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25 pages, 1542 KB  
Article
Cooperative Task Planning of Heterogeneous Unmanned Aerial Vehicle Formations Driven by a Multi-Objective Dolphin Echolocation Optimization Algorithm
by Chengyuan Pang, Zongpu Li, Le Ru, Fan Sun and Jiaxu Chen
Drones 2026, 10(6), 473; https://doi.org/10.3390/drones10060473 (registering DOI) - 22 Jun 2026
Abstract
In the task planning of heterogeneous unmanned aerial vehicle formations, problems such as dynamic topological instability and sparse Pareto front exist, which affect the robustness of the planning. To address this, this paper proposes a cooperative task planning method based on multi-objective dolphin [...] Read more.
In the task planning of heterogeneous unmanned aerial vehicle formations, problems such as dynamic topological instability and sparse Pareto front exist, which affect the robustness of the planning. To address this, this paper proposes a cooperative task planning method based on multi-objective dolphin echolocation optimization driving. Firstly, a differentiated dynamic model of heterogeneous unmanned aerial vehicles covering different configurations such as rotors and fixed wings is constructed, and a dynamic communication topology model is established based on time-varying graph theory to quantify transmission delay and link stability. Then, a multi-objective optimization model is designed with task completion, energy balance, and time cost as the core, Bayesian networks are introduced to construct a dynamic threat field, and risk assessment and real-time response are achieved in complex environments. Based on this, a multi-objective dolphin echo optimization algorithm is adopted to solve the model, and its echo beam focusing search and adaptive weight allocation mechanism are utilized to effectively improve the convergence and distribution of the Pareto solution set. Finally, a “decision execution” hierarchical collaborative control architecture is constructed, utilizing the decision layer to output a global planning scheme and the execution layer to achieve rolling optimization and precise tracking of instructions through distributed model predictive control. The simulation test results show that this method can maintain high task completion, energy balance, and communication stability in different formation sizes and complex environments significantly better than traditional algorithms. When the formation size is between 20 and 60 sorties, the hypervolume (HV) index of this method is superior to that of the comparison method. In cases of sudden obstacles and complex electromagnetic interference scenarios, the average energy consumption of a single unmanned aerial vehicle after applying this method is maintained at 150–250 Wh, and the transmission delay is stable at 50–200 ms. The experimental results verify that this method has good planning robustness and collaborative real-time performance. Full article
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21 pages, 24404 KB  
Article
Research on Damage Mechanism of Ceramic Balls in Hybrid Rolling Friction Pairs
by Oleksandr Stelmakh, Yiqiao Guo, Anatoliy Maystrenko, Yansong Liu, Ruslan Kostunik, Alexsandr Vasylchuk, Dmytry Kustovskyi and Hao Zhang
Lubricants 2026, 14(6), 234; https://doi.org/10.3390/lubricants14060234 - 10 Jun 2026
Viewed by 189
Abstract
In hybrid rolling bearings operating under extreme high-temperature and high-load conditions, steel rolling elements are prone to early failure, which has accelerated the widespread adoption of ceramic materials. To address the limitations of conventional studies, which have focused mainly on macroscopic wear parameters [...] Read more.
In hybrid rolling bearings operating under extreme high-temperature and high-load conditions, steel rolling elements are prone to early failure, which has accelerated the widespread adoption of ceramic materials. To address the limitations of conventional studies, which have focused mainly on macroscopic wear parameters while neglecting subsurface failure mechanisms and the relationship among sintering process, microstructure, and fatigue performance, this work systematically compares the tribological behavior of Si3N4 ceramic balls fabricated by high-pressure electric resistance hot-pressing (REHP) and B4C ceramic balls prepared by conventional hot pressing (HP) against 52100 steel counterparts. The central innovation of this study lies in clarifying, based on Hertzian contact theory and Lundberg-Palmgren life theory, that subsurface orthogonal shear stress, rather than surface compressive stress, is the fundamental driving force for contact fatigue failure of ceramic balls. In addition, two distinct damage evolution modes are revealed: B4C exhibits early-stage brittle fracture and large-scale spalling, whereas REHP-Si3N4 is characterized by microcrack initiation and slow crack propagation. Moreover, the intrinsic mechanism by which the REHP process significantly enhances the contact fatigue life of ceramics is elucidated; namely, it refines grain size, eliminates residual porosity, and increases densification. The results show that, under the same high-load conditions, the mass loss of REHP-Si3N4 ceramic balls is only 35.7% of that of HP-B4C, while the service life is extended by 20%. This work provides a key theoretical basis for ceramic material selection and sintering process optimization in high-performance hybrid bearings. Full article
(This article belongs to the Special Issue Tribological Characteristics of Bearing System, 4th Edition)
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20 pages, 20044 KB  
Article
Study on the Polishing Mechanism of Composite Magnetic Field-Controlled Internal Flow Channels in Additive Manufacturing
by Hao Li, Rui Wang, Jinxu Zhang, Suhuan Guo, Guosheng Su, Jin Du, Binxun Li, Peirong Zhang, Yan Xia and Yujing Sun
Materials 2026, 19(11), 2390; https://doi.org/10.3390/ma19112390 - 3 Jun 2026
Viewed by 229
Abstract
Surface defects in additively manufactured internal channels limit their practical applications. Conventional post-processing methods suffer from limited accessibility and a tendency toward over-polishing, whereas magnetic abrasive finishing (MAF) offers high adaptability and precise process controllability. This study systematically investigates the material removal mechanisms [...] Read more.
Surface defects in additively manufactured internal channels limit their practical applications. Conventional post-processing methods suffer from limited accessibility and a tendency toward over-polishing, whereas magnetic abrasive finishing (MAF) offers high adaptability and precise process controllability. This study systematically investigates the material removal mechanisms in magnetic abrasive polishing and clarifies the distinctions and transitions between two-body and three-body wear modes. Based on these findings, a rolling removal model grounded in rough surface contact theory and a sliding removal model incorporating correction factors are established. Experiments were conducted on AlSi10Mg internal channels fabricated via selective laser melting (SLM) using a composite magnetic field polishing apparatus. The results verify the accuracy of the proposed models and demonstrate that the process effectively reduces surface defects and surface roughness. Although some deviations arise from model idealization and non-uniform magnetic field distribution, this study establishes a systematic theoretical framework for material removal in additively manufactured complex internal channels. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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14 pages, 1811 KB  
Article
Composite Learning Finite-Time Control for Nonlinear Suspensions of Heavy-Duty Vehicles Under Varying Loads
by Wei Zhang, Yaokang Wang and Dingxuan Zhao
Processes 2026, 14(11), 1813; https://doi.org/10.3390/pr14111813 - 3 Jun 2026
Viewed by 117
Abstract
This paper proposes a finite-time adaptive backstepping active suspension control strategy, integrating command filtering and composite learning, to address the degradation of ride comfort and attitude stability in heavy-duty vehicles caused by shifting loads and harsh roads. First, a nonlinear dynamic vehicle model [...] Read more.
This paper proposes a finite-time adaptive backstepping active suspension control strategy, integrating command filtering and composite learning, to address the degradation of ride comfort and attitude stability in heavy-duty vehicles caused by shifting loads and harsh roads. First, a nonlinear dynamic vehicle model is established, treating multi-source complex disturbances as a single lumped disturbance and accounting for suspension stiffness and damping nonlinearities. To stabilize the body attitude, a tri-axis controller governing the vertical, pitch, and roll motions is developed, incorporating the practical physical constraints of actuators. By employing a composite learning Radial Basis Function neural network, the controller achieves smooth approximation and precise compensation of lumped disturbances, significantly enhancing the system’s active disturbance rejection performance under complex excitations. Furthermore, the finite-time stability of the closed-loop system is rigorously proven using Lyapunov stability theory. Finally, the strategy is evaluated under a 40% load mass mismatch and continuous random road excitations. Results indicate that the proposed strategy effectively curbs the deterioration of suspension nonlinearities during overloads, ensuring smoother dynamic transitions across all three axes. Compared to conventional backstepping control, the proposed approach reduces the root mean square values of vertical, pitch, and roll accelerations by 19%, 13%, and 35%, respectively. Ultimately, this framework effectively improves vehicle stability and disturbance rejection, providing a robust reference for heavy-duty vehicle chassis control. Full article
(This article belongs to the Section Automation Control Systems)
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32 pages, 1345 KB  
Article
Finite-Capacity Spacetime and Entropic Contributions to Cosmological Structure Formation
by Florian Neukart, Eike Marx and Valerii Vinokur
Physics 2026, 8(2), 49; https://doi.org/10.3390/physics8020049 - 2 Jun 2026
Viewed by 231
Abstract
We investigatewhether a finite local information capacity of spacetime can account for the gravitational phenomena commonly attributed to cold dark matter. Starting from a covariant effective-field-theory description, we modelcoarse-grained entropy deposition as a dynamical scalar field S(x) whose stress–energy tensor [...] Read more.
We investigatewhether a finite local information capacity of spacetime can account for the gravitational phenomena commonly attributed to cold dark matter. Starting from a covariant effective-field-theory description, we modelcoarse-grained entropy deposition as a dynamical scalar field S(x) whose stress–energy tensor contributes to structure formation. The macroscopic action contains a single dimensionless coupling λ multiplying the canonical kinetic term, ensuring ghost-free dynamics and conservation of the associated stress–energy tensor. In a slow-roll regime, defined by a covariant source term ΓS¨+3HS˙=0, where H is the Hubble parameter and overdot denotes derivative with respect to cosmic time, and |S¨|H|S˙|, the entropy sector behaves as pressureless dust at background and in linear order. Implemented in a modified Cosmic Linear Anisotropy Solving System (CLASS) Boltzmann solver, the entropy component fits Planck satellite 2018 cosmic microwave background (CMB) data, baryon acoustic oscillation (BAO) measurements, and the Pantheon + Type Ia supernova sample for 0.5λ2, while preserving the linear growth factor to within 0.2% over Euclid space telescope scales. To regulate ultraviolet contributions, we introduce a holographically motivated prescription in which gravitationally active entropy deposition is confined to causal two-surfaces, yielding a ρr2 halo envelope with a finite-density core determined by local entropy saturation. Fixing the flux scale A from astrophysical entropy budgets reproduces Milky-Way-mass halos without introducing fine-tuned length scales. Pilot N-body simulations that evolve the entropy field on a staggered grid reproduce the halo mass function down to 1010.5M, mitigate the cusp–core and missing-satellite tensions, and remain consistent with cluster lensing constraints. On linear scales, the model predicts percent-level, scale-dependent deviations in the lensing convergence and matter power spectra, testable by Euclid space telescope, the Roman Space Telescope High Latitude Survey, and the CMB-S4 experiment. Full article
(This article belongs to the Section Astrophysics, Astronomy and Planetology)
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23 pages, 10507 KB  
Article
Experimental Study on Seismic Performance and Non-Equal Calculation Method for Prefabricated Reinforced Cage—Cast-In-Situ Concrete Columns
by Zhongwei Zhang, Fajiang Luo, Wenna Ma, Yan Li and Guoliang Bai
Buildings 2026, 16(11), 2101; https://doi.org/10.3390/buildings16112101 - 25 May 2026
Viewed by 212
Abstract
To promote the industrial development of reinforced concrete engineering and enhance the construction quality of prefabricated buildings, an innovative partial prefabricated construction method is proposed in this paper, namely the prefabricated reinforced cage–cast in situ concrete (PRC-CISC) structure with an innovative steel bar [...] Read more.
To promote the industrial development of reinforced concrete engineering and enhance the construction quality of prefabricated buildings, an innovative partial prefabricated construction method is proposed in this paper, namely the prefabricated reinforced cage–cast in situ concrete (PRC-CISC) structure with an innovative steel bar connection technology. The connection techniques, including direct thread rolling of steel bars and hot-forged sleeves, are adopted. With the design axial compression ratio and the layout of couplers in the reinforcement cage as the main parameters, quasi-static tests are carried out to investigate the failure mode, seismic behavior, and mechanical mechanism of couplers of PRC-CISC columns. The results indicate that all specimens present typical compression–bending failure with plump hysteretic curves, gradual stiffness degradation, good ductility, and energy dissipation capacity. The new couplers can effectively satisfy the seismic performance requirements of PRC-CISC columns. With the increase in axial compression ratio, the bearing capacity rises while ductility decreases, and the stress of longitudinal bars increases. The layout of couplers exerts a controllable influence on the mechanical and deformation performance of specimens. The steel stress in the core stress region of PRC-CISC columns shows a bilinear distribution with stress concentration at both ends of the sleeves, which is related to the material difference in couplers. Finally, two “non-equal” calculation methods (plastic hinge model and fiber model) are established based on experimental results and finite element analysis, forming a systematic calculation theory for the new material–new technology–new structure system. The research provides important references for the engineering application of such structures. Full article
(This article belongs to the Section Building Structures)
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18 pages, 1091 KB  
Article
Informational Content of the VIX Index: Dynamic Entropy Approach
by Joanna Olbryś and Dawid Toczydłowski
Entropy 2026, 28(5), 528; https://doi.org/10.3390/e28050528 - 6 May 2026
Viewed by 434
Abstract
The aim of this study is to thoroughly assess the informational content of the CBOE Volatility Index® (VIX® Index) in the context of various turbulent periods. The VIX Index is especially important from an investor perspective. It is often referred to [...] Read more.
The aim of this study is to thoroughly assess the informational content of the CBOE Volatility Index® (VIX® Index) in the context of various turbulent periods. The VIX Index is especially important from an investor perspective. It is often referred to as the “investor fear gauge”, because its level tends to spike during periods of market turmoil and other extreme events. Therefore, this index significantly differs from other market indices and financial instruments. Information theory and normalized Shannon entropy, combined with a rolling-window dynamic approach, are used to explore the evolution of the VIX Index over time. The research hypothesis states that the informational content of the VIX Index varies substantially across periods affected by crucial events. To verify this hypothesis, three important periods of the twenty-first century are analyzed: (1) the Global Financial Crisis, (2) the COVID-19 pandemic outbreak, and (3) the period covering the sub-periods before and after the Donald Trump’s Presidential Inauguration. The results provide no reason to reject the research hypothesis. The empirical findings show that the entropy values appear to be quite sensitive to the choice of discretizaton procedure. However, this evidence is consistent with the existing literature. Full article
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27 pages, 2110 KB  
Article
Sustainability Investment in Distress: Volatility Spillovers and ESG Markets Portfolio Implications
by Agbortoko Agbortoko Egbe, Serife Zihni Eyupoglu and Mehdi Seraj
Sustainability 2026, 18(9), 4403; https://doi.org/10.3390/su18094403 - 30 Apr 2026
Viewed by 746
Abstract
This study examines sustainability investments under stressful and constrained scenarios. The study exploits a wide range of indices, ranging from sustainability, ESG, to financial. The Diebold and Yilmaz framework and the DCC-GARCH were employed. The analysis covered 2382 observations with results capturing aggregate [...] Read more.
This study examines sustainability investments under stressful and constrained scenarios. The study exploits a wide range of indices, ranging from sustainability, ESG, to financial. The Diebold and Yilmaz framework and the DCC-GARCH were employed. The analysis covered 2382 observations with results capturing aggregate cross-market connectedness. The total volatility index, 76.95% based on static analysis, indicates the markets are highly integrated. The predominant net volatility transmitters are the SPX, TSX, EURUSA, and S&P500, while ESG50, ESG30, CAC, and Midi are net volatility receivers. The dynamics significantly vary, reaffirming the fact that the ESG50 and ESG30 are shock absorbers with an inverse behavioral pattern seen in the S&P500. Meaningful results based on the modern portfolio theory weights and DCC-GARCH hedge ratios based on the index pairs provide substantial diversification opportunities with hedge ratios ranging from 0.23 to 0.90. Robustness checks based on sensitivity checks with respect to varying rolling windows and lag specifications confirm the stability and validity of the findings. These empirical results are relevant for the establishment of sustainable portfolio construction and portfolio risk management in the global markets. Full article
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33 pages, 8449 KB  
Article
An Optimized Four-Float Semi-Submersible Offshore Wind Turbine Platform: Hydrodynamic and Motion Response Evaluation
by Shuai Yang, Yajie Li, Zhengang Wang, Zhenjiang Zhao, Jingquan Wang and Ling Zhou
J. Mar. Sci. Eng. 2026, 14(9), 807; https://doi.org/10.3390/jmse14090807 - 28 Apr 2026
Viewed by 547
Abstract
As floating offshore wind turbines (FOWTs) scale towards 10 MW+ capacities, suppressing wave-induced rotational resonance becomes critical for system survivability. This study introduces an optimized, highly symmetrical four-float semi-submersible platform, explicitly tailored to support the DTU 10 MW wind turbine and paired with [...] Read more.
As floating offshore wind turbines (FOWTs) scale towards 10 MW+ capacities, suppressing wave-induced rotational resonance becomes critical for system survivability. This study introduces an optimized, highly symmetrical four-float semi-submersible platform, explicitly tailored to support the DTU 10 MW wind turbine and paired with an orthogonal four-point mooring system. Using three-dimensional linear potential flow theory via ANSYS AQWA, comprehensive frequency- and time-domain hydrodynamic evaluations were conducted. To address the inherent limitations of inviscid potential flow assumptions, an empirical added-damping method was implemented. Quantitative results demonstrate a drastic reduction in motion responses: the peak Response Amplitude Operator (RAO) for heave decreased by 68.6% (from 1.945 m/m to 0.610 m/m). Most notably, the peak RAOs for the critical rotational degrees of freedom—pitch and roll—were reduced by over 92% (from 2.080 °/m and 2.216 °/m to ~0.168 °/m, respectively). Ultimately, compared to traditional asymmetric three-float concepts, this novel symmetric omnidirectional layout provides a more uniform restoring stiffness. The resulting suppression of pitch and roll resonance results in a profound reduction in tower-base bending moments and gyroscopic loads, thereby significantly enhancing the dynamic stability, safety margins, and fatigue life of the 10 MW FOWT under extreme survival sea states. Full article
(This article belongs to the Special Issue Advances of Multiphase Flow in Hydraulic and Marine Engineering)
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18 pages, 3674 KB  
Article
Stress-Modulated Structural and Electronic Evolution in Metals with Different Crystal Structures
by Shushan Hu and Gang Huang
Crystals 2026, 16(4), 267; https://doi.org/10.3390/cryst16040267 - 16 Apr 2026
Viewed by 485
Abstract
While macroscopic stress significantly impacts the performance of metallic components, the underlying atom–electron coupling mechanisms governed by distinct crystal symmetries remain insufficiently understood. To address this gap, this work systematically investigates the structural and electronic evolution of representative metallic materials under applied stress. [...] Read more.
While macroscopic stress significantly impacts the performance of metallic components, the underlying atom–electron coupling mechanisms governed by distinct crystal symmetries remain insufficiently understood. To address this gap, this work systematically investigates the structural and electronic evolution of representative metallic materials under applied stress. Experimentally, X-ray diffraction (XRD) revealed complex macroscopic residual stress distributions in cold rolled titanium alloy and silicon steel. Motivated by these engineering observations, first-principles density functional theory (DFT) calculations were conducted to uncover the underlying physical mechanisms. Specifically, the responses of face-centered cubic (FCC) aluminum and copper, body-centered cubic (BCC) iron, and hexagonal close-packed (HCP) titanium crystals were investigated under tension and compression using the RPBE functional. Stress-dependent elastic properties, density of states (DOS), band structures, and phonon spectra were calculated. Results show that tension softens all metals (Al becomes mechanically unstable), whereas compression stiffens their lattices. Electronically, tensile loading sharpens DOS peaks near the Fermi level and shifts conduction bands closer to it, whereas compression smooths DOS peaks and shifts bands away. Phonon analysis indicates Cu and Ti remain dynamically stable, while Al and Fe exhibit phonon mode softening under high tension. These stress-induced changes highlight crucial atom–electron coupling mechanisms, providing a theoretical basis for tailoring metallic performance via stress engineering. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
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27 pages, 5787 KB  
Article
Stability Analysis of Electric Unmanned Non-Road Vehicles Containing Intelligent Variable-Diameter Wheels
by Xingze Wu, Xiang Zhao, Wen Zeng and Cheng Li
World Electr. Veh. J. 2026, 17(4), 200; https://doi.org/10.3390/wevj17040200 - 10 Apr 2026
Viewed by 403
Abstract
Electric unmanned vehicles applied in complex terrains such as agricultural, forestry, and deep-space exploration scenarios are often required to travel on uneven roads. In particular, during climbing processes, their driving stability and terrain adaptability are of critical importance. To address the above challenges, [...] Read more.
Electric unmanned vehicles applied in complex terrains such as agricultural, forestry, and deep-space exploration scenarios are often required to travel on uneven roads. In particular, during climbing processes, their driving stability and terrain adaptability are of critical importance. To address the above challenges, an electric unmanned vehicle with variable-diameter wheels is proposed. By adjusting the wheel diameter, the vehicle can modify its pitch and roll angles to adapt to uneven terrains. The core research focuses on the relationship between quasi-static stability and wheel diameter variation. First, the configuration and working principle of the electric unmanned vehicle with variable-diameter wheels are introduced, with particular emphasis on the mechanism principle of the novel variable-diameter wheel. A kinematic model between the electric cylinder input and wheel diameter in the variable-diameter wheel is established. On this basis, based on the FASM (Force-Angle Stability Margin)—a stable cone theory, the relationships between stability and wheel diameter variation were investigated separately under lateral, longitudinal, and 45° steering composite conditions on a slope. The results indicate that the unmanned vehicle can achieve omnidirectional attitude adjustment. Finally, the relationship between the electric cylinder input and stability is derived, which can provide a theoretical basis for the quasi-static stability control of outdoor electric unmanned vehicles. Full article
(This article belongs to the Special Issue Recent Advances in Intelligent Vehicle)
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14 pages, 1266 KB  
Article
An Enhanced Envelope Spectroscopy Method for Bearing Diagnosis: Coupling PSO-Adaptive Stochastic Resonance with LMD
by Zhaohong Wu, Jin Xu, Jiaxin Wei, Haiyang Wu, Yusong Pang, Chang Liu and Gang Cheng
Actuators 2026, 15(4), 201; https://doi.org/10.3390/act15040201 - 2 Apr 2026
Viewed by 449
Abstract
Early fault vibration signals from rolling bearings are typically nonlinear, non-stationary, and heavily obscured by background noise, which severely impedes the accurate extraction of fault features. To overcome the limitations of traditional stochastic resonance (SR)—specifically the small-parameter restriction for high-frequency signals and the [...] Read more.
Early fault vibration signals from rolling bearings are typically nonlinear, non-stationary, and heavily obscured by background noise, which severely impedes the accurate extraction of fault features. To overcome the limitations of traditional stochastic resonance (SR)—specifically the small-parameter restriction for high-frequency signals and the subjectivity in parameter selection—this paper proposes an adaptive SR envelope spectroscopy method based on particle swarm optimization (PSO) and local mean decomposition (LMD). First, a variable-scale transformation is introduced to compress the high-frequency fault signals into the effective frequency band required by the adiabatic approximation theory. Second, utilizing the global search capability of PSO, the potential well parameters of the bistable system are adaptively optimized by maximizing the output signal-to-noise ratio (SNR), thereby achieving optimal matching between the nonlinear system and the input signal. Finally, the enhanced signal is decomposed by LMD, and the sensitive components are selected for envelope spectrum analysis to identify fault characteristics. Experimental validation using the Case Western Reserve University bearing dataset demonstrates that the proposed method effectively amplifies weak fault signals under strong noise conditions, exhibiting superior feature extraction accuracy and noise robustness compared to traditional methods. Full article
(This article belongs to the Section Control Systems)
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22 pages, 3445 KB  
Article
Design, Synthesis, and Characterization of Novel Phosphorescent Iridium Complexes with Pyrone Auxiliary Ligands and ppy/dfppy/piq Cyclometalating Ligands
by Wen Jiang, Leyuan Wang, Xiangguang Li, Caixian Yan and Qiaowen Chang
Inorganics 2026, 14(4), 95; https://doi.org/10.3390/inorganics14040095 - 27 Mar 2026
Viewed by 499
Abstract
To develop high-performance iridium phosphorescent complexes, we designed and synthesized a series of iridium phosphorescent complexes (G-1, G-2, B-1, B-2, R-1, R-2) using 3-hydroxy-2-methyl-4-pyrone (maltol, short for mal) and 3-hydroxy-2-ethyl-4-pyrone (ethyl maltol, short for emal) as auxiliary ligands, in combination with 2-phenylpyridine (ppy), [...] Read more.
To develop high-performance iridium phosphorescent complexes, we designed and synthesized a series of iridium phosphorescent complexes (G-1, G-2, B-1, B-2, R-1, R-2) using 3-hydroxy-2-methyl-4-pyrone (maltol, short for mal) and 3-hydroxy-2-ethyl-4-pyrone (ethyl maltol, short for emal) as auxiliary ligands, in combination with 2-phenylpyridine (ppy), 2-(2,4-difluorophenyl)pyridine (dfppy), and 1-phenylisoquinoline (piq) as cyclometalating ligands. We systematically investigated their crystal structures, photophysical behavior, electrochemical properties, and electroluminescent performance. The results revealed that the combination of a pyranone auxiliary ligand with the highly conjugated piq ligand leads to the formation of R-1 and R-2, which possess high molecular symmetry and display favorable photophysical performance. These complexes exhibit solution-phase phosphorescence quantum yields of 64% and 55%, and electroluminescent devices incorporating them reach a maximum external quantum efficiency of 13.4%, with brightness exceeding 13,000 cd/m2 and minimal efficiency roll-off. In contrast, complexes incorporating pyridine-based cyclometalating ligands (ppy, dfppy)—G-1, G-2, B-1, and B-2—display weak emission in solution but show enhanced solid-state emission through π–π stacking, with a maximum quantum yield of 25.8%. Density functional theory calculations and electrochemical analysis indicate that the presence of both the pyranone auxiliary ligand and the piq ligand results in optimized frontier orbital energy alignment, enhanced metal-to-ligand charge transfer, and reduced non-radiative transitions, thereby improving emission efficiency. This study provides a theoretical framework and molecular design strategy for the application of pyranone auxiliary ligands in high-performance iridium phosphorescent materials. Full article
(This article belongs to the Section Coordination Chemistry)
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35 pages, 19503 KB  
Article
Coupled Dynamic Analysis and Experimental Validation of a 1:15 Scaled Multi-Purpose Offshore Platform Prototype
by Yan Gao and Liang Li
J. Mar. Sci. Eng. 2026, 14(7), 601; https://doi.org/10.3390/jmse14070601 - 24 Mar 2026
Viewed by 516
Abstract
Multi-purpose platforms, which combine renewable energy generation devices and diverse functionalities, are a smart way to expand the applications of offshore platforms. An environmentally friendly multi-purpose offshore platform is proposed by the ‘Blue Growth Farm’ project, which includes a wind turbine, a set [...] Read more.
Multi-purpose platforms, which combine renewable energy generation devices and diverse functionalities, are a smart way to expand the applications of offshore platforms. An environmentally friendly multi-purpose offshore platform is proposed by the ‘Blue Growth Farm’ project, which includes a wind turbine, a set of wave energy converters, and an aquaculture system. To assess its feasibility and performance, a field experiment is conducted at an offshore site in Italy using a 1:15 scaled outdoor platform prototype. To provide comprehensive insights into the platform’s behavior, in the present work, aero–hydro–servo–elastic coupled numerical models based on the blade element method and potential flow theory are developed for various experimentally tested configurations of this multi-purpose platform. Time domain analyses are conducted to investigate the performance of the outdoor prototype platform under the recorded realistic environmental loads from the field experiment. The numerical results, including platform motion, mooring line tension forces, and wind turbine responses, agree with the corresponding experimental records. For example, the absolute mean value errors for platform roll and pitch motions are approximately 1 degree, validating the developed numerical model. Meanwhile, the present comparative study demonstrates the feasibility of the proposed multi-purpose concept and can provide a reference for similar projects in the future. Full article
(This article belongs to the Special Issue Advances in Marine Engineering Hydrodynamics, 2nd Edition)
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25 pages, 4663 KB  
Article
Investigation on Rolling Seals for Deep-Sea Applications
by Yucheng Yang, Limin Gao, Yafeng Wu, Guojun Wu and Geyang Hao
Lubricants 2026, 14(3), 132; https://doi.org/10.3390/lubricants14030132 - 18 Mar 2026
Viewed by 607
Abstract
The rolling seal is a pivotal sealing technology for marine equipment such as wet-mateable connectors, ensuring operational integrity in deep-sea environments during both static and mating phases. However, its working mechanisms remain inadequately understood, and the effects of sealing parameters and seawater pressure [...] Read more.
The rolling seal is a pivotal sealing technology for marine equipment such as wet-mateable connectors, ensuring operational integrity in deep-sea environments during both static and mating phases. However, its working mechanisms remain inadequately understood, and the effects of sealing parameters and seawater pressure have yet to be systematically studied. To address these issues, a refined model for rolling seals operating in deep-sea pressure-balanced conditions was developed. The model’s accuracy was enhanced by incorporating two key inputs: experimentally measured boundary lubrication friction coefficients (replacing conventional dry friction values) for finite element simulation and torque calculation, and oil pressure under pressure-balanced conditions, derived from shell theory, as a boundary load. Through systematic parametric simulations, the effects of interference fit, rotational speed, and seawater pressure on sealing performance were elucidated. An experimental torque test setup under atmospheric pressure was constructed to validate the numerical model. The results indicate that, while ensuring reliable static sealing, higher rotational speeds and smaller interference fits help reduce rotational torque. Benefiting from the pressure-balanced design, increasing water depth significantly enhances hydrodynamic performance—accounting for over 90% of the total static contact pressure at 1500 m—while leakage shows a decreasing trend. These findings provide theoretical insights for optimizing deep-sea sealing structures. Full article
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