Search Results (443)

Secondary flow phenomena have a significant influence on the generation of losses and the propagation of coolant on the turbine end walls. The majority of film cooling studies are carried out on linear rather than annular cascades due to the structural simplicity and ease of measurement integration of the former. This approach neglects the effects of the radial pressure gradient that is naturally imposed on the vortex flow in annular cascades. The first part of this paper numerically investigates the effect of the radial pressure gradient on the secondary flow under periodic flow conditions by comparing a linear and an annular case. It is shown that the radial pressure gradient has a significant influence on the propagation of the secondary flow induced vortices in the wake of the nozzle guide vanes (NGV). In the second part of the paper, a novel approach of a five-passage annular sector cascade is presented, which avoids the hub boundary layer separation, as is typical for this type of test rig. To increase the periodicity, a benchmark approach is introduced that includes multiple pointwise and integral flow quantities at different axial positions. Based on the optimized best-case design, general design guidelines are derived that allow a straightforward design process for annular sector cascades. Full article

Some of nuclear power’s primary detractors are the unique environmental challenges and impacts of radioactive wastes generated during fuel cycle operations. Key benefits of spent fuel reprocessing (SFR) are reductions in primary high active waste (HAW) masses, volumes, and lengths of radiotoxicity at the expense of secondary waste generation and high capital and operational costs. By employing advanced waste management and resource recovery concepts in SFR beyond the existing standard PUREX process, such as minor actinide and fission product partitioning, these challenges could be mitigated, alongside further reductions in HAW volumes, masses, and duration of radiotoxicity. This work assesses various current and proposed SFR and fuel cycle options as base cases, with further options for fission product partitioning of the high heat radionuclides (HHRs), rare earths, and platinum group metals investigated. A focus on primary waste outputs and the additional energy that could be generated by the reprocessing of high-burnup PWR fuel from Gen III(+) reactors using a simple fuel cycle model is used; the effects of 5- and 10-year spent fuel cooling times before reprocessing are explored. We demonstrate that longer cooling times are preferable in all cases except where short-lived isotope recovery may be desired, and that the partitioning of high-heat fission products (Cs and Sr) could allow for the reclassification of traditional raffinates to intermediate level waste. Highly active waste volume reductions approaching 50% vs. PUREX raffinate could be achieved in single-target partitioning of the inactive and low-activity rare earth elements, and the need for geological disposal could potentially be mitigated completely if HHRs are separated and utilised. Full article

The continuous casting of Ti-Nb microalloyed steel was simulated with high temperature confocal laser scanning microscopy (HTCLSM). Evolution of the sample surface morphology was observed in-situ, during cooling conditions chosen to represent different locations in a cast slab. Calculations with a thermodynamics model of carbonitride precipitate formation agreed with the transmission electron microscopy (TEM) analysis that fine reliefs observed on the sample surface were actually caused by interior precipitation of (Ti,Nb)(C,N). Precipitation and the resulting reliefs changed with location beneath the slab surface, simulated casting speed, and steel composition. With the same casting speed and steel composition, reliefs in the simulated slab surface sample appeared earlier and were larger than in the slab center. With increased casting speed, reliefs were observed later and decreased in size. With increased titanium or niobium content, reliefs appeared earlier and increased in number. TEM measurement showed that the precipitate diameters were mainly smaller than 4 nm, with a few between 4 and 8 nm. The property of surface reliefs observed via HTCLSM correlated qualitatively with the number and size of internal precipitates measured with TEM, showing this to be an effective tool for indirectly characterizing nanoscale secondary phase precipitation inside the sample. Full article

The phase transformations of Crucible Particle Metallurgy (CPM) American Iron and Steel Institute (AISI) M4 steel were studied during heat treatments using a CALPHAD-based method. The calculated results were compared with experimental observations. The optimum austenitizing temperature was determined to be about 1120 °C using Thermo-Calc software (2024b). Air-cooling and quenching treatments led to the formation of martensite with a hardness of 63–65 Rockwell C (HRC). The annealing treatment promoted the formation of the equilibrium ferrite and carbide phases and resulted in a hardness of 24 HRC. These findings with regard to phases and microconstituents are in agreement with the predictions derived from a Thermo-Calc-calculated time–temperature–transformation diagram at 1120 °C. Additionally, the primary carbides, MC and M₆C, which formed prior to the heat treatment and had a minor influence on the quenched hardness. In contrast, the tempering process primarily led to the formation of fine secondary M₆C carbides, which hardened the tempered martensite to 57 HRC. The present work demonstrates the application of a CALPHAD-based methodology to the design and microstructural analysis of tool steels. Full article

Personal lifestyle choices contribute up to 75% of national emissions and yet the greenhouse gas (GHG) inventories included in the National Inventory Report (NIR) of Canada provide limited insight on these choices. Better insight can be found using carbon footprint calculators that estimate individual emissions; however, they vary in regard to their input parameters, output data, and calculation methods. This study assessed five calculators, which are popular with the public, or compatibility with the Canadian NIR. A quantitative scoring matrix was developed to assess the output depth, academic proficiency, and effectiveness of the calculators to inform lifestyle changes, alongside NIR alignment. The results showed that the calculator with the overall highest cumulative score across all the comparative criteria was the one offered by Carbon Footprint Ltd. The other calculators that scored highly include CoolClimate Calculator and Carbon Independent. The potential of the calculators in regard to informing low-carbon lifestyles can be improved through the incorporation of more depth in terms of capturing the purchase information of goods and services and providing detailed secondary information to users, including mitigation strategies and carbon offset options. The main driver of incompatibility between the calculator tools and the NIR was the different approaches taken to the emissions inventory, with the NIR using a territorial framework and the calculators being consumption driven. The outcomes of this study demonstrate a global need for the evolution of NIR structuring to increase its relatability with citizens and for the improved standardization of publicly available tools. Full article

The Caucasus region, characterized by its complex topography and diverse climatic regimes, exhibits pronounced spatial variability in temperature and precipitation patterns. This study investigates the seasonal behavior of air temperature, precipitation, vertical temperature gradients, and inversion phenomena across distinct landscape types using observational data from 63 meteorological stations for 1950–2022. Temperature trends were analyzed using linear regression, while vertical lapse rates and inversion layers were assessed based on seasonal temperature–elevation relationships. Precipitation regimes were evaluated through Mann-Kendall trend tests and Sen’s slope estimators. Results reveal that temperature regimes are strongly modulated by landscape type and elevation, with higher thermal variability in montane and subalpine zones. Seasonal temperature inversions are most frequent in spring and winter, especially in western lowlands and enclosed valleys. Precipitation patterns vary markedly across landscapes: humid lowlands show autumn–winter maxima, while arid and semi-arid zones peak in spring or late autumn. Some landscapes exhibit secondary maxima and minima, influenced by Mediterranean cyclones and regional atmospheric stability. Statistically significant trends include increasing cool-season precipitation in humid regions and decreasing spring rainfall in arid areas. These findings highlight the critical role of topography and landscape structure in shaping regional climate patterns and provide a foundation for improved climate modeling, ecological planning, and adaptation strategies in the Caucasus. Full article

Background/Objectives: The industrial extraction and purification processes of Cannabis sativa L. compounds are critical steps in creating formulations with reliable and reproducible therapeutic and sensorial attributes. Methods: For this study, standardized preparations of chemotype I were chemically analyzed, and the sensory attributes were studied to characterize the extraction and purification processes, ensuring the maximum retention of cannabinoids and minimization of other secondary metabolites. The industrial process used deep-cooled ethanol for selective extraction. Results: Taking into consideration that decarboxylation occurs in the process, the cannabinoid profile composition was preserved from the herbal substance to the herbal preparations, with wiped-film distillation under deep vacuum conditions below 0.2 mbar, as a final purification step. The profiles of the terpenes and cannabinoids in crude and purified Full-spectrum Extract Cannabis Oil (FECO) were analyzed at different stages to evaluate compositional changes that occurred throughout processing. Subjective intensity and acceptance ratings were received for taste, color, overall appearance, smell, and mouthfeel of FECO preparations. Conclusions: According to sensory analysis, purified FECO was more accepted than crude FECO, which had a stronger and more polarizing taste, and received higher ratings for color and overall acceptance. In contrast, a full cannabis extract in the market resulted in lower acceptance due to taste imbalance. The purification process effectively removed non-cannabinoids, improving sensory quality while maintaining therapeutic potency. Terpene markers of the flower were remarkably preserved in SOMAÍ’s preparations’ fingerprint, highlighting a major qualitative profile reproducibility and the opportunity for their previous separation and/or controlled reintroduction. The study underscores the importance of monitoring the extraction and purification processes to optimize the cannabinoid content and sensory characteristics in cannabis preparations. Full article

Background: Chronic thoracic pain is commonly caused by thoracic facet dysfunction, intercostal neuralgia, surgery, or thoracic pain secondary to cancer and is present in approximately 15% of the population. Conventional treatments, including pharmacotherapy and transcutaneous electrical nerve stimulation, are often ineffective and are often associated with poorly tolerated adverse effects. Cooled radiofrequency ablation (c-RFA) is a minimally invasive procedure that uses radiofrequency energy delivered through a probe to lesion the targeted nerve and provide significant and lasting relief. Methods: This study was a retrospective analysis of data extracted from UW-Health Electronic Medical Health records from October 2015 through June 2024. Patient data were collected, including diagnosis, pre-operative pain score, post-operative pain score, duration of relief, age, sex, and BMI. A two-tailed paired t-test was used to analyze the pre-operative and post-operative pain scores. A p-value < 0.05 was considered significant. Results: A total of 111 thoracic c-RFA procedures were reviewed; 43 were excluded due to absent pre-operative or post-operative pain scores in medical records. A total of 68 procedures were included in the analysis, comprising 55 patients: 25 females and 30 males with an average age of 51.31 ± 18.22 years and a BMI of 29.79 ± 6.48 kg/m². Improvement in pain scores was reported in 77.94% (n = 53), 16.18% (n = 11) reported no change, and 5.88% (n = 4) reported worsening pain. Patients reported an average pre-operative pain score of 5.98 (M = 5.98, SD = 1.91) and an average post-operative pain score of 3.06 (M = 3.06, SD = 2.52); this achieved significance (p < 0.0001). Of the 77.94% (n = 53) charts that noted improvement, there is an average of 62.83 ± 28.48% reduction from their pre-operative pain scores. The average duration of relief lasted 11.85 ± 13.42 months. Conclusions: This study supports the efficacy and safety of c-RFA as a minimally invasive therapy for chronic thoracic pain refractory to conservative measures. Full article

Cobalt-based perovskite oxides exhibit remarkable catalytic activity owing to abundant oxygen vacancies and mixed ionic–electronic conductivity, but they suffer from structural instability. In contrast, iron-based perovskite oxides are thermochemically stable under oxidizing and reducing conditions but are catalytically limited. To combine these complementary properties, a composite perovskite oxide was designed and prepared by infiltrating Sr_0.95Ce_0.05CoO_3−δ (SCC) into Ba_0.5Sr_0.5Fe_0.8Cu_0.2O_3−δ (BSFC). The SCC precursor solution was dropwise applied to a BSFC|SDC|BSFC symmetric cell and heat treated. Surface morphology and compositional analyses confirmed the distribution of SCC nanoparticles on the BSFC surface. High-temperature X-ray diffraction and Rietveld refinement results revealed that both BSFC and SCC retained the cubic perovskite structure (space group Pm-3m) at room temperature. No phase transition or secondary phase formation was observed during heating from 200 to 800 °C, and the peak shifts are attributed to thermal expansion and possible oxygen loss at elevated temperatures. Upon cooling, the diffraction patterns returned to their initial state, confirming a high-temperature structural stability. XPS analysis showed an increase in the satellite peak intensity associated with Fe³⁺ after SCC infiltration, and the average oxidation state of Fe decreased from 3.52 (BSFC) to 3.49 (composite perovskite oxide). The O 1s spectra revealed a higher relative content of surface-adsorbed oxygen species in the composite, indicating increased oxygen vacancy formation. Full article

In the context of global warming, building transformation takes on a dual responsibility to be more energy-efficient and sustainable for climate change mitigation and to be more climate-resilient for occupants’ comfort. The building energy retrofitting is an urgent need due to the large amount of existing building stock. Especially in high-rise and high-density cities under a subtropical climate, like Hong Kong, existing buildings with large glazed façades face the challenges of high energy consumption and overheating risks. An advanced glazing system, namely the vacuum insulating glazing (VIG), shows the potential for effective building envelope retrofitting due to its excellent thermal insulation ability. Yet, its performance for practical applications in the subtropical region has not been investigated. To enhance the energy performance and thermal comfort of existing high-rise buildings, this study proposed a novel retrofitting approach by integrating the VIG into the existing window system as secondary glazing. Field experiments were conducted in a commercial building in Hong Kong to investigate the thermal performance of the VIG retrofit application under real-world conditions. Furthermore, the energy-saving potential and thermal comfort performance of the VIG retrofit were evaluated by building energy simulations. The experimental results indicate that the VIG retrofit can effectively stabilize the fluctuation of the inside glass surface temperature and significantly reduce the heat gain by up to 85.3%. The simulation work shows the significant energy-saving potential of the VIG retrofit in Hong Kong. For the VIG retrofit cases under different scenarios, the energy-saving potential varies from 12.5% to 29.7%. In terms of occupants’ thermal comfort, the VIG retrofit can significantly reduce the overheating risk and improve thermal satisfaction by 9.2%. Due to the thermal comfort improvement, the cooling setpoint could be reset to 1 °C higher without compromising the overall thermal comfort. The average payback period for the VIG application is 5.8 years and 8.6 years for the clear glass retrofit and the coated glass retrofit, respectively. Therefore, the VIG retrofit approach provides a promising solution for building envelope retrofits under subtropical climate conditions. It not only benefits building owners and occupants but also contributes to achieving long-term climate resilience and the carbon neutrality of urban areas. Full article

The propulsion system is a critical component of medium–low-speed maglev trains and the single-sided linear induction motor (SLIM) has been adopted to generate thrust. However, the SLIM operates periodically in maglev trains. The temperature of the secondary plate of the SLIM rises significantly due to eddy currents when the train enters and leaves the station, where large slip occurs. Subsequently, the temperature decreases through natural cooling during the shift interval time. This periodic operating condition is rarely addressed in the existing literature and warrants attention, as the temperature accumulates over successive periods, potentially resulting in thermal damage and thrust variation. Furthermore, the conductivity of plate varies significantly in the process, which affects the losses and thrust, requiring a coupled analysis. To investigate the temperature variation patterns, this paper proposes a coupled model integrating the lumped parameter thermal network (LPTN) and the equivalent circuit (EC) of the SLIM. Given the unique structure of the F-shaped rail, the LPTN mesh is well designed to account for the skin effect. Three experiments and a finite element method (FEM)-based analysis were conducted to validate the proposed model. Finally, optimizations were performed with respect to different shift interval time, plate materials, and carriage numbers. The impact of temperature on thrust is also discussed. The results indicate that the minimum shift interval time and maximum carriage number are 70.7 s and 9, respectively, with thrust increasing by 22.0% and 22.0%. Furthermore, the use of copper as the plate material can reduce the maximum temperature by 22.01% while decreasing propulsion thrust by 26.1%. Full article

The phase composition and morphological characteristics of eutectic carbides are key factors affecting the wear resistance and fatigue life of high-speed steel. In this study, a combination of experimental characterization and thermodynamic calculations was used to systematically reveal the dynamic regulation mechanism of cooling rate on eutectic carbides in M2Al high-speed steel. The results indicate that within a cooling rate range of 5 to 225 °C/min, the steel always contains a small amount of face-centered cubic-structured MC-type eutectic carbides and a large number of hexagonal close-packed structured M₂C-type eutectic carbides. The three-dimensional morphology of MC-type eutectic carbides is smooth and rod-like, and is insensitive to the cooling rate, while the three-dimensional morphology of M₂C-type eutectic carbides evolves from lamellar to dendritic with an increasing cooling rate. The increase in cooling rate significantly reduces the average size of eutectic carbides, increases the total area fraction, and improves the distribution uniformity. Additionally, the increase in cooling rate also promotes the significant refinement of secondary dendrites in M2Al high-speed steel, and the relationship between secondary dendrite arm spacing and cooling rate is ${\lambda }_{SDAS}=149.42\cdot {C_R}^{-0.39}$. Finally, combining thermodynamic calculations with kinetic analysis, this study found that the formation of eutectic carbides is dominated by the segregation of elements such as V, Mo, and C during the final stage of solidification, while the chemical composition and three-dimensional morphological evolution of M₂C-type eutectic carbides are synergistically controlled by the diffusion and competitive growth of elements such as W, Mo, and C in austenite. This study provides a theoretical basis for the solidification process and eutectic carbide control of M2Al high-speed steel. Full article

Optimizing airflow organization is essential for ensuring the energy-efficient and secure operation of data centers. To address common airflow distribution issues in air-cooled systems, such as uneven air supply and cooling capacity imbalance, this study investigates a bidirectional airflow data center room located in a hot-summer and warm-winter region. A computational fluid dynamics (CFD) model was developed based on field-measured data to analyze the airflow distribution characteristics and evaluate the existing thermal conditions. Three optimization strategies were systematically examined: (1) Installation of rack blanking panels, (2) cold aisle containment with varying degrees of closure, and (3) combined implementations of these measures. Performance evaluation was conducted using three thermal metrics: the Return Temperature Index (RTI), Supply Heat Index (SHI), and Rack Cooling Index (RCIHI). The results demonstrate that among individual optimization strategies, rack blanking panels achieved the most significant improvement, reducing SHI by 42.61% while effectively eliminating local hotspots. For combined optimization strategies, the rack blanking panels and fully contained cold aisle containment showed optimal performance, improving cooling utilization efficiency by 88.26%. The optimal retrofit solution for this data center is the rack blanking panels with fully contained cold aisle containment. When considering budget constraints, the secondary option would be rack blanking panels with cold aisle top-only containment. These findings provide practical guidance for energy efficiency improvements in similar data center environments. Full article

MWC 342 (V1972 Cyg) was discovered nearly 90 years ago as an early-type emission-line star. It was among the first hot stars whose strong infrared excess was detected in the early 1970s. Several mostly short-term photometric and spectroscopic studies resulted in contradictory conclusions about the nature and evolutionary status of MWC 342. It has been classified as a pre-main-sequence Herbig Be star, an evolved suspected binary system, and a long-period variable star. Suggestions on the nature of the secondary component to this B0/B1 primary included a cool M-type giant and an X-ray source. We collected medium- and high-resolution optical spectra of MWC 342 taken in 1994–2024 as well as optical photometric data taken in 1986–2024. Analysis of these data shows strong variations in the object’s brightness and spectral line properties at various time scales, but no strictly periodic phenomena have been found. Inparticular, such a long-term dataset allowed us to reveal the optical brightness variations over a nearly 20-year-long quasi-period, as well as their anti-correlation with the H$\alpha$ emission-line strength. Also, we did not confirm the presence of He ii emission lines and absorption lines of the star’s atmosphere that were suspected in previously published studies. Full article

This study examines the temperature-resolved, polymorph-specific crystallinity of poly(lactic acid), PLA, during cooling and heating at 10 °C/min, with a focus on the effects of N, N-bis(benzoyl) hexanedioic acid dihydrazide (BHAD, commercially known as TMC306) as nucleating agent and PEG 1000 as plasticizer. A semicrystalline (PLA-1) and amorphous (PLA-2) PLA grade were investigated. The study emphasizes the importance of using temperature-dependent, polymorph-specific transition enthalpies to accurately calculate crystallinities from Differential Scanning Calorimetry (DSC). Polymorphism is independently confirmed using Wide Angle X-ray Diffraction (WAXD). Pure PLA-1 reached an α′ crystallinity of 2% during cooling, which increased to 38% through cold crystallization upon heating. At BHAD concentrations of at least 0.4%, α crystallites formed instead of α′, reaching a maximum crystallinity of 38% during cooling. The addition of 10 wt% PEG to PLA-1 facilitated primary α crystallization during cooling, followed by secondary intraspherulitic α′ crystallization upon heating, resulting ultimately in a crystallinity of 34%. Adding 1 wt% BHAD into PLA-1 with 10 wt% PEG shifted the crystallization temperature upward by 40 °C and enhanced the α crystallinity to 44%, highlighting the synergistic effect of PEG and BHAD on crystallization. Full article