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Keywords = rubberized bitumen

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19 pages, 2980 KB  
Article
Development of a Soft Asphalt Mix for Pedestrian Pavements Using Crumb Rubber from Recycled Tires
by Beatriz Ribeiro, Josias Breda, Francisco Machado and Jorge Pais
Infrastructures 2026, 11(4), 141; https://doi.org/10.3390/infrastructures11040141 - 19 Apr 2026
Viewed by 193
Abstract
This paper develops a shock-absorbing asphalt mixture for pedestrian pavements that mitigates the impact of normal walking on pedestrians’ bodies by incorporating crumb rubber from recycled tires to produce a soft mixture. This aims to reduce injuries to vulnerable road users, enable the [...] Read more.
This paper develops a shock-absorbing asphalt mixture for pedestrian pavements that mitigates the impact of normal walking on pedestrians’ bodies by incorporating crumb rubber from recycled tires to produce a soft mixture. This aims to reduce injuries to vulnerable road users, enable the rethinking of urban pavement designs, and address the major challenges facing societies, ultimately achieving more sustainable, resilient, and safer cities. To promote land sustainability, the designed asphalt mixture should be pervious, allowing water to infiltrate into the underlying soil. The development of the asphalt mixture followed an experimental methodology that involved formulating asphalt mixtures with conventional bitumen, polymer-modified bitumen, and bituminous emulsion. The shock-absorbing capability was evaluated by measuring the deformation of the asphalt mixture over time in response to a falling weight from a Light Falling Weight Deflectometer. Permeability capabilities were assessed through the permeability test. Subsequently, the asphalt mixture was characterized according to its macrotexture, friction, air void content, rutting resistance, and stiffness to assess its suitability as a walking surface material. Results indicate that increasing rubber content enhances deformation capacity and improves cushioning but reduces stiffness. Among the solutions, mixtures with polymer-modified bitumen and intermediate rubber content achieved the balance between impact attenuation and mechanical performance. Full article
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25 pages, 1971 KB  
Article
Quantitative Evaluation of Rubber–Asphalt Compatibility: Multivariate Correlation Study of Process Parameters, Base Asphalt Components, and Rheological Properties
by Na Ni, Manzhi Li, Lingkang Zhang, Yaling Tan, Haitao Yuan and Zhongbin Luo
Buildings 2026, 16(8), 1531; https://doi.org/10.3390/buildings16081531 - 14 Apr 2026
Viewed by 283
Abstract
In this study, an L16(43) orthogonal experimental design was employed to optimize the preparation process of rubber-modified asphalt, and a series of rheological tests were conducted using a dynamic shear rheometer to systematically investigate the compatibility mechanisms among the [...] Read more.
In this study, an L16(43) orthogonal experimental design was employed to optimize the preparation process of rubber-modified asphalt, and a series of rheological tests were conducted using a dynamic shear rheometer to systematically investigate the compatibility mechanisms among the four components: base asphalt and rubber particles. The results indicate that process parameters exert varying degrees of influence on performance. The optimal combination determined was: base bitumen temperature of 170 °C, shear rate of 4000 r/min, and shear time of 40 min, followed by isothermal curing at 170 °C for 60 min. Rheological analysis indicates that resin and asphalt are the key components determining the high-temperature rheological properties of rubber-modified asphalt; notably, L74, which has the highest asphalt content, exhibits excellent high-temperature performance. Grey correlation analysis shows that the correlation coefficient between resin content and creep recovery capacity is 0.82, while the correlation coefficient between asphalt content and resistance to permanent deformation is 0.86. Furthermore, the goodness-of-fit value of the multiple regression model exceeded 0.99, further confirming the reliability of the research results. This study provides a precise characterization of compatibility, thereby offering a theoretical foundation and technical support for material selection and process control in the application of rubber-modified asphalt. Full article
(This article belongs to the Special Issue Mechanical Properties of Asphalt and Asphalt Mixtures: 2nd Edition)
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12 pages, 1100 KB  
Article
Assessment of Flexible Pavement Containing Rubberized Asphalt
by Noorance Al-Mukaram, Tariq Al-Mansoori, Ali M. Lafta, Karzan Ismael and Pooyan Ayar
Polymers 2026, 18(8), 927; https://doi.org/10.3390/polym18080927 - 10 Apr 2026
Viewed by 486
Abstract
This work deals with a practical method of using crumb rubber resulting from waste tires to produce modified bitumen via a wet mixing method for road construction in Iraq. Due to wide variation in temperatures and over-loading traffic in Iraq, rutting deformation is [...] Read more.
This work deals with a practical method of using crumb rubber resulting from waste tires to produce modified bitumen via a wet mixing method for road construction in Iraq. Due to wide variation in temperatures and over-loading traffic in Iraq, rutting deformation is the most observed structural pavement problem. Also, tire wear and tear are higher in Iraq than in other countries due to high temperature and dry weather most of the year, which makes considerable amounts of waste tire piles easily accessible. Utilizing this waste material could be crucial to the environment and economy of the country, as well as to the sustainability of resources. Using waste tire materials as bitumen modifiers in the production of hot mix asphalt is a widely practiced experiment, although it is applied differently depending on the weather, type of bitumen used, and its availability. In the methodology of this research, it is suggested to modify asphalt grades 60/70 by a certain amount of crumb rubber (5–20%). The modified asphalt and asphalt grade 40/50 were used in preparing two types of asphalt concretes to examine their volumetric properties and evaluate their rutting behavior. The results for both mixtures were compared to the Iraqi General Specifications for Roads and Bridges (SORB/R9). The findings showed significant improvements in Marshall stability and flow, as well as in the percentages of voids satisfied in the modified mixture. After using rubberized asphalt in the mixture, the rutting depth was recorded below 20 mm and decreased by 30% and 26% at temperatures of 40 °C and 60 °C, respectively, compared to the controlled mixture. Full article
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16 pages, 2472 KB  
Article
Characteristics of Asphalt–Concrete Mixtures Produced by Hot Asphalt Recycling Using Thermal Energy from the Combustion of Waste Automobile Tires
by Andrey Akimov, Mikhail Lebedev, Valentina Yadykina, Natalia Kozhukhova and Marina Kozhukhova
J. Compos. Sci. 2026, 10(3), 160; https://doi.org/10.3390/jcs10030160 - 16 Mar 2026
Viewed by 593
Abstract
The use of resource-saving technology in road construction material production is a current problem, the solution of which will allow us to increase the environmental and economic efficiency of the road construction industry. Nowadays, secondary raw materials are widely used in highway construction, [...] Read more.
The use of resource-saving technology in road construction material production is a current problem, the solution of which will allow us to increase the environmental and economic efficiency of the road construction industry. Nowadays, secondary raw materials are widely used in highway construction, obtained both from the waste of old road construction materials and collected from other industries. During asphalt production, up to 90% of raw materials can be replaced by reclaimed asphalt pavement (RAP). This technology requires residual binder modification to reduce the negative impact on the technological and operational asphalt concrete properties. On the other hand, the use of rubber crumbs or granules obtained from the disposal of old car tires in asphalt–concrete mixtures is widespread. However, some types of car tires cannot be used as raw materials to produce an effective modifier. Truck tires and tires from special vehicles are suitable for use as a modifier for asphalt–concrete mixtures. Tires designed for passenger cars do not contain enough polymer. As an experiment on asphalt–concrete mixture production using secondary resources only, a testing facility was developed. The testing facility uses hot gas obtained by burning automobile tires in a special oven as a heat source. Rubber residues from the recycling of automobile tires are used as fuel, which cannot be used to produce rubber powder or granules. RAP obtained by cold milling of the pavements of city and public roads was used as the object of the research. When studying the characteristics of the asphalt–concrete-mixture-based binder, it was found that the sulfur compounds present in the composition of hot gases change the properties of the binder, leading to a serious deterioration in the technological characteristics of asphalt–concrete mixtures. The asphalt–concrete mixture obtained during RAP processing is characterized by a narrow temperature range in which it can be laid and compacted to the required density values. After laying the pavement, quality control revealed a significant variation (the number of air voids ranged from 0.8 to 5.5%) in the average density of samples taken from the compacted layer. In addition, there were significant violations of the longitudinal evenness of the finished coating. Experiments were carried out to extract the binder from asphalt–concrete mixtures before and after regeneration. The physico-mechanical and rheological characteristics were studied and qualitative analysis of the binder was realized by IR spectroscopy. The data obtained allow us to establish the mechanism of how sulfur-containing gases influence the bitumen binder’s properties in asphalt mixtures. Additionally, the features of thermo-oxidative degradation occurring during the hot recycling of asphalt–concrete mixtures were established. A justification is also given for the need to use anti-aging modifiers to restore the properties of the residual binder. Full article
(This article belongs to the Special Issue Advanced Asphalt Composite Materials)
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28 pages, 2076 KB  
Review
Detecting the Invisible: Analytical Advances and Regulatory Gaps in Tyre and Road Wear Particle Pollution
by Rumana Hossain, Bikesh Ghinangju, Montajar Sarkar and Veena Sahajwalla
Microplastics 2026, 5(1), 47; https://doi.org/10.3390/microplastics5010047 - 5 Mar 2026
Viewed by 734
Abstract
Tyre and road wear particles (TRWPs) represent one of the most significant yet under-recognised sources of global microplastic pollution, contributing up to 28% of total emissions. Generated from the complex interaction between vehicle tyres and road surfaces, TRWPs are chemically diverse, morphologically heterogeneous, [...] Read more.
Tyre and road wear particles (TRWPs) represent one of the most significant yet under-recognised sources of global microplastic pollution, contributing up to 28% of total emissions. Generated from the complex interaction between vehicle tyres and road surfaces, TRWPs are chemically diverse, morphologically heterogeneous, and environmentally persistent, making their detection and management particularly challenging. This review provides a critical synthesis of current knowledge on TRWP generation mechanisms, influenced by tyre composition, road types, and vehicle operation, and their environmental dispersion through air, stormwater runoff, snow removal, and roadside deposition. The chemical and physical complexity of TRWPs—often composed of rubber, bitumen, road paint, and heavy metals—necessitates multifaceted analytical approaches. We synthesise current advancements in TRWP identification techniques, including microscopy, micro-spectroscopy, and thermal desorption methods, while benchmarking their applicability using ISO standards. Furthermore, we develop an integrated framework synthesising current classification schemes, detection strategies, and regional policy responses for TRWP assessment. By identifying analytical and regulatory gaps, this review highlights the need for harmonised methodologies, improved analytical comparability, and coordinated policy interventions to address the environmental and health implications of TRWPs. Full article
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14 pages, 1099 KB  
Article
Cradle-to-Grave Life Cycle Assessment of Asphalt Pavements Incorporating Recycled Tire Rubber and Warm Mix Additives
by Ana María Rodríguez-Alloza and Daniel Garraín
Coatings 2026, 16(2), 229; https://doi.org/10.3390/coatings16020229 - 11 Feb 2026
Cited by 1 | Viewed by 455
Abstract
Reducing the environmental impacts associated with road infrastructure is a key challenge in the transition toward more sustainable construction practices. Asphalt pavements, due to their extensive material use and energy demand over long service periods, offer significant opportunities for improvement through innovative materials [...] Read more.
Reducing the environmental impacts associated with road infrastructure is a key challenge in the transition toward more sustainable construction practices. Asphalt pavements, due to their extensive material use and energy demand over long service periods, offer significant opportunities for improvement through innovative materials and production technologies. This study evaluates the environmental performance of an asphalt pavement incorporating recycled tire crumb rubber and a warm mix asphalt additive (CR + WMA) in comparison with a conventional hot mix asphalt (HMA) pavement. A comprehensive cradle-to-grave life cycle assessment (LCA) was conducted in accordance with ISO 14040/44 standards, encompassing material production, construction, maintenance, and end-of-life stages. Different pavement service life scenarios were considered, and environmental impacts were quantified using sixteen midpoint categories of the environmental footprint (EF) 2.0 method. To enable a consistent comparison between pavement alternatives with different durability, results were normalized using a functional unit of 1 m2·year. The results show that the CR + WMA pavement consistently exhibits lower environmental impacts than the conventional HMA pavement across all impact categories. When identical service lives are assumed, impact reductions are primarily associated with lower production temperatures, partial substitution of virgin bitumen with recycled crumb rubber, reduced maintenance needs, and the normalization of life cycle impacts when results are expressed per m2·year. Overall, the CR + WMA pavement reduces life cycle environmental impacts by approximately 45%–60% across all EF midpoint categories compared to the conventional HMA pavement, depending on the impact category and service life scenario considered. These findings demonstrate the importance of explicitly accounting for service life and maintenance in pavement LCAs and highlight the potential of CR + WMA technology to reduce the life cycle environmental footprint of asphalt pavements, supporting more informed infrastructure design decisions and the development of more sustainable road pavement solutions. Full article
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11 pages, 1207 KB  
Article
Mathematical Modeling and Sustainable Optimization of Rubberized Asphalt Mix Design Using Deep Learning Approach
by Uneb Gazder, Adnan Qadir, Md Kamrul Islam and Md Arifuzzaman
Processes 2026, 14(4), 621; https://doi.org/10.3390/pr14040621 - 11 Feb 2026
Viewed by 623
Abstract
The integration of recycled materials, such as tire rubber, into asphalt mixtures is a critical strategy for sustainable pavement engineering. This research aimed to employ deep learning (DL) to mathematically model and optimize Marshall stability and flow for asphalt mixes prepared with recycled [...] Read more.
The integration of recycled materials, such as tire rubber, into asphalt mixtures is a critical strategy for sustainable pavement engineering. This research aimed to employ deep learning (DL) to mathematically model and optimize Marshall stability and flow for asphalt mixes prepared with recycled rubber. The Multi-Layer Perceptron (MLP) regressor was used to predict these parameters using six design parameters. The DL approach could handle multiple outputs and provided noticeable improvement over the baseline regressor models. The analysis identified the sample volume as the most important variable followed by proportion of the recycled rubber and air voids. Using the DL model as a digital simulator, the optimal mix characteristics were found to be in the range of 3.8% to 4% bitumen and 4% to 5.5% recycled rubber. These findings validate the use of DL for efficient design of sustainable infrastructure materials. Full article
(This article belongs to the Section AI-Enabled Process Engineering)
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21 pages, 2076 KB  
Article
Synergistic Effects of Devulcanized Rubber, Polyethylene, and Fumed Silica on the Rheological and Structural Stability of Bitumen
by Akkenzhe Bussurmanova, Anar Akkenzheyeva, Viktors Haritonovs, Remo Merijs-Meri, Janis Zicans, Uzilkhan Yensegenova, Yerzhan Imanbayev, Yerbolat Ayapbergenov, Maira Turkmenbayeva, Murshida Aimova, Assiya Boranbayeva, Martynas Jankauskas and Romans Kornisovs
Polymers 2026, 18(2), 208; https://doi.org/10.3390/polym18020208 - 12 Jan 2026
Viewed by 541
Abstract
This study examines the influence of virgin polyethylene (vPE), recycled polyethylene (rPE), and Aerosil (A) on the performance of bitumen binders modified with partially devulcanized rubber (DVR). The experimental program included morphology analysis, determination of devulcanization degree, dynamic viscosity measurements, shear stress–shear rate [...] Read more.
This study examines the influence of virgin polyethylene (vPE), recycled polyethylene (rPE), and Aerosil (A) on the performance of bitumen binders modified with partially devulcanized rubber (DVR). The experimental program included morphology analysis, determination of devulcanization degree, dynamic viscosity measurements, shear stress–shear rate analysis, load–displacement (F–Δl) testing, storage-stability evaluation, ring and ball softening point (R&B), penetration (P), and elastic recovery (ER) testing. The results show that DVR-rPE-modified bitumen binders exhibit 20–35% higher viscosity and up to 25% greater elongation at the break compared to DVR-vPE-modified bitumen systems, indicating more effective interaction with the bitumen matrix. The incorporation of Aerosil increased viscosity ca. 1.5–2 times for DVR-rPE and DVR-vPE-modified systems, respectively. Meanwhile, top and bottom differences in R&B decreased by a factor of 1.6–5 for DVR-rPE and DVR-vPE-containing composites, respectively, demonstrating significant enhancement in structural stability during storage. Mechanical testing further revealed that DVR-rPE + A binders absorbed 10–20% more deformation energy and consistently maintained ER values above 70–80%, corresponding to a higher elastic recovery grade at 25 °C. Overall, the DVR-rPE + A system provided the most balanced improvements in rheological, mechanical, and thermal properties, confirming its potential for use in high-performance, thermally stable, and environmentally sustainable bituminous materials for pavement applications. Full article
(This article belongs to the Special Issue Functional Polymer Composites: Synthesis and Application)
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20 pages, 2564 KB  
Article
Effects of Synthetic Fibers and Rubber Powder from ELTs on the Rheology of Mineral Filler–Bitumen Compositions
by Krzysztof Maciejewski, Witalij Zankowicz, Anna Chomicz-Kowalska and Przemysław Zaprzalski
Materials 2026, 19(1), 52; https://doi.org/10.3390/ma19010052 - 23 Dec 2025
Viewed by 601
Abstract
This study investigates the influence of synthetic fibers and rubber powder derived from end-of-life tires (ELTs) on the rheological behavior of asphalt mastics composed of paving-grade bitumen and mineral filler. Nine asphalt mastic formulations were prepared with varying fiber and rubber contents, reflecting [...] Read more.
This study investigates the influence of synthetic fibers and rubber powder derived from end-of-life tires (ELTs) on the rheological behavior of asphalt mastics composed of paving-grade bitumen and mineral filler. Nine asphalt mastic formulations were prepared with varying fiber and rubber contents, reflecting the composition of stone mastic asphalt mixtures. Dynamic shear rheometer tests were conducted to assess dynamic stiffness modulus, phase angle, non-recoverable creep compliance, and elastic recovery. The results demonstrated that ELT-derived additives significantly enhanced high-temperature stiffness and elasticity, while maintaining satisfactory viscoelastic balance at lower temperatures. Synergistic effects between fibers and rubber were observed, improving both non-recoverable compliance and percent recovery, particularly at elevated shear stresses. Prolonged exposure to production temperatures (175 °C) confirmed the thermal stability of the modified mastics, with the most notable performance gains occurring during the first hour of heating. Based on the findings, it was concluded that ELT-based fiber–rubber additives can improve high-temperature performance of asphalt mastics without negative effects in intermediate and, possibly, also low service temperatures. This permits expanding the use cases for these kinds of additives beyond the role of inert stabilizers in stone mastic asphalt to an active modifier for extending asphalt mix performance. Full article
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23 pages, 2467 KB  
Article
New Type of Asphalt Concrete with Bitumen Emulsion in Terms of Type and Quantity of Binder
by Maciej Krasowski, Przemysław Buczyński, Grzegorz Mazurek and Matúš Kozel
Materials 2025, 18(23), 5437; https://doi.org/10.3390/ma18235437 - 2 Dec 2025
Viewed by 589
Abstract
This paper presents the effect of modifiers on the properties of a mixture of asphalt concrete with bitumen emulsion (ACBE). The mineral-asphalt mixture is the only one that can be produced using the cold-mix technology (CMA). The theoretical part of the article details [...] Read more.
This paper presents the effect of modifiers on the properties of a mixture of asphalt concrete with bitumen emulsion (ACBE). The mineral-asphalt mixture is the only one that can be produced using the cold-mix technology (CMA). The theoretical part of the article details the characteristics of the methods for producing mineral-asphalt mixtures in terms of their production temperature. Thus, hot (HMA), half-warm (H-WMA), warm (WMA) and cold (CMA) mixtures are discussed. The research section presents the design of the asphalt concrete composition with bitumen emulsion, the research methods, the experiment design and the research results. The design of the mixture of asphalt concrete with bitumen emulsion was carried out in accordance with the guidelines set out in EN 13108-31. In the experiment, Portland cement (C), bitumen emulsion (A), synthetic latex (styrene-butadiene rubber SBR) (B) and redispersible polymer powder EVA (polyethylene-co-vinyl acetate) (P) were used as modifiers. Twenty-four mixtures were designed as part of the experiment, according to the 34 experiment design. The following physical and mechanical properties were assessed in the design of the research: air void content Vm, water ab-sorption nw, indirect tensile strength ITS and IT-CY stiffness modulus. When analysing the research results, the authors observed a noticeable impact of the content of asphalt (A) and synthetic latex (B) on the air void content Vm. A significant effect was also observed for the interaction of Portland cement (C) and redispersible polymer powder (P) on the indirect tensile strength ITS. The next step was the optimisation of the ACBE mixture composition, which effect made it possible to identify the optimum amounts of modifiers in the mixture of asphalt concrete with bitumen emulsion (ACBE), which constituted recommendations for the requirements for mixtures of asphalt concrete with bitumen emulsion. Full article
(This article belongs to the Special Issue Innovative Approaches in Asphalt Binder Modification and Performance)
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18 pages, 1899 KB  
Review
Comparative Review of Marshall and Superpave Mix Designs: Enhancing Asphalt Performance with Polymers
by Gulzar Hussain Jatoi, Giuseppe Loprencipe and Laura Moretti
Materials 2025, 18(18), 4273; https://doi.org/10.3390/ma18184273 - 12 Sep 2025
Cited by 1 | Viewed by 2042
Abstract
The durability of asphalt pavements is crucial for sustainable road infrastructures. This systematic review compares the Marshall and Superpave asphalt mix design protocols, with a particular focus on the integration of polymer-modified bitumen (PMB) and rejuvenators. Although the Marshall method remains widely used [...] Read more.
The durability of asphalt pavements is crucial for sustainable road infrastructures. This systematic review compares the Marshall and Superpave asphalt mix design protocols, with a particular focus on the integration of polymer-modified bitumen (PMB) and rejuvenators. Although the Marshall method remains widely used for its simplicity and cost-efficiency, its empirical basis limits its effectiveness to meet modern pavement performance demands. In contrast, the Superpave system offers improved resistance to rutting, longer fatigue life, and better mitigation of moisture damage. The review traces the evolution of asphalt mix design, identifies current challenges, and emphasizes the need for transitioning toward performance-based frameworks. Special attention is given to the incorporation of polymers such as Styrene–Butadiene–Styrene (SBS), Styrene–Butadiene–Rubber (SBR), and Polyethylene (PE), which significantly enhance the mechanical properties of asphalt mixtures. The role of rejuvenators in restoring aged binders and enabling pavement recycling is also examined. Finally, the manuscript provides strategic recommendations for adopting Superpave to enhance pavement durability and reduce lifecycle maintenance costs. Overall, this comprehensive review advances knowledge on asphalt mix design, fostering innovation and sustainability while promoting long-term resilience in road pavement infrastructures. Full article
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24 pages, 3537 KB  
Article
Macro–Mesoscale Equivalent Evaluation of Interlayer Shear Behavior in Asphalt Pavements with a Granular Base
by Fang Wang, Zhouqi Zhang, Chaoliang Fu and Zhiping Ma
Materials 2025, 18(17), 3935; https://doi.org/10.3390/ma18173935 - 22 Aug 2025
Cited by 1 | Viewed by 1131
Abstract
To reduce reflective cracking in asphalt pavements, gravel base layers are commonly employed to disperse stress and delay structural damage. However, the loose nature of gravel bases results in complex interlayer contact conditions, typically involving interlocking between gravel particles in the base and [...] Read more.
To reduce reflective cracking in asphalt pavements, gravel base layers are commonly employed to disperse stress and delay structural damage. However, the loose nature of gravel bases results in complex interlayer contact conditions, typically involving interlocking between gravel particles in the base and aggregates in the asphalt surface course. In order to accurately simulate this interaction and to improve the interlayer shear performance, a mesoscale finite element model was developed and combined with macroscopic tests. Effects due to the type and amount of binder material, type of asphalt surface layer, and external loading on shear strength were systematically analyzed. The results indicate that SBS (Styrene–Butadiene–Styrene)-modified asphalt provides the highest interlayer strength, followed by SBR (Styrene–Butadiene Rubber)-modified emulsified asphalt and unmodified base bitumen. SBS (Styrene–Butadiene–Styrene)-modified asphalt achieves optimal interlaminar shear strength at a coating rate of 0.9 L/m2. Additionally, shear strength increases with applied load but decreases with increasing void ratio and the nominal maximum aggregate size of the surface course in the analyzed spectra. Based on simulation and experimental data, an equivalent macro–meso predictive model relating shear strength to key influencing factors was established. This model effectively bridges mesoscale mechanisms and practical engineering applications, providing theoretical support for the design and performance optimization of asphalt pavements with gravel bases. Full article
(This article belongs to the Section Construction and Building Materials)
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14 pages, 2309 KB  
Article
Modification of Bitumen with Mechanochemically Devulcanized Crumb Rubber
by Anar Akkenzheyeva, Akkenzhe Bussurmanova, Uzilkhan Yensegenova, Viktors Haritonovs, Remo Merijs Meri, Yerzhan Imanbayev, Yerbolat Ayapbergenov, Serik Sydykov and Aibar Murzabekov
Processes 2025, 13(8), 2489; https://doi.org/10.3390/pr13082489 - 7 Aug 2025
Cited by 3 | Viewed by 1475
Abstract
This study investigates the modification of bitumen using mechanochemically devulcanized crumb rubber. The objective of this research is to enhance the performance characteristics of bituminous binders while addressing the inherent limitations associated with conventional crumb rubber (CCR), such as insufficient dispersion, elevated viscosity, [...] Read more.
This study investigates the modification of bitumen using mechanochemically devulcanized crumb rubber. The objective of this research is to enhance the performance characteristics of bituminous binders while addressing the inherent limitations associated with conventional crumb rubber (CCR), such as insufficient dispersion, elevated viscosity, and phase instability. Preliminary chemical activation of the crumb rubber was performed using a planetary ball mill, followed by thermomechanical devulcanization on a two-roll open mixing mill. Structural features of the devulcanized crumb rubber were analyzed using infrared spectroscopy, which confirmed the breakdown of S–S bonds. This study presents a comparative analysis of the performance characteristics of rubber–bitumen binders produced using both conventional rubber crumb (CRC) and devulcanized rubber crumb (DRC). The use of DCR, obtained mechanochemically from rubber waste, improved penetration, Fraass breaking point and the ring and ball softening point on average at high concentrations (20; 25% crumb rubber) compared to conventional crumb rubber by 33%, 66% and 2.4%, respectively. Optical microscopy revealed the formation of a uniform mesh-like rubber structure within the bitumen matrix, which contributes to enhanced performance characteristics of the modified binder and improved mechanical strength of the material. The key contribution of this work lies in the development and experimental validation of an efficient approach to deep devulcanization of crumb rubber via mechanochemical activation using readily available nitrogen-containing reagents. Furthermore, the study establishes a direct correlation between the degree of devulcanization, the dispersion quality of rubber particles within the bitumen matrix, and the resultant performance characteristics of the modified binder. Full article
(This article belongs to the Special Issue Green Chemistry: From Wastes to Value-Added Products (2nd Edition))
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15 pages, 1076 KB  
Article
Eco-Friendly Bitumen Composites with Polymer and Rubber Waste for Sustainable Construction
by Gaini Zhumagalievna Seitenova, Rizagul Muslimovna Dyussova, Daulet Abaykhanovich Aspanbetov, Assel Yermekovna Jexembayeva, Kinga Korniejenko, Lyazat Aruova and Darkhan Kuandykovich Sakanov
Buildings 2025, 15(15), 2608; https://doi.org/10.3390/buildings15152608 - 23 Jul 2025
Cited by 1 | Viewed by 1378
Abstract
The modern road industry requires a more effective solution according to efficiency and minimizing environmental burden. This article discusses the use of recycled materials to modify bitumen binders within the concept of the circular economy. The main aim of this article was to [...] Read more.
The modern road industry requires a more effective solution according to efficiency and minimizing environmental burden. This article discusses the use of recycled materials to modify bitumen binders within the concept of the circular economy. The main aim of this article was to create a new composite based on waste materials, including polymer waste and rubber crumb. The important element is the usage of locally available waste that has not been investigated previously as a material for asphalt modification. The prepared composition was preliminarily assessed according to chemical composition. Next, research dedicated to road application was conducted, including the following: determination of the resistance to hardening, aging under the influence of high temperature and air, as well as oxidation processes, assessment of penetration, and evaluation of the softening point. The conducted studies showed that the new composites with the addition of polymer waste and rubber crumb improve the thermal stability, elasticity, and resistance of bitumen to aging. Optimum concentrations of modifiers were determined that provide an increase in the performance characteristics of bitumen, including a decrease in the brittleness temperature and an increase in the softening temperature. The obtained results demonstrate the potential for the introduction of new composites based on recycled materials in road construction, contributing to increased environmental sustainability and economic efficiency. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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26 pages, 1319 KB  
Review
Analysis of the Opportunities, Benefits and Risks Associated with the Use of Recycled Materials in Flexible Aircraft Pavements
by Sean Jamieson, Luke Verstraten and Greg White
Materials 2025, 18(13), 3036; https://doi.org/10.3390/ma18133036 - 26 Jun 2025
Cited by 3 | Viewed by 1424
Abstract
International waste policy promotes the reduction and re-use of waste materials, and in some cases, specifically calls for the use of recycled materials in pavements. In countries like Australia, most of the aircraft pavement network is constructed of flexible pavements. Consequently, understanding the [...] Read more.
International waste policy promotes the reduction and re-use of waste materials, and in some cases, specifically calls for the use of recycled materials in pavements. In countries like Australia, most of the aircraft pavement network is constructed of flexible pavements. Consequently, understanding the opportunities for recycled materials in flexible aircraft pavements is paramount to increasing the technology uptake. This paper reviews opportunities for the incorporation of recycled materials in flexible airport pavement construction, specifically, their application to particle substitution in unbound and asphaltic layers, use in stabilization treatments, and use as a bitumen modifier. Additionally, environmental product declarations are reviewed to provide a range of typical environmental costs for each recycled material when considering material processing for incorporation into flexible pavements. These materials are compared to virgin material environmental costs to determine which recycled materials provide the highest environmental benefit potential. It was concluded that particle replacement in unbound layers with waste materials had a similar environmental cost to using virgin materials. However, the requirement to dispose of waste material to the landfill can be significantly reduced. For asphaltic layers, recycled asphalt pavement as an asphalt mixture replacement, fly ash as a hydrated lime replacement, and waste plastic and crumbed rubber as a virgin polymer replacement all are effective in reducing the environmental cost. To further increase the technology uptake, a risk-based approach for the implementation of waste materials in airport flexible pavements is recommended, which considers performance testing, the depth of the pavement layer, and the pavement functional area. Full article
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