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22 pages, 3002 KiB  
Review
Overview of Operational Global and Regional Ocean Colour Essential Ocean Variables Within the Copernicus Marine Service
by Vittorio E. Brando, Rosalia Santoleri, Simone Colella, Gianluca Volpe, Annalisa Di Cicco, Michela Sammartino, Luis González Vilas, Chiara Lapucci, Emanuele Böhm, Maria Laura Zoffoli, Claudia Cesarini, Vega Forneris, Flavio La Padula, Antoine Mangin, Quentin Jutard, Marine Bretagnon, Philippe Bryère, Julien Demaria, Ben Calton, Jane Netting, Shubha Sathyendranath, Davide D’Alimonte, Tamito Kajiyama, Dimitry Van der Zande, Quinten Vanhellemont, Kerstin Stelzer, Martin Böttcher and Carole Lebretonadd Show full author list remove Hide full author list
Remote Sens. 2024, 16(23), 4588; https://doi.org/10.3390/rs16234588 - 6 Dec 2024
Cited by 3 | Viewed by 1886
Abstract
The Ocean Colour Thematic Assembly Centre (OCTAC) of the Copernicus Marine Service delivers state-of-the-art Ocean Colour core products for both global oceans and European seas, derived from multiple satellite missions. Since 2015, the OCTAC has provided global and regional high-level merged products that [...] Read more.
The Ocean Colour Thematic Assembly Centre (OCTAC) of the Copernicus Marine Service delivers state-of-the-art Ocean Colour core products for both global oceans and European seas, derived from multiple satellite missions. Since 2015, the OCTAC has provided global and regional high-level merged products that offer value-added information not directly available from space agencies. This is achieved by integrating observations from various missions, resulting in homogenized, inter-calibrated datasets with broader spatial coverage than single-sensor data streams. OCTAC enhanced continuously the basin-level accuracy of essential ocean variables (EOVs) across the global ocean and European regional seas, including the Atlantic, Arctic, Baltic, Mediterranean, and Black seas. From 2019 onwards, new EOVs have been introduced, focusing on phytoplankton functional groups, community structure, and primary production. This paper provides an overview of the evolution of the OCTAC catalogue from 2015 to date, evaluates the accuracy of global and regional products, and outlines plans for future product development. Full article
(This article belongs to the Special Issue Oceans from Space V)
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23 pages, 5168 KiB  
Article
Optical Characterization of Coastal Waters with Atmospheric Correction Errors: Insights from SGLI and AERONET-OC
by Hiroto Higa, Masataka Muto, Salem Ibrahim Salem, Hiroshi Kobayashi, Joji Ishizaka, Kazunori Ogata, Mitsuhiro Toratani, Kuniaki Takahashi, Fabrice Maupin and Stephane Victori
Remote Sens. 2024, 16(19), 3626; https://doi.org/10.3390/rs16193626 - 28 Sep 2024
Cited by 1 | Viewed by 1523
Abstract
This study identifies the characteristics of water regions with negative normalized water-leaving radiance (nLw(λ)) values in the satellite observations of the Second-generation Global Imager (SGLI) sensor aboard the Global Change Observation Mission–Climate (GCOM-C) satellite. SGLI Level-2 [...] Read more.
This study identifies the characteristics of water regions with negative normalized water-leaving radiance (nLw(λ)) values in the satellite observations of the Second-generation Global Imager (SGLI) sensor aboard the Global Change Observation Mission–Climate (GCOM-C) satellite. SGLI Level-2 data, along with atmospheric and in-water optical properties measured by the sun photometers in the AErosol RObotic NETwork-Ocean Color (AERONET-OC) from 26 sites globally, are utilized in this study. The focus is particularly on Tokyo Bay and the Ariake Sea, semi-enclosed water regions in Japan where previous research has pointed out the occurrence of negative nLw(λ) values due to atmospheric correction with SGLI. The study examines the temporal changes in atmospheric and in-water optical properties in these two regions, and identifies the characteristics of regions prone to negative nLw(λ) values due to atmospheric correction by comparing the optical properties of these regions with those of 24 other AERONET-OC sites. The time series results of nLw(λ) and the single-scattering albedo (ω(λ)) obtained by the sun photometers at the two sites in Tokyo Bay and Ariake Sea, along with SGLI nLw(λ), indicate the occurrence of negative values in SGLI nLw(λ) in blue band regions, which are mainly attributed to the inflow of absorptive aerosols. However, these negative values are not entirely explained by ω(λ) at 443 nm alone. Additionally, a comparison of in situ nLw(λ) measurements in Tokyo Bay and the Ariake Sea with nLw(λ) values obtained from 24 other AERONET-OC sites, as well as the inherent optical properties (IOPs) estimated through the Quasi-Analytical Algorithm version 5 (QAA_v5), identified five sites—Gulf of Riga, Long Island Sound, Lake Vanern, the Tokyo Bay, and Ariake Sea—as regions where negative nLw(λ) values are more likely to occur. These regions also tend to have lower nLw(λ)  values at shorter wavelengths. Furthermore, relatively high light absorption by phytoplankton and colored dissolved organic matter, plus non-algal particles, was confirmed in these regions. This occurs because atmospheric correction processing excessively subtracts aerosol light scattering due to the influence of aerosol absorption, increasing the probability of the occurrence of negative nLw(λ) values. Based on the analysis of atmospheric and in-water optical measurements derived from AERONET-OC in this study, it was found that negative nLw(λ)  values due to atmospheric correction are more likely to occur in water regions characterized by both the presence of absorptive aerosols in the atmosphere and high light absorption by in-water substances. Full article
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29 pages, 10168 KiB  
Article
Developing a Semi-Automated Near-Coastal, Water Quality-Retrieval Process from Global Multi-Spectral Data: South-Eastern Australia
by Avik Nandy, Stuart Phinn, Alistair Grinham and Simon Albert
Remote Sens. 2024, 16(13), 2389; https://doi.org/10.3390/rs16132389 - 28 Jun 2024
Cited by 1 | Viewed by 1793
Abstract
The estimation of water quality properties through satellite remote sensing relies on (1) the optical characteristics of the water body, (2) the resolutions (spatial, spectral, radiometric and temporal) of the sensor and (3) algorithm(s) applied. More than 80% of global water bodies fall [...] Read more.
The estimation of water quality properties through satellite remote sensing relies on (1) the optical characteristics of the water body, (2) the resolutions (spatial, spectral, radiometric and temporal) of the sensor and (3) algorithm(s) applied. More than 80% of global water bodies fall under Case I (open ocean) waters, dominated by scattering and absorption associated with phytoplankton in the water column. Globally, previous studies show significant correlations between satellite-based retrieval methods and field measurements of absorbing and scattering constituents, while limited research from Australian coastal water bodies appears. This study presents a methodology to extract chlorophyll a properties from surface waters from near-coastal environments, within 2 km of coastline, in Tasmania, south-eastern Australia. We use general purpose, global, long-time series, multi-spectral satellite data, as opposed to ocean colour-specific sensor data. This approach may offer globally applicable tools for combining global satellite image archives with in situ field sensors for water quality monitoring. To enable applications from local to global scales, a cloud-based geospatial analysis workflow was developed and tested on several sites. This work represents the initial stage in developing a semi-automated near-coastal water-quality workflow using easily accessed, fully corrected global multi-spectral datasets alongside large-scale computation and delivery capabilities. Our results indicated a strong correlation between the in situ chlorophyll concentration data and blue-green band ratios from the multi-spectral sensor. In line with published research, environment-specific empirical models exhibited the highest correlations between in situ and satellite measurements, underscoring the importance of tailoring models to specific coastal waters. Our findings may provide the basis for developing this workflow for other sites in Australia. We acknowledge the use of general purpose multi-spectral data such as the Sentinel-2 and Landsat Series, their corrections and algorithms may not be as accurate and precise as ocean colour satellites. The data we are using are more readily accessible and also have true global coverage with global historic archives and regular, global collection will continue at least 10 years in the future. Regardless of sensor specifications, the retrieval method relies on localised algorithm calibration and validation using in situ measurements, which demonstrates close-to-realistic outputs. We hope this approach enables future applications to also consider these globally accessible and regularly updated datasets that are suited to coastal environments. Full article
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16 pages, 1353 KiB  
Article
Sensor Selection for an Electronic Tongue for the Rapid Detection of Paralytic Shellfish Toxins: A Case Study
by Mariana Raposo, Maria Teresa S. R. Gomes, Sara T. Costa, Maria João Botelho and Alisa Rudnitskaya
Chemosensors 2024, 12(6), 115; https://doi.org/10.3390/chemosensors12060115 - 19 Jun 2024
Cited by 2 | Viewed by 1303
Abstract
The performance of an electronic tongue can be optimized by varying the number and types of sensors in the array and by employing data-processing methods. Sensor selection is typically performed empirically, with sensors picked up either by analyzing their characteristics or through trial [...] Read more.
The performance of an electronic tongue can be optimized by varying the number and types of sensors in the array and by employing data-processing methods. Sensor selection is typically performed empirically, with sensors picked up either by analyzing their characteristics or through trial and error, which does not guarantee an optimized sensor array composition. This study focuses on developing a method for sensor selection for an electronic tongue using simulated sensor data and Lasso regularization. Simulated sensor responses were calculated using sensor parameters such as sensitivity and selectivity, which were determined in the individual analyte solutions. Sensor selection was carried out using Lasso regularization, which removes redundant or highly correlated variables without much loss of information. The objective of the optimization of the sensor array was twofold, aiming to minimize both quantification errors and the number of sensors in the array. The quantification of toxins belonging to one of the groups of marine toxins—paralytic shellfish toxins (PSTs)—using arrays of potentiometric chemical sensors was used as a case study. Eight PSTs corresponding to the toxin profiles in bivalves due to the two common toxin-producing phytoplankton species, G. catenatum (dcSTX, GTX5, GTX6, and C1+2) and A. minitum (STX, GTX2+3), as well as total sample toxicity, were included in the study. Experimental validation with mixed solutions of two groups of toxins confirmed the suitability of the proposed method of sensor array optimization with better performance obtained for the a priori optimized sensor arrays. The results indicate that the use of simulated sensor responses and Lasso regularization is a rapid and efficient method for the selection of an optimized sensor array. Full article
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14 pages, 2799 KiB  
Article
Evaluation of Ocean Color Algorithms to Retrieve Chlorophyll-a Concentration in the Mexican Pacific Ocean off the Baja California Peninsula, Mexico
by Patricia Alvarado-Graef, Beatriz Martín-Atienza, Ramón Sosa-Ávalos, Reginaldo Durazo and Rafael Hernández-Walls
Remote Sens. 2024, 16(10), 1748; https://doi.org/10.3390/rs16101748 - 15 May 2024
Viewed by 1822
Abstract
Mathematical algorithms relate satellite data of ocean color with the surface Chlorophyll-a concentration (Chl-a), a proxy of phytoplankton biomass. These mathematical tools work best when they are adapted to the unique bio-optical properties of a particular oceanic province. Ocean color [...] Read more.
Mathematical algorithms relate satellite data of ocean color with the surface Chlorophyll-a concentration (Chl-a), a proxy of phytoplankton biomass. These mathematical tools work best when they are adapted to the unique bio-optical properties of a particular oceanic province. Ocean color algorithms should also consider that there are significant differences between datasets derived from different sensors. Common solutions are to provide different parameters for each sensor or use merged satellite data. In this paper, we use satellite data from the Copernicus merged product suite and in situ data from the southernmost part of the California Current System to test two widely used global algorithms, OCx and CI, and a regional algorithm, CalCOFI2. The OCx algorithm yielded the most favorable results. Consequently, we regionalized it and conducted further testing, leading to significant improvements, especially in eutrophic and oligotrophic waters. The database was then separated according to (a) dynamic boundaries in the area, (b) bio-optical properties, and (c) climatic conditions (El Niño/La Niña). Regional algorithms were obtained and tested for each partition. The Chl-a retrievals for each model were tested and compared. The best fit for the data was for the regional algorithms that considered the climatic conditions (El Niño/La Niña). These results will allow for the construction of consistent regionally adapted time series and, therefore, will demonstrate the importance of El Niño/La Niña events on the bio-optical properties of the area. Full article
(This article belongs to the Section Ocean Remote Sensing)
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34 pages, 15432 KiB  
Article
Physics-Based Satellite-Derived Bathymetry (SDB) Using Landsat OLI Images
by Minsu Kim, Jeff Danielson, Curt Storlazzi and Seonkyung Park
Remote Sens. 2024, 16(5), 843; https://doi.org/10.3390/rs16050843 - 28 Feb 2024
Cited by 7 | Viewed by 4892
Abstract
The estimation of depth in optically shallow waters using satellite imagery can be efficient and cost-effective. Active sensors measure the distance traveled by an emitted laser pulse propagating through the water with high precision and accuracy if the bottom peak intensity of the [...] Read more.
The estimation of depth in optically shallow waters using satellite imagery can be efficient and cost-effective. Active sensors measure the distance traveled by an emitted laser pulse propagating through the water with high precision and accuracy if the bottom peak intensity of the waveform is greater than the noise level. However, passive optical imaging of optically shallow water involves measuring the radiance after the sunlight undergoes downward attenuation on the way to the sea floor, and the reflected light is then attenuated while moving back upward to the water surface. The difficulty of satellite-derived bathymetry (SDB) arises from the fact that the measured radiance is a result of a complex association of physical elements, mainly the optical properties of the water, bottom reflectance, and depth. In this research, we attempt to apply physics-based algorithms to solve this complex problem as accurately as possible to overcome the limitation of having only a few known values from a multispectral sensor. Major analysis components are atmospheric correction, the estimation of water optical properties from optically deep water, and the optimization of bottom reflectance as well as the water depth. Specular reflection of the sky radiance from the water surface is modeled in addition to the typical atmospheric correction. The physical modeling of optically dominant components such as dissolved organic matter, phytoplankton, and suspended particulates allows the inversion of water attenuation coefficients from optically deep pixels. The atmospheric correction and water attenuation results are used in the ocean optical reflectance equation to solve for the bottom reflectance and water depth. At each stage of the solution, physics-based models and a physically valid, constrained Levenberg–Marquardt numerical optimization technique are used. The physics-based algorithm is applied to Landsat Operational Land Imager (OLI) imagery over the shallow coastal zone of Guam, Key West, and Puerto Rico. The SDB depths are compared to airborne lidar depths, and the root mean squared error (RMSE) is mostly less than 2 m over water as deep as 30 m. As the initial choice of bottom reflectance is critical, along with the bottom reflectance library, we describe a pure bottom unmixing method based on eigenvector analysis to estimate unknown site-specific bottom reflectance. Full article
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28 pages, 4379 KiB  
Article
Estimation of the Biogeochemical and Physical Properties of Lakes Based on Remote Sensing and Artificial Intelligence Applications
by Kaire Toming, Hui Liu, Tuuli Soomets, Evelyn Uuemaa, Tiina Nõges and Tiit Kutser
Remote Sens. 2024, 16(3), 464; https://doi.org/10.3390/rs16030464 - 25 Jan 2024
Cited by 13 | Viewed by 2606
Abstract
Lakes play a crucial role in the global biogeochemical cycles through the transport, storage, and transformation of different biogeochemical compounds. Their regulatory service appears to be disproportionately important relative to their small areal extent, necessitating continuous monitoring. This study leverages the potential of [...] Read more.
Lakes play a crucial role in the global biogeochemical cycles through the transport, storage, and transformation of different biogeochemical compounds. Their regulatory service appears to be disproportionately important relative to their small areal extent, necessitating continuous monitoring. This study leverages the potential of optical remote sensing sensors, specifically Sentinel-2 Multispectral Imagery (MSI), to monitor and predict water quality parameters in lakes. Optically active parameters, such as chlorophyll a (CHL), total suspended matter (TSM), and colored dissolved matter (CDOM), can be directly detected using optical remote sensing sensors. However, the challenge lies in detecting non-optically active substances, which lack direct spectral characteristics. The capabilities of artificial intelligence applications can be used in the identification of optically non-active compounds from remote sensing data. This study aims to employ a machine learning approach (combining the Genetic Algorithm (GA) and Extreme Gradient Boost (XGBoost)) and in situ and Sentinel-2 Multispectral Imagery data to construct inversion models for 16 physical and biogeochemical water quality parameters including CHL, CDOM, TSM, total nitrogen (TN), total phosphorus (TP), phosphate (PO4), sulphate, ammonium nitrogen, 5-day biochemical oxygen demand (BOD5), chemical oxygen demand (COD), and the biomasses of phytoplankton and cyanobacteria, pH, dissolved oxygen (O2), water temperature (WT) and transparency (SD). GA_XGBoost exhibited strong predictive capabilities and it was able to accurately predict 10 biogeochemical and 2 physical water quality parameters. Additionally, this study provides a practical demonstration of the developed inversion models, illustrating their applicability in estimating various water quality parameters simultaneously across multiple lakes on five different dates. The study highlights the need for ongoing research and refinement of machine learning methodologies in environmental monitoring, particularly in remote sensing applications for water quality assessment. Results emphasize the need for broader temporal scopes, longer-term datasets, and enhanced model selection strategies to improve the robustness and generalizability of these models. In general, the outcomes of this study provide the basis for a better understanding of the role of lakes in the biogeochemical cycle and will allow the formulation of reliable recommendations for various applications used in the studies of ecology, water quality, the climate, and the carbon cycle. Full article
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21 pages, 3079 KiB  
Article
A New Algorithm Using Support Vector Machines to Detect and Monitor Bloom-Forming Pseudo-nitzschia from OLCI Data
by Luis González Vilas, Evangelos Spyrakos, Yolanda Pazos and Jesus M. Torres Palenzuela
Remote Sens. 2024, 16(2), 298; https://doi.org/10.3390/rs16020298 - 11 Jan 2024
Cited by 2 | Viewed by 1953
Abstract
Pseudo-nitzschia spp. blooms are a recurrent problem in many coastal areas globally, imposing some significant threats to the health of humans, ecosystems and the economy. Monitoring programmes have been established, where feasible, to mitigate the impacts caused by Pseudo-nitzschia spp. and other harmful [...] Read more.
Pseudo-nitzschia spp. blooms are a recurrent problem in many coastal areas globally, imposing some significant threats to the health of humans, ecosystems and the economy. Monitoring programmes have been established, where feasible, to mitigate the impacts caused by Pseudo-nitzschia spp. and other harmful algae blooms. The detection of such blooms from satellite data could really provide timely information on emerging risks but the development of taxa-specific algorithms from available multispectral data is still challenged by coupled optical properties with other taxa and water constituents, availability of ground data and generalisation capabilities of algorithms. Here, we developed a new set of algorithms (PNOI) for the detection and monitoring of Pseudo-nitzschia spp. blooms over the Galician coast (NW Iberian Peninsula) from Sentinel-3 OLCI reflectances using a support vector machine (SVM). Our algorithm was trained and tested with reflectance data from 260 OLCI images and 4607 Pseudo-nitzschia spp. match up data points, of which 2171 were of high quality. The performance of the no bloom/bloom model in the independent test set was robust, showing values of 0.80, 0.72 and 0.79 for the area under the curve (AUC), sensitivity and specificity, respectively. Similar results were obtained by our below detection limit/presence model. We also present different model thresholds based on optimisation of true skill statistic (TSS) and F1-score. PNOI outperforms linear models, while its relationship with in situ chlorophyll-a concentrations is weak, demonstrating a poor correlation with the phytoplankton abundance. We showcase the importance of the PNOI algorithm and OLCI sensor for monitoring the bloom evolution between the weekly ground sampling and during periods of ground data absence, such as due to COVID-19. Full article
(This article belongs to the Section Ocean Remote Sensing)
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19 pages, 6426 KiB  
Article
Diel Variation in Phytoplankton Biomass Driven by Hydrological Factors at Three Coastal Monitoring Buoy Stations in the Taiwan Strait
by Cun Jia, Lei Wang, Youquan Zhang, Meihui Lin, Yan Wan, Xiwu Zhou, Chunsheng Jing and Xiaogang Guo
J. Mar. Sci. Eng. 2023, 11(12), 2252; https://doi.org/10.3390/jmse11122252 - 28 Nov 2023
Cited by 3 | Viewed by 1498
Abstract
To investigate the diurnal variation in phytoplankton biomass and its regulating factors during the diurnal cycle, we conducted in situ observations in June 2018 at three buoy stations, including Douwei Buoy Station, Minjiang Estuary Buoy Station, and Huangqi Buoy Station on the western [...] Read more.
To investigate the diurnal variation in phytoplankton biomass and its regulating factors during the diurnal cycle, we conducted in situ observations in June 2018 at three buoy stations, including Douwei Buoy Station, Minjiang Estuary Buoy Station, and Huangqi Buoy Station on the western side of the Taiwan Strait. The calibration of buoy sensor data, including temperature, salinity, dissolved oxygen, pH, chlorophyll, and phycoerythrin, was conducted simultaneously. In addition, water sampling was conducted to measure chlorophyll a and phycoerythrin concentrations at hourly time intervals. The results showed that the 24 h cumulative chlorophyll a concentration order for the buoys was Minjiang Estuary (10.280 μg/L) > Huangqi (7.411 μg/L) > Douwei (4.124 μg/L). The Minjiang Estuary had a lower nighttime biomass proportion than Douwei and Huangqi. The diurnal variation in phytoplankton was jointly regulated by water masses, tides, and light. There were three response patterns, including the “light trumps tidal influences” pattern at Douwei, the “Low-tide, High-biomass” pattern at Minjiang Estuary, and the “High-tide, High-biomass” pattern at Huangqi. The prediction of algal blooms and hypoxia using buoy monitoring needs to be based on seasonal water mass background and tidal influence. Full article
(This article belongs to the Topic Marine Ecology, Environmental Stress and Management)
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22 pages, 8060 KiB  
Article
A Hybrid Chlorophyll a Estimation Method for Oligotrophic and Mesotrophic Reservoirs Based on Optical Water Classification
by Xiaoyan Dang, Jun Du, Chao Wang, Fangfang Zhang, Lin Wu, Jiping Liu, Zheng Wang, Xu Yang and Jingxu Wang
Remote Sens. 2023, 15(8), 2209; https://doi.org/10.3390/rs15082209 - 21 Apr 2023
Cited by 5 | Viewed by 2565
Abstract
Low- and medium-resolution satellites have been a relatively mature platform for inland eutrophic water classification and chlorophyll a concentration (Chl-a) retrieval algorithms. However, for oligotrophic and mesotrophic waters in small- and medium-sized reservoirs, problems of low satellite resolution, insufficient water sampling, and higher [...] Read more.
Low- and medium-resolution satellites have been a relatively mature platform for inland eutrophic water classification and chlorophyll a concentration (Chl-a) retrieval algorithms. However, for oligotrophic and mesotrophic waters in small- and medium-sized reservoirs, problems of low satellite resolution, insufficient water sampling, and higher uncertainty in retrieval accuracy exist. In this paper, a hybrid Chl-a estimation method based on spectral characteristics (i.e., remote sensing reflectance (Rrs)) classification was developed for oligotrophic and mesotrophic waters using high-resolution satellite Sentinel-2 (A and B) data. First, 99 samples and quasi-synchronous Sentinel-2 satellite data were collected from four small- and medium-sized reservoirs in central China, and the usability of the Sentinel-2 Rrs data in inland oligotrophic and mesotrophic waters was verified by accurate atmospheric correction. Second, a new optical classification method was constructed based on different water characteristics to classify waters into clear water, phytoplankton-dominated water, and water dominated by phytoplankton and suspended matter together using the thresholds of Rrs490/Rrs560 and Rrs665/Rrs560. The proposed method has a higher classification accuracy compared to other classification methods, and the band-ratio algorithm is simpler and more effective for satellite sensors without NIR bands. Third, given the sensitivity of the empirical method to water variability and the ease of development and implementation, a nonlinear least squares fitted one-dimensional nonlinear function was established based on the selection of the best-fitting spectral indices for different optical water types (OWTs) and compared with other Chl-a estimation algorithms. The validation results showed that the hybrid two-band method had the highest accuracy with squared correlation coefficient, root mean squared difference, mean absolute percentage error, and bias of 0.85, 2.93, 32.42%, and −0.75 mg/m3, respectively, and the results of the residual values further validated the applicability and reliability of the model. Finally, the performance of the classification and estimation algorithms on the four reservoirs was evaluated to obtain images mapping the Chl-a in the reservoirs. In conclusion, this study improves the accuracy of Chl-a estimation for oligotrophic and mesotrophic waters by combining a new classification algorithm with a two-band hybrid model, which is an important contribution to solving the problem of low resolution and high uncertainty in the retrieval of Chl-a in oligotrophic and mesotrophic waters in small- and medium-sized reservoirs and has the potential to be applied to other optically similar oligotrophic and mesotrophic lakes and reservoirs using similar spectrally satellite sensors. Full article
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28 pages, 4787 KiB  
Review
The Arctic Amplification and Its Impact: A Synthesis through Satellite Observations
by Igor Esau, Lasse H. Pettersson, Mathilde Cancet, Bertrand Chapron, Alexander Chernokulsky, Craig Donlon, Oleg Sizov, Andrei Soromotin and Johnny A. Johannesen
Remote Sens. 2023, 15(5), 1354; https://doi.org/10.3390/rs15051354 - 28 Feb 2023
Cited by 23 | Viewed by 7148
Abstract
Arctic climate change has already resulted in amplified and accelerated regional warming, or the Arctic amplification. Satellite observations have captured this climate phenomenon in its development and in sufficient spatial details. As such, these observations have been—and still are—indispensable for monitoring of the [...] Read more.
Arctic climate change has already resulted in amplified and accelerated regional warming, or the Arctic amplification. Satellite observations have captured this climate phenomenon in its development and in sufficient spatial details. As such, these observations have been—and still are—indispensable for monitoring of the amplification in this remote and inhospitable region, which is sparsely covered with ground observations. This study synthesizes the key contributions of satellite observations into an understanding and characterization of the amplification. The study reveals that the satellites were able to capture a number of important environmental transitions in the region that both precede and follow the emergence of the apparent amplification. Among those transitions, we find a rapid decline in the multiyear sea ice and subsequent changes in the surface radiation balance. Satellites have witnessed the impact of the amplification on phytoplankton and vegetation productivity as well as on human activity and infrastructure. Satellite missions of the European Space Agency (ESA) are increasingly contributing to amplification monitoring and assessment. The ESA Climate Change Initiative has become an essential provider of long-term climatic-quality remote-sensing data products for essential climate variables. Still, such synthesis has found that additional efforts are needed to improve cross-sensor calibrations and retrieval algorithms and to reduce uncertainties. As the amplification is set to continue into the 21st century, a new generation of satellite instruments with improved revisiting time and spectral and spatial resolutions are in high demand in both research and stakeholders’ communities. Full article
(This article belongs to the Special Issue Earth Observations for Sustainable Development Goals)
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21 pages, 17640 KiB  
Article
Carbon Air–Sea Flux in the Arctic Ocean from CALIPSO from 2007 to 2020
by Siqi Zhang, Peng Chen, Zhenhua Zhang and Delu Pan
Remote Sens. 2022, 14(24), 6196; https://doi.org/10.3390/rs14246196 - 7 Dec 2022
Cited by 9 | Viewed by 3016
Abstract
Quantified research on the Arctic Ocean carbon system is poorly understood, limited by the scarce available data. Measuring the associated phytoplankton responses to air–sea CO2 fluxes is challenging using traditional satellite passive ocean color measurements due to low solar elevation angles. We [...] Read more.
Quantified research on the Arctic Ocean carbon system is poorly understood, limited by the scarce available data. Measuring the associated phytoplankton responses to air–sea CO2 fluxes is challenging using traditional satellite passive ocean color measurements due to low solar elevation angles. We constructed a feedforward neural network light detection and ranging (LiDAR; FNN-LID) method to assess the Arctic diurnal partial pressure of carbon dioxide (pCO2) and formed a dataset of long-time-series variations in diurnal air–sea CO2 fluxes from 2001 to 2020; this study represents the first time spaceborne LiDAR data were employed in research on the Arctic air–sea carbon cycle, thus providing enlarged data coverage and diurnal pCO2 variations. Although some models replace Arctic winter Chl-a with the climatological average or interpolated Chl-a values, applying these statistical Chl-a values results in potential errors in the gap-filled wintertime pCO2 maps. The CALIPSO measurements obtained through active LiDAR sensing are not limited by solar radiation and can thus provide ‘fill-in’ data in the late autumn to early spring seasons, when ocean color sensors cannot record data; thus, we constructed the first complete record of polar pCO2. We obtained Arctic FFN-LID-fitted in situ measurements with an overall mean R2 of 0.75 and an average RMSE of 24.59 µatm and filled the wintertime observational gaps, thereby indicating that surface water pCO2 is higher in winter than in summer. The Arctic Ocean net CO2 sink has seasonal sources from some continental shelves. The growth rate of Arctic seawater pCO2 is becoming larger and more remarkable in sectors with significant sea ice retreat. The combination of sea surface partial pressure and wind speed impacts the diurnal carbon air–sea flux variability, which results in important differences between the Pacific and Atlantic Arctic Ocean. Our results show that the diurnal carbon sink is larger than the nocturnal carbon sink in the Atlantic Arctic Ocean, while the diurnal carbon sink is smaller than the nocturnal carbon sink in the Pacific Arctic Ocean. Full article
(This article belongs to the Special Issue Oceanographic Lidar in the Study of Marine Systems)
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20 pages, 4894 KiB  
Article
Remote Sensing of the Seasonal and Interannual Variability of Surface Chlorophyll-a Concentration in the Northwest Pacific over the Past 23 Years (1997–2020)
by Shuangling Chen, Yu Meng, Sheng Lin and Jingyuan Xi
Remote Sens. 2022, 14(21), 5611; https://doi.org/10.3390/rs14215611 - 7 Nov 2022
Cited by 9 | Viewed by 3282
Abstract
Phytoplankton in the northwest Pacific plays an important role in absorbing atmospheric CO2 and promoting the ocean carbon cycle. However, our knowledge on the long-term interannual variabilities of the phytoplankton biomass in this region is quite limited. In this study, based on [...] Read more.
Phytoplankton in the northwest Pacific plays an important role in absorbing atmospheric CO2 and promoting the ocean carbon cycle. However, our knowledge on the long-term interannual variabilities of the phytoplankton biomass in this region is quite limited. In this study, based on the Chlorophyll-a concentration (Chl-a) time series observed from ocean color satellites of Sea-viewing Wide Field-of-view Sensor (SeaWiFS) and Moderate Resolution Imaging Spectroradiometer (MODIS) in the period of 1997–2020, we investigated the variabilities of Chl-a on both seasonal and interannual scales, as well as the long-term trends. The phytoplankton Chl-a showed large spatial dynamics with a general decreasing pattern poleward. The seasonal phytoplankton blooms dominated the seasonal characteristics of Chl-a, with spring and fall blooms identified in subpolar waters and single spring blooms in subtropical seas. On interannual scales, we found a Chl-a increasing belt in the subpolar oceans from the marginal sea toward the northeast open ocean waters, with positive trends (~0.02 mg m−3 yr−1, on average) in Chl-a at significant levels (p < 0.05). In the subtropical gyre, Chl-a showed slight but significant negative trends (i.e., <−0.0006 mg m−3 yr−1, at p < 0.05). The negative Chl-a trends in the subtropical waters tended to be driven by the surface warming, which could inhibit nutrient supplies from the subsurface and thus limit phytoplankton growth. For the subpolar waters, although the surface warming also prevailed over the study period, the in situ surface nitrate reservoir somehow showed significant increases in the targeted spots, indicating potential external nitrate supplies into the surface layer. We did not find significant connections between the Chl-a interannual variabilities and the climate indices in the study area. Environmental data with finer spatial and temporal resolutions will further constrain the findings. Full article
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27 pages, 7194 KiB  
Article
Retrieving Pigment Concentrations Based on Hyperspectral Measurements of the Phytoplankton Absorption Coefficient in Global Oceans
by Jing Teng, Tinglu Zhang, Kunpeng Sun and Hong Gao
Remote Sens. 2022, 14(15), 3516; https://doi.org/10.3390/rs14153516 - 22 Jul 2022
Cited by 5 | Viewed by 2864
Abstract
Phytoplankton communities, which can be easily observed by optical sensors deployed on various types of platforms over diverse temporal and spatial scales, are crucial to marine ecosystems and biogeochemical cycles, and accurate pigment concentrations make it possible to effectively derive information from them. [...] Read more.
Phytoplankton communities, which can be easily observed by optical sensors deployed on various types of platforms over diverse temporal and spatial scales, are crucial to marine ecosystems and biogeochemical cycles, and accurate pigment concentrations make it possible to effectively derive information from them. To date, there is no practical approach, however, to retrieving concentrations of detailed pigments from phytoplankton absorption coefficients (aph) with acceptable accuracy and robustness in global oceans. In this study, a novel method, which is a stepwise regression method improved by early stopping (the ES-SR method) based on the derivative of hyperspectral aph, was proposed to retrieve pigment concentrations. This method was developed from an extensive global dataset collected from layers at different depths and contains phytoplankton pigment concentrations and aph. In the case of the logarithm, strong correlations were found between phytoplankton pigment concentrations and the absolute values of the second derivative (aph)/the fourth derivative (aph4) of aph. According to these correlations, the ES-SR method is effective in obtaining the characteristic wavelengths of phytoplankton pigments for pigment concentration inversion. Compared with the Gaussian decomposition method and principal component regression method, which are based on the derivatives, the ES-SR method implemented on aph is the optimum approach with the greatest accuracy for each phytoplankton pigment. More than half of the determination coefficient values (R2log) for all pigments, which were retrieved by performing the ES-SR method on aph, exceeded 0.7. The values retrieved for all pigments fit well to the one-to-one line with acceptable root mean square error (RMSElog: 0.146–0.508) and median absolute percentage error (MPElog: 8.2–28.5%) values. Furthermore, the poor correlations between the deviations from the values retrieved by the ES-SR method and impact factors related to pigment composition and cell size class show that this method has advantageous robustness. Therefore, the ES-SR method has the potential to effectively monitor phytoplankton community information from hyperspectral optical data in global oceans. Full article
(This article belongs to the Special Issue Bio-Optical Oceanic Remote Sensing)
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20 pages, 7934 KiB  
Article
Methodology for Phytoplankton Taxonomic Group Identification towards the Development of a Lab-on-a-Chip
by Denise A. M. Carvalho, Vânia C. Pinto, Paulo J. Sousa, Vitor H. Magalhães, Emilio Fernández, Pedro A. Gomes, Graça Minas and Luís M. Gonçalves
Appl. Sci. 2022, 12(11), 5376; https://doi.org/10.3390/app12115376 - 26 May 2022
Cited by 4 | Viewed by 2757
Abstract
This paper presents the absorbance and fluorescence optical properties of various phytoplankton species, looking to achieve an accurate method to detect and identify a number of phytoplankton taxonomic groups. The methodology to select the excitation and detection wavelengths that results in superior identification [...] Read more.
This paper presents the absorbance and fluorescence optical properties of various phytoplankton species, looking to achieve an accurate method to detect and identify a number of phytoplankton taxonomic groups. The methodology to select the excitation and detection wavelengths that results in superior identification of phytoplankton is reported. The macroscopic analyses and the implemented methodology are the base for designing a lab-on-a-chip device for a phytoplankton group identification, based on cell analysis with multi-wavelength lighting excitation, aiming for a cheap and portable platform. With such methodology in a lab-on-a-chip device, the analysis of the phytoplankton cells’ optical properties, e.g., fluorescence, diffraction, absorption and reflection, will be possible. This device will offer, in the future, a platform for continuous, autonomous and in situ underwater measurements, in opposition to the conventional methodology. A proof-of-concept device with LED light excitation at 450 nm and a detection photodiode at 680 nm was fabricated. This device was able to quantify the concentration of the phytoplankton chlorophyll a. A lock-in amplifier electronic circuit was developed and integrated in a portable and low-cost sensor, featuring continuous, autonomous and in situ underwater measurements. This device has a detection limit of 0.01 µ/L of chlorophyll a, in a range up to 300 µg/L, with a linear voltage output with chlorophyll concentration. Full article
(This article belongs to the Special Issue Novel Technology and Applications of Micro/Nano Devices and System)
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