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15 pages, 2879 KiB  
Article
Study on the Eye Movement Transfer Characteristics of Drivers Under Different Road Conditions
by Zhenxiang Hao, Jianping Hu, Xiaohui Sun, Jin Ran, Yuhang Zheng, Binhe Yang and Junyao Tang
Appl. Sci. 2025, 15(15), 8559; https://doi.org/10.3390/app15158559 (registering DOI) - 1 Aug 2025
Viewed by 115
Abstract
Given the severe global traffic safety challenges—including threats to human lives and socioeconomic impacts—this study analyzes visual behavior to promote sustainable transportation, improve road safety, and reduce resource waste and pollution caused by accidents. Four typical road sections, namely, turning, straight ahead, uphill, [...] Read more.
Given the severe global traffic safety challenges—including threats to human lives and socioeconomic impacts—this study analyzes visual behavior to promote sustainable transportation, improve road safety, and reduce resource waste and pollution caused by accidents. Four typical road sections, namely, turning, straight ahead, uphill, and downhill, were selected, and the eye movement data of 23 drivers in different driving stages were collected by aSee Glasses eye-tracking device to analyze the visual gaze characteristics of the drivers and their transfer patterns in each road section. Using Markov chain theory, the probability of staying at each gaze point and the transfer probability distribution between gaze points were investigated. The results of the study showed that drivers’ visual behaviors in different road sections showed significant differences: drivers in the turning section had the largest percentage of fixation on the near front, with a fixation duration and frequency of 29.99% and 28.80%, respectively; the straight ahead section, on the other hand, mainly focused on the right side of the road, with 31.57% of fixation duration and 19.45% of frequency of fixation; on the uphill section, drivers’ fixation duration on the left and right roads was more balanced, with 24.36% of fixation duration on the left side of the road and 25.51% on the right side of the road; drivers on the downhill section looked more frequently at the distance ahead, with a total fixation frequency of 23.20%, while paying higher attention to the right side of the road environment, with a fixation duration of 27.09%. In terms of visual fixation, the fixation shift in the turning road section was mainly concentrated between the near and distant parts of the road ahead and frequently turned to the left and right sides; the straight road section mainly showed a shift between the distant parts of the road ahead and the dashboard; the uphill road section was concentrated on the shift between the near parts of the road ahead and the two sides of the road, while the downhill road section mainly occurred between the distant parts of the road ahead and the rearview mirror. Although drivers’ fixations on the front of the road were most concentrated under the four road sections, with an overall fixation stability probability exceeding 67%, there were significant differences in fixation smoothness between different road sections. Through this study, this paper not only reveals the laws of drivers’ visual behavior under different driving environments but also provides theoretical support for behavior-based traffic safety improvement strategies. Full article
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21 pages, 2519 KiB  
Review
Distribution and Ecological Risk Assessment of Perfluoroalkyl and Polyfluoroalkyl Substances in Chinese Soils: A Review
by Junyi Wang, Otgontuya Tsogbadrakh, Jichen Tian, Faisal Hai, Chenpeng Lyu, Guangming Jiang and Guoyu Zhu
Water 2025, 17(15), 2246; https://doi.org/10.3390/w17152246 - 28 Jul 2025
Viewed by 360
Abstract
Per- and polyfluoroalkyl substances (PFASs) are emerging pollutants of global concern due to their high environmental persistence and bioaccumulative characteristics. This study investigates PFAS concentrations in soils from China through an extensive literature review, covering soil samples from seventeen provinces and the years [...] Read more.
Per- and polyfluoroalkyl substances (PFASs) are emerging pollutants of global concern due to their high environmental persistence and bioaccumulative characteristics. This study investigates PFAS concentrations in soils from China through an extensive literature review, covering soil samples from seventeen provinces and the years from 2009 to 2024. It was found that the total concentration of PFAS in soil ranged from 0.25 to 6240 ng/g, with the highest contamination levels observed in coastal provinces, particularly Fujian (620 ng/g) and Guangdong (1090 ng/g). Moreover, Fujian Province ranked the highest among multiple regions with a median PFAS concentration of 15.7 ng/g for individual compounds. Ecological risk assessment, focusing on areas where perfluorooctanoic acid (PFOA) or perfluorooctane sulfonate (PFOS) were identified as the primary soil PFAS compounds, showed moderate ecological risk from PFOA in Shanghai (0.24), while PFOS posed a high ecological risk in Fujian and Guangdong, with risk values of 43.3 and 1.4, respectively. Source analysis revealed that anthropogenic activities, including PFAS production, firefighting foam usage, and landfills, were the primary contributors to soil contamination. Moreover, soil PFASs tend to migrate into groundwater via adsorption and seepage, ultimately entering the human body through bioaccumulation or drinking water, posing health risks. These findings enhance our understanding of PFAS distribution and associated risks in Chinese soils, providing crucial insights for pollution management, source identification, and regulation strategies in diverse areas. Full article
(This article belongs to the Section Soil and Water)
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19 pages, 6870 KiB  
Article
Impact of Urban Elevated Complex Roads on Acoustic Environment Quality in Adjacent Areas: A Field Measurement Study
by Guangrui Yang, Lingshan He, Yimin Wang and Qilin Liu
Buildings 2025, 15(15), 2662; https://doi.org/10.3390/buildings15152662 - 28 Jul 2025
Viewed by 128
Abstract
The current focus of urban environmental governance is on the traffic noise pollution caused by road transportation. Elevated complex roads, defined as transportation systems comprising elevated roads and underlying ground-level roads, exhibit unique traffic noise distribution characteristics due to the presence of double-decked [...] Read more.
The current focus of urban environmental governance is on the traffic noise pollution caused by road transportation. Elevated complex roads, defined as transportation systems comprising elevated roads and underlying ground-level roads, exhibit unique traffic noise distribution characteristics due to the presence of double-decked roads and viaducts. This study conducted noise measurements at two sections of elevated complex roads in Guangzhou, including assessing noise levels at the road boundaries and examining noise distribution at different distances from roads and building heights. The results show that the horizontal distance attenuation of noise in adjacent areas exhibits no significant difference from that of ground-level roads, but substantial discrepancies exist in vertical height distribution. The under-viaduct space experiences more severe noise pollution than areas above the viaduct height, and the installation of sound barriers alters the spatial distribution trend of traffic noise. Given that installing sound barriers solely on elevated roads is insufficient to improve the acoustic environment, systematic noise mitigation strategies should be developed for elevated composite road systems. Additionally, the study reveals that nighttime noise fluctuations are significantly greater than those during the day, further exacerbating residents’ noise annoyance. Full article
(This article belongs to the Special Issue Vibration Prediction and Noise Assessment of Building Structures)
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19 pages, 12174 KiB  
Article
Spatiotemporal Trends and Exceedance Drivers of Ozone Concentration in the Yangtze River Delta Urban Agglomeration, China
by Junli Xu and Jian Wang
Atmosphere 2025, 16(8), 907; https://doi.org/10.3390/atmos16080907 - 26 Jul 2025
Viewed by 298
Abstract
The Yangtze River Delta urban agglomeration, characterized by high population density, an advanced transportation system, and a concentration of industrial activity, is one of the regions severely affected by O3 pollution in central and eastern China. Using data collected from 251 monitoring [...] Read more.
The Yangtze River Delta urban agglomeration, characterized by high population density, an advanced transportation system, and a concentration of industrial activity, is one of the regions severely affected by O3 pollution in central and eastern China. Using data collected from 251 monitoring stations between 2015 and 2025, this paper analyzed the spatio-temporal variation of 8 h O3 concentrations and instances of exceedance. On the basis of exploring the influence of meteorological factors on regional 8 h O3 concentration, the potential source contribution areas of pollutants under the exceedance condition were investigated using the HYSPLIT model. The results indicate a rapid increase in the 8 h O3 concentration at a rate of 0.91 ± 0.98 μg·m−3·a−1, with the average number of days exceeding concentration standards reaching 41.05 in the Yangtze River Delta urban agglomeration. Spatially, the 8 h O3 concentrations were higher in coastal areas and lower in inland regions, as well as elevated in plains compared to hilly terrains. This distribution was significantly distinct from the concentration growth trend characterized by higher levels in the northwest and lower levels in the southeast. Furthermore, it diverged from the spatial characteristics where exceedances primarily occurred in the heavily industrialized northeastern region and the lightly industrialized central region, indicating that the growth and exceedance of 8 h O3 concentrations were influenced by disparate factors. Local human activities have intensified the emissions of ozone precursor substances, which could be the key driving factor for the significant increase in regional 8 h O3 concentrations. In the context of high temperatures and low humidity, this has contributed to elevated levels of 8 h O3 concentrations. When wind speeds were below 2.5 m·s−1, the proportion of 8 h O3 concentrations exceeding the standards was nearly 0 under almost calm wind conditions, and it showed an increasing trend with rising wind speeds, indicating that the potential precursor sources that caused high O3 concentrations originated occasionally from inland regions, with very limited presence within the study area. This observation implies that the main cause of exceedances was the transport effect of pollution from outside the region. Therefore, it is recommended that the Yangtze River Delta urban agglomeration adopt economic and technological compensation mechanisms within and between regions to reduce the emission intensity of precursor substances in potential source areas, thereby effectively controlling O3 concentrations and improving public living conditions and quality of life. Full article
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19 pages, 8699 KiB  
Article
Study on the Spatio-Temporal Characteristics and Driving Factors of PM2.5 in the Inter-Provincial Border Region of Eastern China (Jiangsu, Anhui, Shandong, Henan) from 2022 to 2024
by Xiaoli Xia, Shangpeng Sun, Xinru Wang and Feifei Shen
Atmosphere 2025, 16(8), 895; https://doi.org/10.3390/atmos16080895 - 22 Jul 2025
Viewed by 239
Abstract
The inter-provincial border region in eastern China, encompassing the junction of Jiangsu, Anhui, Shandong, and Henan provinces, serves as a crucial zone that connects the important economic zones of Beijing–Tianjin–Hebei and the Yangtze River Delta. It is of great significance to study the [...] Read more.
The inter-provincial border region in eastern China, encompassing the junction of Jiangsu, Anhui, Shandong, and Henan provinces, serves as a crucial zone that connects the important economic zones of Beijing–Tianjin–Hebei and the Yangtze River Delta. It is of great significance to study the temporal variation characteristics, spatial distribution patterns, and driving factors of PM2.5 concentrations in this region. Based on the PM2.5 concentration observation data, ground meteorological data, environmental data, and socio-economic data from 2022 to 2024, this study conducted in-depth and systematic research by using advanced methods, such as spatial autocorrelation analysis and geographical detectors. The research results show that the concentration of PM2.5 rose from 2022 to 2023, but decreased from 2023 to 2024. From the perspective of seasonal variations, the concentration of PM2.5 shows a distinct characteristic of being “high in winter and low in summer”. The monthly variation shows a “U”-shaped distribution pattern. In terms of spatial changes, the PM2.5 concentration in the inter-provincial border region of eastern China (Jiangsu, Anhui, Shandong, Henan) forms a gradient difference of “higher in the west and lower in the east”. The high-concentration agglomeration areas are mainly concentrated in the Henan part of the study region, while the low-concentration agglomeration areas are distributed in the eastern coastal parts of the study region. The analysis of the driving factors of the PM2.5 concentration based on geographical detectors reveals that the average temperature is the main factor affecting the PM2.5 concentration. The interaction among the factors contributing to the spatial differentiation of the PM2.5 concentration is very obvious. Temperature and population density (q = 0.92), temperature and precipitation (q = 0.95), slope and precipitation (q = 0.97), as well as DEM and population density (q = 0.96), are the main combinations of factors that have continuously affected the spatial differentiation of the PM2.5 concentration for many years. The research results from this study provide a scientific basis and decision support for the prevention, control, and governance of PM2.5 pollution. Full article
(This article belongs to the Special Issue Atmospheric Pollution Dynamics in China)
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16 pages, 2206 KiB  
Article
Turning Waste into Wealth: Sustainable Amorphous Silica from Moroccan Oil Shale Ash
by Anas Krime, Sanaâ Saoiabi, Mouhaydine Tlemcani, Ahmed Saoiabi, Elisabete P. Carreiro and Manuela Ribeiro Carrott
Recycling 2025, 10(4), 143; https://doi.org/10.3390/recycling10040143 - 20 Jul 2025
Viewed by 271
Abstract
Moroccan oil shale ash (MOSA) represents an underutilized industrial by-product, particularly in the Rif region, where its high mineral content has often led to its neglect in value-added applications. This study highlights the successful conversion of MOSA into amorphous mesoporous silica (AS-Si) using [...] Read more.
Moroccan oil shale ash (MOSA) represents an underutilized industrial by-product, particularly in the Rif region, where its high mineral content has often led to its neglect in value-added applications. This study highlights the successful conversion of MOSA into amorphous mesoporous silica (AS-Si) using a sol–gel process assisted by polyethylene glycol (PEG-6000) as a soft template. The resulting AS-Si material was extensively characterized to confirm its potential for environmental remediation. FTIR analysis revealed characteristic vibrational bands corresponding to Si–OH and Si–O–Si bonds, while XRD confirmed its amorphous nature with a broad diffraction peak at 2θ ≈ 22.5°. SEM imaging revealed a highly porous, sponge-like morphology composed of aggregated nanoscale particles, consistent with the nitrogen adsorption–desorption isotherm. The material exhibited a specific surface area of 68 m2/g, a maximum in the pore size distribution at a pore diameter of 2.4 nm, and a cumulative pore volume of 0.11 cm3/g for pores up to 78 nm. DLS analysis indicated an average hydrodynamic diameter of 779 nm with moderate polydispersity (PDI = 0.48), while a zeta potential of –34.10 mV confirmed good colloidal stability. Furthermore, thermogravimetric analysis (TGA) and DSC suggested the thermal stability of our amorphous silica. The adsorption performance of AS-Si was evaluated using methylene blue (MB) and ciprofloxacin (Cipro) as model pollutants. Kinetic data were best fitted by the pseudo-second-order model, while isotherm studies favored the Langmuir model, suggesting monolayer adsorption. AS-Si could be used four times for the removal of MB and Cipro. These results collectively demonstrate that AS-Si is a promising, low-cost, and sustainable adsorbent derived from Moroccan oil shale ash for the effective removal of organic contaminants from aqueous media. Full article
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15 pages, 2997 KiB  
Article
Contribution to Distribution and Toxicity Prediction of Organic Pollutants in Receiving Waters from Wastewater Plant Tailwater: A Case Study of the Yitong River, China
by Xiaoyu Zhang, Mingxuan Bai, Ang Dong, Xinrong Du, Yuzhu Ding and Ke Zhao
Water 2025, 17(14), 2061; https://doi.org/10.3390/w17142061 - 10 Jul 2025
Viewed by 319
Abstract
Urban river ecosystems are increasingly threatened by anthropogenic activities, with wastewater discharge being a significant contributor. The complex nature and diverse sources of wastewater pose challenges in assessing its impact on water quality and ecological health. This study investigated the distribution, toxicity, and [...] Read more.
Urban river ecosystems are increasingly threatened by anthropogenic activities, with wastewater discharge being a significant contributor. The complex nature and diverse sources of wastewater pose challenges in assessing its impact on water quality and ecological health. This study investigated the distribution, toxicity, and ecological effects of organic pollutants in an urban river system during the dry season. A comprehensive analysis was conducted of 16 phthalate esters (PAEs), 16 polycyclic aromatic hydrocarbons (PAHs), and 8 antibiotics, with a focus on several key pollutants. The results revealed distinct pollutant profiles: Dibutyl phthalate (DBP), Dimethyl phthalate (DEHP), and Diisobutyl phthalate (DIBP) were the predominant PAEs, while Chrysene was the most abundant PAH. Among antibiotics, Oxytetracycline and Norfloxacin were the dominant compounds. Wastewater treatment plant (WWTP) effluents significantly altered the composition of organic pollutants in receiving waters. Although dilution reduced the concentrations of some pollutants, certain organic compounds were detected for the first time downstream of the WWTP, and some specific compounds exhibited increased concentrations. Toxicity prediction using the Concentration Addition (CA) model identified DBP as the primary contributor to overall toxicity, accounting for the highest toxic load among all detected pollutants. Furthermore, WWTP effluents induced significant shifts in microbial community structure downstream, with incomplete recovery to upstream conditions. Integrated analysis of 16S rRNA gene sequencing, water quality assessment, and toxicity prediction elucidated the multifaceted impacts of pollution sources on aquatic ecosystems. This study provides critical insights into the composition, spatial distribution, and toxicity characteristics of organic pollutants in urban rivers, as well as their effects on bacterial community structure. The findings offer a scientific foundation for urban river water quality management and ecological protection strategies. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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17 pages, 2554 KiB  
Article
Pilot Study of Microplastics in Snow from the Zhetysu Region (Kazakhstan)
by Azamat Madibekov, Laura Ismukhanova, Christian Opp, Botakoz Sultanbekova, Askhat Zhadi, Renata Nemkaeva and Aisha Madibekova
Appl. Sci. 2025, 15(14), 7736; https://doi.org/10.3390/app15147736 - 10 Jul 2025
Viewed by 395
Abstract
The pilot study is devoted to the assessment of both the accumulation and spatial distribution of microplastics in the snow cover of the Zhetysu region. The height of snow cover in the study area varied from 4.0 to 80.5 cm, with a volume [...] Read more.
The pilot study is devoted to the assessment of both the accumulation and spatial distribution of microplastics in the snow cover of the Zhetysu region. The height of snow cover in the study area varied from 4.0 to 80.5 cm, with a volume of melt water ranging from 1.5 to 143 L. The analysis of 53 snow samples taken at different altitudes (from 350 to 1500 m above sea level) showed the presence of microplastics in 92.6% of samples in concentrations from 1 to 12 particles per square meter. In total, 170 microplastic particles were identified. The main polymers identified by Raman spectroscopy were polyethylene (PE), polypropylene (PP), and polystyrene (PS). These are typical components of plastic waste. The spatial distribution of microplastics showed elevated concentrations near settlements and roads. Notable contaminations were also recorded in remote mountainous areas, confirming the significant role of long-range atmospheric transport. Particles smaller than 0.5 mm dominated, having high aerodynamic mobility and capable of long-range atmospheric transport. Quantitative and qualitative characteristics of microplastics in snow cover have been realized for the first time both in Kazakhstan and in the Central Asian region, which contributes to the formation of primary ideas and future approaches about microplastic pollution in continental inland regions. The obtained results demonstrate the importance of atmospheric transport in the distribution of microplastics. They indicate the need for further monitoring and microplastic pollution analyses in Central Asia, taking into account its detection even in hard-to-reach and remote areas. Full article
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18 pages, 6234 KiB  
Article
Autonomous System for Air Quality Monitoring on the Campus of the University of Ruse: Implementation and Statistical Analysis
by Maciej Kozłowski, Asen Asenov, Velizara Pencheva, Sylwia Agata Bęczkowska, Andrzej Czerepicki and Zuzanna Zysk
Sustainability 2025, 17(14), 6260; https://doi.org/10.3390/su17146260 - 8 Jul 2025
Viewed by 364
Abstract
Air pollution poses a growing threat to public health and the environment, highlighting the need for continuous and precise urban air quality monitoring. The aim of this study was to implement and evaluate an autonomous air quality monitoring platform developed by the University [...] Read more.
Air pollution poses a growing threat to public health and the environment, highlighting the need for continuous and precise urban air quality monitoring. The aim of this study was to implement and evaluate an autonomous air quality monitoring platform developed by the University of Ruse, “Angel Kanchev”, under Bulgaria’s National Recovery and Resilience Plan (project BG-RRP-2.013-0001), co-financed by the European Union through the NextGenerationEU initiative. The system, based on Libelium’s mobile sensor technology, was installed at a height of two meters on the university campus near Rodina Boulevard and operated continuously from 1 March 2024 to 30 March 2025. Every 15 min, it recorded concentrations of CO, CO2, NO2, SO2, PM1, PM2.5, and PM10, along with meteorological parameters (temperature, humidity, and pressure), transmitting the data via GSM to a cloud-based database. Analyses included a distributional assessment, Spearman rank correlations, Kruskal–Wallis tests with Dunn–Sidak post hoc comparisons, and k-means clustering to identify temporal and meteorological patterns in pollutant levels. The results indicate the high operational stability of the system and reveal characteristic pollution profiles associated with time of day, weather conditions, and seasonal variation. The findings confirm the value of combining calibrated IoT systems with advanced statistical methods to support data-driven air quality management and the development of predictive environmental models. Full article
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23 pages, 4667 KiB  
Article
An Experimental Study on the Charging Effects and Atomization Characteristics of a Two-Stage Induction-Type Electrostatic Spraying System for Aerial Plant Protection
by Yufei Li, Qingda Li, Jun Hu, Changxi Liu, Shengxue Zhao, Wei Zhang and Yafei Wang
Agronomy 2025, 15(7), 1641; https://doi.org/10.3390/agronomy15071641 - 5 Jul 2025
Viewed by 330
Abstract
To address the technical problems of broad droplet size spectrum, insufficient atomization uniformity, and spray drift in plant protection unmanned aerial vehicle (UAV) applications, this study developed a novel two-stage aerial electrostatic spraying device based on the coupled mechanisms of hydraulic atomization and [...] Read more.
To address the technical problems of broad droplet size spectrum, insufficient atomization uniformity, and spray drift in plant protection unmanned aerial vehicle (UAV) applications, this study developed a novel two-stage aerial electrostatic spraying device based on the coupled mechanisms of hydraulic atomization and electrostatic induction, and, through the integration of three-dimensional numerical simulation and additive manufacturing technology, a new two-stage inductive charging device was designed on the basis of the traditional hydrodynamic nozzle structure, and a synergistic optimization study of the charging effect and atomization characteristics was carried out systematically. With the help of a charge ratio detection system and Malvern laser particle sizer, spray pressure (0.25–0.35 MPa), charging voltage (0–16 kV), and spray height (100–1000 mm) were selected as the key parameters, and the interaction mechanism of each parameter on the droplet charge ratio (C/m) and the particle size distribution (Dv50) was analyzed through the Box–Behnken response surface experimental design. The experimental data showed that when the charge voltage was increased to 12 kV, the droplet charge-to-mass ratio reached a peak value of 1.62 mC/kg (p < 0.01), which was 83.6% higher than that of the base condition; the concentration of the particle size distribution of the charged droplets was significantly improved; charged droplets exhibited a 23.6% reduction in Dv50 (p < 0.05) within the 0–200 mm core atomization zone below the nozzle, with the coefficient of variation of volume median diameter decreasing from 28.4% to 16.7%. This study confirms that the two-stage induction structure can effectively break through the charge saturation threshold of traditional electrostatic spraying, which provides a theoretical basis and technical support for the optimal design of electrostatic spraying systems for plant protection UAVs. This technology holds broad application prospects in agricultural settings such as orchards and farmlands. It can significantly enhance the targeted deposition efficiency of pesticides, reducing drift losses and chemical usage, thereby enabling agricultural enterprises to achieve practical economic benefits, including reduced operational costs, improved pest control efficacy, and minimized environmental pollution, while generating environmental benefits. Full article
(This article belongs to the Section Agricultural Biosystem and Biological Engineering)
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14 pages, 496 KiB  
Review
Analysis of Heavy Metal Pollution Characteristics and Biological Effects in Lake Sediments: Implications for Health Risk Assessment
by Zheng Li, Weiwei Zhang, Shuhang Wang, Xia Jiang, Huaicheng Guo, Yong Liu and Zhenghui Fu
Processes 2025, 13(7), 2140; https://doi.org/10.3390/pr13072140 - 5 Jul 2025
Viewed by 477
Abstract
Heavy metals have long been a significant and challenging topic in the research and treatment of lake water environments due to their non-degradability and ease of bioaccumulation. With the advancement of industries such as manufacturing, agriculture, and heavy industry, coupled with the increasing [...] Read more.
Heavy metals have long been a significant and challenging topic in the research and treatment of lake water environments due to their non-degradability and ease of bioaccumulation. With the advancement of industries such as manufacturing, agriculture, and heavy industry, coupled with the increasing demand for heavy metals, the levels of heavy metals entering the environment have been rising annually. This trend necessitates more refined control measures for heavy metals in the environment. Currently, research on heavy metals in lake sediments in China mainly focuses on spatial distribution, morphological analysis, and ecological risk assessment. However, the characteristics of heavy metal migration, transformation, and biological effects are still largely unquantifiable. This article analyzes soil pollution cases in multiple regions of China and summarizes the nine main sources of heavy metals in the environment. It discusses the characteristics and biological effects of heavy metal migration and transformation. Finally, from the perspective of human health risk assessment, it explores the future development direction of heavy metal research. Full article
(This article belongs to the Special Issue Advances in Water Resource Pollution Mitigation Processes)
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14 pages, 1622 KiB  
Article
Neonicotinoid Residues in Tea Products from China: Contamination Patterns and Implications for Human Exposure
by Yulong Fan, Hongwei Jin, Jinru Chen, Kai Lin, Lihua Zhu, Yijia Guo, Jiajia Ji and Xiaming Chen
Toxics 2025, 13(7), 550; https://doi.org/10.3390/toxics13070550 - 29 Jun 2025
Viewed by 470
Abstract
Neonicotinoids (NEOs) are a class of systemic insecticides widely used in agriculture owing to their high efficacy and selectivity. As one of the most globally consumed beverages, tea may represent a potential dietary source of pesticide residues. However, limited research has examined NEO [...] Read more.
Neonicotinoids (NEOs) are a class of systemic insecticides widely used in agriculture owing to their high efficacy and selectivity. As one of the most globally consumed beverages, tea may represent a potential dietary source of pesticide residues. However, limited research has examined NEO contamination in tea and its implications for human exposure, highlighting the need for further investigation. Therefore, this study comprehensively evaluated the residue characteristics, processing effects, and human exposure risks of six NEOs—dinotefuran (DIN), imidacloprid (IMI), acetamiprid (ACE), thiamethoxam (THM), clothianidin (CLO), and thiacloprid (THI)—in Chinese tea products. According to the findings, the primary pollutants, ACE, DIN, and IMI, accounted for 95.65% of the total NEO residues in 137 tea samples, including green, oolong, white, black, dark, and herbal teas. The highest total target NEO (∑6NEOs) residue level was detected in oolong tea (mean: 57.86 ng/g). Meanwhile, IMI exhibited the highest residue level (78.88 ng/g) in herbal tea due to the absence of high-temperature fixation procedures. Concentrations of DIN in 61 samples (44.5%) exceeded the European Union’s maximum residue limit of 10 ng/g. Health risk assessment indicated that both the chronic hazard quotient (cHQ) and acute hazard quotient (aHQ) for adults and children were below the safety threshold (<1). However, children required special attention, as their exposure risk was 1.28 times higher than that of adults. The distribution of NEO residues was significantly influenced by tea processing techniques, such as full fermentation in black tea. Optimizing processing methods (e.g., using infrared enzyme deactivation) and implementing targeted pesticide application strategies may help mitigate risk. These results provide a scientific foundation for enhancing tea safety regulations and protecting consumer health. Full article
(This article belongs to the Special Issue Human Biomonitoring in Health Risk Assessment of Emerging Chemicals)
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16 pages, 3686 KiB  
Article
Modeling of Droplet Deposition in Air-Assisted Spraying
by Jian Song, Zhichong Wang, Changyuan Zhai, Chenchen Gu, Kang Zheng, Xuecheng Li, Ronghua Jiang and Ke Xiao
Agronomy 2025, 15(7), 1580; https://doi.org/10.3390/agronomy15071580 - 28 Jun 2025
Viewed by 253
Abstract
Air-assisted spraying is the primary method of plant protection in orchards, and precision spraying according to the canopy characteristics of fruit trees can reduce waste and pollution due to pesticide drift. To facilitate targeted pesticide application in the canopy of fruit trees, this [...] Read more.
Air-assisted spraying is the primary method of plant protection in orchards, and precision spraying according to the canopy characteristics of fruit trees can reduce waste and pollution due to pesticide drift. To facilitate targeted pesticide application in the canopy of fruit trees, this study employed a newly developed wind-speed-adjustable orchard sprayer and established a prediction model for deposition based on data from orthogonal trials using a central composite design accounting for the coupling effect of three-dimensional spatial parameters. The experimental design systematically quantified the interaction effects of spray distance (1.5–2.5 m), fan wind speed (10–20 m/s), and deposition height (0.5–3 m) on the spatial distribution of droplets. Model significance was p < 0.0001 and the misfit term was significant (p = 0.2193), supporting its validity. The research found that wind speed and distance significantly interact in influencing deposition. By adjusting fan speed and spray distance, variable applications can be achieved in different canopy zones during plant protection operations. The response surface model developed in this study can be applied to variable-rate spraying control systems, thus providing a quantitative basis for dynamic droplet control guided by canopy characteristics. Validation tests revealed that the model’s accuracy was lower in high canopy regions and upwind spraying scenarios, indicating areas for further research. Full article
(This article belongs to the Special Issue Advances in Precision Pesticide Spraying Technology and Equipment)
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26 pages, 3657 KiB  
Article
Exploring the Spatio-Temporal Dynamics and Factors Influencing PM2.5 in China’s Prefecture-Level and Above Cities
by Long Chen, Yanyun Nian, Minglu Che, Chengyao Wang and Haiyuan Wang
Remote Sens. 2025, 17(13), 2212; https://doi.org/10.3390/rs17132212 - 27 Jun 2025
Viewed by 457
Abstract
Fine particulate matter (PM2.5) plays a major role in haze, and studying its spatio-temporal dynamics and influencing factors is crucial for improving air quality. However, previous studies have often obscured the spatio-temporal interactions of PM2.5 and neglected local spatio-temporal differences [...] Read more.
Fine particulate matter (PM2.5) plays a major role in haze, and studying its spatio-temporal dynamics and influencing factors is crucial for improving air quality. However, previous studies have often obscured the spatio-temporal interactions of PM2.5 and neglected local spatio-temporal differences in influencing factors. To address these limitations, this research utilized PM2.5 concentration data derived from satellite remote sensing and employed exploratory spatio-temporal data analysis (ESTDA) methods to investigate the spatio-temporal evolution patterns of PM2.5 in Chinese cities from 2000 to 2021. Furthermore, the effects of natural environmental and socioeconomic factors on PM2.5 were analyzed from both global and local perspectives using a spatial econometric model and the geographically and temporally weighted regression (GTWR) model. Key findings include (1) The annual value of PM2.5 from 2000 to 2021 ranged between 27.4 and 42.6 µg/m3, exhibiting a “bimodal” variation trend and phased evolutionary characteristics. Spatially, higher concentrations were observed in the central and eastern regions, as well as along the northwestern border, while lower concentrations were prevalent in other areas. (2) The spatial–temporal distribution of PM2.5 was generally stable, demonstrating a strong spatial dependence during its growth process, with significant path dependence characteristics in local spatial clusters of PM2.5. (3) Precipitation, temperature, wind speed, and the Normalized Difference Vegetation Index (NDVI) significantly reduced PM2.5 levels, whereas relative humidity, per capita Gross Domestic Product (GDP), industrialization level, and energy consumption exerted positive effects. These factors exhibited distinct local spatio-temporal variations. These findings aim to provide scientific evidence for the implementation of coordinated regional efforts to reduce air pollution across China. Full article
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19 pages, 5802 KiB  
Article
Soil Quality and Heavy Metal Source Analyses for Characteristic Agricultural Products in Luzuo Town, China
by Zhaoyu Zhou, Zeming Shi, Linsong Yu, Haiyin Fan and Fang Wan
Agriculture 2025, 15(13), 1360; https://doi.org/10.3390/agriculture15131360 - 25 Jun 2025
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Abstract
Identifying the soil quality and the sources of heavy metals in the production areas of characteristic agricultural products is crucial for ensuring the quality of such products and the sustainable development of agriculture. This research took the farmland soil of Luzuo Town, a [...] Read more.
Identifying the soil quality and the sources of heavy metals in the production areas of characteristic agricultural products is crucial for ensuring the quality of such products and the sustainable development of agriculture. This research took the farmland soil of Luzuo Town, a characteristic production area of Cangshan garlic in Linyi City, as the research object. The contents of Cr, Cu, Ni, Pb, Zn, As, Hg, and Cd in farmland soil were analyzed. The ecological risks were evaluated using the Geographical Cumulative Index (Igeo) and the Potential Ecological Risk Index. The spatial distribution characteristics of the elements were determined through geostatistical analysis, and Positive Matrix Factorization (PMF) was used for source apportionment. The results show the following: (1) The average concentrations of all heavy metals exceeded local background values, with Cr and Hg surpassing the screening thresholds from China’s “Soil Pollution Risk Control Standards” (GB 15618-2018). (2) The results of the Moran’s index show that, except for Hg and Cd, all the elements had a high spatial autocorrelation, and there are two potential highly polluted areas in the study area. (3) Soils were generally uncontaminated or low risk, with Hg and Cd as the primary ecological risk contributors. (4) Five sources were quantified: fertilizer and pesticide sources (32.28%); mixed sources of fertilizer, pesticides, and manure (14.15%); mixed sources of traffic activities and agricultural waste discharge (19.95%); natural sources (20.55%); and incineration sources (13.07%). This study demonstrates the value of integrating geospatial and statistical methods for soil pollution management. Targeted control of Hg/Cd and reduced agrochemical use are recommended to protect this important agricultural region. Full article
(This article belongs to the Section Agricultural Soils)
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