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Keywords = rock–concrete composite

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18 pages, 6753 KiB  
Article
Deformation Analysis of 50 m-Deep Cylindrical Retaining Shaft in Composite Strata
by Peng Tang, Xiaofeng Fan, Wenyong Chai, Yu Liang and Xiaoming Yan
Sustainability 2025, 17(13), 6223; https://doi.org/10.3390/su17136223 - 7 Jul 2025
Viewed by 403
Abstract
Cylindrical retaining structures are widely adopted in intercity railway tunnel engineering due to their exceptional load-bearing performance, no need for internal support, and efficient utilization of concrete compressive strength. Measured deformation data not only comprehensively reflect the influence of construction and hydrogeological conditions [...] Read more.
Cylindrical retaining structures are widely adopted in intercity railway tunnel engineering due to their exceptional load-bearing performance, no need for internal support, and efficient utilization of concrete compressive strength. Measured deformation data not only comprehensively reflect the influence of construction and hydrogeological conditions but also directly and clearly indicate the safety and stability status of structure. Therefore, based on two geometrically similar cylindrical shield tunnel shafts in Shenzhen, the surface deformation, structure deformation, and changes in groundwater outside the shafts during excavation were analyzed, and the deformation characteristics under the soil–rock composite stratum were summarized. Results indicate that the uneven distribution of surface surcharge and groundwater level are key factors causing differential deformations. The maximum horizontal deformation of the shafts wall is less than 0.05% of the current excavation depth (H), occurring primarily in two zones: from H − 20 m to H + 20 m and in the shallow 0–10 m range. Vertical deformations at the wall top are mostly within ±0.2% H. Localized groundwater leakage in joints may lead to groundwater redistribution and seepage-induced fine particle migration, exacerbating uneven deformations. Timely grouting when leakage occurs and selecting joints with superior waterproof sealing performance are essential measures to ensure effective sealing. Compared with general polygonal foundation pits, cylindrical retaining structures can achieve low environmental disturbances while possessing high structural stability. Full article
(This article belongs to the Special Issue Sustainable Development and Analysis of Tunnels and Underground Works)
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22 pages, 2719 KiB  
Article
Itararé Group Sandstone as a Sustainable Alternative Material for Photon Radiation Shielding
by Gabrielli W. Pietralla, Isonel S. Meneguzzo and Luiz F. Pires
Appl. Sci. 2025, 15(13), 7559; https://doi.org/10.3390/app15137559 - 5 Jul 2025
Viewed by 304
Abstract
The materials typically used for radiation shielding include lead, concrete, and polymers. However, some of these materials can be toxic or very expensive to produce. This raises interest in using more readily available natural materials, such as rocks, as an alternative. In this [...] Read more.
The materials typically used for radiation shielding include lead, concrete, and polymers. However, some of these materials can be toxic or very expensive to produce. This raises interest in using more readily available natural materials, such as rocks, as an alternative. In this study, we analyzed the radiation shielding efficiency of sandstones. We evaluated different layers of rock and obtained shielding parameters based on the composition of various oxides. The analysis revealed that these layers showed a predominance of silicon and aluminum oxides. Notably, the lowest photon energies (0.015 MeV and 0.1 MeV) displayed significant differences in photon attenuation, as indicated by linear and mass attenuation coefficients. This suggests that the chemical composition of the samples had a considerable impact on their shielding performance. Samples containing higher amounts of heavier elements proved to be more effective at attenuating radiation, efficiently reducing 50% (half-value layer) and 90% (tenth-value layer) of the photons. Additionally, the presence of these heavier elements decreased the production of secondary photons (buildup factor), further enhancing the samples’ efficiency in shielding against radiation. Our results indicate that sandstones hold potential for radiation shielding, particularly when they contain higher quantities of heavier elements. Full article
(This article belongs to the Special Issue Electromagnetic Radiation and Human Environment)
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16 pages, 3741 KiB  
Article
Mechanical Properties of Large-Volume Waste Concrete Lumps Cemented by Desert Mortar: Laboratory Tests
by Hui Chen, Zhiyuan Qi, Baiyun Yu and Xinyu Li
Buildings 2025, 15(12), 2060; https://doi.org/10.3390/buildings15122060 - 15 Jun 2025
Viewed by 450
Abstract
In response to the high cost and environmental impact of backfill materials in Xinjiang mines, an eco-friendly, large-volume composite was developed by bonding desert-sand mortar to waste concrete. A rock-filled concrete process produced a highly flowable mortar from desert sand, cement, and fly [...] Read more.
In response to the high cost and environmental impact of backfill materials in Xinjiang mines, an eco-friendly, large-volume composite was developed by bonding desert-sand mortar to waste concrete. A rock-filled concrete process produced a highly flowable mortar from desert sand, cement, and fly ash. Waste concrete blocks served as coarse aggregate. Specimens were cured for 28 days, then subjected to uniaxial compression tests on a mining rock-mechanics system using water-to-binder ratios of 0.30, 0.35, and 0.40 and aggregate sizes of 30–40 mm, 40–50 mm, and 50–60 mm. Mechanical performance—failure modes, stress–strain response, and related properties—was systematically evaluated. Crack propagation was tracked via digital image correlation (DIC) and acoustic emission (AE) techniques. Failure patterns indicated that the pure-mortar specimens exhibited classic brittle fractures with through-going cracks. Aggregate-containing specimens showed mixed-mode failure, with cracks flowing around aggregates and secondary branches forming non-through-going damage networks. Optimization identified a 0.30 water-to-binder ratio (Groups 3 and 6) as optimal, yielding an average strength of 25 MPa. Among the aggregate sizes, 40–50 mm (Group 7) performed best, with 22.58 MPa. The AE data revealed a three-stage evolution—linear-elastic, nonlinear crack growth, and critical failure—with signal density positively correlating to fracture energy. DIC maps showed unidirectional energy release in pure-mortar specimens, whereas aggregate-containing specimens displayed chaotic energy patterns. This confirms that aggregates alter stress fields at crack tips and redirect energy-dissipation paths, shifting failure from single-crack propagation to a multi-scale damage network. These results provide a theoretical basis and technical support for the resource-efficient use of mining waste and advance green backfill technology, thereby contributing to the sustainable development of mining operations. Full article
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29 pages, 7198 KiB  
Article
Meridiani Planum Mineralogy Along Part of the Opportunity Rover Track Based on the Mini-TES Spectrum
by Zalewska Natalia and Leszek Czechowski
Remote Sens. 2025, 17(12), 1981; https://doi.org/10.3390/rs17121981 - 7 Jun 2025
Viewed by 549
Abstract
The research uses data from the Mini-TES infrared spectrometer of an Opportunity rover taken at selected locations along its route in Meridiani Planum on Mars. Using emissivity data, the corresponding mineralogical compositions were calculated. Generally, the results are consistent with previous works, in [...] Read more.
The research uses data from the Mini-TES infrared spectrometer of an Opportunity rover taken at selected locations along its route in Meridiani Planum on Mars. Using emissivity data, the corresponding mineralogical compositions were calculated. Generally, the results are consistent with previous works, in particular they indicate the widespread occurrence of clay minerals and minerals from basaltic rocks. However, several interesting facts were also noted. Among other things, clear changes in the hematite content were found, suggesting that certain area spherical concretions (known as blueberries) may be devoid of hematite. A similar phenomenon is known from studies of terrestrial concretions. Moreover, the possibility of pyrite existence was found on a certain section of the route. On Earth, pyrite often occurs with economically valuable minerals. Full article
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20 pages, 5109 KiB  
Article
Mechanical Behavior and Crack Resistance of Modified Polydimethylsiloxane Impermeable Coating for Concrete Lining Subjected to Ultra-High Internal Pressure
by Yong Xia, Jiaqi Wu, Xingyi Yang, Long Qu and Hongqiang Xie
Appl. Sci. 2025, 15(11), 6132; https://doi.org/10.3390/app15116132 - 29 May 2025
Viewed by 330
Abstract
The high water head of some pumped storage power stations will induce the cracking of the concrete lining of their diversion tunnel and the leakage of high-pressure water, which will affect the safety of the tunnel and the surrounding rock. At present, there [...] Read more.
The high water head of some pumped storage power stations will induce the cracking of the concrete lining of their diversion tunnel and the leakage of high-pressure water, which will affect the safety of the tunnel and the surrounding rock. At present, there is no solution to the problem of impermeability of concrete materials after cracking. This paper proposes a composite lining to solve this problem. The composite lining with modified polydimethylsiloxane coating can effectively prevent high-pressure water, but its crack resistance needs to be further studied. Therefore, the tensile mechanical properties, constitutive relationship of modified polydimethylsiloxane impermeable coating, and the crack resistance mechanical properties of modified polydimethylsiloxane impermeable composite lining were studied by laboratory tests and numerical simulations. The results show that the true fracture elongation of the modified polydimethylsiloxane impermeable coating is as high as 118.98%, and its mechanical behavior can be described by a simplified polynomial hyperelastic constitutive model. The in situ stress will affect the crack width of the concrete lining. When the lateral pressure coefficient is less than 1, the crack width decreases with the increase in the lateral pressure coefficient. When the lateral pressure coefficient is greater than 1, the crack width increases with the increase in the lateral pressure coefficient. To prevent the cracking of modified polydimethylsiloxane coating, its spraying thickness needs to increase with the increase in crack width. The ratio of the coating’s thickness to crack width is recommended from 0.162 to 1.930 for internal water pressure from 1 MPa to 10 MPa, respectively. The suggestion provides a reference for designing the impermeable composite lining structure subjected to high internal water pressure. Full article
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15 pages, 669 KiB  
Systematic Review
Basalt Rock Powder in Cementitious Materials: A Systematic Review
by Maryane Pipino Beraldo Almeida, Lays da Silva Sá Gomes, Alex Ramos Silva, Jacqueline Roberta Tamashiro, Fábio Friol Guedes Paiva, Lucas Henrique Pereira Silva and Angela Kinoshita
Resources 2025, 14(6), 86; https://doi.org/10.3390/resources14060086 - 23 May 2025
Cited by 1 | Viewed by 844
Abstract
Concrete and mortar production consumes significant natural resources, leading to environmental concerns and sustainability challenges. Sustainable alternatives, such as industrial byproducts, have been explored to replace clinkers and aggregates. Basalt rock powder (BRP) is a promising option due to its physical and chemical [...] Read more.
Concrete and mortar production consumes significant natural resources, leading to environmental concerns and sustainability challenges. Sustainable alternatives, such as industrial byproducts, have been explored to replace clinkers and aggregates. Basalt rock powder (BRP) is a promising option due to its physical and chemical properties, including its better particle size distribution and compatibility with cementitious composites, and studies have highlighted its pozzolanic activity and its potential to improve mechanical properties (compressive strength, flexural strength, and durability). Reusing rock dust as a raw material could transform it into a mineral byproduct, benefiting the new material and reducing waste volumes. This article presents a systematic literature review on the use of BRP in construction materials, conducted using the Scopus, ScienceDirect, PubMed, and Web of Science databases and following the PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) procedures. The search resulted in 787 articles (up to December 2024) and, after the screening process, 17 met the inclusion criteria. From the selected articles, information regarding the utilization of this waste product; its influence on mechanical properties, pozzolanic activity, and durability; and the sustainability associated with its use was compiled. The risk of bias was low as the search was comprehensive, all the papers were peer-reviewed, and all authors reviewed the papers independently. In conclusion, the studies demonstrate the potential of using BRP as a component of cementitious materials, indicating it as a possible innovative solution to the current challenges in the construction industry. Full article
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22 pages, 5793 KiB  
Article
Concrete Durability Performance in Aggressive Salt and Deicing Environments—Case Study of Select Pavement and Bridge Concrete Mixtures
by Olaniyi S. Arowojolu, Milena Rangelov, Somayeh Nassiri, Fouad Bayomy and Ahmed Ibrahim
Materials 2025, 18(6), 1266; https://doi.org/10.3390/ma18061266 - 13 Mar 2025
Viewed by 709
Abstract
Transportation infrastructure such as concrete pavements, parapets, barriers, and bridge decks in cold regions are usually exposed to a heavy amount of deicing chemicals during the winter for ice and snow control. Various deicer salts can physically and chemically react with concrete and [...] Read more.
Transportation infrastructure such as concrete pavements, parapets, barriers, and bridge decks in cold regions are usually exposed to a heavy amount of deicing chemicals during the winter for ice and snow control. Various deicer salts can physically and chemically react with concrete and result in damage and deterioration. Currently, Idaho uses four different types of deicers during the winter: salt brine, mag bud converse, freeze guard plus, and mag chloride. The most often utilized substance is salt brine, which is created by dissolving rock salt at a concentration of 23.3%. Eight concrete mixtures for paving and structural purposes were made and put through a battery of durability tests. Following batching, measurements were made of the unit weight, entrained air, slump, and super air meter (SAM) fresh characteristics. Rapid freeze–thaw (F-T) cycle experiments, deicing scaling tests, and surface electrical resistivity testing were used to test and assess all mixes. Tests with mag bud converse, freeze guard plus mag chloride, and acid-soluble chloride were conducted following an extended period of soaking in salt brine. Two different structural mixtures were suggested as a result of the severe scaling observed in the structural mixtures lacking supplemental cementitious materials (SCMs) and the moderate scaling observed in the other combinations. The correlated values of the SAM number with the spacing factor have been shown that mixture with no SCMs has a spacing factor of 0.24, which is higher than the recommended value of 0.2 and concentrations of acid soluble chloride over the threshold limit were discernible. In addition, the highest weight of calcium hydroxide using the TGA test was observed. For all examined mixes, the residual elastic moduli after 300 cycles varied between 76.0 and 83.3 percent of the initial moduli. Mixture M5 displayed the lowest percentage of initial E (76.0 percent), while mixtures M1 and M2 showed the highest percentage of residual E (83.3 and 80.0 percent, respectively) among the evaluated combinations. There were no significant variations in the percentage of maintained stiffness between the combinations. As a result, it was difficult to identify distinct patterns about how the air content or SAM number affected the mixture’s durability. Class C coal fly ash and silica fume were present in the suggested mixtures, which were assessed using the same testing matrix as the original mixtures. Because of their exceptional durability against large concentrations of chemical deicers, the main findings suggest altering the concrete compositions to incorporate SCMs in a ternary form. Full article
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17 pages, 7897 KiB  
Article
Research on Adaptive Drilling Control Technology Based on Coal Rock Traits During the Drilling Process
by Bin Liang, Guang Li and Guangpeng Shan
Machines 2025, 13(2), 133; https://doi.org/10.3390/machines13020133 - 10 Feb 2025
Viewed by 688
Abstract
The anti-punch drilling robot is a core piece of equipment used to realize unmanned drilling and pressure relief operations in underground coal mines. Adaptive drilling, conducted according to the coal rock properties encountered during drilling, is essential to improve the safety and efficiency [...] Read more.
The anti-punch drilling robot is a core piece of equipment used to realize unmanned drilling and pressure relief operations in underground coal mines. Adaptive drilling, conducted according to the coal rock properties encountered during drilling, is essential to improve the safety and efficiency of the pressure relief working face. This paper analyzed the composition of the anti-punch drilling robot drilling system and workflow of the drilling system and then calculated the optimal rotary speed and the optimal feed speed for different Platts hardness coefficients of the coal rock through the analysis of the drilling rod force. Based on the characteristics of the drilling electrohydraulic control system, a rotary adaptive controller based on a self-resistant control algorithm and a feed adaptive controller based on sliding mode variable structure control were designed. A joint simulation was carried out using AMESim 2020.1 and Simulink 2020b software to analyze the control performance of each controller. Finally, an experimental platform for the drilling robot electrohydraulic control system was constructed; different hardness coefficients of concrete specimens were used to simulate the hardness of the coal rock with different traits. Single coal rock hardness experiments and drilling experiments with sudden changes in coal rock hardness were carried out. The experimental results showed that the adaptive control strategy proposed in this paper satisfies the requirements of drilling system control. Full article
(This article belongs to the Section Automation and Control Systems)
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22 pages, 4783 KiB  
Article
Enhancement of Air-Entrained Grout-Enriched Vibrated Cemented Sand, Gravel and Rock (GECSGR) for Improving Frost and Thawing Resistance in CSGR Dams
by Wambley Adomako Baah, Jinsheng Jia, Cuiying Zheng, Baozhen Jia, Yue Wang and Yangfeng Wu
Materials 2025, 18(1), 155; https://doi.org/10.3390/ma18010155 - 2 Jan 2025
Viewed by 828
Abstract
Cemented Sand, Gravel, and Rock (CSGR) dams have traditionally used either Conventional Vibrated Concrete (CVC) or Grout-Enriched Roller Compacted Concrete (GERCC) for protective and seepage control layers in low- to medium-height dams. However, these methods are complex, prone to interference, and uneconomical due [...] Read more.
Cemented Sand, Gravel, and Rock (CSGR) dams have traditionally used either Conventional Vibrated Concrete (CVC) or Grout-Enriched Roller Compacted Concrete (GERCC) for protective and seepage control layers in low- to medium-height dams. However, these methods are complex, prone to interference, and uneconomical due to significant differences in the expansion coefficient, elastic modulus, and hydration heat parameters among CSGR, CVC, and GERCC. This complexity complicates quality control during construction, leading to the development of Grout-Enriched Vibrated Cemented Sand, Gravel, and Rock (GECSGR) as an alternative. Despite its potential, GECSGR has limited use due to concerns about freeze–thaw resistance. This project addresses these concerns by developing an air-entrained GECSGR grout formulation and construction technique. The study follows a five-phase approach: mix proportioning of C1806 CSGR; optimization of the grout formulation; determination of grout addition rate; evaluation of small-scale lab samples of GECSGR; and field application. The results indicate that combining 8–12% of 223 kg/m3 cement grout with 2–2.23 kg/m3 of admixtures, mud content of 15%, a marsh time of 26–31 s. and a water/cement ratio of 0.5–0.6 with the C1806 parent CSGR mixture achieved a post-vibration in situ air content of 4–6%, excellent freeze–thaw resistance (F300: mass loss <5% or initial dynamic modulus ≥60%), and permeability resistance (W12: permeability coefficient of 0.13 × 10−10 m/s). The development of a 2-in-1 slurry addition and vibration equipment eliminated performance risks and enhanced efficiency in field applications, such as the conversion of the C1804 CSGR mixture into air-entrained GECSGR grade C9015W6F50 for the 2.76 km Qianwei protection dam. Economic analysis revealed that the unit cost of GECSGR production is 18.3% and 6.33% less than CVC and GERCC, respectively, marking a significant advancement in sustainable cement-based composite materials in the dam industry. Full article
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18 pages, 14445 KiB  
Article
Mechanical Behavior and Failure Mechanism of Rock–Concrete Composites Under the Coupling Effect of Inclined Interface Angle and Ground Temperature
by Shiwei Liu, Jiaxin Zhao, Fang Cheng, Hao Yu and Jiaqi Chen
Symmetry 2025, 17(1), 52; https://doi.org/10.3390/sym17010052 - 31 Dec 2024
Viewed by 905
Abstract
Surrounding rock and lining are composite structures with asymmetric mechanical properties. Understanding the mechanical properties and failure characteristics of rock–concrete composites is crucial for gaining insights into the mechanisms that induce disasters in deep-underground environments. Uniaxial compression and acoustic emission tests were conducted [...] Read more.
Surrounding rock and lining are composite structures with asymmetric mechanical properties. Understanding the mechanical properties and failure characteristics of rock–concrete composites is crucial for gaining insights into the mechanisms that induce disasters in deep-underground environments. Uniaxial compression and acoustic emission tests were conducted on rock–concrete composite specimens cured at temperatures of 20 °C, 40 °C, 60 °C, and 80 °C, with interface angles of 15°, 30°, 45°, 60°, 75°, and 90° respectively. The results indicated that the specimens’ strength decreased at increasing geothermal temperatures. The composites with an 80 °C curing temperature and a 60° interface angle exhibited the lowest strength. A higher geothermal temperature significantly reduced the number of cracks in the concrete component during composite failure and mitigated the influence of the inclined interface angle. The failure modes of the specimens include axial penetration splitting, interface shear, Y-shaped fracture, and interface splitting–concrete shear failure. Finally, a model relating the strength of the rock–concrete composite to the inclined interface angle and the geothermal temperature was derived and verified against the experimental results with a relative error of 9.8%. The findings have significant implications for the safety and stability of tunnels in high-temperature conditions. Full article
(This article belongs to the Section Engineering and Materials)
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20 pages, 3293 KiB  
Article
Study of the Effects of Different Dielectric Environments on the Characteristics of Electro-Explosive Discharge of Metal Wires and Shock Waves
by Jiawei Liu, Jin Wang, Qilong Xue, Yuanyuan Zhang, Hufeng Li and Song Fang
Appl. Sci. 2025, 15(1), 218; https://doi.org/10.3390/app15010218 - 30 Dec 2024
Viewed by 761
Abstract
The electrical explosive fragmentation technique has attracted widespread attention due to its environmental friendliness and high efficiency. However, the mechanism by which dielectrics influence rock fragmentation remains unclear. This study innovatively selected seven types of environmentally friendly dielectrics to systematically investigate their roles [...] Read more.
The electrical explosive fragmentation technique has attracted widespread attention due to its environmental friendliness and high efficiency. However, the mechanism by which dielectrics influence rock fragmentation remains unclear. This study innovatively selected seven types of environmentally friendly dielectrics to systematically investigate their roles in the metallic wire electrical explosive rock fragmentation process. By precisely characterizing the crack morphology of concrete blocks, shock wave–strain responses, and discharge signal characteristics, the diverse mechanisms by which different dielectrics modulate rock fragmentation were revealed. The results indicate that oxide dielectrics release energy continuously through thermochemical reactions, highly conductive solutions accelerate energy deposition, and reductant suspensions generate strong secondary shock waves—all significantly outperforming tap water in terms of rock fragmentation performance. Notably, the energy deposition efficiency shows a nonlinear relationship with fragmentation effectiveness, influenced by factors such as energy release modes, dielectric composition, and bubble dynamics. The energy conversion mechanism of the electrical explosive rock fragmentation process studied in this paper provides a theoretical foundation for the fine-tuning, customization, and greening of electrical explosive rock fragmentation strategies in engineering practice. Full article
(This article belongs to the Section Civil Engineering)
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19 pages, 4128 KiB  
Article
Fracture Characteristics and Tensile Strength Prediction of Rock–Concrete Composite Discs Under Radial Compression
by Tengfei Guo, Houqiang Wang, Xuefeng Si, Chengzhi Pu, Zhixiang Liu, Qi Zhang and Weijun Liu
Mathematics 2024, 12(22), 3510; https://doi.org/10.3390/math12223510 - 10 Nov 2024
Cited by 3 | Viewed by 1682
Abstract
To investigate the fracture mechanism of rock–concrete (R–C) systems with an interface crack, Brazilian splitting tests were conducted, with a focus on understanding the influence of the interface crack angle on failure patterns, energy evolution, and RA/AF characteristics. The study addresses a critical [...] Read more.
To investigate the fracture mechanism of rock–concrete (R–C) systems with an interface crack, Brazilian splitting tests were conducted, with a focus on understanding the influence of the interface crack angle on failure patterns, energy evolution, and RA/AF characteristics. The study addresses a critical issue in rock–concrete structures, particularly how crack propagation differs with varying crack angles, which has direct implications for structural integrity. The experimental results show that the failure paths in R–C disc specimens are highly dependent on the interface crack angle. For crack angles of 0°, 15°, 30°, and 45°, cracks initiate from the tips of the interface crack and propagate toward the loading ends. However, for angles of 60°, 75°, and 90°, crack initiation shifts away from the interface crack tips. The AE parameters RA (rise time/amplitude) and AF (average frequency) were used to characterize different failure patterns, while energy evolution analysis revealed that the highest percentage of energy consumption occurs at a crack angle of 45°, indicating intense microcrack activity. Moreover, a novel tensile strength prediction model, incorporating macro–micro damage interactions caused by both microcracks and macrocracks, was developed to explain the failure mechanisms in R–C specimens under radial compression. The model was validated through experimental results, demonstrating its potential for predicting failure behavior in R–C systems. This study offers insights into the fracture mechanics of R–C structures, advancing the understanding of their failure mechanisms and providing a reliable model for tensile strength prediction. Full article
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21 pages, 4160 KiB  
Article
Investigating the Timing of Carbonate Precipitations and Their Potential Impact on Fossil Preservation in the Hell Creek Formation
by Daigo Yamamura
Minerals 2024, 14(11), 1133; https://doi.org/10.3390/min14111133 - 9 Nov 2024
Viewed by 1299
Abstract
Because fossilized skeletal remains and enclosing sedimentary rocks experience similar diagenetic conditions (i.e., temperature, pressure, and pore fluid interaction,) enclosing sedimentary rocks may provide insight into bone diagenesis. A fossil assemblage, including in situ dinosaur fossils, was discovered in Makoshika State Park near [...] Read more.
Because fossilized skeletal remains and enclosing sedimentary rocks experience similar diagenetic conditions (i.e., temperature, pressure, and pore fluid interaction,) enclosing sedimentary rocks may provide insight into bone diagenesis. A fossil assemblage, including in situ dinosaur fossils, was discovered in Makoshika State Park near Glendive, MT. Fossil-bearing sandstone is a crevasse splay deposit, and fossils show no sorting or preferred orientation. Bone-bearing sandstone exhibits evidence for intense diagenesis, suggesting a maximum temperature of ~90 °C. Concretion associated with fossils includes two distinctive matrices: dark- and light-colored matrices. Another concretion was found in channel sandstone near the base of the outcrop. These carbonate phases have distinctive isotopic compositions; δ13C values for dark-colored matrices, light-colored matrices, and spheroidal concretion are −7.5, 2.1, and −22.4‰ (VPDB), respectively, and their δ18O values are 16.4, 25.9, and 17.8‰ (VSMOW), respectively. In contrast, fossilized bone δ13C and δ18O values were −4.4‰ (VPDB) and 20.6‰ (VSMOW), respectively, suggesting fractionation with pore fluid was limited. Early carbonate precipitation evidenced by grain coating may have reduced interaction between pore fluids and fossils. Although concretion formation and permineralization do not appear to directly aid in fossil preservation, concretions preserve valuable evidence for diagenetic history. Full article
(This article belongs to the Special Issue Recent Advances in Bone Diagenesis)
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33 pages, 7015 KiB  
Article
A Novel Polymerized Sulfur Concrete for Underground Hydrogen Storage in Lined Rock Caverns
by Abdel-Mohsen O. Mohamed and Maisa El Gamal
Sustainability 2024, 16(19), 8595; https://doi.org/10.3390/su16198595 - 3 Oct 2024
Cited by 3 | Viewed by 1844
Abstract
Hydrogen is increasingly recognized as a viable solution to meet the growing global energy demand, making large-scale hydrogen storage essential for successfully realizing a full-scale hydrogen economy. Geological formations, such as depleted oil and gas reservoirs, salt caverns, and aquifers, have been identified [...] Read more.
Hydrogen is increasingly recognized as a viable solution to meet the growing global energy demand, making large-scale hydrogen storage essential for successfully realizing a full-scale hydrogen economy. Geological formations, such as depleted oil and gas reservoirs, salt caverns, and aquifers, have been identified as potential storage options. Additionally, unconventional methods like manufactured lined rock caverns and abandoned coal mines are gaining interest. This study introduces polymerized sulfur concrete (PSC) as a promising alternative to replace the current construction systems, which rely on Portland cement concrete and lining materials like stainless steel or polypropylene plastic liners. The paper presents the formulation of PSC, optimization of its compositional design, and evaluation of its physico-mechanical-chemical properties. The results demonstrate that PSC offers excellent mechanical strength, chemical resistance, and low permeability, making it highly suitable for underground hydrogen storage in lined rock caverns. The results showed that the manufactured PSC exhibits excellent physicochemical properties in terms of compressive strength (35–58 MPa), density (2.277–2.488 g/cm3), setting time (30–60 min), curing time (24 h), air content (4–8%), moisture absorption potential (0.17–0.3%), maximum volumetric shrinkage (1.69–2.0%), and maximum service temperature (85–90 °C). Moreover, the PSC is nonconductive and classified with zero flame spread classification and fuel contribution. In addition, the SPC was found to be durable in harsh environmental conditions involving pressure, humidity, and pH variations. It is also capable of resisting corrosive environments. In addition, the statistical modeling indicates that an overall mixture proportion of 32.5 wt.% polymerized sulfur, 32.5 wt.% dune sands, 17.5 wt. % LFS, and 17.5 wt.% GGBFS appear optimal for density values ranging from 2.43 to 2.44 g/cm3 and compressive strength ranging from 52.0 to 53.2 MPa, indicating that the PSC can sustain formation pressure up to about 5.3 km below the ground surface. Therefore, by addressing the critical limitations of traditional materials, PSC proves to be a durable, environmentally sustainable solution for lined rock caverns, reducing the risk of hydrogen leakage and ensuring the integrity of storage systems. Full article
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15 pages, 6799 KiB  
Article
Hardening of Mortars from Blended Cement with Opoka Additive in CO2 Environment
by Raimundas Siauciunas, Edita Prichockiene, Zenonas Valancius and Arunas Elsteris
Ceramics 2024, 7(4), 1301-1315; https://doi.org/10.3390/ceramics7040086 - 26 Sep 2024
Cited by 1 | Viewed by 1299
Abstract
The influence of the parameters of accelerated carbonization in a 99.9% CO2 environment on the hardening kinetics of blended cement with 15 wt% opoka additive, the physical and mechanical properties of the resulting products, the mineralogical composition, and the amount of absorbed [...] Read more.
The influence of the parameters of accelerated carbonization in a 99.9% CO2 environment on the hardening kinetics of blended cement with 15 wt% opoka additive, the physical and mechanical properties of the resulting products, the mineralogical composition, and the amount of absorbed CO2 were investigated. Sedimentary rock opoka was found to have opal silica and calcite as its predominant constituent parts. Therefore, these properties determine that it serves as an extremely suitable raw material and a source of both SiO2 and CaO. The strength properties of the mortars (blended cement/standard sand = 1:3) were similar or even better than those of samples based on Ordinary Portland cement (OPC): the compressive strength exceeded 50 MPa under optimal conditions. In blended cement, some of the pores are filled with fine-dispersed opoka, which can lead to an increase in strength. By reducing the amount of OPC in mixtures, the negative impact of its production on the environment is reduced accordingly. Using XRD, DSC, and TG methods, it was determined that replacing 15 wt% of OPC clinker with opoka does not affect the mineralogy of the crystalline phases as the same compounds are obtained. After determining the optimal parameters for sample preparation and hardening, in accordance with the obtained numbers, concrete pavers of industrial dimensions (100 × 100 × 50 mm) were produced. Their strength indicators were even ~10% better. Full article
(This article belongs to the Special Issue Ceramic Materials for Industrial Decarbonization)
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