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Keywords = potential controlled friction

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37 pages, 2573 KiB  
Article
Assessing Blockchain Health Devices: A Multi-Framework Method for Integrating Usability and User Acceptance
by Polina Bobrova and Paolo Perego
Computers 2025, 14(8), 300; https://doi.org/10.3390/computers14080300 - 23 Jul 2025
Viewed by 149
Abstract
Integrating blockchain into healthcare devices offers the potential for improved data control but faces significant usability and acceptance challenges. This study addresses this gap by evaluating CipherPal, an improved blockchain-enabled Smart Fidget Toy prototype, using a multi-framework approach to understand the interplay between [...] Read more.
Integrating blockchain into healthcare devices offers the potential for improved data control but faces significant usability and acceptance challenges. This study addresses this gap by evaluating CipherPal, an improved blockchain-enabled Smart Fidget Toy prototype, using a multi-framework approach to understand the interplay between technology, design, and user experience. We synthesized insights from three complementary frameworks: an expert review assessing adherence to Web3 Design Guidelines, a User Acceptance Toolkit assessment with professionals based on UTAUT2, and an extended three-day user testing study. The findings revealed that users valued CipherPal’s satisfying tactile interaction and perceived benefits for well-being, such as stress relief. However, significant usability barriers emerged, primarily related to challenging device–application connectivity and data synchronization. The multi-framework approach proved valuable in revealing these core tensions. While the device was conceptually accepted, the blockchain integration added significant interaction friction that overshadowed its potential benefits during the study. This research underscores the critical need for user-centered design in health-related blockchain applications, emphasizing that seamless usability and abstracting technical complexity are paramount for adoption. Full article
(This article belongs to the Special Issue When Blockchain Meets IoT: Challenges and Potentials)
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16 pages, 4597 KiB  
Article
Synthesis and Property Analysis of a High-Temperature-Resistant Polymeric Surfactant and Its Promoting Effect on Kerogen Pyrolysis Evaluated via Molecular Dynamics Simulation
by Jie Zhang, Zhen Zhao, Jinsheng Sun, Shengwei Dong, Dongyang Li, Yuanzhi Qu, Zhiliang Zhao and Tianxiang Zhang
Polymers 2025, 17(15), 2005; https://doi.org/10.3390/polym17152005 - 22 Jul 2025
Viewed by 198
Abstract
Surfactants can be utilized to improve oil recovery by changing the performance of reservoirs in rock pores. Kerogen is the primary organic matter in shale; however, high temperatures will affect the overall performance of this surfactant, resulting in a decrease in its activity [...] Read more.
Surfactants can be utilized to improve oil recovery by changing the performance of reservoirs in rock pores. Kerogen is the primary organic matter in shale; however, high temperatures will affect the overall performance of this surfactant, resulting in a decrease in its activity or even failure. The effect of surfactants on kerogen pyrolysis has rarely been researched. Therefore, this study synthesized a polymeric surfactant (PS) with high temperature resistance and investigated its effect on kerogen pyrolysis under the friction of drill bits or pipes via molecular dynamics. The infrared spectra and thermogravimetric and molecular weight curves of the PS were researched, along with its surface tension, contact angle, and oil saturation measurements. The results showed that PS had a low molecular weight, with an MW value of 124,634, and good thermal stability, with a main degradation temperature of more than 300 °C. It could drop the surface tension of water to less than 25 mN·m−1 at 25–150 °C, and the use of slats enhanced its surface activity. The PS also changed the contact angles from 127.96° to 57.59° on the surface of shale cores and reversed to a water-wet state. Additionally, PS reduced the saturated oil content of the shale core by half and promoted oil desorption, indicating a good cleaning effect on the shale oil reservoir. The kerogen molecules gradually broke down into smaller molecules and produced the final products, including methane and shale oil. The main reaction area in the system was the interface between kerogen and the surfactant, and the small molecules produced on the interface diffused to both ends. The kinetics of the reaction were controlled by two processes, namely, the step-by-step cleavage process of macromolecules and the side chain cleavage to produce smaller molecules in advance. PS could not only desorb oil in the core but also promote the pyrolysis of kerogen, suggesting that it has good potential for application in shale oil exploration and development. Full article
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32 pages, 3675 KiB  
Article
Gibbs Quantum Fields Computed by Action Mechanics Recycle Emissions Absorbed by Greenhouse Gases, Optimising the Elevation of the Troposphere and Surface Temperature Using the Virial Theorem
by Ivan R. Kennedy, Migdat Hodzic and Angus N. Crossan
Thermo 2025, 5(3), 25; https://doi.org/10.3390/thermo5030025 - 22 Jul 2025
Viewed by 212
Abstract
Atmospheric climate science lacks the capacity to integrate thermodynamics with the gravitational potential of air in a classical quantum theory. To what extent can we identify Carnot’s ideal heat engine cycle in reversible isothermal and isentropic phases between dual temperatures partitioning heat flow [...] Read more.
Atmospheric climate science lacks the capacity to integrate thermodynamics with the gravitational potential of air in a classical quantum theory. To what extent can we identify Carnot’s ideal heat engine cycle in reversible isothermal and isentropic phases between dual temperatures partitioning heat flow with coupled work processes in the atmosphere? Using statistical action mechanics to describe Carnot’s cycle, the maximum rate of work possible can be integrated for the working gases as equal to variations in the absolute Gibbs energy, estimated as sustaining field quanta consistent with Carnot’s definition of heat as caloric. His treatise of 1824 even gave equations expressing work potential as a function of differences in temperature and the logarithm of the change in density and volume. Second, Carnot’s mechanical principle of cooling caused by gas dilation or warming by compression can be applied to tropospheric heat–work cycles in anticyclones and cyclones. Third, the virial theorem of Lagrange and Clausius based on least action predicts a more accurate temperature gradient with altitude near 6.5–6.9 °C per km, requiring that the Gibbs rotational quantum energies of gas molecules exchange reversibly with gravitational potential. This predicts a diminished role for the radiative transfer of energy from the atmosphere to the surface, in contrast to the Trenberth global radiative budget of ≈330 watts per square metre as downwelling radiation. The spectral absorptivity of greenhouse gas for surface radiation into the troposphere enables thermal recycling, sustaining air masses in Lagrangian action. This obviates the current paradigm of cooling with altitude by adiabatic expansion. The virial-action theorem must also control non-reversible heat–work Carnot cycles, with turbulent friction raising the surface temperature. Dissipative surface warming raises the surface pressure by heating, sustaining the weight of the atmosphere to varying altitudes according to latitude and seasonal angles of insolation. New predictions for experimental testing are now emerging from this virial-action hypothesis for climate, linking vortical energy potential with convective and turbulent exchanges of work and heat, proposed as the efficient cause setting the thermal temperature of surface materials. Full article
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55 pages, 8888 KiB  
Article
Single, Multi-, and Many-Objective Optimization of Manufacturing Processes Using Two Novel and Efficient Algorithms with Integrated Decision-Making
by Ravipudi Venkata Rao and Joao Paulo Davim
J. Manuf. Mater. Process. 2025, 9(8), 249; https://doi.org/10.3390/jmmp9080249 - 22 Jul 2025
Viewed by 607
Abstract
Manufacturing processes are inherently complex, multi-objective in nature, and highly sensitive to process parameter settings. This paper presents two simple and efficient optimization algorithms—Best–Worst–Random (BWR) and Best–Mean–Random (BMR)—developed to solve both constrained and unconstrained optimization problems of manufacturing processes involving single, multi-, and [...] Read more.
Manufacturing processes are inherently complex, multi-objective in nature, and highly sensitive to process parameter settings. This paper presents two simple and efficient optimization algorithms—Best–Worst–Random (BWR) and Best–Mean–Random (BMR)—developed to solve both constrained and unconstrained optimization problems of manufacturing processes involving single, multi-, and many-objectives. These algorithms are free from metaphorical inspirations and require no algorithm-specific control parameters, which often complicate other metaheuristics. Extensive testing reveals that BWR and BMR consistently deliver competitive, and often superior, performance compared to established methods. Their multi- and many-objective extensions, named MO-BWR and MO-BMR, respectively, have been successfully applied to tackle 2-, 3-, and 9-objective optimization problems in advanced manufacturing processes such as friction stir processing (FSP), ultra-precision turning (UPT), laser powder bed fusion (LPBF), and wire arc additive manufacturing (WAAM). To aid in decision-making, the proposed BHARAT can be integrated with MO-BWR and MO-BMR to identify the most suitable compromise solution from among a set of Pareto-optimal alternatives. The results demonstrate the strong potential of the proposed algorithms as practical tools for intelligent decision-making in real-world manufacturing applications. Full article
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17 pages, 2870 KiB  
Article
Influence of Magnetorheological Finishing on Surface Topography and Functional Performance of Shoulder Joint Cap Surface
by Manpreet Singh, Gagandeep Singh, Riyad Abu-Malouh, Sumika Chauhan and Govind Vashishtha
Materials 2025, 18(14), 3397; https://doi.org/10.3390/ma18143397 - 20 Jul 2025
Viewed by 329
Abstract
The surface quality of biomedical implants, such as shoulder joint caps, plays a critical role in their performance, longevity, and biocompatibility. Most biomedical shoulder joints fail to reach their optimal functionality when finished through conventional techniques like grinding and lapping due to their [...] Read more.
The surface quality of biomedical implants, such as shoulder joint caps, plays a critical role in their performance, longevity, and biocompatibility. Most biomedical shoulder joints fail to reach their optimal functionality when finished through conventional techniques like grinding and lapping due to their inability to achieve nanometer-grade smoothness, which results in greater wear and friction along with potential failure. The advanced magnetorheological finishing (MRF) approach provides enhanced surface quality through specific dimensional control material removal. This research evaluates how MRF treatment affects the surface roughness performance and microhardness properties and wear resistance behavior of cobalt–chromium alloy shoulder joint caps which have biocompatible qualities. The study implements a magnetorheological finishing system built with an electromagnetic tool to achieve the surface roughness improvements from 0.35 µm to 0.03 µm. The microhardness measurements show that MRF applications lead to a rise from HV 510 to HV 560 which boosts the wear protection of samples. After MRF finishing, the coefficient of friction demonstrates a decrease from 0.12 to 0.06 which proves improved tribological properties of these implants. The results show that MRF technology delivers superior benefits for biomedical use as it extends implant life span and decreases medical complications leading to better patient health outcomes. The purposeful evaluation of finishing techniques and their effects on implant functionality demonstrates MRF is an advanced technology for upcoming orthopedic implants while yielding high precision and enhanced durability and functional output. Full article
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17 pages, 3902 KiB  
Article
Electrical Potential-Induced Lubricity Changes in an Ionic Liquid-Lubricated Friction Pair
by Raimondas Kreivaitis, Audrius Žunda and Albinas Andriušis
Lubricants 2025, 13(7), 311; https://doi.org/10.3390/lubricants13070311 - 17 Jul 2025
Viewed by 316
Abstract
The control of lubricity induced by electric potential is appealing for numerous applications. On the other hand, the high polarity of ionic liquids facilitates the adsorption of equally charged molecules onto polar surfaces. This phenomenon and its consequences are well understood at the [...] Read more.
The control of lubricity induced by electric potential is appealing for numerous applications. On the other hand, the high polarity of ionic liquids facilitates the adsorption of equally charged molecules onto polar surfaces. This phenomenon and its consequences are well understood at the nanoscale; however, they have recently garnered significant attention at the macroscale. This study investigates the lubricity of trihexyltetradecylphosphonium dicyanamide, a phosphonium ionic liquid, when used as a neat lubricant in reciprocating sliding under electrically charged conditions. Two different polarities with the same potential were applied to the friction pair of bearing steel against bearing steel while monitoring electrical contact resistance. The lubricity was evaluated through measurements of friction, wear, surface morphology, and composition. It was found that the application of electric potential significantly alters the lubricity of the investigated ionic liquid where a positive potential applied to the ball resulted in the least damaging situation. The recorded electrical contact resistance enabled the monitoring of tribofilm formation during reciprocation. It was found that there was minimal to no separation between interacting surfaces when the ball was changing direction. Full article
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19 pages, 7661 KiB  
Article
Bioinspired Kirigami Structure for Efficient Anchoring of Soft Robots via Optimization Analysis
by Muhammad Niaz Khan, Ye Huo, Zhufeng Shao, Ming Yao and Umair Javaid
Appl. Sci. 2025, 15(14), 7897; https://doi.org/10.3390/app15147897 - 15 Jul 2025
Viewed by 253
Abstract
Kirigami-inspired geometries offer a lightweight, bioinspired strategy for friction enhancement and anchoring in soft robotics. This study presents a bioinspired kirigami structure designed to enhance the anchoring performance of soft robotic systems through systematic geometric and actuation parameter optimization. Drawing inspiration from the [...] Read more.
Kirigami-inspired geometries offer a lightweight, bioinspired strategy for friction enhancement and anchoring in soft robotics. This study presents a bioinspired kirigami structure designed to enhance the anchoring performance of soft robotic systems through systematic geometric and actuation parameter optimization. Drawing inspiration from the anisotropic friction mechanisms observed in reptilian scales, we integrated linear, triangular, trapezoidal, and hybrid kirigami cuts onto flexible plastic sheets. A compact 12 V linear actuator enabled cyclic actuation via a custom firmware loop, generating controlled buckling and directional friction for effective locomotion. Through experimental trials, we quantified anchoring efficiency using crawling distance and stride metrics across multiple cut densities and actuation conditions. Among the tested configurations, the triangular kirigami with a 4 × 20 unit density on 100 µm PET exhibited the most effective performance, achieving a stride efficiency of approximately 63% and an average crawling speed of ~47 cm/min under optimized autonomous operation. A theoretical framework combining buckling mechanics and directional friction validated the observed trends. This study establishes a compact, tunable anchoring mechanism for soft robotics, offering strong potential for autonomous exploration in constrained environments. Full article
(This article belongs to the Special Issue Advances in Robotics and Autonomous Systems)
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13 pages, 5099 KiB  
Article
Effect of Grain Size Distribution on Frictional Wear and Corrosion Properties of (FeCoNi)86Al7Ti7 High-Entropy Alloys
by Qinhu Sun, Pan Ma, Hong Yang, Kaiqiang Xie, Shiguang Wan, Chunqi Sheng, Zhibo Chen, Hongji Yang, Yandong Jia and Konda Gokuldoss Prashanth
Entropy 2025, 27(7), 747; https://doi.org/10.3390/e27070747 - 12 Jul 2025
Viewed by 226
Abstract
Optimization of grain size distribution in high-entropy alloys (HEAs) is a promising design strategy to overcome wear and corrosion resistance. In this study, a (FeCoNi)86Al7Ti7 high-entropy alloy with customized isometric and heterogeneous structure, as well as fine-crystal isometric [...] Read more.
Optimization of grain size distribution in high-entropy alloys (HEAs) is a promising design strategy to overcome wear and corrosion resistance. In this study, a (FeCoNi)86Al7Ti7 high-entropy alloy with customized isometric and heterogeneous structure, as well as fine-crystal isometric design by SPS, is investigated for microstructure, surface morphology, hardness, frictional wear, and corrosion resistance. The effects of the SPS process on the microstructure and mechanical behavior are elucidated, and the frictional wear and corrosion resistance of the alloys are improved with heterogeneous structural fine-grain strengthening and uniform fine-grain strengthening. The wear mechanisms and corrosion behavior mechanisms of (FeCoNi)86Al7Ti7 HEAs with different phase structure designs are elaborated. This work highlights the potential of using powder metallurgy to efficiently and precisely control and optimize the multi-scale microstructure of high-entropy alloys, thereby improving their frictional wear and corrosion properties in demanding applications. Full article
(This article belongs to the Special Issue Recent Advances in High Entropy Alloys)
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45 pages, 1648 KiB  
Review
Tribological Performance Enhancement in FDM and SLA Additive Manufacturing: Materials, Mechanisms, Surface Engineering, and Hybrid Strategies—A Holistic Review
by Raja Subramani, Ronit Rosario Leon, Rajeswari Nageswaren, Maher Ali Rusho and Karthik Venkitaraman Shankar
Lubricants 2025, 13(7), 298; https://doi.org/10.3390/lubricants13070298 - 7 Jul 2025
Viewed by 804
Abstract
Additive Manufacturing (AM) techniques, such as Fused Deposition Modeling (FDM) and Stereolithography (SLA), are increasingly adopted in various high-demand sectors, including the aerospace, biomedical engineering, and automotive industries, due to their design flexibility and material adaptability. However, the tribological performance and surface integrity [...] Read more.
Additive Manufacturing (AM) techniques, such as Fused Deposition Modeling (FDM) and Stereolithography (SLA), are increasingly adopted in various high-demand sectors, including the aerospace, biomedical engineering, and automotive industries, due to their design flexibility and material adaptability. However, the tribological performance and surface integrity of parts manufactured by AM are the biggest functional deployment challenges, especially in wear susceptibility or load-carrying applications. The current review provides a comprehensive overview of the tribological challenges and surface engineering solutions inherent in FDM and SLA processes. The overview begins with a comparative overview of material systems, process mechanics, and failure modes, highlighting prevalent wear mechanisms, such as abrasion, adhesion, fatigue, and delamination. The effect of influential factors (layer thickness, raster direction, infill density, resin curing) on wear behavior and surface integrity is critically evaluated. Novel post-processing techniques, such as vapor smoothing, thermal annealing, laser polishing, and thin-film coating, are discussed for their potential to endow surface durability and reduce friction coefficients. Hybrid manufacturing potential, where subtractive operations (e.g., rolling, peening) are integrated with AM, is highlighted as a path to functionally graded, high-performance surfaces. Further, the review highlights the growing use of finite element modeling, digital twins, and machine learning algorithms for predictive control of tribological performance at AM parts. Through material-level innovations, process optimization, and surface treatment techniques integration, the article provides actionable guidelines for researchers and engineers aiming at performance improvement of FDM and SLA-manufactured parts. Future directions, such as smart tribological, sustainable materials, and AI-based process design, are highlighted to drive the transition of AM from prototyping to end-use applications in high-demand industries. Full article
(This article belongs to the Special Issue Wear and Friction in Hybrid and Additive Manufacturing Processes)
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21 pages, 4008 KiB  
Article
Assessing the Impact of Hydraulic Control Structures on Hydrodynamic Modelling in Shallow Waters
by Alfonso Arrieta-Pastrana, Edwin A. Martínez-Padilla, Modesto Pérez-Sánchez, Oscar E. Coronado-Hernández and Helena M. Ramos
J. Mar. Sci. Eng. 2025, 13(7), 1233; https://doi.org/10.3390/jmse13071233 - 26 Jun 2025
Viewed by 232
Abstract
Currently, hydrodynamic models for bay and estuarine systems involve many parameters that require proper calibration to design coastal structures effectively. However, in coastal regions with limited data availability, the implementation of such models becomes challenging. This research introduces a simplified hydrodynamic methodology designed [...] Read more.
Currently, hydrodynamic models for bay and estuarine systems involve many parameters that require proper calibration to design coastal structures effectively. However, in coastal regions with limited data availability, the implementation of such models becomes challenging. This research introduces a simplified hydrodynamic methodology designed to analyse the impact of hydraulic control structures in shallow waters. This approach offers a computationally efficient alternative that allows engineers to rapidly evaluate the impact of horizontal and vertical constrictions in shallow waters experiencing wave propagation. A practical application is demonstrated in a one-dimensional channel with a length of 200,000 m and an average depth of 5 m. The only parameter required for calibration in the proposed methodology is bed friction. The three analysed scenarios—longitudinal constriction, plan-view constriction, and the influence of bed friction—demonstrate the model’s sensitivity to these variations, highlighting its reliability as a decision-making tool for coastal engineering projects. Moreover, the comparison of the proposed hydrodynamic simulation methodology at the stabilised tidal inlet structure in Cartagena de Indias, Colombia, demonstrated its ability to reproduce observed water levels accurately, reinforcing its reliability and potential for broader application. Full article
(This article belongs to the Section Coastal Engineering)
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24 pages, 3638 KiB  
Article
Digital Control of an Inverted Pendulum Using a Velocity-Controlled Robot
by Marco Costanzo, Raffaele Mazza and Ciro Natale
Machines 2025, 13(6), 528; https://doi.org/10.3390/machines13060528 - 17 Jun 2025
Viewed by 379
Abstract
This research article tackles the control problem of an inverted pendulum, also known as the Furuta pendulum, mounted on a velocity-controlled robot manipulator in two configurations: the rotary pendulum and the translational pendulum. Differently from most of the existing control architectures where the [...] Read more.
This research article tackles the control problem of an inverted pendulum, also known as the Furuta pendulum, mounted on a velocity-controlled robot manipulator in two configurations: the rotary pendulum and the translational pendulum. Differently from most of the existing control architectures where the motor actuating the pendulum motion is torque-controlled, the proposed control architecture exploits the inner velocity loop usually available on industrial robots, thus easing the implementation of an inverted pendulum. Another aspect investigated in this paper and mostly overlooked in the literature is the digital implementation of the control and, specifically, the latency introduced by the digital controller. The proposed control solution explicitly models such effects in the control design phase, improving the closed-loop performance. The additional novelty introduced by this paper is the friction compensation that is essential in the swing-up phase of the inverted pendulum, whereas classical control strategies for the nonlinear swing-up usually neglect this effect, and their solutions lead to control failures in practical systems. This paper presents detailed modeling and experimental identification phases followed by the control design of both the nonlinear swing-up algorithm and the linear stabilization controller, both experimentally validated on a Meca500 robotic arm controlled via an EtherCAT communication protocol by a mini PC featuring a Xenomai real-time operating system. The overall system showcases the potential of high-performance digital control systems in industrial robotic applications. Full article
(This article belongs to the Section Robotics, Mechatronics and Intelligent Machines)
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26 pages, 855 KiB  
Article
Diabatic and Frictional Controls of an Axisymmetric Vortex Using Available Potential Energy Theory with a Non-Resting State
by Bethan L. Harris and Rémi Tailleux
Atmosphere 2025, 16(6), 700; https://doi.org/10.3390/atmos16060700 - 10 Jun 2025
Viewed by 902
Abstract
The concept of thermodynamic efficiency is central to the theoretical understanding of tropical cyclone intensity and intensification, but the issue has remained controversial owing to the existence of distinct and incompatible definitions. Physically, thermodynamic efficiency relates to the fraction of the surface enthalpy [...] Read more.
The concept of thermodynamic efficiency is central to the theoretical understanding of tropical cyclone intensity and intensification, but the issue has remained controversial owing to the existence of distinct and incompatible definitions. Physically, thermodynamic efficiency relates to the fraction of the surface enthalpy fluxes and diabatic processes that contributes to the generation of the potential energy available (APE) for conversions into kinetic energy, so that the main difficulty is how best to define APE. In this study, we revisit the available energetics of axisymmetric vortex motions by redefining APE relative to a non-resting reference state in gradient wind balance instead of a resting state. Our approach, which accounts for both diabatic and frictional effects, reveals that the choice of reference state significantly impacts the prediction of APE generation and its conversion to kinetic energy. By using idealised numerical experiments of axisymmetric tropical cyclone intensification, we demonstrate that the APE production estimated from a non-resting reference state is a much more accurate predictor of APE to KE conversion than those based on other choices of reference states such as initial, mean, and sorted profiles. These findings suggest that incorporating the balanced dynamical structure of tropical cyclones into APE-based theories could lead to improved potential intensity models, with implications for forecasting and understanding cyclone behaviour. Full article
(This article belongs to the Special Issue Typhoon/Hurricane Dynamics and Prediction (2nd Edition))
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20 pages, 7982 KiB  
Article
Harvesting Friction Energy on Zinc Oxide and Zinc Oxide/Europium Oxide Sol-Gel Catalysts for Tribocatalytic Paracetamol Degradation
by Dobrina Ivanova, Hristo Kolev, Ralitsa Mladenova, Bozhidar I. Stefanov and Nina Kaneva
Molecules 2025, 30(11), 2265; https://doi.org/10.3390/molecules30112265 - 22 May 2025
Viewed by 829
Abstract
In the natural environment, mechanical energy is widely available as a sustainable and green energy source. In this paper, we successfully convert mechanical energy on ZnO and ZnO/Eu2O3 tribocatalysts via a friction route. Electrons were transferred across the contact interface [...] Read more.
In the natural environment, mechanical energy is widely available as a sustainable and green energy source. In this paper, we successfully convert mechanical energy on ZnO and ZnO/Eu2O3 tribocatalysts via a friction route. Electrons were transferred across the contact interface when the catalyst particles and the polytetrafluoroethylene (PTFE)-sealed magnetic bar rubbed against each other under magnetic stirring. At the same time, holes were left on the catalyst while the PTFE absorbed the electrons. Similar to photocatalysis, organic pollutants can be effectively oxidized by the holes in the valence band of sol-gel catalysts due to their strong oxidative ability. The tribocatalytic tests demonstrated that ZnO and ZnO/Eu2O3 could eliminate organic analgesics (paracetamol) under magnetic stirring in the dark. By controlling the quantity of rare earth elements (1, 2, and 3 mol%), stirring speed, and the number of magnetic rods, we could further enhance the tribocatalytic performance. In addition to developing a green tribocatalysis approach for the oxidative purification of organic pollutants, this work offers a potential route for converting environmental mechanical energy into chemical energy, which could be used in sustainable energy and environmental remediation. Full article
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21 pages, 2034 KiB  
Article
Stabilization of Sandy Soil Against Internal Erosion Using Fly Ash with Alkali-Activated Binder
by Mohammad Almasaeid, Mousa Attom, Magdi El-Emam and Mohamad G. Arab
Water 2025, 17(10), 1552; https://doi.org/10.3390/w17101552 - 21 May 2025
Viewed by 1445
Abstract
Seepage forces due to the flow of water inside embankment hydraulic structures, such as dams or levees, result in internal erosion or piping. This will result in a reduction in soil strength, causing the failure of hydraulic structures. Stabilization of the soil is [...] Read more.
Seepage forces due to the flow of water inside embankment hydraulic structures, such as dams or levees, result in internal erosion or piping. This will result in a reduction in soil strength, causing the failure of hydraulic structures. Stabilization of the soil is one of the most effective approaches to avoid such catastrophic failure and prevent significant loss of life and property. The objective of this research is to stabilize sandy soil against internal erosion using fly ash (FA) alone and fly ash mixed with alkali-activated binder (NaOH). Although fly ash is commonly used for clay soil, its reactivity with alkali activators like NaOH makes it a potential candidate for stabilizing non-cohesive sandy soils when combined with alkaline solutions. A well-graded sandy soil was selected and mixed with fly ash alone and fly ash with sodium hydroxide at different percentages. Compaction curves were determined for each percentage, and specimens from the mix were remolded at 98% relative compaction and optimum moisture content corresponding to the compaction curve value. The hole erosion test (HET) was employed to evaluate internal erosion parameters. During the hole erosion test, seepage conditions were simulated by applying a controlled water flow through remolded specimens to replicate erosion caused by internal seepage forces. Additionally, the internal erosion parameters were evaluated at different curing times (2 days, 7 days, and 28 days were selected to capture short-term, intermediate, and long-term effects of chemical reactions on soil stabilization). Parameters such as the friction factor, coefficient of soil erosion, and critical shear stress were obtained, and the erosion rate index (IHET) was determined. It was found that using FA–NaOH significantly reduced internal erosion and increased the erosion rate index and the critical shear of the soil. The addition of 10% fly ash mixed with activated-alkali binder at 7 days curing time stabilized the soil against erosion. At this percentage, the erosion rate index equal to 5.3 and soil was categorized as: “very slow erosion”. However, mixing the sand with fly ash alone has a small or insignificant effect on the internal erosion of the soil, especially at higher percentages of fly ash. The optimum percentage of fly ash alone to improve the soil resistance to internal erosion was found to be 5% at 28 days of curing time where the soil rated as “moderately slow”. Full article
(This article belongs to the Special Issue Soil Erosion and Sedimentation by Water)
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17 pages, 3659 KiB  
Article
Tribological Performance of TiN–WS2 Soft–Hard Multifunctional Composite Coatings Deposited by Magnetron Sputtering
by Hu Qiao, Shengchao Zhu, Suixin Fan, Jiawei Kang, Peichao Tian, Jianxin Yang and Youqing Wang
Coatings 2025, 15(5), 596; https://doi.org/10.3390/coatings15050596 - 17 May 2025
Viewed by 922
Abstract
Titanium nitride (TiN) is a widely used industrial hard coating material, known for its excellent hardness and chemical stability. However, its relatively high coefficient of friction (COF) often leads to interfacial heat accumulation and adhesive wear during service, limiting its applicability in high-temperature [...] Read more.
Titanium nitride (TiN) is a widely used industrial hard coating material, known for its excellent hardness and chemical stability. However, its relatively high coefficient of friction (COF) often leads to interfacial heat accumulation and adhesive wear during service, limiting its applicability in high-temperature tribological environments. To enhance its tribological performance, a TiN–WS2 soft–hard composite coating was fabricated on cemented carbide substrates using reactive co-sputtering magnetron deposition. By adjusting the sputtering parameters and target power ratio, a synergistic deposition of the hard (TiN) and lubricating (WS2) phases was achieved and compared with a pure TiN coating. The results revealed that the incorporation of WS2 significantly reduced the COF at both room temperature (25 °C) and an elevated temperature (200 °C), with the average values decreasing from 0.61 to 0.39 at 25 °C and from 0.53 to 0.36 at 200 °C. A white light interferometry analysis showed that the TiN–WS2 coating exhibited narrower wear tracks and less surface damage than TiN at elevated temperatures, demonstrating superior friction-reducing and wear-resistant capabilities. In terms of mechanical properties, the composite coating showed a reduction in the hardness, the reduced elastic modulus (Er), and the adhesion strength by 27.3%, 19.8%, and 9.5%, respectively, compared to pure TiN. These findings indicate that the introduction of a quantitatively controlled lubricating WS2 phase allows for a balance between nanoscale hardness and wear resistance, offering promising potential for engineering applications under complex working conditions. Full article
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