined the non-toxicity of the developed biomaterials with regard to murine fibroblasts, and the proliferation assay highlighted the efficacy of all the surfaces with regard to murine osteoblasts. In conclusion, SiO₂/SiC NWs offer a suitable substrate to develop platforms and membranes useful for biomedical applications in tissue engineering due to their peculiar characteristics. Full article