Search Results (119)

This study presents an experimental evaluation of the bioenergy potential of Enterolobium cyclocarpum (“orejero”) fruit peel residue, an underutilized agroforestry by-product in tropical America. Although the species is widely used for shade and fodder in livestock systems, its fruit peel has not yet been characterized for energy recovery purposes. Fruit samples were collected in rural areas of Tesalia (Huila, Colombia), and the peel fraction was analyzed in certified laboratories. The moisture content of the peel was determined as 11 wt%, and the lower heating value was measured as 0.015 TJ/t following ASTM E711-06. Elemental analysis according to ASTM D5373-16 yielded (dry basis): 37.2 wt% C, 4.09 wt% H, 0.45 wt% N and 0.13 wt% S. Based on Colombian cultivation and production data, the theoretical energy potential was estimated as 3.6 TJ/year per hectare. The technical energy potential reached 0.18 and 0.21 TJ/year per hectare for combustion and gasification, respectively. CO₂-equivalent emissions were also estimated for both conversion routes, revealing a trade-off between the higher energy yield and higher specific emissions associated with gasification. Overall, the results show that E. cyclocarpum fruit peel residue has a calorific value comparable to widely used agri-food residues in Colombia (e.g., sugarcane bagasse and oil palm fiber), but with a substantially higher per-hectare energy potential due to its large residue fraction. Its high availability, favorable fuel properties, and compatibility with decentralized combustion and gasification technologies support its use as a promising feedstock for bioenergy generation in rural or off-grid areas, in line with circular economy and sustainable energy transition strategies. Full article

Wood polymer composite (WPC), composed of polymer matrices reinforced with natural fibers, is increasingly used in structural and non-structural applications due to its sustainability and performance. Although teak and rice husk are common natural reinforcements, the use of oil palm empty fruit bunches (OPEFB) remains underexplored despite their abundance as agricultural waste. This study investigates the potential of OPEFB as an alternative reinforcement for recycled polyethylene-based WPC containing 20 wt% fiber and compares its morphology and performance with teak and rice husk. Compositional analysis shows that OPEFB exhibits lignin and cellulose contents as well as crystallinity comparable to teak, while exceeding rice husk in several structural parameters. These characteristics contribute to the highest tensile strength observed among the composites (37.45 MPa). Although its Shore D hardness is the lowest (58.8), the value remains within the acceptable range for construction applications. Combined with its favorable production costs, OPEFB emerges as a viable, resource-efficient alternative to conventional natural fibers, expanding the options for sustainable WPC development. Full article

Lipases (EC 3.1.1.3) catalyze the hydrolysis of triacylglycerols into mono- and diacylglycerols and free fatty acids. This study investigated the production of lipase by Hypocrea pseudokoningii under solid-state fermentation (SSF), followed by its immobilization, purification, and biochemical characterization. Maximum activity was achieved using wheat fiber after 168 h of cultivation. Supplementation with oils enhanced production, particularly palm oil (315U; 1.58-fold increase) and soybean oil (Glycine max) (298U; 1.49-fold increase). The addition of micronutrients further improved yields, with Khanna (445U) and Vogel (400U) salts promoting more than a two-fold increase in activity. Immobilization on Octyl-Sepharose significantly altered the enzyme’s properties. The free lipase exhibited optimal activity at 45 °C and pH 4.5–5.5, while the immobilized enzyme showed maximum activity at 35–40 °C and pH 5.5. Thermal stability was notable enhanced: the free lipase had a half-life of 10 min at 50 °C, whereas the immobilized enzyme remained stable for 60 min and retained over 30% activity at 70 °C. Both the free and immobilized forms were stable across a broad pH range (4.0–10.0), maintaining more than 70% residual activity. The enzyme was stabilized by Tween 80 but inhibited by SDS. It was activated by Ca²⁺ and showed resistance to Pb²⁺, Zn²⁺, and Cu²⁺. Hydrolytic assays revealed murumuru (Astrocaryum murumuru), cupuaçu (Theobroma grandiflorum), and soybean oils as preferred substrates. TLC confirmed the formation of mono- and diglycerides, as well as the presence of fatty acids. Full article

A palm oil company based in Bangka is actively expanding its operations in the palm oil processing industry. The company specializes in producing crude palm oil (CPO) and palm kernel, with its production process encompassing five key stages: weighing, sterilization, threshing, pressing, and clarification. Oil loss, especially at the pressing station, is one of the company’s biggest problems. Nuts, fibers, empty bunches, and effluent are some of the sources of oil loss in CPO production. Since extreme losses that exceed set norms can cause serious inefficiencies and financial repercussions, it is imperative that the organization identifies and mitigates the underlying causes of oil loss. One option that the business could use is the fault tree analysis (FTA) method, which offers a methodical way to pinpoint the root causes of production inefficiencies to solve this problem. According to current assessments, empty bunches caused the largest average oil loss over a one-month period, with a loss rate of 0.11%. Oil loss at the pressing station is caused by a number of factors, such as inadequate maintenance practices, non-compliance with established work procedures, suboptimal ripeness levels of harvested palm fruit, and operator neglect in maintaining optimal machine pressure in accordance with company standards. To reduce oil loss in the production process and increase efficiency, these concerns need to be addressed. Full article

Palm oil production generates substantial underutilized biomass wastes, including empty fruit bunches, fiber, palm kernel shells, and palm oil mill effluent (POME). Waste-to-energy systems offer a viable pathway to convert these residues into electricity and fertilizer, supporting circular economy goals and sustainability targets. This study takes an example of palm oil waste from the Indragiri Hulu region in Riau Province in Indonesia. It develops a multi-objective optimization framework to evaluate palm oil mill WtE systems from economic, environmental, and energy output. Three scenarios are analyzed: maximal profit (MP), maximal profit with carbon tax (MPCT), and all waste processing (AWP). The MP scenario favors high-return technologies such as gasification and incineration, leading to significant greenhouse gas emissions. The MPCT scenario favors lower-emission technologies like composting and excludes high-emission, low-profit options such as POME digestion. In contrast, the AWP scenario mandates the processing of all wastes, leading to the lowest profits and the highest emissions among all scenarios. The sensitivity analysis reveals that POME processing is not feasible when electricity prices are below the government-set rate, but becomes viable once prices exceed this threshold. These findings offer valuable insights for companies and policymakers seeking to develop and implement effective strategies for optimal waste utilization. Full article

This work presents an effective design of a strategy to manage biomass waste (empty fruit bunch—EFB, kernel shell, and fiber) available from the processing of oil palm (Elaeis guineensis) in Colombia as a renewable energy source. This type of study is conducted for the first time in the country, and the proposed strategy is structured in four phases. Firstly, an inventory of available biomass waste was prepared based on information from 45 African palm oil companies of the approximately 70 that exist in the country. It was determined that the country had about 2762 kt of available waste (63.64% EFB, 12.55% kernel shell, and 23.81% fiber) for the year 2023. The estimates were conducted using a model that correlates processing capacity, the biomass generated, and the biomass demanded. The validation was performed using national reports. Subsequently, the minimum number (six) of storage centers in Colombia, where the largest amount of biomass can be stored, was determined. The center of gravity method was used to find the geographical location of each bulk storage center (municipality of Aracataca, Agustín Codazzi, San Martín, Puerto Wilches, Castilla La Nueva, and Cabuyaru). The next step was to determine the transportation costs as a decision criterion to select the best bulk storage center. When the required storage capacity does not exceed 211 kt·year⁻¹, Agustín Codazzi is the best option because it has the lowest transportation cost (USD 1.01·t⁻¹). When the storage capacity requirements exceed 211 kt·year⁻¹ but are less than 423 kt·year⁻¹, then Puerto Wilches and/or Aracataca are the best options (transportation cost of USD 1.7·t⁻¹). In all cases, Cabuyaru has the highest costs (USD 6.56·t⁻¹). Finally, an energy potential of 50,196 × 10⁶ GJ·year⁻¹ for the collected biomass was estimated, which makes this kind of waste an environmental alternative that could replace coal in Colombia. Full article

This study aims to optimize the bioconversion of palm kernel cake (PKC) by Pleurotus ostreatus to improve fungal biomass production, lignocellulolytic enzyme expression, and the nutritional value of the substrate as ruminant feed. Three inorganic nitrogen sources (ammonium sulfate, ammonium nitrate, and urea) were evaluated for fungal biomass production using a central composite design (CCD) in liquid fermentations. The formulated culture medium (18.72 g/L glucose and 0.39 g/L urea) effectively yielded better fungal biomass production (8 g/L). Based on these results, an extreme vertex design, mixtures with oil palm by-products (PK, hull, and fiber) supplemented with urea, were formulated, finding that PKC stimulated the highest biomass production and laccase enzyme activity in P. ostreatus. The transcriptome of P. ostreatus was obtained, and the chemical composition of the fermented PKC was determined. Transcriptomic analysis revealed the frequency of five key domains with carbohydrate-activated enzyme (CAZy) function: GH3, GH18, CBM1, AA1, and AA5, with activities on lignocellulose. In the fermented PKC, lignin was reduced by 46.9%, and protein was increased by 69.8%. In conclusion, these results show that urea is efficient in the bioconversion of PKC with P. ostreatus as a supplement for ruminants. Full article

Palm oil mill effluent (POME) is a major contributor to industrial oily wastewater in Malaysia, demanding effective treatment solutions. This study explores the potential of esterified kenaf core (EKC) fiber as an oil adsorbent for oil removal from POME, optimized using a full central composite design (CCD) within the response surface methodology (RSM) framework. The optimum conditions achieved 76% oil removal efficiency, with a 1:0.5 ratio of mercerized kenaf core to stearic acid (MKC:SA), 15 wt% of catalyst, and 1 h reflux time during the esterification process. The regression model exhibited strong predictive capability, with a significant quadratic correlation and an R² value of 0.94. The Fourier transform infrared (FTIR) spectroscopy revealed the existence of ester functional groups characterized by significant hydrophobicity and a decrease in hydroxyl groups, indicating the chemical changes of EKC. Moreover, the scanning electron microscopy (SEM) research demonstrated structural alterations in EKC, including heightened surface roughness, fibrillation, and pore development, which improved oil adhesion relative to raw kenaf core (RKC). These findings indicate that EKC provides an effective, environmentally sustainable solution for managing oil wastewater issues in the palm oil sector, facilitating enhanced ecological sustainability and resource management. Full article

Oryctes monoceros (Olivier, 1789) (Scarabaeidae) and Rhynchophorus phoenicis (Fabricius, 1801) (Curculionidae) are two insects generally known as formidable pests of oil palms and coconuts trees. Although little known, different developmental stages of these insects are consumed. The aim of this study is to determine the composition of these adult Coleopteran species in order to promote their consumption as a strategy for enhancing food security. Chemical analyses were carried out on adults of both species. Samples of O. monoceros and R. phoenicis were collected in three localities in Togo. The ash, protein, vitamin, and lipid contents were determined according to the AOAC reference methods. The fiber contents were obtained by the method of Weende. The minerals and heavy metals were analyzed by atomic absorption spectrophotometry and colorimetry. Fatty acid composition was determined by gas chromatography. The results showed the average protein content ranges from 44.32 ± 0.83 to 45.89 ± 0.83%. The lipid level is between 15.06 ± 0.28% and 14.64 ± 0.54. Their lipids contain unsaturated fatty acids, notably oleic (40.84 ± 0.112 vs. 40.84 ± 0.11%), linoleic (4.49 ± 0.00 vs. 5.07 ± 0.02%), and α-linolenic (5.07 ± 0.02 vs. 6.35 ± 0.01%) acid. They are excellent sources of minerals and vitamins. They are also free of heavy metals. These species could, therefore, contribute to the nutritional balance of consumers. They deserve to be better promoted for human consumption, as they could make a significant contribution to the fight against malnutrition and constitute a novel food source. Full article

Biomass, though a major energy source, remains underutilized. Biochar from biomass pyrolysis, with its high porosity and surface area, is especially useful as catalyst support, enhancing catalytic activity and reducing electron recombination in photocatalysis. Indonesia, the world’s top palm oil producer, generated around 12 million tons of empty fruit bunches (EFBs) in 2023, making EFBs a promising biochar source. This study synthesizes biochar from leftover EFB fibers at 500, 800, and 1000 °C, analyzing structural changes via infrared and Raman spectroscopy, along with particle size and surface area analysis, laying the groundwork for future biochar research. The smallest particle size and highest surface area gained was 71.1 nm and 10.6 × 10² m²/g. Spectroscopic analysis indicates that biochar produced at 1000 °C has produced nano-crystalline graphite with a crystallite size of approximately 5.47 nm. This provides higher defect density, although with lower conductivity. Other studies indicate that our biochar can be used as catalyst support for various green energy-related applications, i.e., counter electrodes, electrocatalysts, and photocatalysts. Full article

This study investigates the potential of sequential solid-state and submerged fermentation (SeqF) to enhance lipase production by Yarrowia lipolytica using by-products from the palm oil production chain. Palm fiber and palm oil deodorizer distillate (PODD) were utilized as substrates in both fermentation stages. Solid-state fermentation (SSF) yielded significant lipase activity when palm fiber was used alone (1.55 U/g in 48 h), while submerged fermentation (SmF) showed improved enzymatic production with the combination of fiber and PODD (1171 U/L in 72 h). The integration of SSF and SmF in SeqF achieved superior lipase activities, reaching 4464.5 U/L, an 8.3-fold increase compared to SmF alone, in Erlenmeyer flasks. SeqF-lyophilized biocatalysts from Erlenmeyer experiments showed better hydrolytic activity (131 U/g) when the best conditions were reproduced in a 4 L bioreactor (33 U/g). The SeqF-lyophilized biocatalyst was employed in esterification reactions to synthesize mono- and diacylglycerols, achieving a 24.3% conversion rate. The study highlights SeqF as a promising and sustainable approach for valorizing agro-industrial residues, contributing to biocatalyst production and advancing circular bioeconomy initiatives. Full article

Due to its poor hydration properties, oil palm kernel expeller dietary fiber (OPKEDF) is rarely used in the food industry, especially in hydrogels, despite its advantages of high availability and low cost. To address this situation, the effects of enzymolysis combined with hydroxypropylation or crosslinking on the structure and hydration properties of OPKEDF were investigated, and the impact of these modified OPKEDFs on the properties of egg white protein gel (EWPG) was studied. Enzymolysis combined with hydroxypropylation or phosphate crosslinking improved the soluble fiber content (5.25–7.79 g/100 g), water-retention and expansion abilities of OPKEDF (p < 0.05). The addition of unmodified OPKEDF or modified OPKEDF increased the random coil content of EWPG and increased the density of its microstructure. Moreover, enzymolysis combined with hydroxypropylation or crosslinking enhanced the effect of OPKEDF on the properties of EWPG, including improvements in its water-retention ability, pH, hardness (from 97.96 to 195.00 g), chewiness (from 78.65 to 147.39 g), and gumminess (from 84.63 to 152.27) and a reduction in its transparency (p < 0.05). Additionally, OPKEDF and enzymolysis and hydroxypropylated OPKEDF increased the resilience (0.297 to 0.359), but OPKEDF treated via enzymolysis and crosslinking reduced it. Therefore, OPKEDF modified by means of enzymolysis in combination with hydroxypropylation or crosslinking improved the gel properties of EWPG. However, further work is required to determine the effects of these modifications on the nutritional profile, scalability, and economic feasibility of OPKEDF and egg white gel. Full article

The global challenge of oil spill treatment has been addressed using nanocomposite-based natural fibers. These materials offer great potential in oil spill cleanup and are considered due to their environmental friendliness, high efficiency, and low cost. Thus, the current study reports a novel composite fabricated from date palm fiber (DPF) and recycled polyethylene terephthalate (rPET) with a proper combination of a mixture of carbon nanotubes (CNTs) and graphene nanosheets (GNSs) for oil removal. The established nanocomposite (DPF-rPET/CNT/GNS) was fabricated via physical mixing of various quantities (0.9, 0.8, and 0.7 g) of PET, along with varying loads of DPF at different proportions of CNT:GNS. The prepared nanocomposite (DPF-rPET/CNT/GNS) was fully characterized using scanning electron microscopy–energy dispersive X-ray (SEM-EDX) analysis, transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FTIR), and Brunauer–Emmett–Teller (BET) analysis. In static experiments and under the optimal parameters of pH, sorbent doze, shaking time, and quantity of diesel oil), the established sorbent (DPF-rPET/CNT-GNS nanocomposite) displayed excellent adsorption capacity (98 mg/g). This study also expands the utility of the sorbent for the reusability of the oil adsorption, maintaining performance after five cycles. The adsorption data fitted well with the Langmuir isotherm model with a correlation coefficient (R²) of 0.99 and maximum adsorption capacity of 99.7 mg/g, indicating monolayer adsorption. Additionally, the adsorption kinetics followed a pseudo-second-order model, with an R² near unity and an adsorption capacity of 99.09 mg/g. This study highlights the promising potential of the DPF-rPET/CNT-GNS composite as an effective adsorbent for treating oily water. Full article

Including dietary fat can increase the energy density of diets fed to ruminants, reducing dry matter intake (DMI). Effects of different fat sources on nutrient digestion and fermentation can vary depending on dietary fat concentration and the forage-to-concentrate ratio (F:C). Therefore, this study’s objective was to screen the effects of fat sources supplemented at different concentrations to high- and low-forage diets on in vitro digestibility and fermentation. Treatments included either low forage (LF; 35%) or high forage (HF; 70%) with two fat levels (6 or 9% DM) using six different fat sources, plus control. The control diet (CON) had a basal level of fat in the diet (3% fat; 0% fat inclusion), and fat sources were added to attain 6% or 9% dietary fat and consisted of the following: Coconut oil, CO; Poultry fat, PF; Palm oil, PO; Palm kernel oil, PKO; Soybean oil, SOY; and Ca Salts, MEG. In vitro Gas Production (GP) modules were randomly assigned to treatments in a 2 × 2 × 7 factorial design and were incubated for four 24 h runs. The CO-fed module had the highest dry matter (DM) apparent digestibility (AD) (p < 0.01), followed by SOY and PF. The true DM digestibility (TDMD) and organic matter (OM) AD were the highest in CO (p < 0.01) than the other fat types. The AD for DM, OM, neutral detergent fiber (NDF), and acid detergent fiber (ADF) was higher in LF (p < 0.01). The 6% fat inclusion had a higher GP (109 vs. 103 mL ± 2.09; p < 0.03). Total volatile fatty acid (VFA) concentration was lower in different fat types than the CON and the acetate molar proportion (p > 0.01). The propionate was the lowest for the CON, which increased the acetate to propionate (A:P) ratio (p < 0.01). These results suggest that LF diets with high fat concentrations can be utilized, and different fat sources may improve DM and fiber digestibility. Full article