Search Results (1,004)

Long-term monitoring of surface-water dynamics in hyper-arid reservoir systems requires consistent remote-sensing methods that can distinguish open water from bright desert surfaces, shallow water, wet sand, and mixed shoreline pixels. This study evaluates Landsat-derived spectral water indices for delineating surface water in Lake Nasser and the adjacent Tushka Lakes, generates a multi-decadal record of surface-water extent using Google Earth Engine, and places the resulting surface-water patterns in the context of available hydrogeological observations. Landsat TM and OLI surface reflectance imagery was used to compare seven commonly applied water indices (NDWI, EWI, NDX, WRI, AWEI_nsh, TCW, and NWI) based on mapped water area, relative area differences, and classification accuracy metrics derived from 1000 stratified reference samples. Among the tested indices, NDWI provided stable water–land separation (overall accuracy ≈ 93.6%; κ ≈ 0.898) and was selected for long-term mapping. The NDWI-based workflow was implemented in Google Earth Engine to generate quarterly composites of surface-water extent for the period 1987–2026. The resulting time series reveals stable, persistent surface water in the central and southern sectors of Lake Nasser, in contrast to pronounced seasonal and interannual variability in the shallow, intermittently connected Tushka basins. Total mapped water area increased from 2631 km² in 1987 to 8923 km² in early 2026, with Lake Nasser ranging from 2411 to 6060.7 km² and the Tushka Lakes expanding from no mapped water before 1998 to more than 3300 km² during 2025. To assess possible surface–subsurface interaction, daily lake-stage records (1965–2014) and monthly groundwater levels from 44 observation wells were used to estimate potential seepage losses from Lake Nasser to the Nubian Sandstone Aquifer System using Darcy’s law. Annual seepage estimates ranged from 15.58 × 10⁶ to 36.68 × 10⁶ m³/year, suggesting spatial variability in potential lake–aquifer seepage along the western lake margin. The combined remote-sensing and hydrogeologic results provide complementary, non-causal evidence for interpreting where surface-water persistence and estimated seepage may co-occur. Because spatial correlation analysis, calibrated ground-water modeling, full water-budget analysis, and independent field validation were not performed, the inferred seepage–surface-water relation should be regarded as a cautious hypothesis rather than proof of causality. Full article

Shallow aquifers in intensively managed alluvial plains worldwide are increasingly impacted by inorganic nitrogen, yet the simultaneous occurrence and interconversion of nitrate (NO₃⁻–N), nitrite (NO₂⁻–N) and ammonium (NH₄⁺–N) often confound source attribution when single indicators are used. Here, we present a transferable, process-linked framework for diagnosing “tri-nitrogen” (tri-N) pollution that integrates hydrogeochemical evolution, data-driven pattern discovery and receptor-model apportionment. We analyzed 409 shallow-groundwater samples from Shijiazhuang City (central North China Plain) for major ions and tri-N species, interpreted within Piper facies and salinization gradients, and then applied a Gaussian mixture model (GMM) to resolve multivariate hydrochemical–nitrogen end-members. Six clusters (I–VI) depict an interpretable progression from background Ca–HCO₃/Ca·Mg–HCO₃ waters to agricultural NO₃⁻–N enrichment under oxic conditions and a distinct NH₄⁺–N-rich point-source end-member under reducing conditions. An attention-based attribution model indicates that total tri-N, Na⁺, NO₃⁻–N, the NO₂⁻ fraction and SO₄²⁻ are the primary discriminators of cluster structure. Species-resolved positive matrix factorization (US EPA PMF 5.0) quantifies dominant controls, with agricultural leaching–nitrification explaining most NO₃⁻–N (Factor 6, 87.9%) and sewage/manure inputs dominating NH₄⁺–N (Factor 3, 95.3%), while NO₂⁻–N reflects mixed contributions consistent with redox-interface transitions. Beyond this case study, the combined GMM–interpretability–PMF workflow provides a general template for separating non-point versus point tri-N inputs and for prioritizing management actions in shallow aquifers where isotope or tracer data are limited. Full article

Groundwater quality remains insufficiently characterized in the rural agriculture–residential interface of the Huaibei Plain, particularly with respect to nitrate (NO₃⁻) occurrence, hydrochemical controls, source contributions, and population-specific health risks. In this study, multivariate statistical analysis, source apportionment models, and health risk assessment models were applied to investigate the hydrochemical characteristics of groundwater and related non-carcinogenic risks to different populations. NO₃⁻ content exceeded the World Health Organization (WHO) guidelines for drinking water in 60.0% and 62.5% of wet- and dry-season groundwater, respectively. Groundwater NO₃⁻ was mainly influenced by agricultural non-point inputs and domestic sewage, whereas major-ion composition was primarily governed by water–rock interactions. Our deterministic health risk assessment model reveals that the hazard index (HI) exceeded the acceptable threshold of 1.0 in 76.25%, 65.00%, 66.25%, and 56.25% of groundwater samples for infants, children, adult females, and adult males, respectively. These results indicate that continuous monitoring, improved sewage collection, and more controlled nitrogen management are required in the rural agricultural–residential interface of the Huaibei Plain with regard to shallow domestic groundwater. Full article

The tritium–helium-3 (³H/³He) dating method was applied to quantify groundwater apparent ages and estimate the migration of anthropogenic tritium in the shallow alluvial aquifer surrounding the Paks Nuclear Power Plant (Hungary). Groundwater samples were collected from monitoring wells between 2013 and 2016 and analyzed for tritium and dissolved noble gases. The investigated aquifer consists mainly of highly permeable sand and gravel deposits hydraulically connected to the Danube River. Reference wells indicate apparent groundwater ages between 26 and 43 years, with an average apparent ³H/³He age of approximately 37 years. Wells located within the operational area of the power plant show apparent ³H/³He ages ranging from 1.3 to 14.1 years, reflecting the transport of tritium released during leakage events associated with damaged sewer pipelines between 2005 and 2007. The spatial distribution of apparent ages reveals heterogeneous groundwater flow paths, and highlights the influence of well-screen sampling on age interpretation. The paper demonstrates that anthropogenic tritium released from nuclear infrastructure can serve as an effective age dating method and improve conceptual models of flow dynamics in shallow alluvial aquifers. Full article

In mountainous river basins, groundwater systems are sustained by complex recharge processes and geological heterogeneity, making groundwater flow simulation challenging in data-scarce regions where hydrological inputs are often assumed to be spatially uniform. This study developed a heterogeneous geological model of the Kofu Basin, Japan, using multiple boreholes and simulated the groundwater flow by integrating MODFLOW with climate-driven recharge outputs from SWAT+. Simulated groundwater flow was evaluated against findings from previous stable isotope studies to assess the plausibility of the simulated recharge system. After calibration, the model performance improved substantially: RMSE decreased by 91.28%, MAE decreased by 84.38%, and NSE increased from 0.9530 to 0.9996. Independent validation showed good regional agreement between observed and simulated groundwater heads (R² = 0.9307; NSE = 0.9254), although RMSE and MAE remained relatively high at 32.70 m and 19.76 m, respectively, suggesting remaining uncertainty in local-scale groundwater head simulation. Simulated velocity vectors indicated localized shallow flow and more coherent regional basinward flow in the deeper aquifer. This pattern is consistent with the interpretation that mountain-derived recharge contributes to the deeper regional groundwater system. The results highlight the value of combining hydrogeological models and geochemical evidence to support recharge-process interpretation in complex mountainous basins. Full article

Shallow groundwater systems of rural municipalities are highly vulnerable to long-term contamination from former on-site sanitation systems, while the hydrochemical response of the aquifer after sewerage network development may be delayed by several factors. In the present study, a total of 147 shallow groundwater samples collected during the summer sampling campaigns of 2018, 2019, 2023, and 2024 were analyzed for general water-quality parameters including pH, EC, NH₄⁺, NO₂⁻, NO₃⁻, PO₄⁻, Cl⁻, SO₄²⁻, microelements, and potentially toxic elements, including As, Pb, Cd, Ni, Cu, Zn, Fe, and Mn. The dataset was evaluated using descriptive statistics, Piper, Wilcox, and Gibbs diagrams, hierarchical cluster analysis, principal component analysis, and GIS-based spatial interpolation. The results indicate that, more than ten years after sewerage network development (2014), shallow groundwater in the study area still shows considerable contamination, primarily characterized by elevated mean concentrations of ammonium (0.836 mg/L), nitrate (177.43 mg/L), and chloride (313.26 mg/L), accompanied by high electrical conductivity (3115 µS/cm) and sodium enrichment (378.12 mg/L). Spatial and boxplot analyses of SAR further indicated increasing sodium-related heterogeneity after 2018, with higher local SAR values in 2023–2024. Hydrochemical diagrams revealed a shift towards Ca-Cl type to Na–Cl types, while multivariate analyses confirmed that salinity enrichment, nitrate contamination, water–rock interaction and redox-sensitive trace element mobilization act as overlapping but partly separable controls. The nitrate–chloride source plot indicated mixed contamination origins, dominated by residual sewage influence and manure-related inputs, with diffuse agricultural nitrogen leaching. Arsenic was used as a supporting indicator of mixing with wastewater; however, As was no longer detectable in most of the investigated wells, suggesting a marked reduction in the former wastewater leakage. These results support the slow attenuation of contamination in the shallow groundwater system affected by former wastewater infiltration and highlight the need for continuous monitoring. Full article

This study investigates nitrogen sources and biogeochemical pathways in a highly urbanized shallow aquifer in Shinagawa Ward, Tokyo, using an integrated approach combining hydrochemical analysis, multivariate statistics (PCA and K-means cluster analysis), and stable nitrogen isotopes (δ¹⁵N-NH₄⁺, δ¹⁵N-NO₃⁻, δ¹⁵N-DON, and dual δ¹⁵N–δ¹⁸O-NO₃⁻). K-means clustering (K = 2, silhouette = 0.54) partitioned all 41 samples into a background group (n = 34) and an ion-enriched group (n = 7; wells sbi 1, 2, 3, 4, 5, 13, and 19), with the latter exhibiting hydrochemical signatures consistent with localized sewage leakage. The convergence of hydrochemical, multivariate, and isotopic evidence suggests that soil organic matter may represent the dominant diffuse background source of nitrogen across the study area. DON constitutes the dominant fraction of total dissolved nitrogen (TDN), while the linear correlations between TDN and DON concentrations (r = 0.77, p < 0.001) and between δ¹⁵N-TDN and δ¹⁵N-DON (r = 0.88, p < 0.001) indicate a common primary source. The dominance of DON combined with the theoretical inverse relationship between δ¹⁵N-DON and DON concentration is consistent with active soil DON mineralization, supported by an isotope fractionation factor (ε = −4.4 ± 0.78‰). Dual isotope analysis of NO₃⁻ (δ¹⁵N–N–δ¹⁸O slope = 0.51) points towards denitrification as an ongoing process in the aquifer. Taken together, the isotopic variations among nitrogen species suggest a transformation sequence from soil organic nitrogen → DON → NH₄⁺/NO₃⁻ → N₂, though each step in this sequence is supported to varying degrees of confidence. These findings highlight the value of δ¹⁵N-DON as a tracer for nitrogen source attribution and cycling in urban groundwater systems, and underscore the importance of considering all dissolved nitrogen fractions in contamination assessments. Full article

Surface water-groundwater interaction zones are critical ecohydrological interfaces in arid regions, yet quantitative spatiotemporal patterns and soil-vegetation responses under coupled water-salt-heat gradients remain poorly documented. Based on a one-year monitoring period (August 2024–August 2025) at four sites along a river-to-desert transect (LW3: 25 m, LW2: 200 m, LW1: 300 m, LW4: 400 m from the Niya River) in the hyper-arid Tarim Basin, this study reveals the following quantitative patterns. Groundwater depth increased with distance from the river and followed an annual decrease-increase trend, with an anomalous shallow peak in March 2025 (−20 cm) linked to precipitation recharge. Soil temperature stability increased with depth: the 20 cm layer recorded the widest annual fluctuation (e.g., −1.5 °C to 24 °C at LW1), whereas the 80 cm layer varied only between approximately −0.2 °C and 28 °C. Proximity to the river dampened thermal extremes. Shallow soil moisture was highly dynamic (with a coefficient of variation [CV] reaching 40–50% at LW1 and LW4), while deeper layers remained stable; LW3 near the river stayed saturated year-round (CV = 0). Soil electrical conductivity (EC) decreased with distance from the river: LW3 exhibited the highest surface values (5000–16,000 μS cm⁻¹), whereas LW1 recorded the lowest (1000–2700 μS cm⁻¹). Vegetation performance was governed by coupled water-salt conditions rather than moisture alone: P. australis at LW1 achieved the tallest growth (>200 cm) and highest photosynthetic rates (20.25–37.38 μmol m⁻² s⁻¹), outperforming LW3 (104 cm, winter photosynthesis dropping to 2.01) and LW4 (~100 cm). Correlation analysis further showed strong vertical temperature coupling (r > 0.96 across all depths) and depth-stratified water-salt relationships (e.g., EC-volumetric water content r = 0.95 at 20 cm in LW4), reflecting spatial differentiation driven by freeze-thaw cycles, evaporative enrichment, and homogeneous silt-textured soils (54–96% fine fraction). These quantitative findings provide a detailed observational baseline for riparian ecohydrology in hyper-arid inland rivers and underscore that sustainable vegetation management requires balancing water availability against salinity stress. Full article

Urban water insecurity is an increasingly critical challenge in rapidly urbanizing regions of the Global South, driven by population growth, environmental degradation, infrastructure limitations, and institutional constraints. Kathmandu Valley, Nepal, exemplifies these interconnected pressures. This study presents a systematic review of 45 peer-reviewed and selected grey literature sources published between 2000 and 2025, conducted in accordance with the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines. Studies were included if they examined drinking water contamination, public health risks, household coping practices, wastewater-related exposure, or governance dynamics in Kathmandu Valley, Nepal. Findings were synthesized using a narrative thematic approach. The review identifies widespread contamination across municipal supply systems, groundwater, tanker water, traditional water sources, and household-stored water. Microbial contamination, particularly total coliforms, fecal coliforms, and Escherichia coli, emerged as the most consistently reported and immediate public health concern. Chemical and physicochemical contaminants, including ammonia, iron, arsenic, nitrate, and turbidity, were also widely reported, especially in shallow and deep groundwater systems. Seasonal dynamics further influenced exposure risks, with increased microbial contamination during monsoon periods and greater dependence on alternative and less regulated water sources during dry seasons. The findings further indicate that unsafe water exposure is associated with a substantial burden of waterborne diseases and emerging risks such as antimicrobial resistance. Although household water treatment practices reduced contamination in some cases, risks often persisted due to recontamination during storage and handling. These burdens disproportionately affected marginalized and peri-urban populations with limited access to safe and reliable water infrastructure. The review also highlights persistent governance challenges, including institutional fragmentation, weak regulatory enforcement, inadequate infrastructure investment, and growing dependence on informal water supply systems. Together, these conditions contribute to a hybrid urban water system in which formal and informal sources coexist without consistent quality control. Overall, the evidence demonstrates that water insecurity in Kathmandu Valley is a systemic condition shaped by the interaction of environmental contamination, unequal exposure, household coping limitations, and fragmented governance. By integrating environmental, public health, and governance evidence, this review advances understanding of urban water insecurity in rapidly urbanizing contexts and highlights the need for integrated, equity-oriented, and governance-informed interventions. These findings have broader relevance for cities across the Global South experiencing similar environmental and infrastructural pressures. Full article

Liquefaction phenomena are strongly influenced by the depositional evolution of the area, including sediment grain size, depositional age, shallow layering, and groundwater depth. This study focuses on a 560 km² wide sector of the eastern Po River Plain (northern Italy), encompassing part of the modern Po Delta, to evaluate the susceptibility of the different geological units to liquefaction. A comprehensive dataset was compiled, integrating lithological, chronological (¹⁴C), geomorphological, hydrological, and hydrogeological information, together with satellite imagery, historical and modern maps, archaeological evidence, and subsurface data from core drilling and CPTu tests. The integrated analysis allowed us to reconstruct a liquefaction susceptibility map recognizing four classes: very high (4% of the investigated area), high (26%), moderate (20%), and non-susceptible (50%). CPTu-based statistical analyses confirm that the Liquefaction Potential Index (LPI) increases with higher susceptibility classes and decreases with increasing groundwater depth (0.5, 1.5, and 3.0 m scenarios). These results provide a scientific basis to support sustainable land management and governance strategies in the Po Delta, an area of high environmental, cultural, and economic value, a large sector of which is included in the Natura 2000 network. Full article

Geological observations, excavation performance records, field monitoring data, and support applications obtained during construction were examined in relation to excavation-induced structural behavior. Monitoring systems, including tiltmeters, extensometers, and distomat measurements, were used to evaluate deformation behavior in buildings located near the tunnel alignment. This study additionally discusses the differences between the preliminary FEM-based deformation predictions reported during the design stage and the structural behavior observed during excavation. The results indicate that groundwater-sensitive claystone sections generated significant excavation and stability problems despite controlled excavation and support measures. High groundwater inflow (30–35 L/s) caused base instability, unfavorable excavation conditions, and increased deformation risks. Field observations indicated substantially greater deformation behavior than the preliminary FEM-based predictions reported during the design stage. The findings demonstrate that shallow urban tunneling in weak and groundwater-sensitive formations may generate more complex ground–structure interactions than those represented in preliminary numerical assessments. This study highlights the importance of continuous field monitoring, adaptive support strategies, groundwater control measures, and observational excavation management practices for improving tunnel safety and reducing risks to nearby urban structures. Full article

Groundwater contamination by redox-sensitive elements (RSEs) such as arsenic (As), chromium (Cr), vanadium (V), and selenium (Se) pose a critical challenge in alluvial aquifers, where seasonal hydrological forcing drives dynamic hydrogeochemical and redox conditions. This study investigates the seasonal evolution of groundwater hydrogeochemistry and multi-metal behavior in shallow aquifers of the Mid-Gangetic Plain, India, with particular emphasis on the role of seasonal redox decoupling. Monsoon conditions were dominated by strongly reducing environments (ORP: −150 to −70 mV), predominantly Ca–Mg–SO₄ and Na–Cl type facies. Under these conditions, significant correlations among RSEs in particular (As–V, As–Se) indicated coupled mobilization governed by the reductive dissolution of Fe–Mn (oxyhydr)oxides. Monsoon groundwater also exhibited strong associations between RSEs and agronomic indicators (NO₃⁻, SO₄²⁻), suggesting the influence of recharge-mediated agricultural inputs on redox-sensitive geochemical processes. In contrast, post-monsoon conditions showed a clear transition to sub-oxic states (ORP up to +121 mV) and were dominated by Ca–Mg–HCO₃ facies, accompanied by substantial increases in bicarbonate (~372%), electrical conductivity (~62%), and total dissolved solids (~21%). Despite the partial oxidation of the aquifer system, redox-sensitive metals did not respond uniformly. Instead, inter-element correlations weakened or disappeared, indicating a transition from coupled to decoupled contaminant behavior. Arsenic concentrations increased up to 20.8 µgL⁻¹, whereas Cr and V displayed variable enrichment controlled by alkali-induced desorption and carbonate-mediated surface interactions. This transition reflects seasonal redox decoupling, whereby seasonal redox shifts lead to metal-specific rather than coordinated multi-metal behavior. We propose a Seasonal Redox Decoupling Framework (SRDF) to explain the shift from coupled reductive release during monsoon conditions to selective mobilization pathways in the post-monsoon period. These findings demonstrate that seasonal redox shifts control not only metal concentrations but also inter-element relationships, leading to metal-specific risk profiles. This underscores the need for seasonally adaptive monitoring and management strategies in hydrologically dynamic alluvial aquifers. Full article

The desert bottomland of Northern Shaanxi, China, features an ecologically fragile environment with a pronounced mismatch between abundant coal resources and scarce water resources. Large-scale coal mining often impairs the water-resisting capacity of overlying strata, leading to shallow groundwater depletion, surface drought, and vegetation degradation. This study focuses on determining the height of the water-conducting fractured zone (WCFZ) and assessing shallow groundwater loss in such ecologically sensitive mining areas. Through analysis of measured WCFZ heights, the empirical formulas currently specified in national codes are found to be inapplicable to the study area. A multi-factor nonlinear prediction model, better suited to local conditions, is therefore established using multiple nonlinear regressions. Taking the Jinjitan Coal Mine as a case study, a 3D hydrogeological conceptual model is developed using FEFLOW to simulate phreatic water responses to mining activities. The results indicate a maximum phreatic water drawdown of 3–4 m, with post-mining burial depths predominantly ranging from 5 to 8 m, reaching a warning level that requires attention and mitigation. This study provides a valuable reference for water hazard prevention and ecological protection in desert bottomland regions. Full article

Groundwater is an important water source in China, yet its quality is increasingly threatened by industrial activities, including petroleum exploration. This study assessed seasonal hydrochemical characteristics, groundwater quality, and human health risks of shallow groundwater in the central Jianghan Plain, with emphasis on potential influences of petroleum-related activities. Groundwater samples collected during dry and wet seasons were analyzed for hydrochemical parameters, classified by hydrochemical facies, and evaluated using the water quality index (WQI), non-carcinogenic health risk assessment, and spatial distribution analysis. Groundwater was generally weakly alkaline and mainly hard to extremely hard, with HCO₃–Ca·Mg as the dominant hydrochemical facies and some samples shifting toward mixed HCO₃–Cl–Ca·Mg types. Most parameters had higher mean concentrations in the dry season, indicating wet-season dilution. Rock weathering dominated groundwater chemistry, whereas evaporation had limited influence. Elevated Cl⁻ suggested possible effects of petroleum-related activities. Overall groundwater quality was poor, with mean WQI values of 394.23 and 292.50 in the dry and wet seasons, respectively. Children showed greater vulnerability than adults, and Fe and As were the main contributors to non-carcinogenic risk. WQI and health-risk hotspots were concentrated near Zhouji and adjacent petroleum exploration areas, indicating the need for long-term monitoring and risk management. Full article

Tree-based machine learning (ML) models offer a powerful classification framework for rapidly screening groundwater for heavy metal contamination and associated health risks. This study applies several tree-based algorithms to classify groundwater samples from the Jamshedpur Township area, Jharkhand, India, as safe or unsafe with respect to selected heavy metals, using physicochemical parameters as predictors and WHO/BIS limits as class thresholds. Groundwater samples collected from shallow and deeper wells were analyzed for pH, EC, TDS, and heavy metals such as As, Pb, Cd, Cr, Ni, Cu, Zn, Fe and Mn, and compared with drinking water standards to define binary class labels. Groundwater samples were classified into safe and unsafe categories based on WHO/BIS standards and health risk thresholds (HI > 1, CR > ${10}^{-4}$). Health risk assessment indicated significant non-carcinogenic and carcinogenic risks, particularly among children. Decision Tree, Random Forest, Gradient Boosting, and an Optimized Forest-type ensemble were trained and evaluated using accuracy, precision, recall, F1-score, and ROC–AUC, supported by confusion matrices. The Optimized Forest and Random Forest models yielded the highest classification performance, achieving high recall for unsafe samples, which is critical for public health screening, while feature importance analysis highlighted EC, TDS, pH, and specific ions as key predictors. The results indicate that tree-based ML models using routinely measured water quality parameters can serve as efficient decision-support tools for rapid identification of heavy metal risk zones in Jamshedpur Township and similar industrial urban environments. Full article