Search Results (176)

The design and adjustable properties of nanoporous materials are important for current and future technological applications, research, and development. In addition, nanoporous ferroelectric materials have the potential to achieve competitive ferroelectric, dielectric, and piezoelectric characteristics. In this work, using the phase-field model, we found that the shape of pores in barium titanite ceramics governs the formation of the ferroelectric domain structure and the switching hysteresis loop. A remanent polarization-coercive field (P_r-E_c) diagram is introduced to denote the shape of the hysteresis loops. We performed a fundamental study in understanding how the domain structures affect the properties of domain-engineered porous ferroelectrics. Simulation results show that the hysteresis loop of porous ferroelectrics can be designed by controlling the shape/orientation of the ellipse-shaped pores. Numerical simulations also verify that the dielectric/piezoelectric properties can be improved with artificially designed porous structures. These phase-field results may be useful in the development of highly performing lead-free ferroelectric/piezoelectric materials. Full article

Pyrochlore Bi_1.8Mn_0.5Ni_0.5Ta₂O_9-Δ (sp.gr. Fd-3m, a = 10.5038(9) Å) was synthesized by the solid-phase reaction method and characterized by vibrational and X-ray spectroscopy. According to scanning electron microscopy, the ceramics are characterized by a porous microstructure formed by randomly oriented oblong grains. The average crystallite size determined by X-ray diffraction is 65 nm. The charge state of transition element cations in the pyrochlore was analyzed by soft X-ray spectroscopy using synchrotron radiation. For mixed pyrochlore, a characteristic shift of Bi4f and Ta4f and Ta5p spectra to the region of lower energies by 0.25 and 0.90 eV is observed compared to the binding energy in Bi₂O₃ and Ta₂O₅ oxides. XPS Mn2p spectrum of pyrochlore has an intermediate energy position compared to the binding energy in MnO and Mn₂O₃, which indicates a mixed charge state of manganese (II, III) cations. Judging by the nature of the Ni2p spectrum of the complex oxide, nickel ions are in the charge state of +(2+ζ). The relative permittivity of the sample in a wide temperature (up to 350 °C) and frequency range (25–10⁶ Hz) does not depend on the frequency and exhibits a constant low value of 25. The minimum value of 4 × 10⁻³ dielectric loss tangent is exhibited by the sample at a frequency of 10⁶ Hz. The activation energy of conductivity is 0.7 eV. The electrical behavior of the sample is modeled by an equivalent circuit containing a Warburg diffusion element. Full article

Polyimide, a class of high-performance polymers, is renowned for its exceptional thermal stability, mechanical strength, and chemical resistance. However, in the context of high-integration and high-frequency electronic packaging, polyimides face critical challenges including relatively high dielectric constants, inadequate thermal conductivity, and mechanical brittleness. Recent advances have focused on molecular design and composite engineering strategies to address these limitations. This review first summarizes the intrinsic properties of polyimides, followed by a systematic discussion of chemical synthesis, surface modification approaches, molecular design principles, and composite fabrication methods. We comprehensively examine both conventional polymerization synthetic routes and emerging techniques such as microwave-assisted thermal imidization and chemical vapor deposition. Special emphasis is placed on porous structure engineering via solid-template and liquid-template methods. Three key modification strategies are highlighted: (1) surface modifications for enhanced hydrophobicity, chemical stability, and tribological properties; (2) molecular design for optimized dielectric performance and thermal stability; and (3) composite engineering for developing high-thermal-conductivity materials with improved mechanical strength and electromagnetic interference (EMI) shielding capabilities. The dielectric constant of polyimide is reduced while chemical stability and wear resistance can be enhanced through the introduction of fluorine groups. Ultra-low dielectric constant and high-temperature resistance can be achieved by employing rigid monomers and porous structures. Furthermore, the incorporation of fillers such as graphene and boron nitride can endow the composite materials with high thermal conductivity, excellent EMI shielding efficiency, and improved mechanical properties. Finally, we discuss representative applications of polyimide and composites in electronic device packaging, EMI shielding, and thermal management systems, providing insights into future development directions. Full article

Multilayer thin films composed of cobalt (Co), carbon (C), and chromium (Cr) possess promising electromagnetic properties, yet the combined Co–C–Cr system remains underexplored, particularly regarding its performance as a microwave absorber. Existing research has primarily focused on binary Co–C or Co–Cr compositions, leaving a critical knowledge gap in understanding how ternary multilayer architectures influence electromagnetic behavior. This study addresses this gap by investigating the structure, phase composition, and microwave absorption performance of Co–C–Cr multilayer coatings fabricated via magnetron sputtering onto porous silicon substrates. This study compares four-layer and eight-layer configurations to assess how multilayer architecture affects impedance matching, reflection coefficients, and absorption characteristics within the 8.2–12.4 GHz frequency range. Structural analyses using X-ray diffraction and transmission electron microscopy confirm the coexistence of amorphous and nanocrystalline phases, which enhance absorption through dielectric and magnetic loss mechanisms. Both experimental and simulated results show that increasing the number of layers improves impedance gradients and broadens the operational bandwidth. The eight-layer coatings demonstrate a more uniform absorption response, while four-layer structures exhibit sharper resonant minima. These findings advance the understanding of ternary multilayer systems and contribute to the development of frequency-selective surfaces and broadband microwave shielding materials. Full article

Activated carbon (AC) is widely used in pollution control, but it faces significant challenges in regeneration due to secondary pollution and structural degradation. Traditional methods, such as thermal and chemical regeneration, are energy-intensive and inefficient. Plasma-based regeneration, which includes high-voltage pulsed discharge and dielectric barrier discharge, provides an effective approach for restoring AC adsorption capacity with minimal environmental impact. While plasma techniques risk damaging AC’s porous structure, recent advances demonstrate their potential for efficient regeneration at lower energy costs. This review examines plasma-driven regeneration processes, focusing on optimizing reactivity control to maintain AC structural integrity while achieving high regeneration performance. The analysis highlights key mechanisms and operational parameters that influence plasma regeneration efficiency. Full article

Utilizing biomass resources to develop carbon-based microwave-absorbing materials adheres to the principles of sustainable development. Nevertheless, the single loss mechanism of pure carbon materials is limited. Additionally, the carbonization of artificially synthesized polymers has poor environmental performance and involves complex processes. These issues restrict their performance and broader applicability. In this study, cobalt-doped seaweed sludge porous carbon (Co/SSPC) with different cobalt contents was synthesized via a simple grinding–carbonization treatment. The addition of cobalt can regulate the graphitization degree of porous carbon, achieving a suitable amorphous-to-crystalline carbon ratio of 2.05. This not only enhances magnetic loss but also modifies dielectric loss and optimizes impedance matching. The construction of synergistic magnetic and dielectric loss mechanisms enables Co/SSPC to exhibit excellent microwave absorption performance. Specifically, Co/SSPC achieved a minimum reflection loss (RL_min) of −66.91 dB at a thickness of 4.79 mm and an effective absorption bandwidth (EAB) of 5.09 GHz at a thickness of 1.6 mm. This study provides a practical approach for the functional application of natural polymer waste algal sludge and highlights its potential in the low-cost production of microwave absorbing materials. Full article

With the evolution of micro/nanotechnology, anodic aluminum oxide (AAO) has received attention for sensor applications due to its regular and high-aspect-ratio nanopore structure with an excellent sensing performance, especially for electrical and optical sensors. Here, we propose the application of these capacitance and porous properties in a facile nanoporous AAO liquid sensor and study an efficient and economical method for preparing AAO substrates for liquid-phase substance sensing. By applying hybrid pulse anodization (HPA), a growth rate of approximately 5.9 μm/h was achieved in AAO fabrication. Compared to traditional low-temperature (0–10 °C) and two-step anodization with a growth rate of 1–3 μm/h, this process is significantly improved. The effect of pore widening on the performance of electrical sensors is also investigated and discussed. After pore widening, the capacitance values of AAO for air as a reference and various liquids, namely deionized water, alcohol, and acetone, are measured as 3.8 nF, 295.3 nF, 243.5 nF, and 210.1 nF, respectively. These results align with the trend in the dielectric constants and demonstrate the ability to clearly distinguish between different substances. The mechanism of AAO capacitive liquid-phase sensors can mainly be explained from two perspectives. First, since an AAO capacitive sensor is a parallel capacitor structure, the dielectric constant of the substance directly influences the capacitance value. In addition, pore widening increases the proportion of liquid filling the structure, enabling the sensor to clearly differentiate between substances. The other is the affinity between the substance and the AAO sensor, which can be determined using a contact angle test. The contact angles are measured as values of 93.2° and 67.7° before and after pore widening, respectively. The better the substance can fully fill the pores, the higher the capacitance value it yields. Full article

Porous PZT films offer significant potential due to tunable electromechanical properties, yet the polarization behavior remains insufficiently understood because of discontinuous morphology and domain structures. In this work, we study the impact of porosity on the spontaneous polarization and electromechanical response of PZT thin films fabricated using a multilayer spin-coating technique with various concentrations (0–14%) of polyvinylpyrrolidone (PVP) as a porogen. Atomic force microscopy (AFM) and piezoresponse force microscopy (PFM) were employed to analyze the local topography, domain distribution, and polarization behavior of the films. The results indicate that increasing porosity leads to substantial changes in grain morphology, dielectric permittivity, and polarization response. Films with higher porosity exhibit a more fragmented polarization distribution and reduced piezoresponse, while certain orientations demonstrate enhanced domain mobility. Despite the decrease in overall polarization, the local coercive field remains relatively stable, suggesting structural stability during the local polarization switching. The findings highlight the crucial role of grain boundaries and local charge redistribution in determining local polarization behavior. Full article

In this research work, two distinct types of three-dimensional (3D) capacitors were successfully fabricated, each with its own unique features and advantages. The first type of capacitor is centered around a 3D nanoporous structure. This structure is formed on a nickel substrate through anodic oxidation. After undergoing high-temperature thermal oxidation, a monolithic Ni-NiO-Pt metal–insulator–metal (MIM) capacitor with a nanoporous dielectric architecture is achieved. Structurally, this innovative design brings about several remarkable benefits. Due to the nanoporous structure, it has a significantly increased surface area, which can effectively store more charges. As a result, it exhibits an equivalent capacitance density of 69.95 nF/cm², which is approximately 18 times higher than that of its planar, non-porous counterpart. This high capacitance density enables it to store more electrical energy in a given volume, making it highly suitable for applications where miniaturization and high energy storage in a small space is crucial. The second type of capacitor makes use of Through-Glass Via (TGV) technology. This technology is employed to create an interdigitated blind-via array within a glass substrate, attaining an impressively high aspect ratio of 22.5:1 (with a via diameter of 20 μm and a depth of 450 μm). By integrating atomic layer deposition (ALD), a conformal interdigital electrode structure is realized. Glass, as a key material in this capacitor, has outstanding insulating properties. This characteristic endows the capacitor with a high breakdown field strength exceeding 8.2 MV/cm, corresponding to a withstand voltage of 5000 V. High breakdown field strength and withstand voltage mean that the capacitor can handle high-voltage applications without breaking down easily, which is essential for power-intensive systems like high-voltage power supplies and some high-power pulse-generating equipment. Moreover, due to the low-loss property of glass, the capacitor can achieve an energy conversion efficiency of up to 95%. Such a high energy conversion efficiency ensures that less energy is wasted during the charge–discharge process, which is highly beneficial for energy-saving applications and systems that require high-efficiency energy utilization. Full article

The partial oxidation of methane in cold atmospheric plasma represents an innovative and promising approach to energy conversion and sustainable chemical processes for obtaining various chemicals and fuels. In present work, dielectric barrier discharge plasma is applied to the partial oxidation of CH₄ combined with Cu-containing catalysts. The catalysts with different porous and acidic properties were obtained, characterized by physico-chemical methods and used in plasma-catalytic reaction. The influence of the oxidizing agent (oxygen vs. air) on the products’ selectivity and yield was studied. It was found that using air as an oxidizer was beneficial in terms of CH₄ conversion and gaseous products yield, as N₂ aided in denser microdischarge formation. Using pure O₂ for methane partial oxidation resulted in enhanced oxygenate (mainly CH₃OH) generation. Furthermore, the Cu-containing catalysts enhanced methanol yield compared to the plasma-only process, as well as the energy efficiency of the process. Full article

This research explores the modification of marl by the incorporation of diopside (CaMgSi₂O₆) to develop a composite material with improved dielectric properties, while addressing environmental and economic challenges through the use of abundant natural resources. X-ray fluorescence (XRF) analysis reveals a high silicate content in the raw marl, mainly SiO₂ (68.12%) and Al₂O₃ (12.54%), while laser particle size analysis indicates a homogeneous grain size distribution centered around 100 µm. The composite was synthesized by the solid-state reaction method, achieving good phase homogeneity. X-ray diffraction (XRD) and infrared spectroscopy confirm the incorporation of diopside, while SEM analysis shows a porous morphology with granular aggregates. The modified material has an average particle size of 11.653 µm, optimizing the electrical properties. Impedance spectroscopy demonstrates improved dielectric performance, with accumulated permittivity and reduced losses, which improves energy storage and dissipation. Tests showed the remarkable stability of dielectric properties over a wide frequency range (10 Hz to 10 MHz) and low-temperature dependence. The performance was demonstrated on a single sample with a thickness of 0.63 mm, demonstrating consistent efficiency. These results position the diopside-modified marl as a promising candidate for electrochemical and microelectronic applications. Full article

The instability of a non-Newtonian dielectric fluid jet of power-law (P-L) type injected when streaming dielectric gas through porous media is examined using electrohydrodynamic (EHD) linear analysis. The interfacial boundary conditions (BCs) are used to derive the dispersion relation for both shear-thinning (s-thin) and shear-thickening (s-thick) fluids. A detailed discussion is outlined on the impact of dimensionless flow parameters. The findings show that jet breakup can be categorized into two instability modes: Rayleigh (RM) and Taylor (TM), respectively. For both fluids, the system in TM is found to be more unstable than that found in RM, and, for s-thick fluids, it is more unstable. For all P-L index values, the system is more unstable if a porous material exists than when it does not. It is demonstrated that the generalized Reynolds number (${Re}_n$), Reynolds number ($Re$), P-L index, dielectric constants, gas-to-liquid density, and viscosity ratios have destabilizing influences; moreover, the Weber number ($We$), electric field (EF), porosity, and permeability of the porous medium have a stabilizing impact. Depending on whether its value is less or more than one, the velocity ratio plays two different roles in stability, and the breakup length and size of P-L fluids are connected to the maximal growth level and the instability range in both modes. Full article

In situ-grown SiC nanowires (SiCnws) on SiC porous material (SiCnws@SiC) were prepared using sol–gel and carbothermal reduction methods, which substantially improves the electromagnetic wave absorption property of composite material. The crystallinity and purity of SiCnws are the best when the sintering temperature is 1600 °C. When the ratio of the carbon source (C) to the silicon source (Si) is 1:1, SiCnws@SiC composite exhibits excellent electromagnetic wave absorption performance, the minimum reflection loss is −56.95 dB at a thickness of 2.30 mm, and the effective absorption bandwidth covers 1.85 GHz. The optimal effective absorption bandwidth is 4.01 GHz when the thickness is 2.59 mm. The enhancement of the electromagnetic wave absorption performance of SiCnws is mainly attributed to the increase in the heterogeneous interface and multiple reflection and scattering caused by the network structure, increasing dielectric loss and conduction loss. In addition, defects could occur during the growth of SiCnws, which could become the center of dipole polarization and increase the polarization loss of composite materials. Therefore, in situ growth of SiCnws on SiC porous ceramics is a promising method to improve electromagnetic wave absorption. Full article

Flaky carbonyl iron (FCI) powder is a typical absorbing material with excellent magnetic loss performance. However, its single absorption mechanism, narrow effective absorption bandwidth (RL < −10 dB), poor corrosion resistance, and high density restrict the application of FCI in marine environments. In this study, carbonized urea-formaldehyde resin (UFC)-coated flaky carbonyl iron (FCI@UFC) composites were prepared by in situ polymerization and pyrolysis. Various characterization techniques were employed to investigate the phase structure, microstructure, absorption performance, and corrosion resistance of FCI@UFC. The results showed that FCI@UFC effectively combined the magnetic loss of FCI and the dielectric loss of the porous carbon layer, achieving a wider effective absorption band (EAB) with a smaller thickness. When the simulated absorption layer thickness was 1.2 mm, the EAB ranged from 10.32 to 18 GHz, which demonstrated excellent microwave absorption performance. Additionally, the porous carbon coating slowed down the direct reaction between the corrosive medium and FCI, and the porous structure could also accommodate electrolytes, maintaining a stable electrochemical environment. As a result, FCI@UFC exhibited a higher corrosion potential (−0.472 V) and a lower corrosion current (1.45 × 10⁻⁷ A/cm²), indicating good corrosion resistance. This work provides new insights for the preparation of composite materials with excellent microwave absorption and corrosion resistance in practical applications. Full article

Nowadays, there is a particular need to estimate soil water content accurately over space and time scales in various applications. For example, precision agriculture, as well as the fields of geology, ecology, and hydrology, necessitate rapid, onsite water content measurements. The time domain reflectometry (TDR) technique is a geophysical method that allows, in a time-varying electric field, the determination of dielectric permittivity and electrical conductivity for a wide class of porous materials. Measuring the volumetric water content in soils is the most frequent application of TDR in soil science and soil hydrology. TDR has grown in popularity over the last 40 years because it is a practical and non-destructive technique that provides laboratory and field-scale measurements. However, a significant limitation of this technique is the relatively high cost of TDR devices, despite the availability of a range of commercial systems with varying prices. This paper aimed to design and implement a low-cost, compact TDR device tailored for classical hydrological applications. A series of laboratory experiments were carried out on soils of different textures to calibrate and validate the proposed measuring system. The results show that the device can be used to obtain predictions for monitoring soil water status with acceptable accuracy (R² = 0.95). Full article