Search Results (21)

Addressing the severe risk of artificial fractures causing vertical pressure channeling and subsequent water flooding during shale oil development in the Ordos Basin, this study investigates the overlapping development zone in Block Shun 269. Through laboratory rock mechanics experiments, the mechanical anisotropy of the overlapping layers was characterized. Utilizing actual production data, a 4D dynamic geomechanical model incorporating 21 years of injection-production history was established to reconstruct the pre-fracturing 3D in situ stress field. Based on this stress field model, a quantitative analysis was conducted on the evolution of injection-production stresses, the vertical superposition distance, the distribution of natural fractures, and the propagation patterns of hydraulic fractures across layers under various fracturing engineering parameters (including pumping rate, fluid viscosity, and perforation cluster, etc.). Research indicates that long-term injection-production disturbances caused the average minimum horizontal principal stress in the Chang 6 layer to decrease by 1.6 MPa, with partial “stress deficit zones” experiencing reductions as high as 3.5 MPa. This significantly weakened the stress shading capability between layers, resulting in the probability of fracturing cracks through the Chang 7 layer in the lower section increasing from 12% to 49%. The propagation of fracture height is jointly governed by geological and engineering factors, the weighting order is as follows: superposition distance > pumping rate > interlayer stress difference. A fracturing cross-layer risk assessment chart based on the coupling of geological and engineering factors has been established, proposing different anti-leakage and fracture control technical models for fracturing sections with different risk levels. Using this model to simulate fracturing in B horizontal wells, the simulation results were consistent with microseismic measurement data. Full article

The growing demand for higher-energy lithium-ion batteries, encompassing consumer electronics, stationary grid storage, and electric mobility to specialized sectors like aerospace, medical devices, and industrial robotics, requires cathode materials that offer higher capacity while remaining cost-effective. This trend has intensified the development of nickel-rich LiNi_1−x−yMn_xCo_yO₂ (NMC) systems. However, high-Ni NMCs such as LiNi_0.9Mn_0.05Co_0.05O₂ (NMC90) suffer from limited thermal and cycling stability. Core–shell architectures using LiNi_0.6Mn_0.2Co_0.2O₂ (NMC622) as a shell can partially alleviate these drawbacks, but structural degradation caused by interdiffusion between the core and shell persists as a major challenge. This study investigates whether a tungsten oxide interlayer can act as a protective barrier that suppresses interdiffusion, stabilizes the crystal structure, and improves long-term electrochemical performance. In this work, NMC cathode powders were synthesized via a one-pot oxalate co-precipitation route, followed by structural characterization using X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and ion scattering spectroscopy (ISS). Electrochemical performance, including capacity retention, cycling stability, and internal resistance, was evaluated through galvanostatic charge–discharge (GCD) testing and electrochemical impedance spectroscopy (EIS). The core–shell configuration delivered higher specific discharge capacity compared to the individually synthesized core-only and shell-only reference materials, and the incorporation of a tungsten oxide interlayer resulted in a twofold increase in cycle life. These results demonstrate that tungsten oxide effectively enhances cycling stability by inhibiting core–shell interdiffusion, offering a promising pathway toward more durable high-Ni NMC cathodes. Full article

Hard carbon is widely recognized as a viable anode candidate for sodium-ion batteries (SIBs) owing to its electrochemical advantages, yet simultaneously enhancing specific capacity and rate capability, arising from insufficient plateau capacity, remains a long-standing challenge. Herein, we present a strategy for fabricating ZnCl₂-modified hard carbon (HCMZ-X) using waste macadamia shells and ZnCl₂ as a multifunctional structural modifier through a facile high-temperature carbonization. This approach effectively expands the graphite interlayer spacing to 0.394 nm, reduces microcrystalline size, and induces abundant closed pores, synergistically improving sodium-ion storage kinetics within the hard carbon framework. Mechanistic investigations confirm an “adsorption-intercalation-filling” storage mechanism. Hence, the optimized HCMZ-3 delivers a high reversible capacity of 382.05 mAh g⁻¹ at 0.05 A g⁻¹, with the plateau region contributing approximately 70%, significantly outperforming that of unmodified hard carbon (262.64 mAh g⁻¹). Remarkably, it achieves stable rate performance, delivering 190 mAh g⁻¹ at 1 A g⁻¹, along with excellent cycling stability, retaining over 90% after 500 cycles. By rational pore-structure modulation rather than excessive surface activation, this cost-effective method utilizing agricultural waste and ZnCl₂ dual-functional modification partially alleviates the intrinsic energy-density limitation of hard carbon anodes, advancing the development of high-performance, eco-friendly anodes for scalable energy storage systems. Full article

The bonding behavior of the Ni-based superalloy CM247LC during transient liquid phase (TLP) bonding is strongly governed by filler metal chemistry, particularly boron activity. In this study, the time-dependent bonding mechanisms of CM247LC joints fabricated using a high-boron MBF-80 filler and a low-boron MBF-20 filler are systematically compared to clarifying the transition between reaction-dominated brazing and diffusion-assisted TLP bonding. Microstructural analyses reveal that MBF-80 promotes the formation of a persistent, reaction-stabilized interlayer characterized by strong boron localization and the development of boron-rich intermetallic reaction products. These features kinetically suppress diffusion-assisted homogenization and prevent isothermal solidification, resulting in pronounced chemical and mechanical discontinuities across the joint. In contrast, MBF-20 enables progressive boron depletion, suppression of stable intermetallic accumulation, and interfacial smoothing, leading to diffusion-assisted chemical redistribution and partial isothermal solidification. This evolution is accompanied by gradual convergence of hardness profiles toward that of the CM247LC base metal, indicating improved mechanical continuity. These results demonstrate that joint hardness alone is insufficient for evaluating bonding quality in CM247LC. Instead, controlled microstructural evolution governed by low-boron filler chemistry is essential for achieving chemically and mechanically compatible joints. The present work establishes a clear mechanistic link between filler metal composition and bonding behavior, providing guidance for the design of reliable TLP bonding strategies in Ni-based superalloys. Full article

The rapid increase in global data generation has intensified the demand for magnetic storage systems with substantially higher areal density. Double-layer bit-patterned media recording (DLBPMR), which integrates the benefits of bit-patterned media recording (BPMR) and double-layer magnetic recording (DLMR), provides a promising pathway by combining nanoscale patterned islands with multilayer recording structures. However, severe two-dimensional intersymbol interference (ISI) within each layer, together with interlayer interference (ILI) between stacked layers, continues to present significant challenges for reliable data detection. To address these issues, this work investigates and advances the structure of DLMR to improve signal separation and recovery. In particular, we emphasize that detection plays a crucial role in mitigating both ISI and ILI. Accordingly, we propose a maximum a posteriori (MAP) detection scheme derived for a newly developed generalized two-layer partial-response (PR) model that accurately characterizes intra-layer ISI and cross-layer interference coupling. A parallel detection architecture is designed and employed for the upper and lower layers of the DLMR system, enabling the exchange of extrinsic information and enhancing MAP detection performance. Simulation results demonstrate that the proposed PR modeling and MAP-based detection framework achieves significant bit error rate (BER) improvements over existing detection methods, highlighting its strong potential for next-generation ultra-high-density DLBPMR systems. Full article

Textile-reinforced concrete (TRC) sandwich panels with lightweight cores are a promising solution for sustainable and slender building envelopes. However, their structural performance depends strongly on the shear connection between the outer shells. This study investigates the flexural behavior of TRC sandwich panels with glass fiber-reinforced polymer (GFRP) rod connectors under four-point bending. Three full-scale specimens were manufactured with high-performance concrete (HPC) face layers, an expanded polystyrene (EPS) core, and 12 mm GFRP rods as shear connectors. The panels were tested up to failure, with measurements of load–deflection behavior, crack development, and interlayer slip. Additionally, a linear-elastic finite element model was developed to complement the experimental campaign, capturing the global stiffness of the system and providing complementary insight into the internal stress distribution. The experimental results revealed stable load-bearing behavior with ductile post-cracking response. A degree of composite interaction of γ = 0.33 was obtained, indicating partially composite action. Slip measurements confirmed effective shear transfer by the GFRP connectors, while no brittle failure or connector rupture was observed. The numerical analysis confirmed the elastic response observed in the tests and highlighted the key role of the GFRP connectors in coupling the TRC shells, extending the interpretation beyond experimental results. Overall, the study demonstrates the potential of TRC sandwich panels with mechanical connectors as a safe and reliable structural solution. Full article

A novel and rapid ball-milling approach was developed in this study to efficiently intercalate hexadecyltrimethylammonium bromide (HDTMA-Br) into vermiculite (VMT) within only 15 min. The raw granular VMT (2–3 mm) was first ground into fine powder using an airflow pulverizer. A suspension containing VMT and HDTMA-Br (1 CEC) in deionized water was then subjected to planetary ball milling at 450 r/min (25 °C), followed by washing and drying to obtain organo-vermiculite (OVMT) with a particle size of 44–5 µm. X-ray diffraction, Fourier-transform Infrared Spectroscopy and Thermogravimetric Analysis analyses confirmed successful intercalation, with the basal spacing $d_{\left(001\right)}$ expanding from 1.46 nm to 4.51 nm. Transmission Electron Microscopy observations further revealed partial delamination of lamellar structures and a pronounced reduction in particle size, supporting the structural reorganization induced by the mechanochemical process. In addition, nitrogen adsorption analysis showed that the BET surface area decreased by 4.05 m²·g⁻¹, while the average pore diameter increased by 3.2 nm, indicating the development of a more hydrophobic interlayer environment. Overall, this approach offers a practical route for producing organophilic silicate materials and shows strong potential for wastewater treatment applications, particularly for the adsorption of organic pollutants and heavy-metal ions. Full article

Pan-connected interlayers are widely present in oil reservoirs, forming flow channels at different positions. However, conventional profile control agents struggle to plug deep interlayer channels in reservoirs, limiting the swept volume of injected water. Additionally, a clear methodology for physically simulating pan-connected reservoirs with interlayer channels and calculating interchannel flow rates remains lacking. In this study, a physical model of pan-connected interlayer reservoirs was constructed to carry out deformable gel particles (DGPs) plugging experiments on interlayer channels. A mass conservation-based flow rate calculation method for interlayer channels with iterative solution was proposed, revealing the variation law of interlayer channel flow rates during DGP injection and subsequent water flooding. Finally, oil displacement and DGP profile control experiments in pan-connected interlayer reservoirs were conducted. The study shows that during DGP injection, injected water enters the potential layer through interlayer channels in the middle and front of the water-channeling layer and bypasses back to the water-channeling layer through channels near the production well. With the increase in DGP injection volume, the flow rate of each channel increases. During subsequent water flooding, DGP breakage leads to a rapid decline in its along-path plugging capability, so water bypasses back to the water-channeling layer from the potential layer through all interlayer channels. As the DGP injection volume increases, the flow rate of each channel decreases. Large-volume DGPs can regulate interlayer channeling reservoirs in the high water cut stage. Its effectiveness mechanism involves particle migration increasing the interlayer pressure difference, which drives injected water to sweep from the water-channeling layer to the potential layer through interlayer channels, improving oil recovery by 19.74%. The flow characteristics of interlayer channels during DGP injection play a positive role in oil displacement, so the oil recovery degree in this process is greater than that in the subsequent water flooding stage under each injection volume condition. The core objective of this study is to investigate the plugging mechanism of DGPs in pan-connected interlayer channels of high-water-cut reservoirs, establish a method to quantify interlayer flow rates, and reveal how DGPs regulate flow redistribution to enhance oil recovery. Full article

Among the various contenders for next-generation sodium-ion battery anodes, hard carbons stand out for their notable reversible capacity, extended cycle life, and cost-effectiveness. Their economic advantage can be further enhanced by using inexpensive precursors, such as biomass waste. Lignin, one of the most abundant natural biopolymers on Earth, which can be readily obtained from wood, possesses a three-dimensional amorphous polymeric structure, making it a suitable candidate for producing carbonaceous materials through appropriate carbonization processes for energy storage applications. In this work, we synthesized hard carbon using lignin containing CaSO₄ to facilitate partial catalytic graphitization to improve the microstructural features, such as interlayer spacing, degree of disorder, and surface defects. Partial catalytic graphitization enables hard carbon to develop an ordered structure compared with hard carbon carbonized without CaSO₄ as analyzed by X-ray diffraction, Raman spectroscopy, scanning/transmission electron microscopy, and X-ray photoelectron spectroscopy. The CaSO₄-aided partially catalytic graphitized hard carbon (CCG-HC) exhibited improved electrochemical performance, showing a larger portion of the low-voltage plateau—an indicator typically associated with a highly ordered structure—compared to simply carbonized hard carbon (HC). Notably, CCG-HC delivered a reversible capacity of 237 mAh g⁻¹, retained 95.6% of its capacity over 100 cycles at 50 mA g⁻¹, and exhibited 127 mAh g⁻¹ at 1.0 A g⁻¹. Full article

TiO₂ used for photocatalytic water purification is most active in the form of nanoparticles (NP), but their use is fraught with difficulties in separation from solution or/and a tendency to agglomerate. The novel materials designed in this work circumvent these problems by immobilizing TiO₂ NPs on the surface of exfoliated clay minerals. A series of TiO₂/clay mineral composites were obtained using five different clay components: the Na-, CTA-, or H-form of montmorillonite (Mt) and Na- or CTA-form of laponite (Lap). The TiO₂ component was prepared using the inverse microemulsion method. The composites were characterized with X-ray diffraction, scanning/transmission electron microscopy/energy dispersive X-ray spectroscopy, FTIR spectroscopy, thermal analysis, and N₂ adsorption–desorption isotherms. It was shown that upon composite synthesis, the Mt interlayer became filled by a mixture of CTA⁺ and hydronium ions, regardless of the nature of the parent clay, while the structure of Lap underwent partial destruction. The composites displayed high specific surface area and uniform mesoporosity determined by the size of the TiO₂ nanoparticles. The best textural parameters were shown by composites containing clay components whose structure was partially destroyed; for instance, Ti/CTA-Lap had a specific surface area of 420 m²g⁻¹ and a pore volume of 0.653 cm³g⁻¹. The materials were tested in the photodegradation of methyl orange and humic acid upon UV irradiation. The photocatalytic activity could be correlated with the development of textural properties. In both reactions, the performance of the most photoactive composites surpassed that of the reference commercial P25 titania. Full article

This paper investigates the impact of varying the part geometric complexity and 3D printing process setup on the resulting structural load bearing capacity of fiber composites. Three levels of geometric complexity are developed through 2.5D topology optimization, 3D topology optimization, and 3D topology optimization with directional material removal. The 3D topology optimization is performed with the SIMP method and accelerated by high-performance computing. The directional material removal is realized by incorporating the advection-diffusion partial differential equation-based filter to prevent interior void or undercut in certain directions. A set of 3D printing and mechanical performance tests are performed. It is interestingly found that, the printing direction affects significantly on the result performance and if subject to the uni direction, the load-bearing capacity increases from the 2.5D samples to the 3D samples with the increased complexity, but the load-bearing capacity further increases for the 3D simplified samples due to directional material removal. Hence, it is concluded that a restricted structural complexity is suitable for topology optimization of 3D-printed fiber composites, since large area cross-sections give more degrees of design freedom to the fiber path layout and also makes the inter-layer bond of the filaments firmer. Full article

Artificially modified adsorbing materials mainly aim to remedy the disadvantages of natural materials as much as possible. Using clay materials such as rectorite, sodium bentonite and metakaolinite (solid waste material) as base materials, hydrothermally modified and unmodified materials were compared. CM-HT and CM (adsorbing materials) were prepared and used to adsorb and purify wastewater containing malachite green (MG) dye, and the two materials were characterized through methods such as BET, FT-IR, SEM and XRD. Results: (1) The optimal conditions for hydrothermal modification of CM-HT were a temperature of 150 °C, a time of 2 h, and a liquid/solid ratio 1:20. (2) Hydrothermal modification greatly increased the adsorptive effect. The measured maximum adsorption capacity of CM-HT for MG reached 290.45 mg/g (56.92% higher than that of CM). The theoretical maximum capacity was 625.15 mg/g (186.15% higher than that of CM). (3) Because Al-OH and Si-O-Al groups were reserved in unmodified clay mineral adsorbing materials with good adsorbing activity, after hydrothermal modification, the crystal structure of the clay became loosened along the direction of the c axis, and the interlayer space increased to partially exchange interlayer metal cations connected to the bottom oxygen, giving CM-HT higher electronegativity and creating more crystal defects and chemically active adsorbing sites for high-performance adsorption. (4) Chemical adsorption was the primary way by which CM-HT adsorbed cationic dye, while physical adsorption caused by developed pore canal was secondary. The adsorption reaction occurred spontaneously. Full article

The buffer material that makes up the geological disposal system of high-level waste swells by contact with groundwater and seals space with rock mass and fractures in rock mass. The buffer material has a function of mechanical buffer with rock pressure, and swelling stress is important in this case. The alteration of bentonite may occur due to the initial replacement of cations (Na⁺ ions) in the interlayer with K⁺ ions upon contact with groundwater, but there are no studies on the swelling stress of K-bentonite. In this study, the author prepared K-montmorillonite samples and obtained thermodynamic data on interlayer water as a function of water content using a relative humidity method. The swelling stress was analyzed based on a thermodynamic model developed in earlier studies and compared with measured data. The activity and the relative partial molar Gibbs free energy of porewater decreased with decreasing water content in the region, below approximately 15%. This behavior significantly differs from that of other ions, such as Na. The swelling stress calculated based on the thermodynamic model and date occurred in the region of high density of 1.9 Mg/m³ with montmorillonite partial density. It was indicated for the first time that K-bentonite scarcely swells under realistic design conditions. Full article

Aqueous zinc-ion batteries (ZIBs) have been regarded as a promising alternative to traditional lithium-based batteries due to their intrinsic advantages of safety, low cost, and abundance. However, the strong electrostatic interaction between Zn²⁺ and the layer-structured cathodes is still a key issue that hinders the batteries from storing more Zn. Herein, we report partially nitrided and cation-doped vanadium oxide for improved Zn storage performance. Specifically, the defects and nitride species that are generated inside the material upon nitriding improve the conductivity of the material and introduce a new Zn storage mechanism. The intercalation of cations, in contrast, widens the interlayer spacing to store more Zn²⁺ ions and enhances the cycling stability of the material. These merits synergistically lead to significantly enhanced electrochemical Zn²⁺ ion storage performance, in terms of a high specific capacity of 418.5 mAh·g⁻¹ at a current density of 0.1 A·g⁻¹ and a capacity retention of 81.2% after 500 cycles at 2.0 A·g⁻¹. The new modification strategy for V₂O₅ suggested in this work could provide insight into the development of high-performance ZIBs. Full article

Over four decades, researchers have extensively focused on bonding flexible pavement layers. Scholars have concentrated on the partial or complete lack of interlayer bonding between asphalt layers, which is the primary cause of premature pavement failures, such as cracking, rutting, slippage of wearing courses, and decline in pavement life. These defects are observed within the high horizontal force areas owing to increased speed, braking, and sharp angles when entering or exiting highways and the variations in paving materials, traffic load, and climatic factors. Various studies have investigated the debonding of flexible pavements, and test methods have been developed to find effective solutions. This review is aimed at summarising and discussing certain factors influencing shear strength performance, such as tack coat material, surface characteristics of multi-layer construction of flexible pavements, and different mechanical shear tests. First, bonding in the interface zone area and its Effect on the shear strength performance is reviewed. Subsequently, the types of materials and construction methods and their effects on the bonding quality of the interface zone area are clarified. Finally, the linear relationships between certain effects and the Ability of nanofibers to improve the emulsion properties are discussed. However, no agreement on the optimum tack coat could be obtained owing to the variety of surfaces. Hence, a milling surface is recommended for higher shear strength. The shear test is the most used method for verifying the interlayer bonding strengths, and continuous research endeavours are recommended to analyse debonding in multi-layer asphalt pavements. Full article