Ceramic Materials for Industrial Decarbonization

A special issue of Ceramics (ISSN 2571-6131).

Deadline for manuscript submissions: 30 November 2025 | Viewed by 2157

Special Issue Editors


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Guest Editor
Mechanical Properties and Mechanics Group, Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA
Interests: refractory ceramics; mechanical characterization; ceramic processing, sintering and chracterization

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Guest Editor
Energy Transitions and Infrastructure Programs, Energy Sciences and Technology Directroate, Oak Ridge, National Laboratory (ORNL), P.O. Box 2008, Oak Ridge, TN 37831, USA
Interests: ceramic matrix composites; ceramic fibers; mechanical properties; materials for power generation and the conversion, transmission, storage and utilization of energy; environmental effects of durability and reliability of structural and functional materials; solid-oxide fuel cells

Special Issue Information

Dear Colleagues,

Decarbonization is vital for the mitigation of climate change. This can take many forms and paths as industrial processes are adapted or changed in an effort to reduce carbon intensity, new technologies are developed, and existing technologies are modified. In all of these approaches, ceramic materials can play a vital role in enabling decarbonization.

Existing ceramic materials are being utilized and new ceramic materials are being developed or need to be developed. The aim of this Special Issue, on “Ceramic Materials for Industrial Decarbonization” is to present the latest developments concerning advanced ceramics being utilized, approaches being taken, and future directions research needs to take to enable successful industrial decarbonization and the mitigation of climate change.

We are asking the research community to propose short communications, full papers, or reviews corresponding to this Special Issue. The following topics can be addressed:

  • Existing ceramic materials being applied to the enabling of industrial decarbonization;
  • New ceramic materials being developed to enable industrial decarbonization;
  • Future ceramic research directions needed to enable industrial decarbonization;
  • Characterization of ceramics for industrial decarbonization;
  • Modeling related to the application of ceramics for industrial decarbonization.

Dr. James G. Hemrick
Dr. Edgar Lara-Curzio
Guest Editors

Manuscript Submission Information

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Keywords

  • advanced ceramics
  • ceramic processing
  • ceramic characterization
  • ceramic modeling
  • industrial decarbonization
  • climate change mitigation

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Published Papers (2 papers)

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Research

23 pages, 10496 KiB  
Article
Synthesis MFI Zeolites Using Alternative Silica Source for CO2 Capture
by Clenildo de Longe, Aryandson da Silva, Anne Beatriz Figueira Câmara, Francisco Gustavo Hayala Silveira Pinto, Lindiane Bieseki, Luciene Santos de Carvalho and Sibele Berenice Castellã Pergher
Ceramics 2025, 8(2), 56; https://doi.org/10.3390/ceramics8020056 - 16 May 2025
Viewed by 230
Abstract
In recent years, climate change has attracted the attention of the scientific community. These changes are attributed to human action, which is responsible for the emission of polluting gases, mainly through the burning of fossil fuels, deforestation, and industrial processes that are responsible [...] Read more.
In recent years, climate change has attracted the attention of the scientific community. These changes are attributed to human action, which is responsible for the emission of polluting gases, mainly through the burning of fossil fuels, deforestation, and industrial processes that are responsible for the greenhouse effect. Post-combustion CO2 capture using solid adsorbents is a technology that is currently gaining prominence as an alternative and viable form of capture to other industrial processes used. Zeolites are adsorbents capable of capturing CO2 selectively due to their properties such as textural properties, high surface area, and active sites. In this context, this work developed materials with a zeolite structure with an alternative low-cost silica source from beach sand, called MPI silica, to make the process eco-friendly. Crystallization time studies were carried out for materials containing MFI-type zeolites with MPI silica with a time of 15 h (ZM 15 h) and 3 days (SM 3 d), with relative crystallinities of 92.90% and 111.90%, respectively. The synthesized materials were characterized by several techniques such as X-ray diffraction (XRD), X-ray fluorescence (XRF), the textural analysis of N2 adsorption/desorption isotherms, absorption spectroscopy in the infrared region with Fourier transform (FTIR), scanning electron microscopy (SEM), and thermal analysis. The evaluation of the experimental adsorption isotherms showed that the best results were for the zeolites synthesized in the basic medium, namely ZMP 3 d, ZM 10.5 h, and ZM 15 h, with capacities of 3.72, 3.10, and 3.22 mmol/g of CO2, respectively, and in the hydrofluoric medium, namely SP 9 d, SM 3 d, and SM 6 d, with capacities of 3.94, 3.78, and 3.60 mmol/g of CO2, respectively. The evaluation of the mathematical models indicated that the zeolites in the basic medium best fitted the Freündlich model, namely ZMP 3 d, ZM 10.5 h, and ZM 15 h, with capacities of 2.56, 1.68, and 1.87 mmol/g of CO2, respectively. The zeolites in the hydrofluoric medium are adjusted to the Langmuir model (SP 9 d and SM 3 d) and Temkin model (SM 6 d), with capacities of 3.79, 2.23, and 2.11 mmol/g of CO2, respectively. Full article
(This article belongs to the Special Issue Ceramic Materials for Industrial Decarbonization)
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15 pages, 6799 KiB  
Article
Hardening of Mortars from Blended Cement with Opoka Additive in CO2 Environment
by Raimundas Siauciunas, Edita Prichockiene, Zenonas Valancius and Arunas Elsteris
Ceramics 2024, 7(4), 1301-1315; https://doi.org/10.3390/ceramics7040086 - 26 Sep 2024
Cited by 1 | Viewed by 1129
Abstract
The influence of the parameters of accelerated carbonization in a 99.9% CO2 environment on the hardening kinetics of blended cement with 15 wt% opoka additive, the physical and mechanical properties of the resulting products, the mineralogical composition, and the amount of absorbed [...] Read more.
The influence of the parameters of accelerated carbonization in a 99.9% CO2 environment on the hardening kinetics of blended cement with 15 wt% opoka additive, the physical and mechanical properties of the resulting products, the mineralogical composition, and the amount of absorbed CO2 were investigated. Sedimentary rock opoka was found to have opal silica and calcite as its predominant constituent parts. Therefore, these properties determine that it serves as an extremely suitable raw material and a source of both SiO2 and CaO. The strength properties of the mortars (blended cement/standard sand = 1:3) were similar or even better than those of samples based on Ordinary Portland cement (OPC): the compressive strength exceeded 50 MPa under optimal conditions. In blended cement, some of the pores are filled with fine-dispersed opoka, which can lead to an increase in strength. By reducing the amount of OPC in mixtures, the negative impact of its production on the environment is reduced accordingly. Using XRD, DSC, and TG methods, it was determined that replacing 15 wt% of OPC clinker with opoka does not affect the mineralogy of the crystalline phases as the same compounds are obtained. After determining the optimal parameters for sample preparation and hardening, in accordance with the obtained numbers, concrete pavers of industrial dimensions (100 × 100 × 50 mm) were produced. Their strength indicators were even ~10% better. Full article
(This article belongs to the Special Issue Ceramic Materials for Industrial Decarbonization)
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