Search Results (69)

This work examines the behaviour of a spark-ignition engine using oxy-fuel combustion, coupled with an oxygen production cycle based on a mixed ionic-electronic ceramic membrane. Through 1D-0D simulations, two compression ratios are studied: the original ratio of 9.6 and the optimised CR of 20, under various load levels and altitude conditions. The results show that operational limits exist at part-load conditions, where reducing the load without implementing additional control strategies may compromise system performance. It is observed that at low loads, the intake pressure can fall below atmospheric pressure, encouraging the presence of N₂ in the combustion process. Additionally, the engine can operate efficiently up to an altitude of 4000 m, although increasing boosting is required to maintain proper membrane conditions. These findings emphasise the importance of load control and the potential need for energy assistance under certain circumstances. Full article

Oxy-fuel combustion technology is a critical pathway for carbon capture in the cement industry. However, the high-concentration CO₂ atmosphere significantly alters multiphysics coupling in the calciner and systematic studies on its comprehensive effects remain limited. To address this, a Computational Particle Fluid Dynamics (CPFD) model using the MP-PIC method was implemented using the commercial software Barracuda Virtual Reactor 22.1.2 to simulate an industrial-scale oxy-fuel cement calciner and validated against industrial data. Under oxy-fuel combustion with 50% oxygen concentration in the tertiary air, simulations showed a 38.4% increase in the solid–gas mass ratio compared to conventional air combustion, resulting in a corresponding 37.7% increase in total pressure drop. Flow resistance was concentrated primarily in the constriction structures. Local temperatures exceeded 1200 °C in high-oxygen regions. The study reveals a competition between the inhibitory effect of high CO₂ partial pressure on limestone decomposition and the promoting effect of elevated overall temperature. Although the CO₂-rich atmosphere thermodynamically suppresses calcination, the higher operating temperature under oxy-fuel combustion effectively compensates, achieving a raw meal decomposition rate of 92.7%, which meets kiln feed requirements. This research elucidates the complex coupling mechanisms among flow, temperature, and reactions in a full-scale oxy-fuel calciner, providing valuable insights for technology design and optimization. Full article

Carbon dioxide (CO₂) is the most significant anthropogenic greenhouse gas (GHG), accounting for approximately 81% of total emissions, with methane (CH₄), nitrous oxide (N₂O), and fluorinated gases contributing the remainder. Rising atmospheric CO₂ concentrations, driven primarily by fossil fuel combustion, industrial processes, and transportation, have surpassed the Earth’s natural sequestration capacity, intensifying climate change impacts. Carbon Capture, Utilization, and Storage (CCUS) offers a portfolio of solutions to mitigate these emissions, encompassing pre-combustion, post-combustion, oxy-fuel combustion, and direct air capture (DAC) technologies. This review synthesizes advancements in CO₂ capture materials including liquid absorbents (amines, amino acids, ionic liquids, hydroxides/carbonates), solid adsorbents (metal–organic frameworks, zeolites, carbon-based materials, metal oxides), hybrid sorbents, and emerging hydrogel-based systems and their integration with utilization and storage routes. Special emphasis is given to CO₂ mineralization using mine tailings, steel slag, fly ash, and bauxite residue, as well as biological mineralization employing carbonic anhydrase (CA) immobilized in hydrogels. The techno-economic performance of these pathways is compared, highlighting that while high-capacity sorbents offer scalability, hydrogels and biomineralization excel in low-temperature regeneration and integration with waste valorization. Challenges remain in cost reduction, material stability under industrial flue gas conditions, and integration with renewable energy systems. The review concludes that hybrid, cross-technology CCUS configurations combining complementary capture, utilization, and storage strategies will be essential to meeting 2030 and 2050 climate targets. Full article

Legal requirements are increasingly promoting the thermal treatment of sewage sludge in Germany, and alternative disposal methods are being investigated. Oxyfuel combustion is one promising thermal process for treating sewage sludge. However, the flue gas produced during the combustion process contains high levels of CO₂, a greenhouse gas that poses environmental harm. To address this issue, this study analyzed oxyfuel combustion and various CO₂ capture methods, aiming to utilize CO₂ as a feedstock for methanol production. Energy and material balance simulations were carried out using Aspen Plus. Four distinct carbon capture methods: membrane carbon capture, cryogenic carbon capture, monoethanolamine carbon capture, and ionic liquid carbon capture were modeled. Three different oxygen configurations were tested: pure air, pure oxygen, and a 50/50 air–oxygen mixture. The oxygen separation systems, including air separation units and alkaline electrolyzers, were also studied and modeled. As a result, 14 different scenarios were created. The performances, energy efficiency, and economic results of each scenario were compared to one another and to existing literature, allowing for the identification of the most effective approaches. The oxyfuel combustion scenarios achieved the highest methanol output. MEA and ionic liquid capture combined with air combustion proved to be the most cost-effective options, while cryogenic capture incurred the highest costs due to its helium-based cooling requirements. Although ASU-based oxyfuel combustion achieved the lowest specific energy requirement for methanol production, electrolysis-integrated configurations remained economically disadvantageous, underscoring the critical influence of electricity prices on the overall feasibility of the system. Full article

Carbon dioxide (CO₂), the primary anthropogenic greenhouse gas, drives significant and potentially irreversible impacts on ecosystems, biodiversity, and human health. Achieving the Paris Agreement target of limiting global warming to well below 2 °C, ideally 1.5 °C, requires rapid and substantial global emission reductions. While recent decades have seen advances in clean energy technologies, carbon capture, utilization, and storage (CCUS) remain essential for deep decarbonization. Despite proven technical readiness, large-scale carbon capture and storage (CCS) deployment has lagged initial targets. This review evaluates CCS technologies and their contributions to net-zero objectives, with emphasis on sector-specific applications. We found that, in the iron and steel industry, post-combustion CCS and oxy-combustion demonstrate potential to achieve the highest CO₂ capture efficiencies, whereas cement decarbonization is best supported by oxy-fuel combustion, calcium looping, and emerging direct capture methods. For petrochemical and refining operations, oxy-combustion, post-combustion, and chemical looping offer effective process integration and energy efficiency gains. Direct air capture (DAC) stands out for its siting flexibility, low land-use conflict, and ability to remove atmospheric CO₂, but it’s hindered by high costs (~$100–1000/t CO₂). Conversely, post-combustion capture is more cost-effective (~$47–76/t CO₂) and compatible with existing infrastructure. CCUS could deliver ~8% of required emission reductions for net-zero by 2050, equivalent to ~6 Gt CO₂ annually. Scaling deployment will require overcoming challenges through material innovations aided by artificial intelligence (AI) and machine learning, improving capture efficiency, integrating CCS with renewable hybrid systems, and establishing strong, coordinated policy frameworks. Full article

The decarbonization of hard-to-defossilize sectors, such as international maritime transport, requires innovative, and at times disruptive, energy solutions that combine efficiency, scalability, and climate benefits. Therefore, power-to-liquid (PtL) routes have stood out for their potential to use low-emission electricity for the production of synthetic fuels, via electrolytic hydrogen and CO₂ capture. However, the high energy demand inherent to these routes poses significant challenges to large-scale implementation. Moreover, PtL routes are usually at most neutral in terms of CO₂ emissions. This study evaluates, from a thermo-energetic perspective, the optimization potential of an e-methanol synthesis route through integration with a biomass oxy-fuel combustion process, making use of electrolytic oxygen as the oxidizing agent and the captured CO₂ as the carbon source. From the standpoint of a first-law thermodynamic analysis, mass and energy balances were developed considering the full oxygen supply for oxy-fuel combustion to be met through alkaline electrolysis, thus eliminating the energy penalty associated with conventional oxygen production via air separation units. The balance closure was based on a small-scale plant with a capacity of around 100 kta of methanol. In this integrated configuration, additional CO₂ surpluses beyond methanol synthesis demand can be directed to geological storage, which, when combined with bioenergy with carbon capture and storage (BECCS) strategies, may lead to net negative CO₂ emissions. The results demonstrate that electrolytic oxygen valorization is a promising pathway to enhance the efficiency and climate performance of PtL processes. Full article

This study presents a comprehensive performance assessment of combustion-based options for Bioenergy with Carbon Capture and Storage (BECCS), widely regarded as key enablers of future climate neutrality. From 972 publications (2000–2025), 16 sources are identified as providing complete data. Seven technologies are considered: Calcium Looping (CaL), Chemical Looping Combustion (CLC), Hot Potassium Carbonate (HPC), low-temperature solvents (mainly amine-based), molten sorbents, Molten Carbonate Fuel Cells (MCFCs), and oxyfuel. First- and second-law efficiencies are reported for 53 bioenergy configurations (19 reference plants without carbon capture and 34 BECCS systems). Performance is primarily evaluated via the reduction in second-law (exergy) efficiency and the Specific Primary Energy Consumption per CO₂ Avoided (SPECCA), both relative to each configuration’s reference plant. MCFC-based systems perform best, followed by CLC; molten sorbents and oxyfuel also show very good performance, although each is documented by a single source. Low-temperature solvents span a wide performance range—from poor to competitive—highlighting the heterogeneity of this category; HPC performs in line with the average of low-temperature solvents. CaL exhibits modest efficiency penalties alongside appreciable energy costs of CO₂ capture, a counterintuitive outcome driven by the high performance of the benchmark plants considered in the definition of SPECCA. To account for BECCS-specific features (multiple outputs and peculiar fuels), a dedicated evaluation framework with a revised SPECCA formulation is introduced. Full article

Fuel combustion is a crucial process in energy utilization. As a key bulk transport mechanism, Stefan flow significantly affects heat and mass transfer during char combustion. However, its physical nature and engineering implications have long been underestimated, and no systematic review has been conducted. This paper presents a comprehensive review of Stefan flow in char combustion, with a focus on its impact on mass transfer and combustion behavior under both air-fuel and oxy-fuel conditions. It also highlights the critical role of Stefan flow in enhancing energy conversion efficiency and optimizing carbon capture processes. The analysis reveals that Stefan flow has been widely neglected in traditional combustion models, resulting in significant errors in calculated mass transfer coefficients (up to 21% in air-fuel combustion and as high as 74% in oxy-fuel combustion). This long-overlooked deviation severely compromises the accuracy of combustion efficiency predictions and model reliability. In oxy-fuel combustion, the gasification reaction (C + CO₂ = 2CO) induces a much stronger outward Stefan flow, reducing CO₂ transport by up to 74%, weakening local CO₂ enrichment, and substantially increasing the energy cost of carbon capture. In contrast, the oxidation reaction (2C + O₂ = 2CO) results in only an 18% reduction in O₂ transport. Stefan flow hinders the inward mass transfer of O₂ and CO₂ toward the char surface and increases heat loss during combustion, resulting in reduced reaction rates and lower particle temperatures. These effects contribute to incomplete fuel conversion and diminished thermal efficiency. Simulation studies that neglect Stefan flow produce significant errors when predicting combustion characteristics, particularly under oxy-fuel conditions. The impact of Stefan flow on energy balance is more substantial in the kinetic/diffusion-controlled regime than in the diffusion-controlled regime. This review is the first to clearly identify Stefan flow as the fundamental physical mechanism responsible for the differences in combustion behavior between air-fuel and oxy-fuel environments. It addresses a key gap in current research and offers a novel theoretical framework for improving low-carbon combustion models, providing important theoretical support for efficient combustion and clean energy conversion. Full article

Driven by the “dual carbon” goal, virtual power plants (VPPs) are the core vehicle for integrating distributed energy resources, but the multiple uncertainties in wind power, electricity/heat load, and electricity price, coupled with the impact of carbon-trading cost, make it difficult for traditional scheduling methods to balance the robustness and economy of VPPs. Therefore, this paper proposes an oxy-fuel combustion capture (OCC)-VPP architecture, integrating an OCC unit to improve the energy efficiency of the system through the “electricity-oxygen-carbon” cycle. Ten typical scenarios are generated by Latin hypercube sampling and K-means clustering to describe the uncertainties of source and load probability distribution, combined with the polyhedral uncertainty set to delineate the boundary of source and load fluctuations, and the stepped carbon-trading mechanism is introduced to quantify the cost of carbon emission. Then, a three-stage stochastic–robust scheduling model is constructed. The simulation based on the arithmetic example of OCC-VPP in North China shows that (1) OCC-VPP significantly improves the economy through the synergy of electric–hydrogen production and methanation (52% of hydrogen is supplied with heat and 41% is methanated), and the cost of carbon sequestration increases with the prediction error, but the carbon benefit of stepped carbon trading is stabilized at the base price of 320 DKK/ton; (2) when the uncertainty is increased from 0 to 18, the total cost rises by 45%, and the cost of purchased gas increases by the largest amount, and the cost of energy abandonment increases only by 299.6 DKK, which highlights the smoothing effect of energy storage; (3) the proposed model improves the solution speed by 70% compared with stochastic optimization, and reduces cost by 4.0% compared with robust optimization, which balances economy and robustness efficiently. Full article

Carbon capture technologies are largely considered to play a crucial role in meeting the climate change and global warming target set by Net Zero Emission (NZE) 2050. These technologies can contribute to clean energy transitions and emissions reduction by decarbonizing the power sector and other CO₂ intensive industries such as iron and steel production, natural gas processing oil refining and cement production where there is no obvious alternative to carbon capture technologies. While the progress of carbon capture technologies has fallen behind expectations in the past, in recent years there has been substantial growth in this area, with over 700 projects at various stages of development. Moreover, there are around 45 commercial carbon capture facilities already in operation around the world in different industrial processes, fuel transformation and power generation. Carbon capture technologies including pre/post-combustion, oxyfuel and chemical looping combustion have been widely exploited in the recent years at different Technology Readiness level (TRL). Although, a large number of review studies are available addressing different carbon capture strategies, however, studies related to the commercial status of the carbon capture technologies are yet to be conducted. In this review article, we summarize the state-of-the-art of different carbon capture technologies applied to different emission sources, focusing on emission reduction, net-zero emission, and negative emission. We also highlight the commercial status of the different carbon capture technologies including economics, opportunities, and challenges. Full article

To reduce carbon emission levels and improve the low-carbon performance and economic efficiency of Integrated Energy Systems (IESs), this paper introduces oxy-fuel combustion technology to transform traditional units and proposes a low-carbon economic dispatch method. Considering the stepwise carbon trading mechanism, it provides new ideas for promoting energy conservation, emission reduction, and economic operation of integrated energy systems from both technical and policy perspectives. Firstly, the basic principles and energy flow characteristics of oxy-fuel combustion technology are studied, and a model including an air separation unit, an oxygen storage tank, and carbon capture equipment is constructed. Secondly, a two-stage power-to-gas (P2G) model is established to build a joint operation framework for oxy-fuel combustion and P2G. On this basis, a stepwise carbon trading mechanism is introduced to further constrain the carbon emissions of the system, and a low-carbon economic dispatch model with the objective of minimizing the total system operation cost is established. Finally, multiple scenarios are set up for simulation analysis, which verifies that the proposed low-carbon economic optimal dispatch strategy can effectively reduce the system operation cost by approximately 21.4% and improve the system’s carbon emission level with a total carbon emission reduction of about 38.3%. Meanwhile, the introduction of the stepwise carbon trading mechanism reduces the total cost by 12.3% and carbon emissions by 2010.19 tons, increasing the carbon trading revenue. Full article

The combustion of ammonia with oxygen presents a promising pathway for global energy transformation using carbon dioxide-neutral energy solutions and carbon capture. Ammonia, a carbon-free fuel, offers several benefits, owing to its non-explosive nature, high octane rating, and ease of storage and distribution. However, challenges such as low flammability and excessive nitrogen oxide (NO_x) emissions must be addressed. This paper explores the recent advances in ammonia oxy-combustion and highlights recent experimental and numerical research on NO_x emission traits, combustion, and flame propagation across various applications, including gas furnaces, internal combustion engines, and boilers. Furthermore, this review discusses the diverse approaches to overcoming the challenges of ammonia combustion, including oxygen enrichment, fuel blending, plasma assistance, preheating, multiple injections, and burner design modifications. By summarizing the advancements in ammonia oxy-combustion investigation, this paper aims to provide valuable insights that can serve as reference information for prospective ammonia oxy-combustion research and applications toward the transition to sustainable energy. Full article

This paper provides a comprehensive review of the integration of carbon capture, utilization, and storage (CCUS) technologies in waste-to-energy (WtE) plants, specifically focusing on incineration, the most adopted process for managing residual waste fractions that cannot be recycled. The review examines the current CO₂ capture technologies, including the widely used monoethanolamine (MEA) absorption method, and explores emerging alternatives such as molten carbonate fuel cells and oxyfuel combustion. Additionally, the paper discusses the management options for the captured CO₂, exploring both storage (CCS) and utilization (CCU) options, with a focus on current storage projects involving CO₂ from WtE plants and the potential for its use in sectors like chemicals, construction materials, and synthetic fuels. Currently, only four large-scale WtE plants worldwide have successfully implemented carbon capture technologies, with a combined capacity of approximately 78,000 tons of CO₂ per year. However, numerous feasibility studies and pilot-scale projects are ongoing, particularly in northern Europe, with countries such as Norway, the Netherlands, Sweden, the United Kingdom, and Finland leading the way in the development of CO₂ capture, storage, and utilization strategies within the WtE sector. The paper further discusses techno-economic issues for CCUS implementation, including energy demands and associated costs. The use of MEA systems in WtE plants leads to significant energy penalties, reducing plant efficiency by up to 40%. However, alternative technologies, such as advanced amines and calcium looping, could provide more cost-effective solutions by improving energy efficiency and reducing the overall costs. Life cycle assessment studies indicate that CCUS has the potential to significantly reduce CO₂ emissions, but the achievable environmental benefits depend on factors such as energy consumption, process efficiency, and system integration. Overall, while the implementation of CCUS in WtE plants presents CO₂ mitigation potential and may also be exploited to achieve other benefits, energy requirements and economic viability remain challenging. Full article

With the consequences of climate change becoming more urgent, there has never been a more pressing need for technologies that can help to reduce the carbon dioxide (CO₂) emissions of the most polluting sectors, such as power generation, steel, cement, and the chemical industry. This review summarizes the state-of-the-art technologies for carbon capture, for instance, post-combustion, pre-combustion, oxy-fuel combustion, chemical looping, and direct air capture. Moreover, already established carbon capture technologies, such as absorption, adsorption, and membrane-based separation, and emerging technologies like calcium looping or cryogenic separation are presented. Beyond carbon capture technologies, this review also discusses how captured CO₂ can be securely stored (CCS) physically in deep saline aquifers or depleted gas and oil reservoirs, stored chemically via mineralization, or used in enhanced oil recovery. The concept of utilizing the captured CO₂ (CCU) for producing value-added products, including formic acid, methanol, urea, or methane, towards a circular carbon economy will also be shortly discussed. Real-life applications, e.g., already pilot-scale continuous methane (CH₄) production from flue gas CO₂, are shown. Actual deployment of the most crucial technologies for the future will be explored in real-life applications. This review aims to provide a compact view of the most crucial technologies that should be considered when choosing to capture, store, or convert CO₂, informing future researchers with efforts aimed at mitigating CO₂ emissions and tackling the climate crisis. Full article

Energy shortage and greenhouse gas emission have become bottlenecks in current society development. Improving the efficiency of energy conversion and utilization systems through waste heat recovery and reduction of greenhouse gas through CO₂ capture/conversion are important solutions. Both can be achieved simultaneously by utilizing high-temperature flue gas or CO₂ in flue gas for organic matter gasification, which is called the flue gas chemical recuperative cycle. This paper provides a meaningful review of the latest advancements in the flue gas chemical recuperative cycle system, focusing on its application in diverse gasification systems for organic matters such as methane, sludge, etc. Additionally, this paper reviews methods for the integration of flue gas gasification into energy conversion and utilization systems under the application scenarios of gas turbine flue gas, air combustion flue gas, and oxy-fuel combustion flue gas. Subsequently, in order to improve the conversion efficiency of the chemical recuperative cycle, the applications of emerging gasification technologies in the field of the flue gas recuperative cycle, such as microwave gasification, plasma gasification, etc., are briefly summarized, offering an in-depth analysis of the mechanisms by which new methods enhance the process. Finally, the prospects and challenges of the field are discussed, and a comprehensive outlook is provided to guide future research. Full article