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28 pages, 1146 KiB  
Article
Uncovering Hidden Risks: Non-Targeted Screening and Health Risk Assessment of Aromatic Compounds in Summer Metro Carriages
by Han Wang, Guangming Li, Cuifen Dong, Youyan Chi, Kwok Wai Tham, Mengsi Deng and Chunhui Li
Buildings 2025, 15(15), 2761; https://doi.org/10.3390/buildings15152761 - 5 Aug 2025
Abstract
Metro carriages, as enclosed transport microenvironments, have been understudied regarding pollution characteristics and health risks from ACs, especially during high-temperature summers that amplify exposure. This study applied NTS techniques for the first time across three major Chengdu metro lines, systematically identifying sixteen ACs, [...] Read more.
Metro carriages, as enclosed transport microenvironments, have been understudied regarding pollution characteristics and health risks from ACs, especially during high-temperature summers that amplify exposure. This study applied NTS techniques for the first time across three major Chengdu metro lines, systematically identifying sixteen ACs, including hazardous species such as acetophenone, benzonitrile, and benzoic acid that are often overlooked in conventional BTEX-focused monitoring. The TAC concentration reached 41.40 ± 5.20 µg/m3, with half of the compounds exhibiting significant increases during peak commuting periods. Source apportionment using diagnostic ratios and PMF identified five major contributors: carriage material emissions (36.62%), human sources (22.50%), traffic exhaust infiltration (16.67%), organic solvents (16.55%), and industrial emissions (7.66%). Although both non-cancer (HI) and cancer (TCR) risks for all population groups were below international thresholds, summer tourists experienced higher exposure than daily commuters. Notably, child tourists showed the greatest vulnerability, with a TCR of 5.83 × 10−7, far exceeding that of commuting children (1.88 × 10−7). Benzene was the dominant contributor, accounting for over 50% of HI and 70% of TCR. This study presents the first integrated NTS and quantitative risk assessment to characterise ACs in summer metro environments, revealing a broader range of hazardous compounds beyond BTEX. It quantifies population-specific risks, highlights children’s heightened vulnerability. The findings fill critical gaps in ACs exposure and provide a scientific basis for improved air quality management and pollution mitigation strategies in urban rail transit systems. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
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33 pages, 7414 KiB  
Article
Carbon Decoupling of the Mining Industry in Mineral-Rich Regions Based on Driving Factors and Multi-Scenario Simulations: A Case Study of Guangxi, China
by Wei Wang, Xiang Liu, Xianghua Liu, Luqing Rong, Li Hao, Qiuzhi He, Fengchu Liao and Han Tang
Processes 2025, 13(8), 2474; https://doi.org/10.3390/pr13082474 - 5 Aug 2025
Abstract
The mining industry (MI) in mineral-rich regions is pivotal for economic growth but is challenged by significant pollution and emissions. This study examines Guangxi, a representative region in China, in light of the country’s “Dual Carbon” goals. We quantified carbon emissions from the [...] Read more.
The mining industry (MI) in mineral-rich regions is pivotal for economic growth but is challenged by significant pollution and emissions. This study examines Guangxi, a representative region in China, in light of the country’s “Dual Carbon” goals. We quantified carbon emissions from the MI from 2005 to 2021, employing the generalized Divisia index method (GDIM) to analyze the factors driving these emissions. Additionally, a system dynamics (SD) model was developed, integrating economic, demographic, energy, environmental, and policy variables to assess decarbonization strategies and the potential for carbon decoupling. The key findings include the following: (1) Carbon accounting analysis reveals a rising emission trend in Guangxi’s MI, predominantly driven by electricity consumption, with the non-ferrous metal mining sector contributing the largest share of total emissions. (2) The primary drivers of carbon emissions were identified as economic scale, population intensity, and energy intensity, with periodic fluctuations in sector-specific drivers necessitating coordinated policy adjustments. (3) Scenario analysis showed that the Emission Reduction Scenario (ERS) is the only approach that achieves a carbon peak before 2030, indicating that it is the most effective decarbonization pathway. (4) Between 2022 and 2035, carbon decoupling from total output value is projected to improve under both the Energy-Saving Scenario (ESS) and ERS, achieving strong decoupling, while the resource extraction shows limited decoupling effects often displaying an expansionary connection. This study aims to enhance the understanding and promote the advancement of green and low-carbon development within the MI in mineral-rich regions. Full article
(This article belongs to the Section Energy Systems)
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25 pages, 2973 KiB  
Article
Application of a DPSIR-Based Causal Framework for Sustainable Urban Riparian Forests: Insights from Text Mining and a Case Study in Seoul
by Taeheon Choi, Sangin Park and Joonsoon Kim
Forests 2025, 16(8), 1276; https://doi.org/10.3390/f16081276 - 4 Aug 2025
Abstract
As urbanization accelerates and climate change intensifies, the ecological integrity of urban riparian forests faces growing threats, underscoring the need for a systematic framework to guide their sustainable management. To address this gap, we developed a causal framework by applying text mining and [...] Read more.
As urbanization accelerates and climate change intensifies, the ecological integrity of urban riparian forests faces growing threats, underscoring the need for a systematic framework to guide their sustainable management. To address this gap, we developed a causal framework by applying text mining and sentence classification to 1001 abstracts from previous studies, structured within the DPSIR (Driver–Pressure–State–Impact–Response) model. The analysis identified six dominant thematic clusters—water quality, ecosystem services, basin and land use management, climate-related stressors, anthropogenic impacts, and greenhouse gas emissions—which reflect the multifaceted concerns surrounding urban riparian forest research. These themes were synthesized into a structured causal model that illustrates how urbanization, land use, and pollution contribute to ecological degradation, while also suggesting potential restoration pathways. To validate its applicability, the framework was applied to four major urban streams in Seoul, where indicator-based analysis and correlation mapping revealed meaningful linkages among urban drivers, biodiversity, air quality, and civic engagement. Ultimately, by integrating large-scale text mining with causal inference modeling, this study offers a transferable approach to support adaptive planning and evidence-based decision-making under the uncertainties posed by climate change. Full article
(This article belongs to the Section Forest Economics, Policy, and Social Science)
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22 pages, 1247 KiB  
Article
Evaluating and Predicting Urban Greenness for Sustainable Environmental Development
by Chun-Che Huang, Wen-Yau Liang, Tzu-Liang (Bill) Tseng and Chia-Ying Chan
Processes 2025, 13(8), 2465; https://doi.org/10.3390/pr13082465 - 4 Aug 2025
Abstract
With the rapid pace of urbanization, cities are increasingly facing severe challenges related to environmental pollution, ecological degradation, and climate change. Extreme climate events—such as heatwaves, droughts, heavy rainfall, and wildfires—have intensified public concern about sustainability, environmental protection, and low-carbon development. Ensuring environmental [...] Read more.
With the rapid pace of urbanization, cities are increasingly facing severe challenges related to environmental pollution, ecological degradation, and climate change. Extreme climate events—such as heatwaves, droughts, heavy rainfall, and wildfires—have intensified public concern about sustainability, environmental protection, and low-carbon development. Ensuring environmental preservation while maintaining residents’ quality of life has become a central focus of urban governance. In this context, evaluating green indicators and predicting urban greenness is both necessary and urgent. This study incorporates international frameworks such as the EU Green City Index, the European Green Capital Award, and the United Nations Sustainable Development Goals to assess urban sustainability. The Extreme Gradient Boosting (XGBoost) algorithm is employed to predict the green level of cities and to develop multiple optimized models. Comparative analysis with traditional models demonstrates that XGBoost achieves superior performance, with an accuracy of 0.84 and an F1-score of 0.81. Case study findings identify “Greenhouse Gas Emissions per Person” and “Per Capita Emissions from Transport” as the most critical indicators. These results provide practical guidance for policymakers, suggesting that targeted regulations based on these key factors can effectively support emission reduction and urban sustainability goals. Full article
(This article belongs to the Section Environmental and Green Processes)
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28 pages, 2743 KiB  
Article
Unlocking Synergies: How Digital Infrastructure Reshapes the Pollution-Carbon Reduction Nexus at the Chinese Prefecture-Level Cities
by Zhe Ji, Yuqi Chang and Fengxiu Zhou
Sustainability 2025, 17(15), 7066; https://doi.org/10.3390/su17157066 - 4 Aug 2025
Abstract
In the context of global climate governance and the green transition, digital infrastructure serves as a critical enabler of resource allocation in the digital economy, offering strategic value in tackling synergistic pollution and carbon reduction challenges. Using panel data from 280 prefecture-level cities, [...] Read more.
In the context of global climate governance and the green transition, digital infrastructure serves as a critical enabler of resource allocation in the digital economy, offering strategic value in tackling synergistic pollution and carbon reduction challenges. Using panel data from 280 prefecture-level cities, this study employs a multiperiod difference-in-differences (DID) approach, leveraging smart city pilot policies as a quasinatural experiment, to assess how digital infrastructure affects urban synergistic pollution-carbon mitigation (SPCM). The empirical results show that digital infrastructure increases the urban SPCM index by 1.5%, indicating statistically significant effects. Compared with energy and income effects, digital infrastructure can influence this synergistic effect through indirect channels such as the energy effect, economic agglomeration effect, and income effect, with the economic agglomeration effect accounting for a larger share of the total effect. Additionally, fixed-asset investment has a nonlinear moderating effect on this relationship, with diminishing marginal returns on emission reduction when investment exceeds a threshold. Heterogeneity tests reveal greater impacts in eastern, nonresource-based, and environmentally regulated cities. This study expands the theory of collaborative environmental governance from the perspective of new infrastructure, providing a theoretical foundation for establishing a long-term digital technology-driven mechanism for SPCM. Full article
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25 pages, 1165 KiB  
Article
China’s Low-Carbon City Pilot Policy, Eco-Efficiency, and Energy Consumption: Study Based on Period-by-Period PSM-DID Model
by Xiao Na Li and Hsing Hung Chen
Energies 2025, 18(15), 4126; https://doi.org/10.3390/en18154126 - 4 Aug 2025
Abstract
The sustainable development of Chinese cities is of long-term significance. Multiple environmental regulatory instruments aim to promote the parallel advancement of environmental conservation and economic growth. This study examines three batches of low-carbon city pilot (LCCP) programs, employing eco-efficiency as the outcome variable. [...] Read more.
The sustainable development of Chinese cities is of long-term significance. Multiple environmental regulatory instruments aim to promote the parallel advancement of environmental conservation and economic growth. This study examines three batches of low-carbon city pilot (LCCP) programs, employing eco-efficiency as the outcome variable. Using conventional difference-in-differences (DID) models, time-varying DID models, and period-by-period propensity score matching DID (PSM-DID) models with city and time fixed effects, we investigate the comprehensive impact of pilot policies on both economic and environmental performance. Eco-efficiency, measured through the Data Envelopment Analysis (DEA) model, exhibits a strong correlation with energy consumption patterns, as carbon emissions and air pollutants predominantly originate from non-clean energy utilization. The analysis reveals that LCCP policies significantly enhance eco-efficiency. These findings demonstrate robustness across placebo tests, endogeneity treatments, and alternative outcome variable specifications. The first and third LCCP batches significantly improve eco-efficiency, whereas the second batch demonstrates no statistically significant effect. Significant impacts emerge in regions where cities hold pilot status while provinces do not; conversely, regions where both cities and provinces participate in pilot programs show no significant effects. Finally, from an energy consumption perspective, policy recommendations are proposed to further enhance eco-efficiency through regulatory instruments. Full article
(This article belongs to the Special Issue Sustainable Energy Futures: Economic Policies and Market Trends)
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16 pages, 1207 KiB  
Article
Study of Multi-Stakeholder Mechanism in Inter-Provincial River Basin Eco-Compensation: Case of the Inland Rivers of Eastern China
by Zhijie Cao and Xuelong Chen
Sustainability 2025, 17(15), 7057; https://doi.org/10.3390/su17157057 - 4 Aug 2025
Abstract
Based on a comprehensive review of the current research status of ecological compensation both domestically and internationally, combined with field survey data, this study delves into the issue of multi-stakeholder participation in the ecological compensation mechanisms of the Xin’an River Basin. This research [...] Read more.
Based on a comprehensive review of the current research status of ecological compensation both domestically and internationally, combined with field survey data, this study delves into the issue of multi-stakeholder participation in the ecological compensation mechanisms of the Xin’an River Basin. This research reveals that the joint participation of multiple stakeholders is crucial to achieving the goals of ecological compensation in river basins. The government plays a significant role in macro-guidance, financial support, policy guarantees, supervision, and management. It promotes the comprehensive implementation of ecological environmental protection by formulating relevant laws and regulations, guiding the public to participate in ecological conservation, and supervising and punishing pollution behaviors. The public, serving as the main force, forms strong awareness and behavioral habits of ecological protection through active participation in environmental protection, monitoring, and feedback. As participants, enterprises contribute to industrial transformation and green development by improving resource utilization efficiency, reducing pollution emissions, promoting green industries, and participating in ecological restoration projects. Scientific research institutions, as technology enablers, have effectively enhanced governance efficiency through technological research and innovation, ecosystem value accounting to provide decision-making support, and public education. Social organizations, as facilitators, have injected vitality and innovation into watershed governance by extensively mobilizing social forces and building multi-party collaboration platforms. Communities, as supporters, have transformed ecological value into economic benefits by developing characteristic industries such as eco-agriculture and eco-tourism. Based on the above findings, further recommendations are proposed to mobilize the enthusiasm of upstream communities and encourage their participation in ecological compensation, promote the market-oriented operation of ecological compensation mechanisms, strengthen cross-regional cooperation to establish joint mechanisms, enhance supervision and evaluation, and establish a sound benefit-sharing mechanism. These recommendations provide theoretical support and practical references for ecological compensation worldwide. Full article
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29 pages, 1867 KiB  
Article
Exploring the Triple Dividend Effect and Threshold Effect of Environmental Protection Tax: Evidence from Chinese Listed Companies
by Chenghao Ye, Hongjie Gao and Igor A. Mayburov
Sustainability 2025, 17(15), 7038; https://doi.org/10.3390/su17157038 - 3 Aug 2025
Viewed by 99
Abstract
This study uses financial data from 872 Chinese listed companies (2018–2022). It tests the triple dividend effect and threshold effect of China’s environmental protection tax (EPT) using high-dimensional fixed effects models and panel threshold models. We document that (1) EPT creates an environmental [...] Read more.
This study uses financial data from 872 Chinese listed companies (2018–2022). It tests the triple dividend effect and threshold effect of China’s environmental protection tax (EPT) using high-dimensional fixed effects models and panel threshold models. We document that (1) EPT creates an environmental dividend for Chinese listed companies. It significantly reduces pollution emissions. A 1-unit tax increase reduces LnTPPE by 2.5%. (2) EPT creates a significant innovation dividend. It forces enterprises to improve the quality of authorized patents. A 1-unit tax increase raises patent technological complexity by 0.79%. (3) EPT creates an economic dividend. It significantly improves firm performance. A 1-unit tax increase raises relative corporate revenue by 38.1%. (4) EPT exerts significant threshold effects on micro-level triple dividend outcomes among Chinese listed companies. A heterogeneity analysis shows significant differences in threshold effects between non-heavily polluting and heavily polluting industries. This study confirms that China’s EPT generates a micro-level triple dividend effect alongside coexisting threshold effects for listed companies. This provides literature references for China to design and implement differentiated policies and offers a quantitative empirical case for implementing globally sustainable EPT strategies. Full article
(This article belongs to the Section Air, Climate Change and Sustainability)
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21 pages, 4415 KiB  
Article
Friction and Regenerative Braking Shares Under Various Laboratory and On-Road Driving Conditions of a Plug-In Hybrid Passenger Car
by Dimitrios Komnos, Alessandro Tansini, Germana Trentadue, Georgios Fontaras, Theodoros Grigoratos and Barouch Giechaskiel
Energies 2025, 18(15), 4104; https://doi.org/10.3390/en18154104 - 2 Aug 2025
Viewed by 194
Abstract
Although particulate matter (PM) pollution from vehicles’ exhaust has decreased significantly over the years, the contribution from non-exhaust sources (brakes, tyres) has remained at the same levels. In the European Union (EU), Euro 7 regulation introduced PM limits for vehicles’ brake systems. Regenerative [...] Read more.
Although particulate matter (PM) pollution from vehicles’ exhaust has decreased significantly over the years, the contribution from non-exhaust sources (brakes, tyres) has remained at the same levels. In the European Union (EU), Euro 7 regulation introduced PM limits for vehicles’ brake systems. Regenerative braking, i.e., recuperation of the deceleration kinetic and potential energy to the vehicle battery, is one of the strategies to reduce the brake emission levels and improve vehicle efficiency. According to the regulation, the shares of friction and regenerative braking can be determined with actual testing of the vehicle on a chassis dynamometer. In this study we tested the regenerative capabilities of a plug-in hybrid vehicle, both in the laboratory and on the road, under different protocols (including both smooth and aggressive braking) and covering a wide range of driving conditions (urban, rural, motorway) over 10,000 km of driving. Good agreement was obtained between laboratory and on-road tests, with the use of the friction brakes being on average 7% and 5.3%, respectively. However, at the same time it was demonstrated that the friction braking share can vary over a wide range (up to around 30%), depending on the driver’s behaviour. Full article
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19 pages, 440 KiB  
Article
Cost-Benefit Analysis of Diesel vs. Electric Buses in Low-Density Areas: A Case Study City of Jastrebarsko
by Marko Šoštarić, Marijan Jakovljević, Marko Švajda and Juraj Leonard Vertlberg
World Electr. Veh. J. 2025, 16(8), 431; https://doi.org/10.3390/wevj16080431 - 1 Aug 2025
Viewed by 128
Abstract
This paper presents a comprehensive analysis comparing the implementation of electric and diesel buses for public transport services in the low-density area of the City of Jastrebarsko in Croatia. It utilizes a multidimensional approach and incorporates direct and indirect costs, such as vehicle [...] Read more.
This paper presents a comprehensive analysis comparing the implementation of electric and diesel buses for public transport services in the low-density area of the City of Jastrebarsko in Croatia. It utilizes a multidimensional approach and incorporates direct and indirect costs, such as vehicle acquisition, operation, charging, maintenance, and environmental impact costs during the lifecycle of the buses. The results show that, despite the higher initial investment in electric buses, these vehicles offer savings, especially when coupled with significantly reduced emissions of pollutants, which decreases indirect costs. However, local contexts differ, leading to a need to revise whether or not a municipality can finance the procurement and operations of such a fleet. The paper utilizes a robust methodological framework, integrating a proposal based on real-world data and demand and combining it with predictive analytics to forecast long-term benefits. The findings of the paper support the introduction of buses as a sustainable solution for Jastrebarsko, which provides insights for public transport planners, urban planners, and policymakers, with a discussion about the specific issues regarding the introduction, procurement, and operations of buses of different propulsion in a low-density area. Full article
(This article belongs to the Special Issue Zero Emission Buses for Public Transport)
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15 pages, 1071 KiB  
Article
A Synthetic Difference-in-Differences Approach to Assess the Impact of Shanghai’s 2022 Lockdown on Ozone Levels
by Yumin Li, Jun Wang, Yuntong Fan, Chuchu Chen, Jaime Campos Gutiérrez, Ling Huang, Zhenxing Lin, Siyuan Li and Yu Lei
Sustainability 2025, 17(15), 6997; https://doi.org/10.3390/su17156997 - 1 Aug 2025
Viewed by 177
Abstract
Promoting sustainable development requires a clear understanding of how short-term fluctuations in anthropogenic emissions affect urban environmental quality. This is especially relevant for cities experiencing rapid industrial changes or emergency policy interventions. Among key environmental concerns, variations in ambient pollutants like ozone (O [...] Read more.
Promoting sustainable development requires a clear understanding of how short-term fluctuations in anthropogenic emissions affect urban environmental quality. This is especially relevant for cities experiencing rapid industrial changes or emergency policy interventions. Among key environmental concerns, variations in ambient pollutants like ozone (O3) are closely tied to both public health and long-term sustainability goals. However, traditional chemical transport models often face challenges in accurately estimating emission changes and providing timely assessments. In contrast, statistical approaches such as the difference-in-differences (DID) model utilize observational data to improve evaluation accuracy and efficiency. This study leverages the synthetic difference-in-differences (SDID) approach, which integrates the strengths of both DID and the synthetic control method (SCM), to provide a more reliable and accurate analysis of the impacts of interventions on city-level air quality. Using Shanghai’s 2022 lockdown as a case study, we compare the deweathered ozone (O3) concentration in Shanghai to a counterfactual constructed from a weighted average of cities in the Yangtze River Delta (YRD) that did not undergo lockdown. The quasi-natural experiment reveals an average increase of 4.4 μg/m3 (95% CI: 0.24–8.56) in Shanghai’s maximum daily 8 h O3 concentration attributable to the lockdown. The SDID method reduces reliance on the parallel trends assumption and improves the estimate stability through unit- and time-specific weights. Multiple robustness checks confirm the reliability of these findings, underscoring the efficacy of the SDID approach in quantitatively evaluating the causal impact of emission perturbations on air quality. This study provides credible causal evidence of the environmental impact of short-term policy interventions, highlighting the utility of SDID in informing adaptive air quality management. The findings support the development of timely, evidence-based strategies for sustainable urban governance and environmental policy design. Full article
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20 pages, 1701 KiB  
Article
Life Cycle Assessment of Biomass Waste and Coal Co-Firing: Advancing Circular Economy in Energy Production
by Stiven J. Sofán-Germán, Miguel E. Doria-Oviedo, Jesus D. Rhenals-Julio and Jorge M. Mendoza-Fandiño
Recycling 2025, 10(4), 151; https://doi.org/10.3390/recycling10040151 - 1 Aug 2025
Viewed by 162
Abstract
This study uses life cycle analysis (LCA) to evaluate the environmental impacts of co-firing bituminous coal with agricultural biomass waste, such as coconut and rice husks, emphasising circular economy principles. Seven experimental scenarios with different coal-to-biomass ratios were designed, ranging from pure coal [...] Read more.
This study uses life cycle analysis (LCA) to evaluate the environmental impacts of co-firing bituminous coal with agricultural biomass waste, such as coconut and rice husks, emphasising circular economy principles. Seven experimental scenarios with different coal-to-biomass ratios were designed, ranging from pure coal to pure biomass. The results show that Scenario B (100% rice husk) achieved the best overall environmental performance, with the lowest global warming potential (300 kg CO2 equivalent), eutrophication potential (4.742 kg PO4 equivalent), and smog formation potential (0.012 kg C2H4 equivalent). Additionally, Scenario F (15% biomass mix) recorded the lowest acidification potential (57.39 kg SO2 eq), indicating that even partial substitution can yield significant environmental benefits. In contrast, Scenario C (100% coal) exhibited the highest acidification (164.08 kg SO2 eq) and eutrophication (8.82 kg PO4 eq) potential. Overall, the results demonstrate that co-firing biomass waste significantly reduces pollutant emissions compared to burning coal alone. This study highlights the effectiveness of biomass waste co-firing in mitigating environmental impacts, promoting resource recovery, and supporting a sustainable energy transition within a circular economy framework. Full article
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19 pages, 950 KiB  
Article
How the Adoption of EVs in Developing Countries Can Be Effective: Indonesia’s Case
by Ida Nyoman Basmantra, Ngurah Keshawa Satya Santiarsa, Regina Dinanti Widodo and Caren Angellina Mimaki
World Electr. Veh. J. 2025, 16(8), 428; https://doi.org/10.3390/wevj16080428 - 1 Aug 2025
Viewed by 183
Abstract
Indonesia’s worsening air pollution and traffic emissions have thrust electric vehicles (EVs) into the spotlight, but what really drives Indonesians to make the switch? This study integrates Protection Motivation Theory with green branding and policy frameworks to explain electric vehicle (EV) adoption in [...] Read more.
Indonesia’s worsening air pollution and traffic emissions have thrust electric vehicles (EVs) into the spotlight, but what really drives Indonesians to make the switch? This study integrates Protection Motivation Theory with green branding and policy frameworks to explain electric vehicle (EV) adoption in Indonesia. Using a nationwide survey (n = 986) and partial-least-squares structural-equation modeling, we test how environmental awareness, consumer expectancy, threat appraisal, and coping appraisal shape adoption both directly and through green brand image (GBI), while perceived policy incentives moderate the GBI–adoption link. The model accounts for 54% of the variance in adoption intention. These findings highlight that combining public awareness campaigns, compelling green brand messaging, and carefully calibrated policy incentives is essential for accelerating Indonesia’s transition to cleaner transport. Full article
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20 pages, 3979 KiB  
Article
Theoretical Study of CO Oxidation on Pt Single-Atom Catalyst Decorated C3N Monolayers with Nitrogen Vacancies
by Suparada Kamchompoo, Yuwanda Injongkol, Nuttapon Yodsin, Rui-Qin Zhang, Manaschai Kunaseth and Siriporn Jungsuttiwong
Sci 2025, 7(3), 101; https://doi.org/10.3390/sci7030101 - 1 Aug 2025
Viewed by 210
Abstract
Carbon monoxide (CO) is a major toxic gas emitted from vehicle exhaust, industrial processes, and incomplete fuel combustion, posing serious environmental and health risks. Catalytic oxidation of CO into less harmful CO2 is an effective strategy to reduce these emissions. In this [...] Read more.
Carbon monoxide (CO) is a major toxic gas emitted from vehicle exhaust, industrial processes, and incomplete fuel combustion, posing serious environmental and health risks. Catalytic oxidation of CO into less harmful CO2 is an effective strategy to reduce these emissions. In this study, we investigated the catalytic performance of platinum (Pt) single atoms doped on C3N monolayers with various vacancy defects, including single carbon (CV) and nitrogen (NV) vacancies, using density functional theory (DFT) calculations. Our results demonstrate that Pt@NV-C3N exhibited the most favorable catalytic properties, with the highest O2 adsorption energy (−3.07 eV). This performance significantly outperforms Pt atoms doped at other vacancies. It can be attributed to the strong binding between Pt and nitrogen vacancies, which contributes to its excellent resistance to Pt aggregation. CO oxidation on Pt@NV-C3N proceeds via the Eley–Rideal (ER2) mechanism with a low activation barrier of 0.41 eV for the rate-determining step, indicating high catalytic efficiency at low temperatures. These findings suggest that Pt@NV-C3N is a promising candidate for CO oxidation, contributing to developing cost-effective and environmentally sustainable catalysts. The strong binding of Pt atoms to the nitrogen vacancies prevents aggregation, ensuring the stability and durability of the catalyst. The kinetic modeling further revealed that the ER2 mechanism offers the highest reaction rate constants over a wide temperature range (273–700 K). The low activation energy barrier also facilitates CO oxidation at lower temperatures, addressing critical challenges in automotive and industrial pollution control. This study provides valuable theoretical insights for designing advanced single-atom catalysts for environmental remediation applications. Full article
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32 pages, 10052 KiB  
Article
A Study on Large Electric Vehicle Fires in a Tunnel: Use of a Fire Dynamics Simulator (FDS)
by Roberto Dessì, Daniel Fruhwirt and Davide Papurello
Processes 2025, 13(8), 2435; https://doi.org/10.3390/pr13082435 - 31 Jul 2025
Viewed by 311
Abstract
Internal combustion engine vehicles damage the environment and public health by emitting toxic fumes, such as CO2 or CO and other trace compounds. The use of electric cars helps to reduce the emission of pollutants into the environment due to the use [...] Read more.
Internal combustion engine vehicles damage the environment and public health by emitting toxic fumes, such as CO2 or CO and other trace compounds. The use of electric cars helps to reduce the emission of pollutants into the environment due to the use of batteries with no direct and local emissions. However, accidents of battery electric vehicles pose new challenges, such as thermal runaway. Such accidents can be serious and, in some cases, may result in uncontrolled overheating that causes the battery pack to spontaneously ignite. In particular, the most dangerous vehicles are heavy goods vehicles (HGVs), as they release a large amount of energy that generate high temperatures, poor visibility, and respiratory damage. This study aims to determine the potential consequences of large BEV fires in road tunnels using computational fluid dynamics (CFD). Furthermore, a comparison between a BEV and an ICEV fire shows the differences related to the thermal and the toxic impact. Furthermore, the adoption of a longitudinal ventilation system in the tunnel helped to mitigate the BEV fire risk, keeping a safer environment for tunnel users and rescue services through adequate smoke control. Full article
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