Search Results (99)

Anthropogenic air pollution represents a significant threat to both environmental and human health, with nitrogen oxides (NO_x) playing a substantial role in the formation of photochemical smog, acid rain, eutrophication, and respiratory diseases. In Bangladesh, NO_x emissions primarily originate from combustion sources such as road transportation, power generation, and industrial activities, while natural sources include lightning, wildfires, and soil emissions. Furthermore, ammonia emissions from fertilizers and livestock exacerbate air quality issues in both urban and rural settings. Despite the acknowledgment of vehicular and industrial contributions, comprehensive and systematic assessments of NO₂ trends across the nation remain scarce. This study presents a complementary, side-by-side assessment of ground-based NO₂ measurements from the Department of Environment (DoE) with atmospheric NO₂ retrieved from the Sentinel-5P TROPOMI Level-3 product via Google Earth Engine (GEE). Spatial distribution patterns of both ground-level and atmospheric NO₂ were analyzed using ArcGIS Pro, along with seasonal and interannual trend assessments from 2018 to 2024. Results indicated pronounced spatial and temporal variability in NO₂ concentrations. The highest levels were consistently recorded over Dhaka and surrounding industrial zones, with moderate accumulation in Chattogram. Winter months (December–February) exhibited hazardous concentrations, with a national maximum of 205.21 µg/m³, while monsoon periods recorded the lowest levels overall, as reflected in its seasonal mean (see below). Seasonal averages indicated the highest concentrations in winter (35.03 µg/m³), followed by pre-monsoon (29.16 µg/m³), with monsoon recording the lowest seasonal mean (19.94 µg/m³). Long-term analysis showed the highest national annual mean NO₂ con-centration in 2018 (44.32 µg/m³), decreasing to 14.81 µg/m³ by 2024, with non-monotonic year-to-year fluctuation in the intervening period (2020–2021 data were unavailable). These findings underscore the necessity for stricter emission regulations and targeted mitigation measures. As a policy recommendation, this may include the implementation of NO_x-selective catalytic reduction (SCR) using NH₃ over metal oxide and zeolite catalysts. This study provides evidence-based insights to support cleaner air initiatives and sustainable environmental management strategies in Bangladesh. Full article

Supported Pt catalysts are highly active for the selective catalytic oxidation of ammonia (NH₃-SCO), but their practical use is limited by poor N₂ selectivity and insufficient hydrothermal durability under high-temperature exhaust conditions. Herein, we report a composition-regulated high-entropy oxide interface strategy to stabilize Pt–Cu dual sites and steer NH₃ oxidation toward selective N₂ formation. A series of fluorite-type Ce-based high-entropy oxides, including CeZrLaPrYO_x, CeSmLaPrYO_x, and CeSnLaPrYO_x, were constructed as thermally robust supports for Pt and Cu loading. Among them, PtCu/HEO-Zr calcined at 1000 °C exhibits the best NH₃-SCO performance, achieving 90% NH₃ conversion at 260 °C while maintaining N₂ selectivity above 80% over a broad temperature window of 100–300 °C under a high weight hourly space velocity of 100,000 mL·g⁻¹·h⁻¹. More importantly, after harsh hydrothermal aging at 800 °C with 10 vol% H₂O for 12 h, the catalyst shows negligible activity loss and nearly unchanged N₂ selectivity, demonstrating exceptional structural and catalytic robustness. Structural and surface analyses reveal that Zr incorporation optimizes the fluorite high-entropy lattice, increases oxygen vacancy concentration, promotes lattice oxygen mobility, strengthens surface acidity, and enriches active Cu²⁺ species, thereby enhancing the interfacial cooperation between NH₃ activation and oxygen-assisted intermediate conversion. In situ DRIFTS further reveals that PtCu/HEO-Zr favors an O_lat-assisted internal selective catalytic reduction pathway, in which adsorbed NH₃ is activated to -NH₂ species and subsequently reacts with lattice oxygen-derived intermediates to form N₂O₂²⁻-like species that decompose into N₂ and H₂O. Meanwhile, the formation of nonselective NO_x and N₂O products is suppressed. This work highlights high-entropy oxide-supported Pt–Cu interfaces as a promising platform for designing hydrothermally durable and N₂-selective NH₃-SCO catalysts. Full article

Electrocatalytic nitric oxide reduction (NORR) shows great potential for mitigating NO_x emissions from motor vehicles and other internal combustion engine exhausts, enabling the resource utilization of pollutant NO and the synthesis of NH₃ under mild conditions. The overall performance of NORR largely depends on the development of efficient electrocatalysts. Based on a coordination-engineering strategy, this study constructs a series of Sc-based single-atom catalyst systems coordinated with nonmetal heteroatoms (X = B, C, O, Si, P, S, As, Se, Te), denoted as Sc@XN₃, and systematically investigates their NORR reaction pathways, limiting potentials (U_L, the minimum applied potential required to make all elementary steps downhill in free energy), and selectivity using density functional theory (DFT) calculations. The results indicate that Sc@CN₃, Sc@PN₃, and Sc@SN₃ possess relatively low U_L, with values of −0.17, −0.31, and −0.07 V, respectively, among which Sc@SN₃ is thermodynamically the most favorable. Moreover, Sc@CN₃ and Sc@SN₃ can suppress the hydrogen evolution reaction (HER) and the formation of N₂O/N₂ by-products, thereby affording higher selectivity toward NH₃ formation. Considering the characteristics of NO_x emissions from engine exhaust, these coordination-engineered Sc centers show promising potential for future electrified aftertreatment systems that couple NO_x control with ammonia-based energy utilization in vehicles. This study clarifies at the atomic scale how the coordination environment modulates the electronic structure and catalytic behavior of Sc single-atom centers and provides theoretical guidance for the rational design of high-performance NORR electrocatalysts targeted at automotive exhaust NO_x control. Full article

Effective abatement of nitrogen oxides (NO_x) is achieved by ammonia selective catalytic reduction (NH₃-SCR). In this paper, the effects of single WO₃ doping and WO_x-VO_x co-doping into the MnO_x/TiO₂ catalyst on NH₃-SCR of NO_x removal, sulfur and water resistance, and reaction mechanisms were systematically investigated. The 5MnO_x/TiO₂, WO₃-5MnO_x/TiO₂, and WO₃-V₂O₅-5MnO_x/TiO₂ were prepared using the incipient-wetness impregnation method. Furthermore, the monolithic WO₃-V₂O₅-5MnO_x/TiO₂-CC (cordierite support) catalyst involved a coating process. The WO₃-V₂O₅-5MnO_x/TiO₂ catalyst demonstrated superior NO conversion and maintained over 80% activity following prolonged exposure to SO₂ and H₂O. Characterization results indicated that the introduction of WO₃ regulated Mn valence through the formation of W-O-Mn bonds. The synergistic effect of V₂O₅ and WO₃ further promoted electron transfer, increased surface chemisorbed oxygen and oxygen vacancies, and strengthened reactant adsorption and activation. In situ DRIFTS analysis suggested that WO₃ modulated the reaction pathway, and while 5MnO_x/TiO₂ followed the Langmuir–Hinshelwood (L-H) mechanism, both WO₃-5MnO_x/TiO₂ and WO₃-V₂O₅-5MnO_x/TiO₂ exhibited a combined L-H and Eley–Rideal (E-R) pathway. This study confirmed that WO₃ played a crucial regulatory role in both single-metal and multi-metal systems, and the synergistic interaction between V₂O₅ and WO₃ was the key to achieving superior denitration performance and poisoning resistance. Full article

A novel K-resistant CeSbTi mixed oxide catalyst was prepared by co-precipitation method for ammonia selective catalytic reduction (NH₃-SCR) of NO_x. The experimental results show that the introduction of Sb₂O₅ can significantly improve the catalytic activity of the CeTi catalyst. The modulated CeSbTi catalyst has good resistance to K, and the NO_x conversion rate was as high as 95% after K poisoning. Its superior catalytic activity could be ascribed to the large specific surface area with increased acid sites and more oxygen defects and Ce³⁺ species after the introduction of Sb₂O₅, which prompt NH₃ adsorption and activation. In addition, NH₃-SCR reaction over CeSbTi and K/CeSbTi catalysts follows the E-R mechanism. The introduced Sb-O bond as the base capture site preferentially binds to potassium and releases part of the active Ce sites, thus retaining more acid sites and oxygen defects to a certain extent. Full article

A 660 MW coal-fired unit was investigated to clarify the combustion behavior over a wide load range and the effects of static mixers on selective catalytic reduction (SCR) performance. A full-process CFD model covering the furnace, rear pass duct, and SCR system was established, and the combustion characteristics, NO_x formation, and SCR performance were analyzed over a boiler load range of 25–100%. The results showed that, as the boiler load decreased, the furnace heat release weakened, the high-temperature zone contracted, and the flame center shifted downward, with more pronounced flame maldistribution at 25% load. The average NO_x concentration at the SCR inlet first decreased and then increased with decreasing boiler load, reaching a minimum at 75% load. Without a static mixer, the NO_x concentration at the SCR inlet increased from 238 mg/Nm³ at 100% load to 312 mg/Nm³ at 25% load. After a static mixer was installed, the distance required for NH₃ homogenization downstream of the ammonia injection grid was markedly shortened, and the uniformity of the velocity, NH₃ concentration, and temperature fields at the SCR catalyst inlet was improved. In particular, the coefficient of variation in NH₃ concentration decreased from about 4–5% to about 2–3%, while the denitrification efficiency increased by about 1–5 percentage points compared with the case without a static mixer. The variation in denitrification efficiency among different boiler loads was also significantly reduced, indicating improved adaptability of the SCR system to wide-load operation. Among the tested configurations, the static mixer with small blades and a larger blade angle relative to the vertical plane showed the best overall performance. These results provide useful guidance for SCR system improvement in coal-fired units operating over a wide load range. Full article

The emission of hydrogen cyanide (HCN) from formaldehyde (CH₂O) during ammonia-assisted selective catalytic reduction (NH₃-SCR) remains a critical challenge for aftertreatment of bio-hybrid fuel combustion exhaust. The mechanistic details of HCN formation are still poorly understood, especially on widely deployed commercial catalysts like Cu-SSZ-13. In this work, we employed density functional theory calculations in combination with the Energetic Span Model to elucidate HCN formation pathways from CH₂O in the presence of NO₂ and H₂O over Cu-SSZ-13. The results revealed the HCN formation pathway with intermediate methylene imine as the dominant one under typical reaction conditions. These findings resonate very well with reports of hexamethylenetetramine (HMT) formation during NH₃-SCR with CH₂O, for which methylene imine is a critical intermediate. Turnover frequency (TOF) estimations highlighted the strong influence of NO₂ and H₂O: higher NO₂ concentrations promoted CO selectivity and suppressed HCN by oxidizing CH₂O to HCOOH, while lower H₂O enhanced HCN formation. These findings establish a detailed mechanistic framework for HCN emission on Cu-SSZ-13 and suggest that controlling NO₂/NO_x ratios and water content can mitigate HCN formation during NH₃-SCR. Full article

Underground mining environments present elevated occupational health risks, primarily due to substantial exposure to diesel exhaust emissions within confined and poorly ventilated spaces. This study assesses the real-world performance of two advanced retrofit emission control systems—Proventia NOxBuster and Purifilter—installed on underground mining trucks operating in a Spanish mine. Emissions of carbon monoxide (CO), nitric oxide (NO), and nitrogen dioxide (NO₂) were quantified using a Testo 350 multigas analyser, while ultrafine particle (UFP) concentrations were measured with an Engine Exhaust Particle Sizer (EEPS-3090) equipped with a thermodiluter. Controlled tests under both idling and acceleration conditions revealed substantial reductions in pollutant emissions: CO decreased by 60–98%, NO by 51–92%, and NO₂ by 20–87%, depending on the system and operational phase. UFP concentrations during idling dropped by approximately 90%, from 542,000 particles/cm³ in untreated trucks to below 50,000 particles/cm³ in retrofitted vehicles. Under acceleration, the Proventia NOxBuster achieved reductions exceeding 95%. Conversely, Purifilter-equipped trucks exhibited a counterintuitive increase in UFPs within the 5.6–40 nm range, potentially due to ammonia slip events during selective catalytic reduction (SCR). Despite these discrepancies, both systems demonstrated considerable mitigation potential, albeit highly dependent on exhaust temperature (optimal: 200–450 °C), urea dosing precision, and maintenance protocols. This work underscores the necessity of in situ performance verification, regulatory vigilance, and targeted intervention strategies to protect underground workers effectively. Further investigation is warranted into the long-term health benefits, system durability, and nanoparticle emission dynamics under variable load conditions. Full article

The emissions from biomass combustion systems have recently been the subject of increased attention. In addition to elevated concentrations of particulate matter and hydrocarbons (HCs) in the flue gas, significant levels of NO_x emissions occur depending on the used fuel, such as biogenic residues. In response to legal requirements, owners of medium-sized plants (≈100 kW) are now also forced to minimize these emissions by means of selective catalytic reduction systems (SCR). The implementation of a selective sensor is essential for the efficient dosing of the reducing agent, which is converted to ammonia (NH₃) in the flue gas. Preliminary laboratory investigations on a capacitive NH₃ sensor based on a zeolite functional film have demonstrated a high sensitivity to ammonia with minimal cross-influences from H₂O and NO_x. Further investigations concern the application of this sensor in the real flue gas of an ordinary wood-burning stove and of combustion plants for biogenic residues with an ammonia dosage. The findings demonstrate a high degree of agreement between the NH₃ concentration measured by the sensor and an FTIR spectrometer. Furthermore, the investigation of the long-term stability of the sensor and the poisoning effects of SO₂ and HCl are of particular relevance to the laboratory measurements in this study, which show promising results. Full article

In response to increasingly stringent emission regulations, low-carbon fuels have received significant attention as sustainable energy sources for internal combustion engines. This study investigates four representative low-carbon fuels, methane, methanol, hydrogen, and ammonia, by systematically summarizing their combustion characteristics and emission profiles, along with a review of existing after-treatment technologies tailored to each fuel type. For methane engines, unburned hydrocarbon (UHC) produced during low-temperature combustion exhibits poor oxidation reactivity, necessitating integration of oxidation strategies such as diesel oxidation catalyst (DOC), particulate oxidation catalyst (POC), ozone-assisted oxidation, and zoned catalyst coatings to improve purification efficiency. Methanol combustion under low-temperature conditions tends to produce formaldehyde and other UHCs. Due to the lack of dedicated after-treatment systems, pollutant control currently relies on general-purpose catalysts such as three-way catalyst (TWC), DOC, and POC. Although hydrogen combustion is carbon-free, its high combustion temperature often leads to elevated nitrogen oxide (NO_x) emissions, requiring a combination of optimized hydrogen supply strategies and selective catalytic reduction (SCR)-based denitrification systems. Similarly, while ammonia offers carbon-free combustion and benefits from easier storage and transportation, its practical application is hindered by several challenges, including low ignitability, high toxicity, and notable NO_x emissions compared to conventional fuels. Current exhaust treatment for ammonia-fueled engines primarily depends on SCR, selective catalytic reduction-coated diesel particulate filter (SDPF). Emerging NO_x purification technologies, such as integrated NO_x reduction via hydrogen or ammonia fuel utilization, still face challenges of stability and narrow effective temperatures. Full article

Selective catalytic reduction filter (SDPF) technology constitutes a critical methodology for controlling nitrogen oxide (NOx) and particulate matter emissions from light-duty diesel vehicles. A series of SDPFs with different sulfur poisoning times and concentrations were prepared using the worldwide harmonized light vehicles test cycle (WLTC). Bench testing revealed that sulfur poisoning diminished the catalyst’s NH₃ storage capacity, impaired the transient NOx reduction efficiency, and induced premature ammonia leakage. After multiple sulfur poisoning incidents, the NOx reduction performance stabilized. Higher SO₂ concentrations accelerated catalyst deactivation and hastened the attainment of this equilibrium state. The characterization results for the catalyst indicate that the catalyst accumulated the same sulfur content after tail gas poisoning with different sulfur concentrations and that sulfur existed in the form of SO₄²⁻. The sulfur species in low-sulfur-poisoning-concentration catalysts mainly included sulfur ammonia and sulfur copper species, while high-sulfur-poisoning-concentration catalysts contained a higher proportion of sulfur copper species. Neither species type significantly altered the zeolite coating’s crystalline structure. Sulfur ammonia species could easily lead to a significant decrease in the specific surface area of the catalyst, which could be decomposed at 500 °C to achieve NOx reduction performance regeneration. In contrast, sulfur copper species required higher decomposition temperatures (600 °C), achieving only partial regeneration. Full article

This study proposes a data-driven optimization framework to enhance emission control performance in diesel engine selective catalytic reduction (SCR) systems under transient operating conditions. A one-dimensional SCR model was constructed in GT-Power, and simulation datasets were generated using experimentally measured inputs from the World Harmonized Transient Cycle (WHTC), with representative emission responses obtained by varying fixed ammonia-to-NOx (A/N) ratios. Building on these datasets, a hybrid prediction model combining Long Short-Term Memory (LSTM) networks and multi-head attention mechanisms was developed to accurately forecast SCR outlet NH₃ leakage and NOx emissions. The model exhibited high predictive accuracy, achieving R² values exceeding 0.977 and low RMSE across training, validation, and test sets. Based on the model predictions, a constrained dynamic multi-objective optimization strategy was implemented to adaptively adjust ammonia dosing, aiming to simultaneously minimize NH₃ leakage and NOx emissions. The optimized NH₃ injection profiles were validated through reapplication in the GT-Power simulation environment. Compared to the baseline fixed-ratio control strategy, the proposed approach reduced NH₃ leakage and NOx emissions by 34.40% and 11.15%, respectively, as determined for the transient segment of the WHTC cycle. These results demonstrate the effectiveness of integrating physics-based simulation, deep learning prediction, and dynamic optimization for improving aftertreatment adaptability and emission compliance in real-world diesel engine applications. All reported values are based on a single simulated WHTC cycle without statistical uncertainty analysis. Full article

The selective catalytic reduction (SCR) of NO_x emissions by hydrocarbons (HCs) using a silver (Ag)-based catalyst offers significant advantages over conventional SCR systems that rely on ammonia reductants and vanadium-based catalysts. However, the conversion rate of SCR is influenced by several factors, among which catalyst poisoning is a major concern. Toxic metals such as sodium (Na), potassium (K), magnesium (Mg), and calcium (Ca) can degrade catalyst activity and lead to deactivation. Poisoned catalysts suffer from reduced conversion rates and premature deactivation before reaching their intended operational lifespan. In particular, calcium poisoning results in the formation of CaO (calcium oxide), which reacts to produce a CaWO₄ compound that severely impairs SCR performance. This study investigates the role of antimony (Sb) in mitigating Ca-induced deactivation in HC-SCR of NO_x. Five catalysts with varying Sb loadings were prepared and tested to evaluate Sb’s effect on NO_x conversion rate at a space velocity of 30,000 h⁻¹. The results demonstrate that Sb effectively suppresses Ca deactivation, enhancing the conversion rate across all engine test conditions. The highest NO_x conversion rate (95.88%) was achieved using a catalyst with 3% Sb. Full article

Platinum- and/or palladium-containing silica-based supports were applied for the selective catalytic reduction of NO_x with hydrogen (H₂-SCR-DeNO_x). To obtain enhanced activity and N₂ selectivity below 150 °C, we varied the type and loading of noble metals (Pt and Pd both individually and paired, 0.1–1.0 wt.-%), silica-containing supports (ZrO₂/SiO₂, ZrO₂/SiO₂/Al₂O₃, Al₂O₃/SiO₂/TiO₂), as well as the H₂ concentration in the feed (2000–4000 ppm). All of these contributed to enhancing N₂ selectivity during H₂-SCR-DeNO_x over the (0.5 wt.-%)Pt/Pd/ZrO₂/SiO₂ catalyst in the presence of 10 vol.-% of O₂. H₂ was completely consumed at 150 °C. A comparison of the catalytic results obtained during H₂-SCR-DeNO_x,(H₂-)NH₃-SCR-DeNO_x, as well as stop-flow H₂-SCR-DeNO_x and temperature-programmed studies, revealed that in the temperature range between 150 and 250 °C, the continuously coupled or overlaying mechanism of NO reduction by hydrogen and ammonia based on NH₃ formation at lower temperatures, which is temporarily stored at the acid sites of the support and desorbed in this temperature range, could be postulated. Full article

Ammonia, as a hydrogen carrier and an ideal zero-carbon fuel, can be liquefied and stored under ambient temperature and pressure. Its application in internal combustion engines holds significant potential for promoting low-carbon emissions. However, due to its unique physicochemical properties, ammonia faces challenges in achieving ignition and combustion when used as a single fuel. Additionally, the presence of nitrogen atoms in ammonia results in increased NOx emissions in the exhaust. High-temperature selective non-catalytic reduction (SNCR) is an effective method for controlling flue gas emissions in engineering applications. By injecting ammonia as a NOx-reducing agent into exhaust gases at specific temperatures, NOx can be reduced to N₂, thereby directly lowering NOx concentrations within the cylinder. Based on this principle, a numerical simulation study was conducted to investigate two high-pressure injection strategies for sequential diesel/ammonia dual-fuel injection. By varying fuel spray orientations and injection durations, and adjusting the energy ratio between diesel and ammonia under different operating conditions, the combustion and emission characteristics of the engine were numerically analyzed. The results indicate that using in-cylinder high-pressure direct injection can maintain a constant total energy output while significantly reducing NOx emissions under high ammonia substitution ratios. This reduction is primarily attributed to the role of ammonia in forming NH₂, NH, and N radicals, which effectively reduce the dominant NO species in NOx. As the ammonia substitution ratio increases, CO₂ emissions are further reduced due to the absence of carbon atoms in ammonia. By adjusting the timing and duration of diesel and ammonia injection, tailpipe emissions can be effectively controlled, providing valuable insights into the development of diesel substitution fuels and exhaust emission control strategies. Full article