Search Results (514)

Accelerated artificial aging of zinc oxide (ZnO)-based acrylic artists’ paint, filled with calcium carbonate (CaCO₃) as an extender, was carried out for a total of 1963 h (~8 × 10⁷ lux·h), with assessments at specific intervals. The total color difference ΔE* was <2 (CIELab-76 system) over 1725 h of aging, while the human eye notices color change at ΔE* > 2. Oxidative degradation of organic components in the paint to form volatile products was revealed by attenuated total reflectance–Fourier transform infrared (ATR-FTIR) spectroscopy, micro-Raman spectroscopy, and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). It appears that deep oxidation of organic intermediates and volatilization of organic matter may be responsible for the relatively small value of ΔE* color difference during aging of the samples. To elucidate the degradation pathways, principal component analysis (PCA) was applied to the spectral data, revealing: (1) the catalytic role of ZnO in accelerating photodegradation, (2) the Kolbe photoreaction, (3) the decomposition of the binder to form volatile degradation products, and (4) the relative photoinactivity of CaCO₃ compared with ZnO, showing slower degradation in areas with a higher CaCO₃ content compared with those dominated by ZnO. These results provide fundamental insights into formulation-specific degradation processes, offering practical guidance for the development of more durable artist paints and conservation strategies for acrylic artworks. Full article

Contemporary murals are highly susceptible to rapid color fading due to outdoor urban exposure. This study investigates the photodegradation mechanisms affecting synthetic organic pigments (SOPs) and commercial acrylic–vinyl paints under simulated visible light exposure. Artificial aging experiments were conducted on two types of systems: (a) pigment pellets, composed of pre-fixed pigments on mineral bases, as supplied by the manufacturer, and (b) commercial paints applied on glass substrates. Both systems were aged under controlled and uncontrolled relative humidity (RH) conditions. Colorimetric analyses revealed significant color fading, particularly in pigments PR112, PO5, and PV23. Vibrational spectroscopies highlighted the reduction in pigment-related bands after aging, indicating SOPs’ vulnerability to photodegradation. In paint mock-ups, FTIR-ATR measurements indicated binder degradation and an increase in signals from inorganic fillers. A superficial layer enriched in inorganic components was investigated non-invasively by Micro Spatially Offset Raman spectroscopy (Micro-SORS) in the beamsteer modality. It highlighted a gradient of calcite to pigment with depth. These findings indicate that color fading in mural paints results from the combined degradation of both pigments and binders. Full article

This study’s objective was to evaluate genotoxic effects on automotive paint workers who are exposed to a complex mixture of VOCs, heavy metals, and solvents. Biological samples, including blood, urine, and buccal epithelial cells, were collected from 80 exposed workers and 80 demographically matched control subjects. DNA damage was assessed using the alkaline COMET assay in lymphocytes and whole blood. The Buccal Micronucleus Cytome (BMCyt) assay was also employed to identify cytogenetic abnormalities. Additionally, trichloroacetic acid (TCA), hippuric acid (HA), phenol, and lead (Pb) levels were measured as biomarkers of exposure. A significant increase in DNA damage was observed in the lymphocytes and whole blood of exposed workers (p < 0.05) BMCyt analysis also revealed higher frequencies of micronuclei (MN), binucleated cells, condensed chromatin (CC), and karyorrhectic (KHC) and pyknotic cells (PYC) in buccal cells (p < 0.05). Elevated levels of urinary HA, phenol, TCA, and blood lead indicated systemic chemical exposure. DNA damage positively correlated with these biomarkers, supporting a strong link between chronic occupational exposure and genotoxicity. The findings from this study highlight the critical importance of implementing effective safety measures and consistent biomonitoring for paint workers to prevent adverse health effects. Full article

In our previous study, the transition behavior of a flared cone–swept fin configuration was investigated under an angle of attack (AoA) of 0°. To further explore the role of AoA in complex three-dimensional geometries with strong fin–body interactions, wind tunnel experiments were conducted at Ma = 9.3, Re = 1.36 × 10⁷/m, with AoA ranging from −6° to 6°. Global surface temperature distributions were obtained using temperature-sensitive paint (TSP), while localized heat flux and pressure fluctuations were captured using thin-film thermocouples and high-frequency pressure sensors. The results show that varying AoA shifts the location of high heat flux between the upper and lower surfaces of the flared cone and induces a switch from streamwise to separation vortices. The windward side exhibits stronger disturbance responses than the leeward side. The junction region between the flared cone and the near-horizontal surface is highly sensitive to AoA variations, consistently exhibiting pronounced second-mode instabilities. These findings provide experimental support for understanding transition mechanisms under the combined effects of shock/boundary layer interaction (SBLI), crossflow, and adverse pressure gradients, with implications for transition prediction and thermal protection system design. Full article

Chinese ancient calligraphy and paintings, as priceless cultural heritage, face dual conservation challenges: cleaning accumulated contaminants and combating microbial deterioration. Addressing these issues, this study develops a multifunctional poly(vinyl alcohol)/poly(2-hydroxyethyl acrylate) (PVA/PHEAA)-based hydrogel system, including a basic robust hydrogel, an ethylene glycol (EG)-modified antifreeze version, and a polyhexamethylene biguanide (PHMB)-composite antibacterial hydrogel. By tuning interfacial adhesion energy at the molecular level, these hydrogels enable gentle yet effective cleaning of delicate substrates such as Xuan paper, efficiently removing surface and embedded dirt without mechanical damage. Molecular dynamics simulations revealed a “capture-and-fixation” dual-mode mechanism driven by hydrogen bonding and network reconfiguration, supporting the experimental findings. The EG-modified hydrogel retains elasticity at −20 °C, allowing conservation work in cold environments. Meanwhile, the PHMB-integrated hydrogel achieves a 99.6% antibacterial rate against E. coli and S. aureus, combining cleaning and long-term antimicrobial protection. Quantitative cleaning tests (n = 3) showed the PVA/PHEAA gel removed >90% of particulates, significantly outperforming traditional methods while leaving no detectable residues. Experimental results confirm the hydrogels’ compatibility with cultural materials and their multifunctionality in Xuan paper conservation. This study introduces a novel material solution for restoring traditional Chinese calligraphy and paintings, significantly advancing the application of functional hydrogels in cultural heritage preservation. By extending the lifespan of ancient artworks through a safe, residue-free, and reversible cleaning approach, it contributes to the enduring transmission of Chinese civilization. Full article

Chromosomal instability plays a significant role in karyotype evolution and speciation in mammalian groups with notable intraspecific chromosomal variation. The Cervidae family, known for its rapid karyotypic evolution due to chromosomal fragility, shows substantial chromosomal diversity, making it a focal point for studies on chromosomal evolution, particularly with respect to conservation and taxonomic classification. The Amazon gray brocket deer (Passalites nemorivagus) exhibits pronounced chromosomal polymorphism, including two distinct sex chromosome systems: the ancestral XX/XY system and a new system due to an X–autosome fusion (neo-X), where males present XY1Y2. This variation is intriguing, especially given that the effects on hybrids have not been previously reported. This study uses bovine whole-chromosome painting (WCP) and BAC probes to document karyotypic variation in P. nemorivagus. A male with the XY system and a heterozygous autosomal Robertsonian fusion was paired with a female with neo-X chromosomes, and the resulting female offspring displayed an X–autosome fusion in heterozygosity. The females in this study, hybrids for the sex system, exhibited estrus, copulated, and both gave birth to offspring. This characterization is the first step in investigating the effects of sex chromosome system variation on hybrid viability and fertility, and provides insights into the reproductive biology of Neotropical deer. Full article

In this study, poplar boards were bleached and treated with two types of urea–formaldehyde-coated ternary system thermochromic microcapsules (UF@TS), which were mixed with UV primer. The bleached poplar boards were manually painted with two layers of primer and topcoat. Coating samples with varying microcapsule contents were prepared and evaluated based on factors such as glossiness, reflectivity, and other surface properties. The experimental results showed that bleaching treatment significantly increased the whiteness of poplar wood, with an improvement rate of up to 17%. Among the two microcapsule types, the coating containing #2 microcapsules exhibited superior surface quality compared to #1 microcapsules. As the microcapsule content increased, the coating glossiness showed an overall decreasing trend and a certain degree of fluctuation, and the #2 microcapsule showed lower reflectivity values. The addition of UF@TS microcapsules negatively affected the coating adhesion but had little effect on hardness. The #2 microcapsule enhanced the impact resistance of the coating to a certain extent and increased surface roughness. Regarding thermochromic performance, the #1 microcapsule exhibited higher color-changing temperature and larger color difference, while the #2 microcapsule showed color-changing temperature closer to room temperature. Despite a decline in thermochromic performance and glossiness during aging, the 1# microcapsule showed slightly better stability. The coating containing 10% #2 microcapsules demonstrated the best comprehensive performance on bleached poplar wood, with glossiness of 2.1 GU, reflectivity of 67.95%, adhesion grade of 1, hardness of 6 H, impact resistance grade of 4, and surface roughness of 0.681 μm. The ΔE in the range of −20 °C to 50 °C was 7.434. After aging, ΔE was 5.846, and the light loss rate was 9%, with excellent comprehensive performance. Full article

This paper presents a deep learning-based system designed for generating, storing, and retrieving embeddings, specifically tailored for analyzing craquelure networks in paintings. Craquelure, the fine pattern of the craquelure network formed on a painting’s surface over time, is a unique “fingerprint” for artwork item authentication. The system utilizes a modified VGG19 backbone, which effectively balances computational efficiency with the ability to extract rich, multi-scale features from high-resolution grayscale images. By leveraging this architecture, the model captures global structural patterns and local texture information, which are essential for reliable analysis. Full article

Contemporary muralism has gained increasing cultural and social relevance in recent years, becoming a prominent form of urban artistic expression. However, its outdoor exposure makes it highly vulnerable to environmental degradation, raising significant challenges for long-term preservation. While solar radiation is widely recognized as a main agent of deterioration, the impact of rainfall has received comparatively little attention. This study addresses this gap by evaluating the durability of commercial protective coatings applied to modern paints (alkyd, acrylic, and styrene-acrylic) under simulated rain exposure. The ageing protocol replicates approximately 10 years of cumulative rainfall in Central-Southern Europe. A key innovation of this research is the use of a custom-built rain chamber, uniquely designed to expose a large number of samples simultaneously under highly uniform and controlled rain conditions. The system ensures reproducible exposure through a precision-controlled moving platform and programmable rain delivery. A comprehensive set of analytical techniques was employed to assess morphological, chemical, and functional changes in the coatings and paints before and after ageing. Results highlight the limited performance of current protective materials and the need for more effective solutions for the conservation of contemporary outdoor artworks. Full article

This research develops a dual physics-based machine learning system to forecast fuel consumption and CO₂ emissions for a 100 m oil tanker across six operational scenarios: Original, Paint, Advanced Propeller, Fin, Bulbous Bow, and Combined. The combination of hydrodynamic calculations with Monte Carlo simulations provides a solid foundation for training machine learning models, particularly in cases where dataset restrictions are present. The XGBoost model demonstrated superior performance compared to Support Vector Regression, Gaussian Process Regression, Random Forest, and Shallow Neural Network models, achieving near-zero prediction errors that closely matched physics-based calculations. The physics-based analysis demonstrated that the Combined scenario, which combines hull coatings with bulbous bow modifications, produced the largest fuel consumption reduction (5.37% at 15 knots), followed by the Advanced Propeller scenario. The results demonstrate that user inputs (e.g., engine power: 870 kW, speed: 12.7 knots) match the Advanced Propeller scenario, followed by Paint, which indicates that advanced propellers or hull coatings would optimize efficiency. The obtained insights help ship operators modify their operational parameters and designers select essential modifications for sustainable operations. The model maintains its strength at low speeds, where fuel consumption is minimal, making it applicable to other oil tankers. The hybrid approach provides a new tool for maritime efficiency analysis, yielding interpretable results that support International Maritime Organization objectives, despite starting with a limited dataset. The model requires additional research to enhance its predictive accuracy using larger datasets and real-time data collection, which will aid in achieving global environmental stewardship. Full article

The Western genre has traditionally been associated with American identity and male-dominated narratives. However, recent decades have seen increasing attention to female protagonists, particularly the European woman as a cultural mediator within the frontier context. This study aims to identify the archetypes of the European woman in the Western genre through a diachronic and comparative analysis of the visual language found in European painting from the late 17th to early 19th centuries and in 20th–21st century cinema. The research methodology combines narrative, visual, and semiotic analysis, with a focus on intermedial and intertextual parallels between visual art and film. The study identifies nine archetypal models corresponding to goddesses of the Greek pantheon and traces their transformation across different aesthetic systems. These archetypes, rooted in artistic traditions such as Baroque, Classicism, Romanticism, and others, reappear in Western films through compositional, symbolic, and iconographic strategies, demonstrating their persistence and ability to transcend temporal, medial, and geographical boundaries. The findings suggest that the woman in the Western genre is not merely a central character, but a visual sign that activates cultural memory and engages with deep archetypal structures embedded in the collective unconscious. Full article

This article traces the historical evolution of mural painting as a medium of cultural expression from prehistoric cave art to contemporary street interventions. Adopting a diachronic and interdisciplinary approach, it investigates how muralism has developed across civilizations in relation to techniques, symbolic systems, social function, and its embeddedness in architectural and urban contexts. The analysis is structured around key historical periods using emblematic case studies to examine the interplay between materiality, iconography, and socio-political meaning. From sacred enclosures and civic monuments to post-industrial walls and digital projections, murals reflect shifting cultural paradigms and spatial dynamics. This study emphasizes how mural painting, once integrated into sacred and imperial architecture, has become a tool for public participation, protests, and urban storytelling. Particular attention is paid to the evolving relationship between wall painting and the spaces it inhabits, highlighting the transition from permanence to ephemerality and from monumentality to immediacy. This article contributes to mural studies by offering a comprehensive framework for understanding the technical and symbolic transformations of the medium while proposing new directions for research in the context of digital urbanism and cultural memory. Full article

Antifouling coatings are integral to the maritime economy. The efficacy of the applied painting system is closely correlated with susceptibility to fouling and the adhesion strength of contaminants. A fouled hull might result in an elevated fuel consumption and journey expenses. Biofouling on ship hulls also has detrimental environmental consequences due to the release of biocides during maritime travel. Therefore, it is imperative to develop eco-friendly antifouling paints that inhibit the robust adhesion of marine organisms. This study aimed to assess a biocide-free antifouling coating formulated with polymers intended to diminish molecular adhesion interactions between marine species’ adhesives and the coating. The evaluation included laboratory corrosion experiments in artificial seawater and the immersion of samples in a marine environment in Attica, Greece, for varying durations. The research indicates that an antifouling coating applied to naval steel in an artificial seawater solution improves corrosion resistance by more than 60%. The conductive polymer covering, comprising polyaniline and graphene oxide, diminishes corrosion current values, lowers the corrosion rate, and enhances corrosion potentials. The impedance parameters exhibit analogous behavior, with the coating preventing water absorption and displaying corrosion resistance. The coating serves as a low-permeability barrier, exhibiting exceptional durability for naval steel over time, with an operational performance up to 98%. Full article

A Sanskrit manuscript of the Prajñāpāramitā or Perfection of Wisdom in eight thousand verses, now in the Cambridge University Library, Add.1643, is one of the most ambitiously designed South Asian manuscripts from the eleventh century, with the highest number of painted panels known among the dated manuscripts from medieval South Asia until 1400 CE. Thanks to the unique occurrence of a caption written next to each painted panel, it is possible to identify most images in this manuscript as representing those of famous pilgrimage sites or auspicious images of specific locales. The iconographic program transforms Add.1643 into a portable device containing famous pilgrimage sites of the Buddhist world known to the makers and users of the manuscript in eleventh-century Nepal. It is one compact colorful package of a book, which can be opened and experienced in its unfolding three-dimensional space, like a virtual or imagined pilgrimage. Building on the recent research focusing on early medieval Buddhist sites across Monsoon Asia and analyzing the representational potentials and ontological values of painting, this essay demonstrates how this early eleventh-century Nepalese manuscript (Add.1643) and its visual program document and remember the knowledge of maritime travels and the transregional and intraregional activities of people and ideas moving across Monsoon Asia. Despite being made in the Kathmandu Valley with a considerable physical distance from the actual sea routes, the sites remembered in the manuscript open a possibility to connect the dots of human movement beyond the known networks and routes of “world systems”. Full article

Background: Serious videogames have already demonstrated their positive impact on rehabilitation and of particular interest is the virtual reality (VR) technology. This immersive technology has been used in this study to create a neuroaesthetic experience based on the Michelangelo effect for the rehabilitation of patients with spinal cord injury. The aim of this study was to test the usability of a system for virtual art therapy and its capacity to assess patients’ deficits performances. Methods: A VR headset was worn by the participants who experienced a painting simulation of famous artworks (artistic stimuli) against a coloring canvas (non-artistic stimuli). The trajectories of the hand were studied to obtain different kinematic and spectral parameters to evaluate the user performances. A total of 13 healthy subjects and 13 patients with spinal cord injury participated in this study. Results: Significative differences were obtained for most of the parameters between the two groups, except for the normalized jerk and energy of the spectrum. Analysis in the frequency domain showed that both groups preferred horizontal movements for painting the canvas. The NASA and USEQ scores reported a comfortable and user-friendly system according to the patients’ point of view. Conclusions: The system can be a usable tool, the rehabilitative efficacy of which should be tested in patients with spinal cord injury. The kinematic and spectral parameters would allow for the evaluation of the performances alongside the clinical scales, distinguish pathological and physiological performances. Full article