Search Results (40)

Boron-containing concrete is an important neutron-shielding material for nuclear engineering, but the addition of boron compounds may adversely affect cement hydration and mechanical properties. This study employed boric acid and boron carbide as boron-10 neutron-absorbing sources. Within the material system investigated, the comprehensive effects of boric acid, boron carbide, and their combined use on setting time, mechanical properties, and effective boron loading were compared. MAA-based mix design and the analytic hierarchy process (AHP) were then employed to screen candidate mix proportions. Based on particle packing optimization, a series of concrete mixtures were prepared to evaluate workability, setting time, mechanical strength, boron content, and hydration products. The results show that boric acid provides good boron dispersibility but strongly retards cement hydration, leading to prolonged setting time and reduced strength. Pretreatment with calcium hydroxide and the use of an early strength admixture can partly mitigate this negative effect; the final setting time of the boric acid-containing mixtures still reached as high as 34 h 11 min. Boron carbide exhibits better chemical stability and has less influence on cement hydration. When incorporated at 5–10%, boron carbide improves the balance between mechanical performance and neutron-shielding potential. In particular, the 10% boron carbide mixture achieved a 28-day compressive strength of 47.3 MPa and a splitting tensile strength of 4.21 MPa, compared with 55.5 MPa and 6.2 MPa, respectively, for the control mixture, while maintaining relatively high strength. An analytic hierarchy process was further applied to comprehensively evaluate compressive strength, splitting tensile strength, final setting time, and boron content. Furtherly, XRD results confirmed the different interaction mechanisms of boric acid and boron carbide in cementitious systems. The study provides a framework for developing boron-containing concrete with potential neutron-shielding applications. Full article

To address the technical challenges of hydration retardation and low early strength of foamed concrete in low-temperature environments of cold regions, this study investigated the effects of low-temperature curing (cycling between −5 °C and 5 °C) on the mechanical properties and microstructure of foamed concrete. Single-factor experiments were conducted to explore the effects of triethanolamine (TEA), urea, and polypropylene fibers (PPF) on the mechanical performance of foamed concrete. A response surface methodology (RSM) was employed to establish regression models between the dosages of each component and the compressive strength (CS), thereby determining the optimal mix proportion under low-temperature curing. The experimental results indicate that increasing the urea dosage leads to an increase in the flowability of foamed concrete, and the effects of the three types of admixtures on the CS all exhibit a non-linear characteristic that first increases and then decreases. The significance of the three factors on the CS of the material follows the order: TEA > PPF > urea. The obtained optimal mix proportion is 0.052% TEA, 1.08% urea, and 0.194% PPF, yielding 3, 7, and 28 d CS of 1.088 MPa, 1.342 MPa, and 2.301 MPa, respectively. Microstructural analysis via SEM observations and XRD analysis suggest that the admixtures effectively compensate for the hydration retardation induced by low temperatures, promoting the abundant generation of needle-like ettringite (AFt) and C-S-H gels that interweave into a dense network, thereby achieving higher strength. This study provides a theoretical basis and technical support for the low-temperature construction of foamed concrete subgrades in cold regions. Full article

Traditional research was mostly focused on the effects of emulsions on the mechanical properties and durability of cement mortar, while studies on the regulation mechanism of emulsions on the rheological properties of cement-based materials and the coupling mechanism with the hydration process were rarely conducted. In this paper, a novel core–shell structured emulsion was prepared by free radical polymerization. The regulation of cement mortar yield stress, creep recovery, dynamic viscosity, and thixotropy by different dosages (0–10%) of the emulsion admixture was systematically investigated, and combined with characterization by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR), the microscopic action mechanism of the emulsion was elucidated. It was demonstrated that the Bingham fluid behavior of cement mortar was not altered by the core–shell emulsion, whereas a significant dosage-dependent regulatory effect on its rheological parameters was observed, and a critical regulation interval of 4–6% was identified. At an emulsion dosage of 10%, the yield stress of the mortar was increased by 937.0% compared to that of the control group. At dosages of 2–4%, the static structural stability and construction flowability of the mortar were synergistically optimized, and the weakest thixotropy and the best structural stability were exhibited at an emulsion dosage of 4%. A more pronounced shear-thinning behavior was shown by all modified mortars, and their high-shear flowability was not affected. Microstructural analysis confirmed that no chemical reaction occurred between the emulsion and the cement hydration products. Through the triple effects of “hydration retardation by physical coating, pore filling and densification, and composite network enhancement”, a film was formed on the surface of cement particles by the emulsion, which hindered the diffusion of water and ions, thereby regulating the cement hydration process and microstructural evolution. Full article

Due to the tendency of backfill slurry to stagnate within pipelines during transportation, a time-dependent rheological model for basalt fiber-reinforced gangue cemented slurry was developed based on the H-B rheological model and flocculation structure theory to ensure unimpeded slurry flow within pipelines over specified time periods. Experiments were conducted to investigate the time-dependent yield stress evolution of 9 mm fiber-reinforced gangue cemented slurry over time under varying conditions, specifically examining the effects of adding 9 mm fiber-reinforced (accounting for 0.5% of the total mass of the slurry) gangue cemented slurry under varying conditions. Significant effects of mass concentration, sucrose admixture content, and fly ash concentration on the yield stress of the slurry under different standing times were investigated. Research findings indicate that the yield stress of the paste increases with rising mass concentration and also rises with extended standing time. For slurries with mass concentrations ranging from 76% to 82%, the yield stress after 120 min of standing increased by 81.03%, 80%, 82%, and 97.48%, respectively, compared to freshly mixed slurries. The yield stress decreases with increasing sucrose dosage. Below 0.5% sucrose dosage, the rate of yield stress increase with standing time is relatively slow; above 0.5%, the rate increases more rapidly. After 120 min of standing, the yield stress of slurries with a sucrose dosage ranging from 0.25% to 1.00% increased by 48.66%, 54.42%, 32.90%, and 33.70%, respectively, compared to freshly mixed slurry. Yield stress decreased with increasing fly ash content and exhibited an overall steady upward trend with standing time. Based on the fitting surfaces depicting the variation in yield stress in filling materials over time under different influencing factors, fitting expressions were derived. Analysis of variance revealed that the time-dependent behavior of filling materials is primarily influenced by mass concentration, followed by retarder dosage and fly ash proportion. Full article

The addition of sulfoaluminate cement (SAC) to ultra-high-performance concrete (UHPC) enables sustainable high-speed construction due to the high 7-day strength without thermal curing. The fast hydration of SAC, however, endangers the admixture efficacy, which may compromise the structural integrity of the infrastructure components. This study investigates the effect of the physical form of polycarboxylate ether (PCE) superplasticizers on the performance of UHPC with the incorporation of SAC in ambient conditions. A paired experimental design of 32 mixtures compared liquid superplasticizers (LSPs) and powder superplasticizers (PSPs) in various binder compositions (OPC/SAC of 1/4–4/1) and water-to-binder ratios (0.18–0.21) at a constant dosage of admixtures of 1% except where w/b 0.18 (1.5% superplasticizers and 1% retarders were used). Findings indicate that LSPs enhance workability and compressive strength by 45% and 10.03%, respectively. The underlying mechanism is explained by comprehensive microstructural characterization through the use of Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD) and Fourier Transform Infrared (FTIR) spectroscopy. SEM study showed a 23% decrease in porosity, and XRD patterns showed the increased formation of amorphous C-S-H gel for LSPs. The higher levels of Al³⁺ incorporated into the gel structure (C-A-S-H) of the liquid forms was also verified by FTIR spectra. Mechanically, the research reveals one of the kinetic mismatches, where the rate of SAC hydration is greater than the rate of powder dissolution, which leads to a failure to fully disperse and shear-controlled failures. LSPs, in contrast, make it possible to disperse particles immediately, so the matrices become more dense and shift to axial failure. These results provide practical guidelines to infrastructure engineers to use liquid superplasticizer in SAC-based systems in order to achieve sustainability and reliability in terms of performance in precast and fast-track construction projects. Full article

Enhancing the freeze–thaw resistance of cement-based materials in a green and efficient manner is crucial for hydraulic structures in cold regions. This study investigated the effects of soybean antifreeze protein (AFP) on the freeze–thaw durability of cement mortar through mechanical testing, low-temperature microscopy, NMR analysis, and frost-heaving stress monitoring. The results show that AFP improves freeze–thaw durability, with 0.5% dosage outperforming 1.0%. Relative to the control, the relative ice content at −20 °C decreased from 62.81% to 40.01%, and frost-heaving stress declined from 321.15 kPa to 123.04 kPa. Microscopy and pore structure analyses revealed that AFP transforms ice crystals from needle-like to fine granular forms, inhibiting ordered growth and retarding pore coarsening. A frost-heaving stress model based on the Gibbs–Thomson effect and ice-crystal fractal characteristics indicated that AFP suppresses stress development by reducing effective ice formation, weakening stress transfer, and increasing ice-crystal boundary complexity. This study offers insights for developing green antifreeze admixtures for cement-based materials in cold regions. Full article

This study synthesizes two highly water-soluble copolymers, p(SA-co-SMAS) and p(SA-co-SMAS-co-AMPS) using sodium alginate (SA), sodium 2-methylprop-2-ene-1-sulfonate (SMAS), and 2-acrylamido-2-methylpropane sulfonic acid (AMPS, with or without addition) as precursors. Under ball milling, these copolymers are blended with aluminum sulfate and glass fibers to produce two series of cement admixtures. Compared to systems without admixtures or with pure aluminum sulfate as sole admixture, the admixture obtained from p(SA-co-SMAS) and aluminum sulfate significantly shortens the initial setting time (4.47 vs. 33.59 and 29.51 min) and final setting time (8.46 vs. 45.26 and 35.12 min), while markedly improving compressive strength (9.2 vs. 3.5 and 4.3 MPa) and flexural strength (3.5 vs. 1.0 and 1.1 MPa). This enhancement is attributed to the formation of a unique boehmite (AlO(OH)) phase in synthesized admixture, which rapidly reacts with tricalcium silicate, gypsum, and water in cement to form ettringite (Ca₆Al₂(SO₄)₃(OH)₁₂·26H₂O). The ettringite interlocks with the two-dimensional C–S–H gel, creating a stable three-dimensional network. Further blending this admixture with 200-mesh glass fibers yields a new admixture containing Al₄SO₄(OH)₁₀·36H₂O. Compared to boehmite, this phase further reduces setting times and increases average compressive strength (10.2 vs. 9.2 MPa). The admixture derived from p(SA-co-SMAS-co-AMPS) and aluminum sulfate shows even better performance: setting times are further shortened and flexural strength is significantly enhanced, owing to the presence of the more effective Al₄SO₄(OH)₁₀·36H₂O phase. Incorporating 200-mesh glass fibers into this system results in the shortest setting times (initial: 2.24 min, final: 5.73 min) and an excellent 24 h compressive strength (9.4 MPa), likely due to a unique and unexpected pore-filling effect. In contrast to conventional uses of sodium alginate as a retarder, glass fibers as mere reinforcements, and aluminum sulfate as a strength-impairing accelerator, this work demonstrates a synergistic strategy, which enables an ultra-rapid and high-strength cement setting process, offering highly significant scientific and practical value. Full article

Calcium magnesium phosphate cements (CMPCs) were obtained starting from dolomite (alone or mixed with fly ash) thermally treated at two different temperatures. Dolomite calcination at 750 °C for 3 h determined the formation of a mixture of MgO and CaCO₃. The mixing of dolomite with fly ash and the increase in the calcination temperature at 1200 °C determined the formation of new compounds (calcium aluminum silicate and calcium magnesium silicates), which are present along with MgO and small amounts of CaO in the thermally treated material. These two precursors were mixed with KH₂PO₄ solution and borax (as a retardant admixture) to obtain the CMPCs. The setting time and compressive strengths of these CMPCs were assessed and the XRD analyses provided insights into their mineralogical composition after hardening and thermal treatment. The cements, as so or mixed with perlite, were applied on steel plates, to assess their behavior when put in direct contact with a flame. The compatibility of these materials with the steel substrate was evaluated by scanning electron microscopy (SEM). The direct contact with the flame up to 60 min provided information regarding the CMPCs’ ability to prevent the rapid increase in the substrate (steel plate) temperature. The findings indicate that CMPC pastes and composites containing perlite can offer a degree of protection for steel structures in the event of a fire. Full article

This study presents a new ternary copolymer synthesized via aqueous free-radical polymerization from sodium humate, sodium 2-methylprop-2-ene-1-sulfonate (SMAS), and 2-acrylamido-2-methylpropane sulfonic acid (AMPS). The resulting highly water-soluble, three-dimensional porous copolymer is complexed with aluminum sulfate to form a composite admixture containing AlO(OH), which acts as a highly effective accelerator for cement hydration. This system significantly shortens the initial and final setting times to averages of 2.62 min and 4.53 min, respectively, and enhances early-age mechanical strength (1.7 MPa compressive, 1.4 MPa flexural at 6 h). These improvements are correlated with the formation of key crystalline phases, including Al₂Si₂O₅(OH)₄ and Ca₃Al₂O₆·xH₂O gel. Incorporation of 50-mesh carbon fibers further reduces setting times (2.21 min initial, 3.93 min final) and increases 24 h strength (5.2 MPa compressive, 2.7 MPa flexural), despite a slight reduction in early strength (at 6 h). In contrast, 200-mesh carbon fibers extend the initial setting time and diminish early strength, associated with the formation of less effective gel phases such as Ca₃Al₂O₆·xH₂O, (CaO)_x(Al₂O₃)₁₁, and Ca₄Al₂O₇·xH₂O. Among these, the Al₂Si₂O₅(OH)₄ phase demonstrates superior performance, while finer carbon fibers show limited effectiveness in bridging hydration products. Conventionally employed as retarders or reinforcing agents, humate-based polymers and carbon fibers are shown here to function as dual-functional admixtures—serving as efficient setting accelerators while enhancing mechanical properties through tailored material design. This strategy offers a promising pathway for developing advanced multifunctional cement admixtures. Full article

This study systematically explored the influence of Polycarboxylate Ether (PCE) content on the fluidity, setting time, and compressive and flexural strength of Ultra-fine Portland Cement (SPC) cement-based grout through the external admixture method. The microstructure and evolution of hydration products were analyzed using XRD and SEM to reveal the modification mechanism. The results showed that the optimal PCE content was 0.25% (calculated based on the mass of SPC), at which the fluidity of the grout reached 273 mm, and the initial and final setting times were extended from 130 min and 235 min to 268 min and 310 min, respectively, reflecting significant plasticizing and retarding effects. The mechanical properties were particularly improved, with the compressive strength of the hardened paste at 7 d and 28 d increasing by 28.78% and 37.09%, respectively, and the flexural strength increasing by 11.20% and 14.52%, respectively. Microscopic analysis indicated that PCE optimized particle packing through adsorption–dispersion effects and moderately delayed the early hydration process, promoting the more thorough and uniform growth of hydration products (such as C-S-H gel), thereby generating a denser microstructure. This is the fundamental reason for the improvement in macroscopic properties. This study provides important theoretical and experimental basis for the performance optimization and engineering application of SPC-based grouting materials under low water–cement ratios. Full article

In order to shorten the curing time of the cement-treated aggregate base, provide a stable paving base for an asphalt mixture, and finally, achieve rapid traffic reopening during the maintenance of the pavement (milling and resurfacing of the base layer), sulphoaluminate cement (SAC) was used to prepare cement-treated aggregate with high early strength. As a result, the SAC was first optimized by adding several cement admixtures (i.e., polycarboxylic water reducer, borax, lithium carbonate, and calcium formate) based on hydration kinetics, setting time, compressive strength, and morphology tests. Then, the optimized SAC was used to prepare the sulphoaluminate cement-treated aggregate (SACTA). The test results show that the addition of compound retarder and compound early strength agent in SAC could delay the hydration, reduce microcracks, and ensure required setting time and high early strength. Compared with ordinary Portland cement-treated aggregates (OPCTAs) with the same cement content, the 1 d unconfined compressive strength and indirect tension strength of SACTAs increased by 87.7–184.6% and 133.8–263.6% respectively. The SACTA had smaller total drying shrinkage strain and better anti-scouring performance than OPCTA when using the same cement content. Besides, the 1 d interfacial bonding strength between SACTA and OPCTA was 0.18 MPa, which was higher than the indirect tension strength of OPCTA. The findings in this study indicate that the prepared SACTA could be used for rapid traffic opening during road maintenance. Full article

This study investigates the fire resistance capabilities of newly developed loose-fill thermal insulation materials crafted from annual plants such as wheat straw, corn stalk, and water reed. Three processing methodologies were employed: mechanical crushing (raw, size ≤ 20 mm), chemi-mechanical pulping (CMP) using 4% sodium hydroxide, and steam explosion (SE). An admixture of boric acid (8%) and tetraborate (7%) was added to all treated materials to enhance fire retardancy. The fire reaction characteristics of the insulation materials were assessed using a cone calorimeter measuring the key parameters like time to ignition, total heat release, heat release rate, and total smoke production. The findings indicate that nearly all tested insulation samples, apart from the raw and SE water reed, demonstrated fire resistance comparable to commercial cellulose insulation, surpassing the fire performance of various synthetic foams and composite materials. Furthermore, the single-flame source fire tests indicated that the developed insulation materials achieved a fire classification E, except for the SE water reed sample. Thus, the fire performance results approve the suitability of developed plant-based insulation materials for competing materials in building constructions. Full article

Water reducer and water-repellent admixture are very important in improving the workability and durability of cement-based materials. However, the synergistic effect of the two types of admixtures has not been well investigated. In this study, polycarboxylate ether-based superplasticizer (PCE) and octyltriethoxysilane (OTS) were adopted as water reducer and water-repellent admixture, respectively. Their synergistic effect on the fluidity, compressive strength, and water absorption rate of cement-based materials was investigated. Particularly, the pore structure and hydration state of cement paste were analyzed using ¹H Low-Field Nuclear Magnetic Resonance (¹H LF NMR). The result showed that the fluidity of cement paste containing different dosages of PCE was reduced by 5–10 mm by incorporating 1% OTS, and the compressive strength at the early age of 3 d of mortar containing high PCE dosage of 0.25% decreased up to 15% by using 1% OTS. In contrast, the compressive strength of mortar containing 0.20% PCE was slightly enhanced by the addition of 1% OTS. ¹H LF NMR analysis revealed that the combination of PCE and OTS would increase the pore size and total pore volume of cement paste, and more bleeding water would be generated at high PCE dosage. The intensity-weighted T₂ values of the main peak ($\overline{T_2}$) implied that both PCE and OTS produced a retardation effect on cement hydration. However, the water absorption rate decreased by 46.6% despite the increase in pore size and total pore volume. The conflict phenomenon powerfully revealed that the internal hydrophobic treatment by OTS has been successfully achieved. Overall, the combination of 0.20% PCE and 1% OTS exerted a positive synergistic effect in improving the compressive strength and water-repelling ability of cement-based materials, which is meaningful for improving their durability and service life. Full article

Magnesium silicate ceramics are promising materials for bone tissue regeneration and can be prepared through 3D printing of magnesium oxide/silica (MgO/SiO₂) cement pastes followed by calcination. Despite the growing interest in these formulations, additive manufacturing technology has only recently been explored for these cements, and the effects of admixtures and additives on such printing inks remain largely unexplored. In this study, we prepared various MgO/SiO₂ cement formulations with differing amounts of sodium orthophosphate, a setting retarder, and cellulose ethers, used as rheo-modifiers. The samples’ setting properties were investigated, and printing parameters were properly adjusted. The most promising formulations were then 3D printed and calcined to obtain forsterite bioceramics, which were further characterized using confocal Raman microscopy, scanning electron microscopy, atomic force microscopy, gas porosimetry, and compressive strength tests. Our results revealed that the cellulose derivatives influence the printability of the MgO/SiO₂ formulations without affecting the hardening time, which can be adjusted by the addition of sodium phosphate. The use of fine-tuned formulations allowed for the preparation of 3D-printed forsterite bioceramics, potentially suitable for biological applications as cancellous bone scaffolds. Full article

The production of flue gas desulfurization gypsum poses a serious threat to the environment. Thus, utilizing gypsum-based self-leveling mortar (GSLM) stands out as a promising and effective approach to address the issue. β-hemihydrate gypsum, cement, polycarboxylate superplasticizer, hydroxypropyl methyl cellulose ether (HPMC), retarder, and defoamer were used to prepare GSLM. The impact of mineral admixtures (steel slag (SS), silica fume (SF), and fly ash (FA)) on the physical, mechanical, and microstructural properties of GSLM was examined through hydration heat, X-ray diffractometry (XRD), Raman spectroscopy, and scanning electron microscopy (SEM) analyses. The GSLM benchmark mix ratio was determined as follows: 94% of desulfurization building gypsum, 6% of cement, 0.638% each of water reducer and retarder, 0.085% each of HPMC and defoamer (calculated additive ratio relative to gypsum), and 0.54 water-to-cement ratio. Although the initial fluidity decreased in the GSLM slurry with silica fume, there was minimal change in 30 min fluidity. Notably, at an SS content of 16%, the GSLM exhibited optimal flexural strength (6.6 MPa) and compressive strength (20.4 MPa). Hydration heat, XRD, and Raman analyses revealed that a small portion of SS actively participated in the hydration reaction, while the remaining SS served as a filler. Full article