Search Results (262)

This study presents a complete and zero-waste valorization strategy for barley straw through the synthesis of bio-polyols and the concurrent utilization of its cellulose fraction as lignin-containing cellulose nanofibers (LCNF) for the development of bio-based polyurethane (PU) foams. Two types of bio-polyols were prepared: one derived from lignin isolated via biomass fractionation, named lignin bio-polyol (LBP), and another obtained directly from unfractionated barley straw, called straw bio-polyol (SBP), thereby incorporating all lignocellulosic constituents into a single reactive matrix. LCNF, produced from the same feedstock, was incorporated at different loadings to achieve full biomass utilization and reinforce the polyurethane foam structure. Foams prepared with LBP exhibited lower density and a more homogeneous structure, whereas those synthesized with SBP developed a stiffer, more crosslinked network. The incorporation of LCNF generally increased apparent density and mechanical performance, with optimal reinforcement at 3 wt.% in foams with SBP and 5 wt.% in LBP foams, corresponding to a 62.5 and 121% enhancement in compressive strength relative to their respective control foams. Moreover, the use of barley straw bio-polyol shifted some thermal degradation peaks toward higher temperatures, evidencing improved thermal resistance. Overall, this dual-route strategy provides a sustainable and versatile methodology for the comprehensive valorization of lignocellulosic biomass, enabling a systematic understanding of the role of each structural component in polyurethane foam synthesis. The resulting materials offer a renewable, low-impact pathway toward high-performance polymeric materials. Full article

Polymeric stabilizers play a critical role in enhancing the stability and performance of firefighting foams. This study evaluated the influence of three polymeric stabilizers (xanthan gum, XG; polyacrylamide, PAM; sodium carboxymethyl cellulose, CMC-Na) on the performance of foam solutions formulated with a zwitterionic short-chain fluorocarbon surfactant. The investigation focused on three performances: interfacial properties, apparent viscosity (at a fixed rotational speed), and foam performance, employing interfacial tension analysis, viscosity measurement, dynamic foam analysis, and foam drainage testing. Results indicate that XG and CMC-Na slightly decrease interfacial activities, reducing spreading coefficients 6.34–15.78% and 0.68–6.35%, respectively. However, these polymeric stabilizers substantially increase apparent viscosity through hydrogen bond network formation, which effectively mitigates foam coarsening and drainage. When adding 0.10 wt.% XG, the foam solution exhibits a characteristic coarsening time of 724.64 s and a 25% drainage time of 1519.15 s. Conversely, PAM exhibits a concentration-dependent dual effect. When below 0.06 wt.%, PAM enhances interfacial properties and foam stability. However, at elevated concentrations, excessive PAM aggregates at interfaces and forms entangled networks that inhibit surfactant adsorption. This impairs foam formation and accelerates foam structural evolution, increasing variation in bubble size and promoting foam drainage by 8.63–57.88%. These findings provide crucial reference for applying polymeric stabilizers in short-chain fluorocarbon surfactant systems. Full article

Flexible polyurethane foam (FPUF) is widely used in ship cabins yet poses significant fire hazards due to its flammability and tendency to melt and drip during combustion. While previous studies have primarily focused on dripping behavior under static conditions, the effect of oscillatory motion, typical in maritime environments, remains poorly understood. This study investigated the dripping behavior of FPUF under both static and oscillating conditions using a custom-made experimental platform simulating ship motions. The results reveal that under static conditions, side ignition leads to a higher dripping frequency than central ignition. Under oscillation, central ignition produces a greater number of drips and higher dripping frequency compared to static conditions. Although oscillation promotes the formation of smaller droplets and reduces the proportion of large-size flaming drips, the absolute number of such flaming drips increases, elevating fire spread risk. Furthermore, while oscillation frequency and amplitude have limited effects on dripping frequency, they significantly expand the dripping spread range, which increased by over 300% at 30° and 0.1 Hz compared to static conditions. These findings provide insights for improving fire risk assessment and safety design of polymeric materials in dynamic operational environments such as ships. Full article

Tannin foams are polymeric, porous materials produced from plant tannins, with good thermal insulation and fire-retardant properties. Although research has mainly concentrated on usage of condensed tannins (CTs), interest in a second group, hydrolyzable tannins (HTs), is growing. This study evaluated the usability of glyoxal as a single crosslinker for condensed and hydrolyzable tannins in foams created through mechanical agitation, using various ratios of chestnut (HT) and quebracho (CT) tannins. Glyoxal could react with chestnut tannin, but foams with only chestnut collapsed before hardening due to its slow reactivity, with 70% chestnut as the maximum viable content. Increasing the chestnut tannin amount reduced the foamability and compression strength, resulting in higher density and increased pore size. At a similar density (~210 kg m⁻³), the 70%-HT foam reached only one-third the compressive strength of the pure CT foam (0.22 vs. 0.61 MPa), while the pure CT foam showed a smaller mean pore size (189 vs. 365 µm) despite its lower mean density (208 vs. 241 kg m⁻³). The fire resistance and thermal conductivity appeared unaffected by the tannin type and instead depended on the foam density, with thermal conductivities ranging from 56 to 71 mW/(m·K). Leaching tests showed a slight increase in leaching for formulations with higher chestnut tannin contents, with 15% to 24% of acid recovered after the leaching cycle. The ¹³C-NMR analysis revealed the glyoxal crosslinks at the free position of the A-ring in CTs and at the free ortho ones of the gallic/ellagic moieties in HTs. Overall, this study demonstrated that tannin foams can be produced using glyoxal as a single crosslinker, allowing for up to 70% substitution of the condensed tannin component in the formulation. Full article

Rigid polyurethane foams (RPUFs) are essential polymeric materials, prized for their low density, high mechanical strength, and superior thermal insulation, making them indispensable in construction, refrigeration, and transportation. Despite these advantages, their highly porous, carbon-rich structure renders them intrinsically flammable, promoting rapid flame spread, intense heat release, and the generation of toxic smoke. Traditional strategies to reduce flammability have primarily focused on incorporating additive or reactive flame retardants into the foam matrix, which can effectively suppress combustion but often compromise mechanical integrity, suffer from migration or compatibility issues, and involve complex synthesis routes. Despite recent progress, the long-term stability, scalability, and durability of surface flame-retardant coatings for RPUFs remain underexplored, limiting their practical application in industrial environments. Recent advances have emphasized the development of surface-engineered flame-retardant coatings, including intumescent systems, inorganic–organic hybrids, bio-inspired materials, and nanostructured composites. These coatings form protective interfaces that inhibit ignition, restrict heat and mass transfer, promote char formation, and suppress smoke without altering the intrinsic properties of RPUFs. Emerging deposition methods, such as layer-by-layer assembly, spray coating, ultraviolet (UV) curing, and brush application, enable precise control over thickness, uniformity, and adhesion, enhancing durability and multifunctionality. Integrating bio-based and hybrid approaches further offers environmentally friendly and sustainable solutions. Collectively, these developments demonstrate the potential of surface-engineered coatings to achieve high-efficiency flame retardancy while preserving thermal and mechanical performance, providing a pathway for safe, multifunctional, and industrially viable RPUFs. Full article

Rail transport is widely regarded as a sustainable and environmentally friendly option for long-distance freight and passenger movement during its operation phase. However, its construction and maintenance phases often result in substantial environmental impacts, which must be addressed to improve the overall sustainability of railways. This study aims to identify solutions that improve the performance of railway tracks, reduce maintenance requirements, and minimize environmental impact. With this objective, the potential of artificial inclusions and innovative composite materials in enhancing the sustainability of railway tracks is investigated through a comprehensive methodology, combining experimental, analytical and numerical approaches. A novel composite material, comprising soil, scrap tire aggregates and an adhesive, demonstrated strong potential as a sustainable base layer for ballastless railway tracks, exhibiting minimal strain accumulation (0.29–0.98%) under 50,000 load cycles and adequate damping. Incorporation of cellular artificial inclusions in the substructure layers of ballasted tracks reduced cumulative settlement by up to 33% and slowed track geometry deterioration. Use of planar artificial inclusions beneath a pile-supported railway embankment enhanced the load transfer efficiency and curtailed settlement, while also lowering environmental impact by reducing concrete usage. The findings of this study highlight strong potential of these approaches in improving track performance and the overall sustainability of railways. Full article

The mechanically activated transition (MAT) from linear viscoelasticity to yielding is considered an essential part of the operational behavior of ductile materials. The MAT region is restricted by proportional limit at σ₀ and ε₀ and the yield point at σ_y and ε_y, or, in terms of this paper, $E_0={\sigma }_0/{\epsilon }_0$ and ε₀ and $E_y={\sigma }_y/{\epsilon }_y$ and ε_y, respectively. This stage precedes yielding and controls the parameters of the yield point. For bulk plastic (co)polymers and cellular polymeric foams, the quantitative correlations between $E_0$, ε₀, $E_y,$ and ε_y were determined. The ratios ${\displaystyle \raisebox{1ex}{$E_0$}\!\left/ \!\raisebox{-1ex}{$E_y$}\right.}=1.55\pm 0.15$ and ${\displaystyle \raisebox{1ex}{${\epsilon }_y$}\!\left/ \!\raisebox{-1ex}{${\epsilon }_0$}\right.}=2.1\pm 0.2$ were specified as yielding criteria. For all the samples studied, their mechanical response within the MAT region was unified in terms of master curve constructed via re-calculation of the experimental “stress–strain” diagrams in the reduced coordinates ${\displaystyle \frac{\mathit{lg} E-\mathit{lg} E_0}{\mathit{lg} E_0-\mathit{lg} E_y}}=f\left({\displaystyle \frac{\mathit{lg} \epsilon -\mathit{lg} {\epsilon }_0}{\mathit{lg} {\epsilon }_y-\mathit{lg} {\epsilon }_0}}\right),$ where $E=\sigma /\epsilon$ and ε are the current modulus and strain, respectively. To generalize these regularities found for bulk plastics and foams, our earlier experimental results concerning the rheology of soil-based pastes and data from the literature concerning the computer simulation of plastic deformation were invoked. Master curves for (1) dispersed pastes, (2) bulk plastics, (3) polymeric foams, and (4) various virtual models were shown to be in satisfactory coincidence. For the materials analyzed, this result was considered as the unification of their mechanical response within the MAT region. An algorithm for the express analysis of the mechanical response of plastic systems within the MAT region is proposed. The limitations and advances of the proposed methodological approach based on correlation studies followed by construction of master curves are outlined. Full article

Polyurethane foams containing heterocyclic rings are characterized by high thermal resistance, but unfortunately, they are flammable. This work examined the effect of halogen-free flame retardants such as melamine and expanded graphite: EG 096 and EG 290 on the properties of foams with a 1,3-pyrimidine ring. Oligoetherol obtained from 6-aminouracil, ethylene carbonate, and propylene oxide was foamed with polymeric diphenylmethane 4,4′-diisocyanate with the addition of flame retardants. The oxygen index was determined, and flammability tests were conducted on the resulting foams. Their apparent density, water absorption, thermal resistance, thermal conductivity coefficient, and compressive strength were also examined. Both melamine and expanded graphite significantly reduce the flammability of foams. The resulting foams are classified as V-0 flammability class, and their oxygen index is in the range of 24.9–29.5 vol.%. Expanded graphite is a better flame retardant and does not cause deterioration of other foam properties. Full article

Endothelial hyperpermeability is a hallmark of diverse inflammatory and vascular pathologies, including sepsis, acute respiratory distress syndrome (ARDS), ischemia–reperfusion injury, and atherosclerosis. Traditionally considered a passive return to baseline following stimulus withdrawal, barrier recovery is now recognized as an active, endothelial-driven process. Earlier work identified individual components of this restorative phase, such as cyclic adenosine monophosphate (cAMP)/exchange protein directly activated by cAMP 1 (Epac1) signaling, Rap1/Rac1 activation, vasodilator-stimulated phosphoprotein (VASP) phosphorylation, and targeted cytoskeletal remodeling, as well as kinase pathways involving PKA, PKG, and Src. However, these were often regarded as discrete events lacking a unifying framework. Recent integrative analyses, combining mechanistic insights from multiple groups, reveal that nitric oxide (NO) generated early during hyperpermeability can initiate a delayed cAMP/Epac1 cascade. This axis coordinates Rap1/Rac1-mediated cortical actin polymerization, VASP-driven junctional anchoring, retro-translocation of endothelial nitric oxide synthase (eNOS) to caveolar domains, PP2A-dependent suppression of actomyosin tension, and Krüppel-like factor 2 (KLF2)-driven transcriptional programs that sustain endothelial quiescence. Together, these pathways form a temporally orchestrated, multi-tiered “inactivation” program capable of restoring barrier integrity even in the continued presence of inflammatory stimuli. This conceptual shift reframes NO from solely a barrier-disruptive mediator to the initiating trigger of a coordinated, pro-resolution mechanism. The unified framework integrates cytoskeletal dynamics, junctional reassembly, focal adhesion turnover, and redox/transcriptional control, providing multiple potential intervention points. Therapeutically, Epac1 activation, Rap1/Rac1 enhancement, RhoA/ROCK inhibition, PP2A activation, and KLF2 induction represent strategies to accelerate endothelial sealing in acute microvascular syndromes. Moreover, applying these mechanisms to arterial endothelium could limit low-density lipoprotein (LDL) entry and foam cell formation, offering a novel adjunctive approach for atherosclerosis prevention. In this review, we will discuss both the current understanding of endothelial hyperpermeability mechanisms and the emerging pathways of its active inactivation, integrating molecular, structural, and translational perspectives. Full article

This study investigates the use of bio-based polyurethane foams (PUFs) containing phase change material (PCM) microparticles as a sustainable alternative for the automotive sector. These foams are synthesized using polyols derived from waste cooking oil (WCO), aligning with circular economy principles. To evaluate the thermophysical properties of these materials and, more in general, their thermal behavior, the use of non-destructive thermographic techniques has been proposed. This technique enables a rapid, full-field thermal analysis without physical contact, making it especially suitable for porous and heterogeneous structures like foams. As a reference, both virgin and foams with PCM were characterized in terms of density and thermal conductivity using well-established methods. Then, Lock-in thermography has been used as the first attempt technique to investigate variations in thermal behavior due to different thermophysical material properties based on the thermal response in transmission configuration. The thermographic approach proves to be an effective tool not only for assessing thermal behavior but also for supporting quality control and process optimization of sustainable polymeric materials. Full article

Foams, as a type of porous materials, have found broad functional and structural application in heat and sound insulation, the mitigation of mechanical vibrations and impacts, packaging, etc. This paper aims to comprehensively review recently developed biobased foams (BBFs) with a comparison with their counterparts—namely, synthetic polymer foams—in terms of their foaming methods, physical and mechanical properties, and broad applications. A brief introduction to general foams, polymeric foams, and BBFs is provided, followed by a comparison of the related foaming methods; physical, mechanical, and chemical properties; and current and prospective applications. Several main polymer foaming methods (e.g., physical, chemical, and mechanical foaming) and their unique features are further examined in detail. The structure-related properties of polymeric foams (e.g., mass density, thermal conductivity, and rate effects in mechanical responses) are discussed, and the fundamental linearly viscoelastic models are summarized to account for the simple rate effect in the mechanical moduli of polymeric foams under varying loading rates. Furthermore, specific focus is placed on the foaming processes and material properties of sustainable BBFs (e.g., soybean-based, corn-based, and starch-based foams) and their potential to substitute conventional synthetic polymer foams. The technical challenges in processing BBFs are discussed, and the most promising applications of BBFs are then considered. Full article

In this study, a shape-changeable 3D scaffold with photothermal effects was developed to address the clinical challenges of complex bone defects. The multifunctional construct was fabricated via in situ polymerization combined with a gas foaming technique, creating hierarchical porous architectures that mimic the native bone extracellular matrix. By incorporating polydopamine (PDA)-modified amorphous calcium phosphate (CA) into poly(propylene glycol) (PPG)- and poly(ԑ-caprolactone) (PCL)-based polyurethane (PU). The obtained scaffolds achieved osteoinductive potential for bone tissue engineering. The surface PDA modification of CA enabled efficient photothermal shape conversion under near-infrared (NIR) irradiation, facilitating non-invasive remote control of localized hyperthermia. The optimized scaffolds exhibited interconnected porosity (approximately 70%) with osteoconductive pore channels (200–500 μm), resulting in good osteoinduction in cell culture, and precise shape-memory recovery at physiological temperatures (~40 °C) under NIR for minimally invasive delivery. The synergistic effect of osteogenesis promotion and photothermal transition demonstrated this programmable scaffold as a promising solution for integrated minimally invasive bone repair and defect reconstruction. Full article

This systematic literature review explores recent advancements in polymer-based composite materials designed for thermal insulation in automotive applications, with a particular focus on sustainability, performance optimization, and scalability. The methodology follows PRISMA 2020 guidelines and includes a comprehensive bibliometric and thematic analysis of 229 peer-reviewed articles published over the past 15 years across major databases (Scopus, Web of Science, ScienceDirect, MDPI). The findings are structured around four central research questions addressing (1) the functional role of insulation in automotive systems; (2) criteria for selecting suitable polymer systems; (3) optimization strategies involving nanostructuring, self-healing, and additive manufacturing; and (4) future research directions involving smart polymers, bioinspired architectures, and AI-driven design. Results show that epoxy resins, polyurethane, silicones, and polymeric foams offer distinct advantages depending on the specific application, yet each presents trade-offs between thermal resistance, recyclability, processing complexity, and ecological impact. Comparative evaluation tables and bibliometric mapping (VOSviewer) reveal an emerging research trend toward hybrid systems that combine bio-based matrices with functional nanofillers. The study concludes that no single material system is universally optimal, but rather that tailored solutions integrating performance, sustainability, and cost-effectiveness are essential for next-generation automotive thermal insulation. Full article

Nowadays, there is wide advocacy for a transition to circular economic models. Fly Ash (FA) in particular is a major by-product of coal combustion and its annual waste has reached one million tonnes. Cenospheres (CSs) are considered as possibly the most valuable element within FA. Thus, in this research, polymeric foam replication was employed to fabricate ceramic foams based on a CS matrix, for potential biomedical applications. For the fabrication of foams, four types of natural marine sponges were used as templates along with a binder agent. The specimens were sintered at 1200 °C for 1 h. The results were encouraging as the specimens obtained retained the given shape and geometry. Further research will enhance the potential of such materials for future use in biomedical engineering. Full article

This study investigates a hybrid manufacturing approach that combines 3D printing and injection molding to extend the limitations of each individual technique. Injection molding is often limited by high initial tooling costs, long lead times, and restricted geometric flexibility, whereas 3D-printed molds tend to suffer from material degradation, extended cooling times, and lower surface quality. By integrating 3D-printed molds into the injection-molding process, this hybrid method enables the production of complex geometries with improved cost-efficiency. The approach is demonstrated using a range of polymeric materials, including ABS, nylon, and polyurethane foam—each selected to enhance the mechanical and thermal performance of the final products. Finite element method (FEM) analysis was conducted to assess thermal distribution, deformation, and stress during manufacturing. Results indicated that both temperature and stress remained within safe operational limits for 3D-printed materials. An economic analysis revealed substantial cost savings compared to fully 3D-printed components, establishing hybrid manufacturing as a viable and scalable alternative. This method offers broad industrial applicability, delivering enhanced mechanical properties, design flexibility, and reduced production costs. Full article