Search Results (1,383)

The increasing deployment of off-grid photovoltaic–battery energy storage systems (PV–BESSs) has intensified operational demands on battery energy storage, particularly when second-life lithium-ion batteries are employed. Due to aging-induced increases in internal resistance and reduced thermal margins, second-life batteries are more vulnerable to high-current operation at a low state-of-charge (SOC), which aggravates heat generation and accelerates degradation. In this study, an SOC-dependent soft current limiting strategy is proposed that reshapes the discharge current reference under low-SOC conditions while maintaining fixed SOC limits, thereby targeting current-domain protection rather than SOC-boundary adaptation for reliable off-grid operation. The proposed method introduces two SOC thresholds to gradually derate the allowable discharge current, preventing abrupt current changes near the lower SOC bound. A unified MATLAB/Simulink-based framework is developed for a 24 h representative off-grid PV–BESS scenario using a second-order equivalent circuit model coupled with a lumped thermal model. Simulation results show that the proposed current shaping reduces low-SOC current stress and associated Joule heating, leading to moderated temperature rise, while only slightly affecting the unmet load under the tested conditions. These findings indicate that SOC-dependent current shaping can provide a control-oriented means to reduce low-SOC electro-thermal stress in second-life batteries within the studied off-grid PV–BESS framework. Full article

Under fault conditions, Photovoltaic-Storage-Charging Integrated Stations (PSCISs) are regarded as a key resource for enhancing distribution network resilience. However, traditional centralized optimization fails to account for conflicts of interest between the distribution network and PSCISs and neglects the actual response behavior of EV users. To address these issues, a coordinated emergency operation strategy for distribution networks and PSCISs based on the master–slave game is proposed. Firstly, a bilevel optimization framework based on the master–slave game is constructed, where the upper level performs system-level coordination and the lower level handles autonomous decision-making. For the upper level, the minimization of distribution network operation cost is set as the optimization objective by the dispatching center to determine power purchase prices and load shedding rates, which serve as guidance signals for lower-level PSCISs. In terms of the lower level, a dual-factor S-shaped response curve is introduced into the lower-level model to precisely characterize EV users’ nonlinear response behavior to price incentives. Furthermore, based on the signals received from the upper level, the maximization of each PSCIS’s profit is set as the optimization objective to determine the PV output, storage dispatch, and V2G incentive prices. Subsequently, Model Predictive Control (MPC) is employed to implement rolling optimization during the fault period, addressing the source-load uncertainties. Finally, an improved IEEE 33-node distribution network is used for case analysis and validation of the proposed operation strategy. The results indicate that the proposed strategy can effectively coordinate the interests of multiple parties, achieving synergistic improvements in both the economy and reliability of the distribution network. Full article

TiO₂ nanotubes were synthesized using the anodization method on Ti foils and decorated with PbS nanoparticles by the SILAR method at different cycle numbers (10, 15, 20, 25, and 30). These samples were characterized using SEM, TEM, XRD, and microhardness tests. Morphologically, the PbS nanoparticles were evenly dispersed on TiO₂ nanotubes in the shape of small spheres. With an increase in the number of cycles, the size and shape of the nanoparticles increased. This also affected the structure and crystallinity of the PbS NPs, as the crystallite size of PbS increased. The in-depth analysis of the tribological characteristics of the coatings conducted using the scratch test allowed us to evaluate the adhesion of the coatings, a crucial aspect in determining their effectiveness and durability. Furthermore, we found that the wear resistance of the coatings increased with the number of PbS cycles up to 15 cycles. However, for the samples with higher size distribution and crystallite size, such as those with more than 15 cycles, the microhardness continued to decrease. This indicates that the addition of PbS can improve the durability of TiO₂ coatings, making them a potential candidate for advanced surface coatings in demanding engineering applications. Electrochemical measurements were conducted to assess the corrosion resistance of the samples. The electrochemical impedance spectra (EIS) results revealed that the PbS/TiO₂ coatings with 15 deposition cycles exhibited the most effective corrosion resistance, with a dense and uniform distribution of PbS nanoparticles forming a compact barrier that effectively protects against corrosion. The charge transfer resistance (R_ct) and the absorption capacitance (Q_ab) values were higher for the 15-cycle sample (4.49 Ω·cm² and 0.9 Fsⁿ⁻¹cm⁻², respectively). Full article

This paper presents the design, development, and evaluation of a Reinforcement Learning (RL)–based torque-split controller for the regenerative braking system (RBS) in battery electric vehicles (BEVs). The controller employs a Deep Deterministic Policy Gradient (DDPG) agent to distribute the braking demand between regenerative and frictional braking systems with the aim of maximizing energy recovery while adhering to the physical and operational constraints. To capture the charging limitation of the battery, a State-of-Power (SoP) calculation mechanism is incorporated, providing a time-varying bound on the regenerative charge power. The agent is trained in a MATLAB/Simulink environment representing the digital twin of a BEV drivetrain, and considers a mix of different braking scenarios, i.e., light braking, medium braking, hard braking, and emergency braking. The RL’s reward shaping promotes efficient utilization of the SoP-limited regenerative capability while discouraging constraint violations and aggressive control behavior. Across a range of State-of-Charge (SoC) conditions and driving cycles, including the Worldwide Harmonized Light–Vehicle Test Procedure (WLTP) and synthetic random-rich driving cycle, the RL controller consistently delivers promising performance, yielding energy recovery of up to ~98% of the total braking energy available on WLTP type 3 driving cycle while being able to operate closely to the battery SoP limit. The results demonstrate the proposed controller’s capability for adaptive, constraint-aware energy management in BEVs and underline its potential for future intelligent braking strategies. Full article

The molecular chaperone paradigm has shaped modern views of assisted protein folding, yet it does not fully capture the physical context in which de novo folding occurs in cells. A defining feature of the cellular milieu is macromolecular tethering in cis, whereby nascent polypeptides remain physically linked—through covalent or persistent associations—to ribosomes, lipid bilayers, or pre-folded domains of multidomain proteins. Because molecular chaperones have traditionally been defined as reversible binders acting in trans, this cis-acting mode has remained conceptually underappreciated. Cellular macromolecules, by virtue of their steric bulk and surface charges, can suppress aggregation of tethered polypeptides, thereby increasing productive folding yield. By analogy to colloidal stability, this repulsion-mediated control of aggregation suggests that cellular macromolecules can exhibit intrinsic chaperone-like activity largely independent of whether the linkage occurs in cis or in trans. This property provides a conceptual basis for linking cis- and trans-acting chaperoning. Thus, macromolecular tethering in cis may constitute a built-in layer of cellular chaperoning, distinct in physical linkage yet mechanistically related to conventional molecular chaperones. Full article

Zr alloy-shaped charge liners (SCLs) offer broad application prospects due to their multiple post-penetration damage effects. However, research on these liners is still in its early stages. The mechanisms of jet formation and penetration for Zr alloys SCL remain unclear, and the specific contribution of different liner regions to the penetration process is not yet understood. This gap in knowledge has limited their structural design to a black-box correlation between global structural parameters and macroscopic penetration efficiency. To address this gap, a region-tracing Smoothed Particle Hydrodynamics (SPH) simulation was employed. Following a strategy of “wall thickness layering + axial segmentation,” the Zr alloy liner was partitioned into ten characteristic regions. This methodology facilitated the tracking of material transport from each region during jet formation and penetration into an AISI 1045 steel target. The contribution of each region to the penetration depth was then quantitatively assessed via post-processing. For the first time, the “critical region” contributing most to penetration depth was identified, and the influence of the liner’s cone angle and wall thickness on the contribution of each region was revealed. This study enhances the theoretical framework for understanding the damage effects of Zr alloy shaped charge liners. It not only advances the fundamental understanding of jet penetration mechanisms but also provides a theoretical basis for the refined design and performance optimization of these liners. Full article

Metal-chalcogenide compounds with perovskite-type compositions have drawn increasing attention for their optical properties for solar energy conversion. Herein, a new α-type polymorph of the ternary sulfide SrHfS₃ is described, crystallizing in the NH₄CdCl₃ structure type. The yellow-colored plate-shaped crystals were synthesized at 1173 K using an elemental tin flux in an evacuated sealed tube. Its crystal structure was characterized at room temperature using single crystal X-ray diffraction to form in the orthorhombic Pnma space group, with the refined cell parameters of a = 8.5041(4) Å, b = 3.8004(2) Å, c = 13.8935(6) Å, and V = 449.02(4) ų. The structure comprises five independent crystallographic sites, having one Sr, one Hf, and three S sites. The structure can be described as containing one-dimensional chains of distorted HfS₆ octahedra extending down the b-axis to form ${\displaystyle \genfrac{}{}{0pt}{}{1}{\infty }}[$HfS₃]²⁻ strips of edge-sharing octahedra. The Sr atoms act as charge-balancing space fillers in the structure. High-purity bulk samples of α-SrHfS₃ could be prepared for measurement of its bandgap by optical diffuse-reflectance spectroscopy, showing a direct bandgap of 2.1(1) eV. Results of electronic structure calculations are consistent with this bandgap and type. The conduction and valence band edges stem from the respective empty Hf d-orbitals and the filled S p-orbital states. In summary, crystal growth of the α-type polymorph of SrHfS₃ has been demonstrated using a Sn flux approach, which can facilitate future broader synthetic explorations at lower temperatures. Full article

In this investigation, the nonlinear dust-acoustic waves in the lunar terminator region are studied in a three-component complex plasma comprising Boltzmann-distributed electrons and ions and inertial, cold, negatively charged dust grains. The fluid model is reduced, via the reductive perturbation technique, to a planar Korteweg–de Vries (KdV) equation that governs the evolution of small-amplitude dust-acoustic structures in this environment. Hirota’s direct method is then employed to derive exact multiple-soliton solutions, which allow us to examine the parameter dependence of dust-acoustic solitons and to characterize their overtaking collisions. The analysis shows that the soliton polarity and amplitude are controlled by the equilibrium electron–ion density ratio and the electron-to-ion temperature ratio, and that multi-soliton interactions remain elastic, with only finite phase shifts after collision. In the second part of the study, the planar integer KdV model is generalized to a time-fractional KdV (FKdV) equation to incorporate nonlocal temporal memory effects in the dust-acoustic dynamics. This FKdV equation is analyzed using two analytical approximation schemes: the Tantawy technique, recently proposed as a direct and rapidly convergent approach to fractional evolution equations, and the new iterative method, a widely used high-accuracy scheme in the fractional literature. For both methods, higher-order approximations are constructed, and their absolute and global maximum residual errors are quantified. The results demonstrate that the Tantawy technique provides compact approximations with superior accuracy and stability compared with the new iterative method for the present FKdV-soliton problem. The combined integer- and fractional-analytic framework provides a physically transparent framework for understanding how nonlinearity, dispersion, and fractional memory jointly shape dust-acoustic solitary structures in the electrostatically complex lunar terminator plasma, which is of paramount interest for future lunar missions like Luna-25 and Luna-27. Full article

Shaped charge is widely used in petroleum drilling, yet the inherent parametric uncertainty of oil shale introduces significant uncertainties that affect perforation outcomes. The complex coupling of oil shale constitutive parameters under extreme strains poses challenges for uncertainty quantification. A coupled algorithm integrating an improved material point method (MPM) and polynomial chaos expansion (PCE) is presented, and polynomial chaos expansion (PCE) is used to systematically analyze the uncertainty and sensitivity of shaped charge jet penetration depth. Mechanical parameters from oil shale samples at Checun Coal Mine well No. 1 were tested to define key parameter ranges and establish a reliable uncertainty space. A benchmark simulation of a single isolated shaped charge jet validated the algorithm, and Sobol’ global sensitivity analysis identified internal friction angle, density, and Poisson’s ratio as strongly sensitive parameters, while tensile strength, Young’s modulus, and cohesion showed weak sensitivity, supporting surrogate model dimensionality reduction. Composite detonation models of three and five charges further revealed the effects of multi-projectile blast wave coupling on jet dynamics, providing new theoretical insights into cluster effects under high-energy, high-pressure, and extreme-strain conditions. Sensitivity and uncertainty analyses based on surrogate models emphasized the critical influence of internal friction angle alongside Poisson’s ratio and density. A reliable numerical framework is established for multi-physics coupled simulations of geomechanical responses under complex multi-source explosive loading. Full article

Hypochlorous acid (HClO) is widely used as a low-cost and effective disinfectant; however, its instability under heat and light necessitates simple and reliable monitoring methods. Herein, we report a morphology-evolving thin-film colorimetric sensor that enables intuitive visual detection of HClO through simultaneous color and pattern transitions. The sensor integrates two polymer films with distinct charge-state response behaviors, patterned in X-shaped and circular geometries on a single substrate. Upon exposure to HClO, chlorine-induced modification of amide and amine groups alters the surface charge states, thereby switching the adsorption preference for anionic and cationic dyes. This mechanism results in a pronounced transformation from a blue X-shaped motif to a red circular pattern, enabling direct visual discrimination between different HClO concentrations. Quantitative analysis of RGB values confirmed semi-quantitative detection in the sub-millimolar to millimolar range. The sensor exhibited a linear response in the range of 0–3 mM (R² > 0.979) with a limit of detection of 0.103 mM. The sensor further demonstrated practical applicability by tracking photodecomposition of a commercial disinfectant. This work demonstrates pattern-coupled colorimetric sensing as a straightforward, user-friendly approach for HClO monitoring. Full article

In this paper, the effects of gravity-gradient potential on a spacecraft of arbitrary shape are outlined. The potential expressing the planet’s gravity-gradient torque on a triaxial spacecraft is formed. The planet’s shape is considered oblate spheroidal, and the dimensions of the spacecraft are assumed small compared to its distance from the center of the planet. The radial, transverse and normal components of the Lorentz force, in terms of orbital elements, are constructed. The variations in the orbital elements due to both gravity-gradient potential and Lorentz force are derived. The charges per unit mass needed to balance such perturbation are obtained. The symmetrical results in mathematical equations are obvious. The International Space Station (ISS) is used as an example to test our model. A three-dimensional diagram was plotted to illustrate the charge per unit mass with the shape and size of the orbits. Full article

Technological advances such as Vehicle-to-Grid (V2G) have the potential to support renewable energy integration and grid stability, but large-scale deployment depends on users’ willingness to participate, particularly in public charging environments. While prior research has examined V2G from technical feasibility and system-level perspectives, everyday public settings remain unexplored. This study investigates electric vehicle (EV) users’ willingness to engage in V2G services in public spaces, with a focus on incentives, expectations, and how participation aligns with existing routines and parking conditions. A mixed-method approach was applied, combining a survey of 544 car users with two waves of user-centered interviews. The survey data were analyzed using factor analysis and linear regression models, while the interview data were thematically analyzed. The results show that users’ evaluations of V2G are shaped by sustainability expectations, perceived efficiency, and uncertainties, and preferences for public V2G participation are strongly influenced by convenience, clarity of the offer, and perceived control. Home charging practices emerged as a key reference point shaping expectations of public V2G services. Across both methods, simple and transparent incentives, such as reduced charging or parking costs, were consistently preferred over more complex reward models, including point-based systems or dynamic energy trading. Concerns related to control over trips, battery degradation, trust in service providers, and added complexity remain important barriers to participation. The findings highlight the need for user-centered and socio-technical design of public V2G services that align with users’ everyday routines, parking conditions, and expectations to support broader adoption beyond the home context. Full article

Phase-change materials (PCMs), such as paraffin wax, are widely used in latent heat storage (LHS) because they store substantial thermal energy at nearly constant temperature; however, their low thermal conductivity limits heat transfer and slows melting/solidification. In this work, two flat-plate solar collectors are coupled with a paraffin-based LHS unit for low-temperature solar heating, and the design is optimized by introducing improved fin-geometry combinations on both the heat transfer fluid (HTF) tube and shell side. The M-shaped fins combined with rectangular fins significantly enhanced convective heat transfer by generating localized vortices, while the extended surface area improved conduction within the solid PCM, facilitating efficient heat dissipation and accelerating the phase transition. The LHS unit without fins showed complete melting in 67 min. However, fin introduction remarkably mitigated charging duration to 44 min, 52.3% faster than bare tubes having no fins. The experimental melting process exhibited a 7 min delay by comparing experimental and numerical results, achieving complete melting in 51 and 44 min, respectively. Discharging was completed in 48 min. During PCM charging, sensible heating produces a rapid temperature rise with only a small energy increase, but once the PCM entered into the melting range (320–324 K), the energy changed more steeply. Adding fins boosts stored energy from 2.10 MJ to 3.25 MJ (54.8%) and exergy from 0.15 MJ to 0.27 MJ (80.0%), yet exergy remains far smaller than energy (92.9% lower without fins and 91.7% lower with fins), indicating fins enhance total heat storage more than recoverable work potential. Full article

Lithium-ion batteries (LIBs) are pivotal for energy storage in electric vehicles and renewable systems, but how to effectively monitor their conditions and ensure their operational reliability is still a concern today. This study employs electrochemical impedance spectroscopy (EIS) to systematically investigate the evolution of impedance characteristics in nickel–cobalt–manganese oxide (NCM) lithium-ion batteries (LIBs) under varying states of charge (SOCs), states of health (SOHs), temperatures, and mechanical compression displacements. Results reveal that higher SOC and temperature reduce impedance by enhancing ion kinetics and interfacial activity, with $R_{ct}$ (charge transfer resistance) exhibiting a U-shaped dependence on SOC, minimized at 40–60%. As SOH declines from 100% to 80%, $R_{SEI}$ (SEI film resistance) and $R_{ct}$ increase progressively, reflecting SEI thickening and electrode degradation. Mechanical compression (0–8 mm) elevates all resistances, particularly $R_{ct}$ at high SOC, due to structural deformation and hindered diffusion. DRT (distribution of relaxation times) spectra highlight amplified low-frequency peaks with aging and low SOC, underscoring diffusion limitations. These findings elucidate multi-scale failure mechanisms, from interfacial polarization to structural instability, providing a framework for non-invasive health monitoring and lifetime prediction. Full article

This article examines how newsroom routines shape the health, safety, and professional experiences of BIPOC (Black, Indigenous, and People of Color) journalists in U.S. broadcast news. While journalistic norms of objectivity and neutrality often frame risk as evenly shared, this study situates safety within routine newsroom practices to show how risk and institutional support are unevenly distributed, particularly during high-stakes coverage such as protests, door-knocks, and politically charged events. The analysis draws on qualitative, in-depth interviews conducted as part of a larger study on journalists’ identities and definitions of fairness and applies a critical framework attentive to power and postcolonial influences in newsroom organizations. Findings indicate that BIPOC journalists routinely navigate tensions between production demands and personal safety, with their lived experiences in the field frequently diverging from the assumptions of white colleagues and newsroom leadership. Participants describe adapting newsroom routines by setting boundaries, asserting professional judgment, and challenging unsafe expectations. These practices illuminate how newsroom routines are both sites of constraint and negotiation. This article concludes that attention to identity and power within newsroom routines is essential for understanding how fairness, safety, and ethical practice are enacted in contemporary broadcast journalism. Full article