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Search Results (136)

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Keywords = petroleum equipment

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15 pages, 630 KiB  
Article
Application of a Low-Cost Electronic Nose to Differentiate Between Soils Polluted by Standard and Biodegradable Hydraulic Oils
by Piotr Borowik, Przemysław Pluta, Miłosz Tkaczyk, Krzysztof Sztabkowski, Rafał Tarakowski and Tomasz Oszako
Chemosensors 2025, 13(8), 290; https://doi.org/10.3390/chemosensors13080290 - 5 Aug 2025
Abstract
Detection of soil pollution by petroleum products is necessary to remedy threats to economic and human health. Pollution by hydraulic oil often occurs through leaks from forestry machinery such as harvesters. Electronic noses equipped with gas sensor arrays are promising tools for applications [...] Read more.
Detection of soil pollution by petroleum products is necessary to remedy threats to economic and human health. Pollution by hydraulic oil often occurs through leaks from forestry machinery such as harvesters. Electronic noses equipped with gas sensor arrays are promising tools for applications of pollution detection and monitoring. A self-made, low-cost electronic nose was used for differentiation between clean and polluted samples, with two types of oils and three levels of pollution severity. An electronic nose uses the TGS series of gas sensors, manufactured by Figaro Inc. Sensor responses to changes in environmental conditions from clean air to measured odor, as well as responses to changes in sensor operation temperature, were used for analysis. Statistically significant response results allowed for the detection of pollution by biodegradable oil, while standard mineral oil was difficult to detect. It was demonstrated that the TGS 2602 gas sensor is most suitable for the studied application. LDA analysis demonstrated multidimensional data patterns allowing differentiation between sample categories and pollution severity levels. Full article
(This article belongs to the Special Issue Electronic Nose and Electronic Tongue for Substance Analysis)
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32 pages, 6134 KiB  
Article
Nonlinear Dynamic Modeling and Analysis of Drill Strings Under Stick–Slip Vibrations in Rotary Drilling Systems
by Mohamed Zinelabidine Doghmane
Energies 2025, 18(14), 3860; https://doi.org/10.3390/en18143860 - 20 Jul 2025
Viewed by 327
Abstract
This paper presents a comprehensive study of torsional stick–slip vibrations in rotary drilling systems through a comparison between two lumped parameter models with differing complexity: a simple two-degree-of-freedom (2-DOF) model and a complex high-degree-of-freedom (high-DOF) model. The two models are developed under identical [...] Read more.
This paper presents a comprehensive study of torsional stick–slip vibrations in rotary drilling systems through a comparison between two lumped parameter models with differing complexity: a simple two-degree-of-freedom (2-DOF) model and a complex high-degree-of-freedom (high-DOF) model. The two models are developed under identical boundary conditions and consider an identical nonlinear friction torque dynamic involving the Stribeck effect and dry friction phenomena. The high-DOF model is calculated with the Finite Element Method (FEM) to enable accurate simulation of the dynamic behavior of the drill string and accurate representation of wave propagation, energy build-up, and torque response. Field data obtained from an Algerian oil well with Measurement While Drilling (MWD) equipment are used to guide modeling and determine simulations. According to the findings, the FEM-based high-DOF model demonstrates better performance in simulating basic stick–slip dynamics, such as drill bit velocity oscillation, nonlinear friction torque formation, and transient bit-to-surface contacts. On the other hand, the 2-DOF model is not able to represent these effects accurately and can lead to inappropriate control actions and mitigation of vibration severity. This study highlights the importance of robust model fidelity in building reliable real-time rotary drilling control systems. From the performance difference measurement between low-resolution and high-resolution models, the findings offer valuable insights to optimize drilling efficiency further, minimize non-productive time (NPT), and improve the rate of penetration (ROP). This contribution points to the need for using high-fidelity models, such as FEM-based models, in facilitating smart and adaptive well control strategies in modern petroleum drilling engineering. Full article
(This article belongs to the Section H: Geo-Energy)
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16 pages, 944 KiB  
Article
Artificial Intelligence in the Oil and Gas Industry: Applications, Challenges, and Future Directions
by Marcelo dos Santos Póvoas, Jéssica Freire Moreira, Severino Virgínio Martins Neto, Carlos Antonio da Silva Carvalho, Bruno Santos Cezario, André Luís Azevedo Guedes and Gilson Brito Alves Lima
Appl. Sci. 2025, 15(14), 7918; https://doi.org/10.3390/app15147918 - 16 Jul 2025
Viewed by 1200
Abstract
This study aims to provide a comprehensive overview of the application of artificial intelligence (AI) methods to solve real-world problems in the oil and gas sector. The methodology involved a two-step process for analyzing AI applications. In the first step, an initial exploration [...] Read more.
This study aims to provide a comprehensive overview of the application of artificial intelligence (AI) methods to solve real-world problems in the oil and gas sector. The methodology involved a two-step process for analyzing AI applications. In the first step, an initial exploration of scientific articles in the Scopus database was conducted using keywords related to AI and computational intelligence, resulting in a total of 11,296 articles. The bibliometric analysis conducted using VOS Viewer version 1.6.15 software revealed an average annual growth of approximately 15% in the number of publications related to AI in the sector between 2015 and 2024, indicating the growing importance of this technology. In the second step, the research focused on the OnePetro database, widely used by the oil industry, selecting articles with terms associated with production and drilling, such as “production system”, “hydrate formation”, “machine learning”, “real-time”, and “neural network”. The results highlight the transformative impact of AI on production operations, with key applications including optimizing operations through real-time data analysis, predictive maintenance to anticipate failures, advanced reservoir management through improved modeling, image and video analysis for continuous equipment monitoring, and enhanced safety through immediate risk detection. The bibliometric analysis identified a significant concentration of publications at Society of Petroleum Engineers (SPE) events, which accounted for approximately 40% of the selected articles. Overall, the integration of AI into production operations has driven significant improvements in efficiency and safety, and its continued evolution is expected to advance industry practices further and address emerging challenges. Full article
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25 pages, 1725 KiB  
Review
Analysis of the Application of Ammonia as a Fuel for a Compression-Ignition Engine
by Wojciech Tutak and Arkadiusz Jamrozik
Energies 2025, 18(12), 3217; https://doi.org/10.3390/en18123217 - 19 Jun 2025
Viewed by 463
Abstract
Piston engines used for powering automobiles as well as machinery and equipment have traditionally relied on petroleum-derived fuels. Subsequently, renewable fuels began to be used in an effort to reduce the combustion of hydrocarbon-based fuels and the associated greenhouse effect. Researchers are currently [...] Read more.
Piston engines used for powering automobiles as well as machinery and equipment have traditionally relied on petroleum-derived fuels. Subsequently, renewable fuels began to be used in an effort to reduce the combustion of hydrocarbon-based fuels and the associated greenhouse effect. Researchers are currently developing technologies aimed at eliminating fuels containing carbon in their molecular structure, which would effectively minimize the emission of carbon oxides into the atmosphere. Ammonia is considered a highly promising carbon-free fuel with broad applicability in energy systems. It serves as an excellent hydrogen carrier (NH3), free from many of the storage and transportation limitations associated with pure hydrogen. Safety concerns regarding the storage and transport of hydrogen make ammonia an increasingly important fuel also due to its larger hydrogen storage capacity. This manuscript investigates the use of ammonia for powering a dual-fuel engine. The results indicate that the addition of ammonia improves engine performance; however, it may also lead to an increase in NOx emissions. Due to the limitations of ammonia as a fuel, approximately 40% of the energy input must still be provided by diesel fuel to achieve optimal engine performance and acceptable NOx emission levels. The presented research findings highlight the significant potential of NH3 as an alternative fuel for compression-ignition engines. Proper control of the injection strategy or the adoption of alternative combustion systems may offer a promising approach to reducing greenhouse gas emissions while maintaining satisfactory engine performance parameters. Full article
(This article belongs to the Special Issue Renewable Fuels for Internal Combustion Engines: 2nd Edition)
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15 pages, 9044 KiB  
Article
Polyether Demulsifier Complexes for Efficient Demulsification of Water-in-Heavy Oil Emulsions
by Jing Li, Xiao Xia, Jinlong Gao, Hao Chen and Jun Ma
Molecules 2025, 30(12), 2550; https://doi.org/10.3390/molecules30122550 - 11 Jun 2025
Viewed by 404
Abstract
In the production process of the heavy oil industry, efficiently demulsifying water-in-heavy oil (W/HO) emulsions can effectively prevent the negative effects of emulsion corrosion on equipment, increase costs, reduce oil quality, and pollute the environment. Herein, polyether demulsifier complexes (PDC) were obtained by [...] Read more.
In the production process of the heavy oil industry, efficiently demulsifying water-in-heavy oil (W/HO) emulsions can effectively prevent the negative effects of emulsion corrosion on equipment, increase costs, reduce oil quality, and pollute the environment. Herein, polyether demulsifier complexes (PDC) were obtained by compounding fatty alcohol nonionic polyether (FAP) with perfluoropolyether (PFPEA, [CF3O(CF2CF2O)nCF3]) through a simple physical blending method. The experimental results demonstrate that PDC exhibited outstanding demulsification performance for W/HO emulsions across varying temperatures: At 60 °C and 400 ppm dosage, PDC achieved complete dehydration (100%) within just 2 min, showing significantly faster demulsification kinetics compared to FAP and PFPEA. Even at the reduced temperature of 40 °C, PDC maintained effective demulsification capability, achieving complete phase separation within 6 min. These findings collectively establish PDC’s superior demulsification efficiency for W/HO emulsions, with particularly remarkable performance under challenging low-temperature conditions. Research on the demulsification mechanism indicates that PDC achieves efficient demulsification performance due to the synergistic effect the synergistic effect of FAP and PFPEA to effectively destroy the non-covalent bonds (hydrogen and π–π stacking) of interfacially active asphaltenes (IAA) at the oil–water interface, thereby achieving demulsification of W/HO emulsion. PDC with outstanding demulsification ability exhibits significant potential for practical applications in heavy crude oil–water emulsion treatment, and this work can provide insights for developing new composite demulsifiers for petroleum production. Full article
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24 pages, 6035 KiB  
Article
Research on Multi-Objective Flexible Job Shop Scheduling Optimization Based on Improved Salp Swarm Algorithm in Rolling Production Mode
by Lei Yin and Qi Gao
Appl. Sci. 2025, 15(11), 5947; https://doi.org/10.3390/app15115947 - 25 May 2025
Viewed by 522
Abstract
To address the multi-objective flexible job shop scheduling problem in rolling production mode (FJSP-RPM), this study proposes a Multi Objective Improved of Salp Swarm Algorithm (MISSA) that simultaneously optimizes equipment utilization and total tardiness. The MISSA generates initial population through various heuristic strategies [...] Read more.
To address the multi-objective flexible job shop scheduling problem in rolling production mode (FJSP-RPM), this study proposes a Multi Objective Improved of Salp Swarm Algorithm (MISSA) that simultaneously optimizes equipment utilization and total tardiness. The MISSA generates initial population through various heuristic strategies to improve the initial population quality. The exploitation capability of the algorithm is enhanced through the global crossover strategy and variety of local search strategies. In terms of improvement strategies, the MISSA (using all three strategies) outperforms other incomplete variant algorithms (using only two strategies) in three metrics: Generational Distance (GD), Inverted Generational Distance (IGD), and diversity metric, achieving superior results in 9 test cases, 8 test cases, and 4 test cases respectively. When compared with NSGA2, NSGA3, and SPEA2 algorithms, the MISSA demonstrates advantages in 8 test cases for GD, 8 test cases for IGD, and 7 test cases for the diversity metric. Additionally, the distribution of the obtained solution sets is significantly better than that of the comparative algorithms, which validats the effectiveness of the MISSA in solving FJSP-RPM. Full article
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64 pages, 6390 KiB  
Review
Greening Fused Deposition Modeling: A Critical Review of Plant Fiber-Reinforced PLA-Based 3D-Printed Biocomposites
by Muneeb Tahir and Abdel-Fattah Seyam
Fibers 2025, 13(5), 64; https://doi.org/10.3390/fib13050064 - 14 May 2025
Cited by 1 | Viewed by 2879
Abstract
Fused deposition modeling (FDM) 3D printing (3DP) of PLA biocomposites reinforced with plant-derived cellulosic fibrous materials, including spun yarn, microcrystalline, microfibrillar, nanofibrillar cellulose, and cellulose nanocrystals, offers an environmentally sustainable solution to the mechanical limitations of polymer-only printed materials. Micron- and submicron-scale cellulosic [...] Read more.
Fused deposition modeling (FDM) 3D printing (3DP) of PLA biocomposites reinforced with plant-derived cellulosic fibrous materials, including spun yarn, microcrystalline, microfibrillar, nanofibrillar cellulose, and cellulose nanocrystals, offers an environmentally sustainable solution to the mechanical limitations of polymer-only printed materials. Micron- and submicron-scale cellulosic fibers are valued for their renewability, non-toxicity, high surface area, and favorable elastic and specific moduli; notably, micron-scale reinforcements are particularly attractive due to their ease of large-scale industrial production and commercial viability. Similarly, PLA benefits from large-scale production, contributes to CO2 sequestration through its raw material precursors, and requires less energy for production than non-biodegradable petroleum-derived polymers. Incorporating these raw materials, each of which offers attractive performance properties, complementary commercial strengths, and environmental benefits, as constituent phases in FDM 3D-printed biocomposites (FDMPBs) can further enhance the environmental responsiveness of an already low-waste FDM 3DP technology. Inspired by these compelling advantages, this paper critically reviews research on FDMPB with cellulosic reinforcements in a PLA matrix, uniquely categorizing studies based on the form of cellulosic reinforcement and its impact on the biocomposite’s structure and mechanical performance. Additionally, the review covers biocomposite filament production methods and the equipment involved, presenting an alternative framework for cataloging FDMPB research. A comprehensive literature analysis reveals that the wide variation in feedstocks, fiber–matrix compounding methods, equipment, and processing parameters used in filament production and 3DP complicates the comparison of FDMPB mechanical properties across studies, often resulting in conflicting outcomes. Key processing parameters have been compiled to bridge this gap and offer a more nuanced understanding of the cause-and-effect relationships governing biocomposite properties. Finally, targeted recommendations for future research on developing FDMPB with a PLA matrix and micron-scale cellulosic reinforcements are provided, addressing the knowledge gaps and challenges highlighted in the peer-reviewed literature. Full article
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34 pages, 2173 KiB  
Review
Advances in Microbial and Plant-Based Biopolymers: Synthesis and Applications in Next-Generation Materials
by Poova Kattil Drishya, M. Venkateswar Reddy, Gunda Mohanakrishna, Omprakash Sarkar, Isha, M. V. Rohit, Aesha Patel and Young-Cheol Chang
Macromol 2025, 5(2), 21; https://doi.org/10.3390/macromol5020021 - 6 May 2025
Cited by 6 | Viewed by 3253
Abstract
Biopolymers are revolutionizing the materials landscape, driven by a growing demand for sustainable alternatives to traditional petroleum-based materials. Sourced from biological origins, these polymers are not only environment friendly but also present exciting solutions in healthcare, packaging, biosensors, high performance, and durable materials [...] Read more.
Biopolymers are revolutionizing the materials landscape, driven by a growing demand for sustainable alternatives to traditional petroleum-based materials. Sourced from biological origins, these polymers are not only environment friendly but also present exciting solutions in healthcare, packaging, biosensors, high performance, and durable materials as alternatives to crude oil-based products. Recently, biopolymers derived from plants, such as lignin and cellulose, alongside those produced by bacteria, like polyhydroxyalkanoates (PHAs), have captured the spotlight, drawing significant interest for their industrial and eco-friendly applications. The growing interest in biopolymers stems from their potential as sustainable, renewable materials across diverse applications. This review provides an in-depth analysis of the current advancements in plant-based and bacterial biopolymers, covering aspects of bioproduction, downstream processing, and their integration into high-performance next-generation materials. Additionally, we delve into the technical challenges of cost-effectiveness, processing, and scalability, which are critical barriers to widespread adoption. By highlighting these issues, this review aims to equip researchers in the bio-based domain with a comprehensive understanding of how plant-based and bacterial biopolymers can serve as viable alternatives to petroleum-derived materials. Ultimately, we envision a transformative shift from a linear, fossil fuel-based economy to a circular, bio-based economy, fostering more sustainable and environmentally conscious material solutions using novel biopolymers aligning with the framework of the United Nations Sustainable Development Goals (SDGs), including clean water and sanitation (SDG 6), industry, innovation, and infrastructure (SDG 9), affordable and clean energy (SDG 7), sustainable cities and communities (SDG 11), responsible production and consumption (SDG 12), and climate action (SDG 13). Full article
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20 pages, 4851 KiB  
Article
Corrosion Behavior of Mild Steel in Various Environments Including CO2, H2S, and Their Combinations
by Yuanguang Yue, Zhibiao Yin, Shiming Li, Ziyue Zhang and Qifu Zhang
Metals 2025, 15(4), 440; https://doi.org/10.3390/met15040440 - 15 Apr 2025
Viewed by 625
Abstract
This paper investigates the corrosion behavior of mild steel in simulated oilfield wastewater under CO2, H2S, and their mixture. Using the electrical resistance method, the corrosion rates were monitored, and the influence of corrosion product films on overall performance [...] Read more.
This paper investigates the corrosion behavior of mild steel in simulated oilfield wastewater under CO2, H2S, and their mixture. Using the electrical resistance method, the corrosion rates were monitored, and the influence of corrosion product films on overall performance was analyzed. The results show that the CO2/H2S mixture causes the highest corrosion rate. Metallographic examination and X-ray diffraction (XRD) provided insights into the nature of the corrosion products formed on the steel surface. While hydrogen sulfide (H2S) does not prevent general corrosion, it plays a role in mitigating localized damage. Corrosion leads to deep, narrow pits that weaken the structural integrity without significant surface damage, making it more dangerous than uniform corrosion. In CO2-only environments, electrochemical reactions form protective oxide layers. However, H2S alters this process by forming iron sulfides (FeS), which are less protective but still act as a barrier against further corrosion. In mixed CO2/H2S environments, interactions between the gases complicate the corrosion dynamics, increasing medium aggressiveness and accelerating material degradation. Understanding these mechanisms is critical for the petroleum industry, where equipment is exposed to harsh conditions with varying CO2 and H2S concentrations. Recognizing the dual role of H2S—its inability to inhibit general corrosion but its effectiveness in reducing pitting—can guide material selection and inhibitor development. This knowledge enhances the durability and safety of oil and gas infrastructure by addressing the most damaging forms of corrosion. Full article
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25 pages, 3579 KiB  
Article
Energy Consumption in Mexican Homes: Using a Reference Building as a Launchpad for Achieving Nearly Zero Energy
by Carlos A. Espino-Reyes, Naghelli Ortega-Avila, Jorge Lucero-Álvarez and Norma A. Rodríguez-Muñoz
Urban Sci. 2025, 9(4), 113; https://doi.org/10.3390/urbansci9040113 - 4 Apr 2025
Viewed by 621
Abstract
The residential sector accounts for over a third of the world’s energy use. Even though this ratio is lower in Mexico, there is a pressing housing deficit, especially regarding low-cost homes. This research aimed to create a reference building (RB) to understand the [...] Read more.
The residential sector accounts for over a third of the world’s energy use. Even though this ratio is lower in Mexico, there is a pressing housing deficit, especially regarding low-cost homes. This research aimed to create a reference building (RB) to understand the current energy consumption of multi-family buildings across different climatic zones. The aim was to assess their energy performance and promote reduced energy requirements as a guideline for designing and constructing affordable, low-energy, or zero-energy buildings. The present work conducts a diagnosis of the current energy consumption of multi-family buildings in eight cities in Mexico. First, a reference building was developed to represent typical Mexican building geometry and construction practices, and then the building’s fixed and variable energy requirements were simulated. Finally, a comparison was made between the energy requirement and the data reported by the national energy survey. Therefore, it was possible to generate a reference building from national data sources complying with national regulations, where materials, occupant behavior, and equipment were chosen to help represent the building’s thermal behavior. Domestic water heating was identified as a driver of variable energy requirements in all cities. In contrast, the simulated heating and cooling requirements were directly linked to the city’s climate. Electricity bills tended to mostly correspond with the results that excluded the use of heating systems. Lastly, while comparing LPG (Liquified Petroleum Gas) consumption was challenging due to the unavailability of national data, LPG requirements were closely estimated for temperate cities. The definition of a reference building is an important step towards developing nZEB in Mexico, as these buildings are valuable tools that can contribute to the energy evaluation of specific types of buildings. This characteristic makes them convenient for revising a building code or setting new national energy policy goals. Full article
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18 pages, 4420 KiB  
Article
Investigation of the Energy Comsuption and Indoor Environment in Rural Residences in South China
by Hua Lei, Miaoyan Qiu, Tianwei Tang, Yanping Yang and Yukang Yuan
Buildings 2025, 15(7), 1129; https://doi.org/10.3390/buildings15071129 - 30 Mar 2025
Viewed by 365
Abstract
With the development of society, energy application and building thermal comfort in rural residences are receiving more and more attention. The rural residences in this survey mainly cover the rural areas of 21 prefectures in Guangdong province, of which 24.7% are in the [...] Read more.
With the development of society, energy application and building thermal comfort in rural residences are receiving more and more attention. The rural residences in this survey mainly cover the rural areas of 21 prefectures in Guangdong province, of which 24.7% are in the Pearl River Delta, 18.9% in western Guangdong, 13.1% in eastern Guangdong, and 43.2% in northern Guangdong. Rural household energy consumption is mainly used for lighting equipment, household appliances, and cooking equipment, where lighting equipment and household appliances mainly consume electrical energy, and cooking equipment consumes different types of energy due to the diversity of types. First, there is a wide variety and variation in rural energy consumption, with electricity and liquefied petroleum gas as the main sources of cooking energy. Hot water is mainly obtained by heating with electricity and natural gas. Secondly, for rural residents, renewable energy is too expensive to build, is also affected by the environment and weather, and is often not convenient to use. Third, rural residents generally experience a warm, humid indoor environment with adequate airflow, but poor kitchen ventilation reduces air quality satisfaction. To enhance renewable energy adoption, technological advancements and cost reductions are necessary, along with increased government efforts in awareness campaigns, policy incentives, and demonstration projects. This study analyses the rural energy structure in Guangdong, proposes the direction of rural energy optimization, and analyses rural energy use and the feasibility of renewable energy promotion, considering the population and income of rural households. Full article
(This article belongs to the Special Issue Healthy, Low-Carbon and Resilient Built Environments)
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34 pages, 2370 KiB  
Review
Enhancing the Performance of Natural Ester Insulating Liquids in Power Transformers: A Comprehensive Review on Antioxidant Additives for Improved Oxidation Stability
by Esther Ogwa Obebe, Yazid Hadjadj, Samson Okikiola Oparanti and Issouf Fofana
Energies 2025, 18(7), 1690; https://doi.org/10.3390/en18071690 - 28 Mar 2025
Cited by 2 | Viewed by 1139
Abstract
The reliability of the electrical grid is vital to economic prosperity and quality of life. Power transformers, key components of transmission and distribution systems, represent major capital investments. Traditionally, these machines have relied on petroleum-based mineral oil as an insulating liquid. However, with [...] Read more.
The reliability of the electrical grid is vital to economic prosperity and quality of life. Power transformers, key components of transmission and distribution systems, represent major capital investments. Traditionally, these machines have relied on petroleum-based mineral oil as an insulating liquid. However, with a global shift toward sustainability, renewable insulating materials like natural esters are gaining attention due to their environmental and fire safety benefits. These biodegradable liquids are poised to replace hydrocarbon-based oils in transformers, aligning with Sustainable Development Goals 7 and 13 by promoting clean energy and climate action. Despite their advantages, natural esters face challenges in high-voltage applications, particularly due to oxidation stability issues linked to their fatty acid composition. Various antioxidants have been explored to address this, with synthetic antioxidants proving more effective than natural ones, especially under high-temperature conditions. Their superior thermal stability ensures that natural esters retain their cooling and dielectric properties, essential for transformer performance. Furthermore, integrating machine learning and artificial intelligence in antioxidant development and monitoring presents a transformative opportunity. This review provides insights into the role of antioxidants in natural ester-filled power equipment, supporting their broader adoption and contributing to a more sustainable energy future. Full article
(This article belongs to the Section D1: Advanced Energy Materials)
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20 pages, 6074 KiB  
Article
Investigation of Turbulence Characteristics Influenced by Flow Velocity, Roughness, and Eccentricity in Horizontal Annuli Based on Numerical Simulation
by Yanchao Sun, Jialiang Sun, Jie Zhang and Ning Huang
Symmetry 2025, 17(3), 409; https://doi.org/10.3390/sym17030409 - 9 Mar 2025
Cited by 1 | Viewed by 829
Abstract
Annular flow channels, which are distinct from circular pipes, represent a complex flow structure widely applied in fields such as food engineering and petroleum engineering. Discovering the internal flow patterns is conducive to the study of heat and mass transfer laws, thereby playing [...] Read more.
Annular flow channels, which are distinct from circular pipes, represent a complex flow structure widely applied in fields such as food engineering and petroleum engineering. Discovering the internal flow patterns is conducive to the study of heat and mass transfer laws, thereby playing a crucial role in optimizing flow processes and selecting equipment. However, the mechanism underlying the influence of annular turbulent flow on macro-pressure drop remains to be further investigated. This paper focuses on the roughness of both inner and outer pipes, as well as positive and negative eccentricities. Numerical simulation is employed to study the microscopic characteristics of the flow field, and the numerical model is validated through indoor experimental measurements of pressure drop laws. Further numerical simulations are conducted to explore the microscopic variations in the flow field, analyzed from the perspectives of wall shear force and turbulence characteristics. The results indicate that an increase in inner pipe roughness significantly enhances the wall shear force on both the inner and outer pipes, and vice versa. In the concentric case, wall shear force and turbulence characteristics exhibit central symmetry. Eccentricity leads to uneven distributions of velocity, turbulence intensity, and shear force, with such unevenness presenting axial symmetry under both positive and negative eccentricities. Additionally, eccentricity demonstrates turbulence drag reduction characteristics. This study enhances our understanding of the mechanism by which annular turbulent flow influences pressure drop. Furthermore, it offers theoretical backing for the design and optimization of annular space piping, thereby aiding in the enhancement of the performance and stability of associated industrial systems. Full article
(This article belongs to the Section Physics)
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33 pages, 7087 KiB  
Article
Demulsification of Water-in-Oil Emulsion with Carbon Quantum Dot (CQD)-Enhanced Demulsifier
by Jhon F. Gallego, Oscar E. Medina, Jose A. Tengono, Camilo Mazo, Andres F. Maya, Cristina Caro, Farid B. Cortés and Camilo A. Franco
Processes 2025, 13(2), 575; https://doi.org/10.3390/pr13020575 - 18 Feb 2025
Cited by 2 | Viewed by 1796
Abstract
This study aims to optimize the demulsification performance of a carbon quantum dot (CQD)-enhanced chemical demulsifier in industrial emulsions under thermal, mechanical, and thermomechanical effects. Experiments were conducted to assess treatments like organic treatment (OT), zeta potential modifier aqueous solution (ZPMAS), and acid [...] Read more.
This study aims to optimize the demulsification performance of a carbon quantum dot (CQD)-enhanced chemical demulsifier in industrial emulsions under thermal, mechanical, and thermomechanical effects. Experiments were conducted to assess treatments like organic treatment (OT), zeta potential modifier aqueous solution (ZPMAS), and acid treatment (9.25 wt.% HCl) at varying dosages, along with CQD–chemical mixtures optimized through a simplex-centroid mixture design (SCMD) to minimize basic sediment and water (BSW). Under the thermomechanical scenario, a system with 500 mg∙L−1 CQDs and OT achieves 0.5% BSW and a droplet size of 63 nm, while an SCMD-optimized system (500 mg∙L−1 CQDs + 380 mg∙L−1 OT + 120 mg∙L−1 ZPMAS) achieves 0% BSW and larger droplets (>70 nm). CQDs enhance demulsifiers by destabilizing water-in-oil (W/O) Pickering emulsions, leveraging their nanometric size, high surface area, thermal conductivity, and amphiphilicity, thanks to their hydrophobic core and surface hydrophilic groups (-OH, NH2, -COOH). This research enhances the understanding of demulsification by employing green demulsifiers based on CQDs and provides a promising cost-efficient solution for breaking stable emulsions in the petroleum industry. It minimizes the use of complex and expensive active ingredients, achieving BSW values below 0.5%, the standard required for crude oil transport and sale, while also reducing separation equipment operation times, and improving overall process efficiency. Full article
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16 pages, 1606 KiB  
Review
A Critical Review of the Phenomenon of Inhibiting Asphaltene Precipitation in the Petroleum Industry
by Soroush Ahmadi, Azizollah Khormali and Yousef Kazemzadeh
Processes 2025, 13(1), 212; https://doi.org/10.3390/pr13010212 - 13 Jan 2025
Cited by 3 | Viewed by 1565
Abstract
This comprehensive review examines chemical and nano-based methods for asphaltene inhibition in the oil industry, focusing on recent developments and challenges. Asphaltene precipitation and deposition remain significant challenges in oil production, affecting wellbore areas, equipment walls, and surface infrastructure. The review analyzes various [...] Read more.
This comprehensive review examines chemical and nano-based methods for asphaltene inhibition in the oil industry, focusing on recent developments and challenges. Asphaltene precipitation and deposition remain significant challenges in oil production, affecting wellbore areas, equipment walls, and surface infrastructure. The review analyzes various chemical inhibition mechanisms and evaluation methods, highlighting the emergence of nanotechnology as a promising solution. Metal oxide nanoparticles, organic nanoparticles, and inorganic nonmetal nanoparticles are discussed as effective inhibitors, with particular attention to their performance in different operational conditions, including CO2 flooding processes. The study reveals that nanoparticles’ effectiveness in asphaltene inhibition is attributed to their large specific surface area, strong adsorption capacity, and unique interaction mechanisms with asphaltene molecules. The review also emphasizes the importance of proper inhibitor selection and concentration optimization, as the effectiveness thereof varies with reservoir conditions and crude oil characteristics. Recent developments in functionalized nanoparticles and their applications in enhanced oil recovery are examined, providing insights into future directions for asphaltene management in the petroleum industry. Full article
(This article belongs to the Section Chemical Processes and Systems)
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