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Keywords = oil palm EFB fiber

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23 pages, 3299 KB  
Systematic Review
Utilization of Oil Palm Residual Biomass Within the Framework of Industrial Symbiosis: A Systematic Review of the Economic Sectors Involved in Its Valorization
by Dalidys Rendón-Camargo, Efrain Boom-Cárcamo, Lina Buelvas-Gutiérrez and Ana Maya-Gonzalez
Biomass 2026, 6(1), 10; https://doi.org/10.3390/biomass6010010 - 2 Feb 2026
Cited by 5 | Viewed by 2523
Abstract
This study analyzes the valorization of oil palm biomass residues within the framework of industrial symbiosis (IS), emphasizing their role in circular economy strategies and sustainable industrial development. Through a systematic literature review and snowball sampling, 156 articles indexed in Scopus and Web [...] Read more.
This study analyzes the valorization of oil palm biomass residues within the framework of industrial symbiosis (IS), emphasizing their role in circular economy strategies and sustainable industrial development. Through a systematic literature review and snowball sampling, 156 articles indexed in Scopus and Web of Science were examined, classifying evidence by country, type of residue, derived products, economic sector (ISIC Rev. 4), and technological approach. The results show a strong geographical concentration of IS experiences in Asia, particularly Malaysia, Indonesia, and Thailand, where residues such as empty fruit bunches (EFB), palm kernel shells (PKS), oil palm mesocarp fibers, palm oil mill effluent (POME), and oil palm trunks (OPT) are integrated into processes for bioenergy, biochemicals, composite materials, construction products, biochar, and bioplastics. In contrast, applications in Latin America and Africa remain incipient, with high potential but limited industrial implementation due to infrastructural and regulatory gaps. Technological trends point toward thermo-chemical and biological conversion routes (pyrolysis, gasification, hydrothermal carbonization, anaerobic digestion), development of advanced materials and catalysts, and the emergence of integrated biorefinery models supported by computational optimization tools. The analysis highlights that palm biomass residues, far from being an environmental liability, constitute strategic resources for low-carbon value chains. However, scaling IS initiatives requires clear public policies, economic incentives, and stronger coordination between industry, government, and academia. The study provides a structured overview of current knowledge, identifies research gaps, and outlines future directions for leveraging oil palm residues as a key input for sustainable IS. Full article
(This article belongs to the Topic The Utilization of Non-Grain Biomass Resources)
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18 pages, 2460 KB  
Article
Techno-Economic and FP2O Resilience Analysis of the Hydrogen Production Process from Palm Rachis in María La Baja, Bolívar
by Tamy Carolina Herrera-Rodríguez, Paola Andrea Acevedo Pabón and Ángel Darío González-Delgado
Processes 2026, 14(3), 489; https://doi.org/10.3390/pr14030489 - 30 Jan 2026
Viewed by 870
Abstract
In Colombia, two main palm varieties, Elaeis guineensis and Elaeis oleifera, are cultivated for the production of crude palm oil (CPO). During the CPO extraction process, several residues are generated, including empty fruit bunches (EFB), nut fiber, palm kernel cake, and Palm [...] Read more.
In Colombia, two main palm varieties, Elaeis guineensis and Elaeis oleifera, are cultivated for the production of crude palm oil (CPO). During the CPO extraction process, several residues are generated, including empty fruit bunches (EFB), nut fiber, palm kernel cake, and Palm Oil Mill Effluent (POME), among others. These residues are commonly used for biochar and compost production to improve soil quality, for biogas generation, and for energy production through biomass combustion. Because the rachis is rich in lignocellulosic material and exhibits physicochemical properties suitable for thermochemical processes, it is proposed as a feedstock for hydrogen synthesis through gasification. In this study, a techno-economic analysis and an FP2O resilience assessment were conducted for a hydrogen production process based on the utilization of palm rachis generated in María la Baja, northern Colombia. The economic evaluation results indicate that the capital investment required for plant installation is USD 10,111,255.23. The economic indicators show favorable performance with a Return on Investment (ROI) of 58.83%, a Net Present Value (NPV) of USD 25.01 million, a B/C ratio of 3.29, and a Discounted Payback Period (DPBP) of 4.54 years. Regarding techno-economic resilience, critical values for processing capacity, selling price, and feedstock cost were identified through parameter variation. The findings suggest that the process has opportunities for improvement, since small changes in these variables could significantly reduce its resilience. Finally, an On-Stream efficiency of 39.65% at the break-even point was obtained, indicating that the process can operate at less than 50% of its maximum capacity while still generating significant profits. Full article
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17 pages, 4429 KB  
Article
Design of a Technical Decision-Making Strategy to Collect Biomass Waste from the Palm Oil Industry as a Renewable Energy Source: Case Study in Colombia
by Jader Alean, Marlon Bastidas, Efraín Boom-Cárcamo, Juan C. Maya, Farid Chejne, Say Ramírez, Diego Nieto, Carlos Ceballos, Adonis Saurith and Marlon Córdoba-Ramirez
Environments 2025, 12(5), 165; https://doi.org/10.3390/environments12050165 - 16 May 2025
Cited by 6 | Viewed by 2602
Abstract
This work presents an effective design of a strategy to manage biomass waste (empty fruit bunch—EFB, kernel shell, and fiber) available from the processing of oil palm (Elaeis guineensis) in Colombia as a renewable energy source. This type of study is [...] Read more.
This work presents an effective design of a strategy to manage biomass waste (empty fruit bunch—EFB, kernel shell, and fiber) available from the processing of oil palm (Elaeis guineensis) in Colombia as a renewable energy source. This type of study is conducted for the first time in the country, and the proposed strategy is structured in four phases. Firstly, an inventory of available biomass waste was prepared based on information from 45 African palm oil companies of the approximately 70 that exist in the country. It was determined that the country had about 2762 kt of available waste (63.64% EFB, 12.55% kernel shell, and 23.81% fiber) for the year 2023. The estimates were conducted using a model that correlates processing capacity, the biomass generated, and the biomass demanded. The validation was performed using national reports. Subsequently, the minimum number (six) of storage centers in Colombia, where the largest amount of biomass can be stored, was determined. The center of gravity method was used to find the geographical location of each bulk storage center (municipality of Aracataca, Agustín Codazzi, San Martín, Puerto Wilches, Castilla La Nueva, and Cabuyaru). The next step was to determine the transportation costs as a decision criterion to select the best bulk storage center. When the required storage capacity does not exceed 211 kt·year−1, Agustín Codazzi is the best option because it has the lowest transportation cost (USD 1.01·t−1). When the storage capacity requirements exceed 211 kt·year−1 but are less than 423 kt·year−1, then Puerto Wilches and/or Aracataca are the best options (transportation cost of USD 1.7·t−1). In all cases, Cabuyaru has the highest costs (USD 6.56·t−1). Finally, an energy potential of 50,196 × 106 GJ·year−1 for the collected biomass was estimated, which makes this kind of waste an environmental alternative that could replace coal in Colombia. Full article
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15 pages, 1807 KB  
Article
Utilizing Indonesian Empty Palm Fruit Bunches: Biochar Synthesis via Temperatures Dependent Pyrolysis
by Fairuz Gianirfan Nugroho, Abu Saad Ansari, Nurul Taufiqu Rochman, Shubhangi Satish Khadtare, Vijaya Gopalan Sree, Nabeen K. Shrestha, Afina Faza Hafiyyan, Hyunsik Im and Abu Talha Aqueel Ahmed
Nanomaterials 2025, 15(1), 50; https://doi.org/10.3390/nano15010050 - 31 Dec 2024
Cited by 9 | Viewed by 5057
Abstract
Biomass, though a major energy source, remains underutilized. Biochar from biomass pyrolysis, with its high porosity and surface area, is especially useful as catalyst support, enhancing catalytic activity and reducing electron recombination in photocatalysis. Indonesia, the world’s top palm oil producer, generated around [...] Read more.
Biomass, though a major energy source, remains underutilized. Biochar from biomass pyrolysis, with its high porosity and surface area, is especially useful as catalyst support, enhancing catalytic activity and reducing electron recombination in photocatalysis. Indonesia, the world’s top palm oil producer, generated around 12 million tons of empty fruit bunches (EFBs) in 2023, making EFBs a promising biochar source. This study synthesizes biochar from leftover EFB fibers at 500, 800, and 1000 °C, analyzing structural changes via infrared and Raman spectroscopy, along with particle size and surface area analysis, laying the groundwork for future biochar research. The smallest particle size and highest surface area gained was 71.1 nm and 10.6 × 102 m2/g. Spectroscopic analysis indicates that biochar produced at 1000 °C has produced nano-crystalline graphite with a crystallite size of approximately 5.47 nm. This provides higher defect density, although with lower conductivity. Other studies indicate that our biochar can be used as catalyst support for various green energy-related applications, i.e., counter electrodes, electrocatalysts, and photocatalysts. Full article
(This article belongs to the Special Issue Functional Carbon Materials and Nano-Interface Modification)
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18 pages, 3895 KB  
Article
Oil Palm Empty Fruit Bunches as Raw Material of Dissolving Pulp for Viscose Rayon Fiber in Making Textile Products
by Siti Nikmatin, Irmansyah Irmansyah, Bambang Hermawan, Teddy Kardiansyah, Frederikus Tunjung Seta, Irma Nur Afiah and Rofiqul Umam
Polymers 2022, 14(15), 3208; https://doi.org/10.3390/polym14153208 - 6 Aug 2022
Cited by 13 | Viewed by 7075
Abstract
The creative fashion industry produces several textile products that play an important role in the national economy. In various countries, this industry has continued to grow along with the strong flow of information technology and e-commerce. The development of textile products for fashion [...] Read more.
The creative fashion industry produces several textile products that play an important role in the national economy. In various countries, this industry has continued to grow along with the strong flow of information technology and e-commerce. The development of textile products for fashion is very dynamic and competitive. Competition is not only about price, but also the quality of organic/synthetic materials, the comfort provided, and designs that change every 4–6 months. Recently, creative fashion not only relies on natural and synthetic polymer-made fibers but also biomass-based waste materials. Therefore, this study aims to manufacture textile products from biomass-based waste materials that can be applied to the creative fashion industry. Two types of raw materials from oil palm empty fruit bunches (EFB), namely, whole-empty fruit bunches (WEFB) and stalk-empty fruit bunches (SEFB), are used as an excellent innovation of rayon viscose fiber (RVF), a noncotton organic yarn capable of providing a solution to the 99% import of global cotton needs. This is expected to increase competitiveness, as well as the added value of palm oil products and their derivatives. The process of manufacturing DP chemically includes prehydrolysis, cooking, bleaching to dissolve the lignin and noncellulosic materials as well as isolation to purify POEFB fiber. Furthermore, DP testing is carried out to determine product quality and compare it with the national product standards. The results show that the alpha-cellulose content reaches >94% with variations in the active alkali of 18%, 20% and 24%. This implies that the WEFB and SEFB are used to fulfill the first requirements of the national standard (SNI 938:2017). The WEFB with an active alkali variation of 24% meets the SNI standard for rayon pulp with a value of S10 = 3.07 and S18 = 7.14%, while all variations of SEFB show opposite results. The use of active alkali at 24% had a brighter color than between 18% and 20%. Additionally, the fiber density of WEFB appears to be higher than that of SEFB. These results correlate positively with DP prepared using 24% alkali as the optimum treatment for all products, as well as the morphological observations performed with scanning electron microscopy (SEM), which shows that WEFB fixated fiber had a larger diameter than SEFB. Full article
(This article belongs to the Section Polymer Fibers)
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23 pages, 3183 KB  
Article
Diet Fermentation Leads to Microbial Adaptation in Black Soldier Fly (Hermetia illucens; Linnaeus, 1758) Larvae Reared on Palm Oil Side Streams
by Patrick Klüber, Dorothee Tegtmeier, Sabine Hurka, Janin Pfeiffer, Andreas Vilcinskas, Martin Rühl and Holger Zorn
Sustainability 2022, 14(9), 5626; https://doi.org/10.3390/su14095626 - 6 May 2022
Cited by 33 | Viewed by 7887
Abstract
Insects offer a promising alternative source of protein to mitigate the environmental consequences of conventional livestock farming. Larvae of the black soldier fly (Hermetia illucens; Linnaeus, 1758) efficiently convert a variety of organic side streams and residues into valuable proteins, lipids, [...] Read more.
Insects offer a promising alternative source of protein to mitigate the environmental consequences of conventional livestock farming. Larvae of the black soldier fly (Hermetia illucens; Linnaeus, 1758) efficiently convert a variety of organic side streams and residues into valuable proteins, lipids, and chitin. Here, we evaluated the suitability of two palm oil industry side streams—empty fruit bunches (EFB) and palm kernel meal (PKM)—as larval feed, and their impact on the larval gut microbiome. Among 69 fungal species we screened, Marasmius palmivorus, Irpex consors, and Bjerkandera adusta achieved the fastest growth and lignin degradation, so these fungi were used for the pretreatment of 7:3 mixtures of EFB and PKM. Larvae reared on the mixture pretreated with B. adusta (BAD) developed significantly more quickly and reached a higher final weight than those reared on the other pretreatments or the non-fermented reference (NFR). Amplicon sequencing of the BAD and NFR groups revealed major differences in the larval gut microbiome. The NFR group was dominated by facultatively anaerobic Enterobacteriaceae (typical of H. illucens larvae) whereas the BAD group favored obligately anaerobic, cellulolytic bacteria (Ruminococcaceae and Lachnospiraceae). We hypothesize that fungal lignin degradation led to an accumulation of mycelia and subsequent cellulolytic breakdown of fiber residues, thus improving substrate digestibility. Full article
(This article belongs to the Collection Sustainable Insect Farming: Feed the Future)
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30 pages, 1789 KB  
Article
Circular Economy Indicators for the Assessment of Waste and By-Products from the Palm Oil Sector
by Pedro-Antonio Cárdenas Bejarano, Juan-Pablo Rodriguez-Miranda, Rayma Ireri Maldonado-Astudillo, Yanik Ixchel Maldonado-Astudillo and Ricardo Salazar
Processes 2022, 10(5), 903; https://doi.org/10.3390/pr10050903 - 3 May 2022
Cited by 24 | Viewed by 6452
Abstract
A circular economy (CE) promotes the reuse, reincorporation and valuation of waste and by-products under the framework of sustainable development through models and indicators that evaluate scenarios of second use and reduction in non-incorporated outputs to reduce negative externalities and pressures on the [...] Read more.
A circular economy (CE) promotes the reuse, reincorporation and valuation of waste and by-products under the framework of sustainable development through models and indicators that evaluate scenarios of second use and reduction in non-incorporated outputs to reduce negative externalities and pressures on the dimensions of development. A CE model applied to the transformation process of RFF in agro-industries is developed, which consists in the identification of the residue coefficients of EFB (22.48% ± 0.8), fiber (15.58% ± 0.49), husk (6.03% ± 0.66) and ash (0.55% ± 1.67). Subsequently, the valuation trends of potential second use were verified through a systematic review, which allowed the construction of the scenario of avoided costs of USD 678,721.5, a product of the total use of the outputs under bioenergy and nutrient source approaches. Finally, the RRSFM indicator was constructed, which can reach the level of 72% and a degree of improvement of 26% by 2026. In parallel, the HCRRS indicator revealed a reduction of 57.1%, 59.6% and 82.8% in emissions of t CO2-eq product in the comparison of scenarios for the use of residues and by-products of palm oil from agro-industries in the Casanare Department. Full article
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15 pages, 2859 KB  
Article
Energy Potential of Oil Palm Empty Fruit Bunch (EFB) Fiber from Subsequent Cultivation of Volvariella volvacea (Bull.) Singer
by Noor Azrimi Umor, Sumaiyah Abdullah, Azhar Mohamad, Shahrul Bin Ismail, Siti Izera Ismail and Azizah Misran
Sustainability 2021, 13(23), 13008; https://doi.org/10.3390/su132313008 - 24 Nov 2021
Cited by 13 | Viewed by 8859
Abstract
EFB and EFB-based mushroom compost (SMC) from Volvariella volvacea cultivation is a promising energy feedstock because it has adequate nutrient quality. The biochemical methane potential (BMP) and calorific value (CV) of this biomass are investigated. Other analyses such as proximate, compositional, and final [...] Read more.
EFB and EFB-based mushroom compost (SMC) from Volvariella volvacea cultivation is a promising energy feedstock because it has adequate nutrient quality. The biochemical methane potential (BMP) and calorific value (CV) of this biomass are investigated. Other analyses such as proximate, compositional, and final analysis; thermogravimetric analysis (TGA); and Fourier transform infrared spectroscopy (FTIR) are also performed. The biomass samples consist of two types of EFB, namely fibers (F) and pellets (P) and SMC from the subsequent cultivation of Volvariella volvacea, with samples FS and PS from the first cultivation and FS2 and PS2 from the second cultivation. P produces the highest biological efficiency (BE) of 28% compared to 9.83% for F. Subsequent cultivation with FS and PS then produces only 2.9 and 6.83% of BE. A higher amount of methane is measured in samples P and PS2, while better biodegradability is observed in PS2 and FS2, suggesting that subsequent cultivation is a good pretreatment of the substrate for anaerobic digestion (AD). CV is highest in F (20.57 MJ/kg), followed by P (19.06 MJ/kg), which is comparable to commercial wood pellet. Samples F, FS, and FS2 have higher ash content, which is due to higher mineral content. The cellulose composition is reduced to almost 50% during cultivation due to fungal metabolism, which is also evidenced by FTIR analysis. TGA analysis revealed that EFB-based SMC exhibits higher weight loss during combustion compared to EFB, which reduces its thermal properties. SMC of EFB is a high potential biomethane feedstock, but not recommended as a fuel pellet. Full article
(This article belongs to the Special Issue Renewable Energy Conversion and Management)
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12 pages, 27243 KB  
Article
Effect of Ozone Treatment on the Properties of Oil Palm Empty Fruit Bunch Sulfonated Chemi-Mechanical Pulp
by Xing Wan, Yang Ping and Jun Li
Forests 2021, 12(8), 1085; https://doi.org/10.3390/f12081085 - 13 Aug 2021
Cited by 4 | Viewed by 3316
Abstract
Oil palm empty fruit bunch (EFB) as an abundant waste material can be utilized for pulp production to alleviate the shortage of raw materials in the paper industry. Sulfonated chemi-mechanical pulp (SCMP) has great potential in paper making industry. However, its poor performance [...] Read more.
Oil palm empty fruit bunch (EFB) as an abundant waste material can be utilized for pulp production to alleviate the shortage of raw materials in the paper industry. Sulfonated chemi-mechanical pulp (SCMP) has great potential in paper making industry. However, its poor performance due to the high surface lignin content limits its application. In this study, we used EFB as raw material to produce SCMP and systematically studied the effect of ozone treatment on pulp properties. Results show that the surface structure and morphology of fibers exhibited distinct differences under different ozone dosage treatments. Compared to the control, the content of surface lignin of pulps was reduced by 2.56%, 4.64%, 13.24% and 25.24% when ozone consumption was 1, 3, 5 and 7 wt%, respectively. Meanwhile, the treated pulp had a lower drainability at the same refining energy level. Moreover, the physical and optical properties of handsheets were improved significantly after ozone treatment. Ozone treatment is a very efficient way to improve the performance of SCMP. Additionally, this method avoids complicated processes and chemical consumption. Therefore, as an effective, environmentally friendly and low-cost treatment method, ozone treatment can improve the performance of EFB SCMP and thus provide a high-quality pulp resource. Full article
(This article belongs to the Special Issue Forests Sustainable Application: Production of Pulp and Paper)
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14 pages, 4151 KB  
Article
Self-Assembled Behavior of Ultralightweight Aerogel from a Mixture of CNC/CNF from Oil Palm Empty Fruit Bunches
by Dian Burhani, Athanasia Amanda Septevani, Ruby Setiawan, Luthfia Miftahul Djannah, Muhammad Andrew Putra, Sukma Surya Kusumah and Dewi Sondari
Polymers 2021, 13(16), 2649; https://doi.org/10.3390/polym13162649 - 10 Aug 2021
Cited by 22 | Viewed by 5340
Abstract
This study aims to explore the use of cellulose nanocrystals (CNC) and cellulose nanofiber (CNF), obtained from unbleached fiber of oil palm empty fruit bunches (EFB), as raw materials in fabricating aerogel, using the facile technique without solvent displacement. The CNC was isolated [...] Read more.
This study aims to explore the use of cellulose nanocrystals (CNC) and cellulose nanofiber (CNF), obtained from unbleached fiber of oil palm empty fruit bunches (EFB), as raw materials in fabricating aerogel, using the facile technique without solvent displacement. The CNC was isolated from sulfuric acid hydrolysis, and the CNF was fibrillated using Ultra Turrax. The CNC and CNF were mixed by ultrasonication in different ratios to produce aerogel using slow freezing (−20 °C), followed by freeze-drying. The obtained aerogel was characterized as ultralightweight and highly porous material, at the density range of 0.0227 to 0.0364 g/cm3 and porosity of 98.027 to 98.667%. Interestingly, the ratio of CNC and CNF significantly affected the characteristics of the obtained aerogel. The mixed aerogel exhibited a higher specific surface area than pure CNC or CNF, with the highest value of 202.72 m2/g for the ratio of 1:3 (CNC/CNF). In addition, the crystallinity degree of obtained aerogel showed a higher value in the range of 76.49 to 69.02%, with the highest value being obtained for higher CNC content. This study is expected to provide insight into nanocellulose-based aerogel, with a promising potential for various applications. Full article
(This article belongs to the Special Issue Advances of Aerogels and Their Polymer Composites)
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12 pages, 730 KB  
Article
Agro-Pellets from Oil Palm Residues/Pine Sawdust Mixtures: Relationships of Their Physical, Mechanical and Energetic Properties, with the Raw Material Chemical Structure
by Artemio Carrillo-Parra, Juan Carlos Contreras-Trejo, Marín Pompa-García, Miguel Ángel Pulgarín-Gámiz, José Guadalupe Rutiaga-Quiñones, Gerardo Pámanes-Carrasco and Maginot Ngangyo-Heya
Appl. Sci. 2020, 10(18), 6383; https://doi.org/10.3390/app10186383 - 13 Sep 2020
Cited by 25 | Viewed by 4201
Abstract
The need for biomass as an alternative source for energy purposes points toward oil palm fruit residues (Elaeis guineensis Jacq.) as an attractive solution. Oil palm industry residue, such as oil palm empty fruit bunch (EFB) composites and mesocarp fiber (PMF), have [...] Read more.
The need for biomass as an alternative source for energy purposes points toward oil palm fruit residues (Elaeis guineensis Jacq.) as an attractive solution. Oil palm industry residue, such as oil palm empty fruit bunch (EFB) composites and mesocarp fiber (PMF), have a high gross calorific value and could help countries meet their energy demands. However, information concerning physical, mechanical, and energy characteristics of agro-pellets made from mixtures of oil palm residue with pine sawdust, is not available. In this research, oil palm residues were mixed at ratios of 100:0, 80:20, 60:40, 40:60, 20:80, and 0:100 with pine sawdust, and were chemically analyzed. Agro-pellets from mixtures were tested on their physical and mechanical properties, and the relationship of these properties with the chemical composition of oil palm residue mixtures was determined. Normality distribution tests of the variables were performed using the Kolmogorov–Smirnov test. Normal variables were analyzed through one-way ANOVA tests. When differences were found, they were validated using the Tukey’s honestly significant difference (HSD) test and were considered statistically significant at p ≤ 0.05. Data not normally distributed were analyzed by the Kruskal–Wallis test. Bulk density, particle density, and gross calorific value of agro-pellets (from mixing 80:20 oil palm residues with pine sawdust) were statistically higher (p < 0.05) to agro-pellets of 100% oil palm residues. Adding pine sawdust to oil palm residues increases some mechanical agro-pellet properties. Addition of pine sawdust to oil palm residues acts to increase some mechanical properties of agro-pellets. Full article
(This article belongs to the Special Issue Biomass Energy Utilization Systems)
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13 pages, 2303 KB  
Article
Characterization of Hybrid Oil Palm Empty Fruit Bunch/Woven Kenaf Fabric-Reinforced Epoxy Composites
by Farah Hanan, Mohammad Jawaid, Md Tahir Paridah and Jesuarockiam Naveen
Polymers 2020, 12(9), 2052; https://doi.org/10.3390/polym12092052 - 9 Sep 2020
Cited by 43 | Viewed by 5277
Abstract
In this research, the physical, mechanical and morphological properties of oil palm empty fruit bunch (EFB) mat/woven kenaf fabric-reinforced epoxy composites have been investigated. The oil palm EFB/woven kenaf fabrics were varied, with weight ratios of 50/0 (T1), 35/15 (T2), 25/25 (T3), 15/35 [...] Read more.
In this research, the physical, mechanical and morphological properties of oil palm empty fruit bunch (EFB) mat/woven kenaf fabric-reinforced epoxy composites have been investigated. The oil palm EFB/woven kenaf fabrics were varied, with weight ratios of 50/0 (T1), 35/15 (T2), 25/25 (T3), 15/35 (T4) and 0/50 (T5). The composites were fabricated using a simple hand lay-up technique followed by hot pressing. The result obtained shows that an increase in kenaf fiber content exhibited higher tensile and flexural properties. On the other hand, the opposite trend was observed in the impact strength of hybrid composites, where an increase in kenaf fiber content reduced the impact strength. This can be corroborated with the physical properties analysis, where a higher void content, water absorption and thickness swelling were observed for pure oil palm EFB (T1) composites compared to other samples. The scanning electron microscopy analysis results clearly show the different failure modes of the tensile fractured samples. Statistical analysis was performed using one-way ANOVA and shows significant differences between the obtained results. Full article
(This article belongs to the Special Issue Epoxy Composites: Processes and Applications)
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16 pages, 4831 KB  
Article
3D Printing of UV-Curable Polyurethane Incorporated with Surface-Grafted Nanocellulose
by Denesh Mohan, Mohd Shaiful Sajab, Hatika Kaco, Saiful Bahari Bakarudin and An’amt Mohamed Noor
Nanomaterials 2019, 9(12), 1726; https://doi.org/10.3390/nano9121726 - 3 Dec 2019
Cited by 53 | Viewed by 6416
Abstract
The recognition of nanocellulose has been prominent in recent years as prospect materials, yet the ineffectiveness of nanocellulose to disperse in an organic solvent has restricted its utilization, especially as a reinforcement in polymer nanocomposite. In this study, cellulose has been isolated and [...] Read more.
The recognition of nanocellulose has been prominent in recent years as prospect materials, yet the ineffectiveness of nanocellulose to disperse in an organic solvent has restricted its utilization, especially as a reinforcement in polymer nanocomposite. In this study, cellulose has been isolated and defibrillated as cellulose nanofibrils (CNF) from oil palm empty fruit bunch (EFB) fibers. Subsequently, to enhance its compatibility with UV-curable polyurethane (PU)-based resin, the surface hydrophilicity of CNF has been tailored with polyethylene glycol (PEG), as well as reduced graphene oxide (rGO). The dispersibility of reinforced modified CNF in UV-curable PU was examined through the transmittance interruption of resin, chemical, and mechanical properties of the composite printed using the stereolithographic technique. Evidently, the enhanced compatibility of modified CNF and UV-curable PU was shown to improve the tensile strength and hardness of the composites by 37% and 129%, respectively. Full article
(This article belongs to the Special Issue Advanced Nanocomposites for 3D Printing Applications)
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12 pages, 3909 KB  
Article
Evaluation of the Compatibility of Organosolv Lignin-Graphene Nanoplatelets with Photo-Curable Polyurethane in Stereolithography 3D Printing
by Fathirrahman Ibrahim, Denesh Mohan, Mohd Shaiful Sajab, Saiful Bahari Bakarudin and Hatika Kaco
Polymers 2019, 11(10), 1544; https://doi.org/10.3390/polym11101544 - 23 Sep 2019
Cited by 59 | Viewed by 6106
Abstract
In this study, lignin has been extracted from oil palm empty fruit bunch (EFB) fibers via an organosolv process. The organosolv lignin obtained was defined by the presence of hydroxyl-containing molecules, such as guaiacyl and syringyl, and by the presence of phenolic molecules [...] Read more.
In this study, lignin has been extracted from oil palm empty fruit bunch (EFB) fibers via an organosolv process. The organosolv lignin obtained was defined by the presence of hydroxyl-containing molecules, such as guaiacyl and syringyl, and by the presence of phenolic molecules in lignin. Subsequently, the extracted organosolv lignin and graphene nanoplatelets (GNP) were utilized as filler and reinforcement in photo-curable polyurethane (PU), which is used in stereolithography 3D printing. The compatibility as well as the characteristic and structural changes of the composite were identified through the mechanical properties of the 3D-printed composites. Furthermore, the tensile strength of the composited lignin and graphene shows significant improvement as high as 27%. The hardness of the photo-curable PU composites measured by nanoindentation exhibited an enormous improvement for 0.6% of lignin-graphene at 92.49 MPa with 238% increment when compared with unmodified PU. Full article
(This article belongs to the Collection Reinforced Polymer Composites)
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19 pages, 5168 KB  
Article
Bio-Pellet Fuel from Oil Palm Empty Fruit Bunches (EFB): Using European Standards for Quality Testing
by Anna Brunerová, Miroslav Müller, Vladimír Šleger, Himsar Ambarita and Petr Valášek
Sustainability 2018, 10(12), 4443; https://doi.org/10.3390/su10124443 - 27 Nov 2018
Cited by 39 | Viewed by 10876
Abstract
The oil palm (Elaeis guineensis Jacq.) represents Indonesian major agriculture crop, nevertheless, its cultivation and processing results in an excessive amount of waste biomass, namely, empty fruit bunches (EFB), which is not always properly processed or reused. Therefore, the present investigation was [...] Read more.
The oil palm (Elaeis guineensis Jacq.) represents Indonesian major agriculture crop, nevertheless, its cultivation and processing results in an excessive amount of waste biomass, namely, empty fruit bunches (EFB), which is not always properly processed or reused. Therefore, the present investigation was performed to attract wide public interest in proper waste management and reuse of waste biomass. The suitability of such waste biomass for bio-pellet fuel production within its ecological EFB reuse was the subject of investigation. Its fuel parameters, mechanical quality and microscopic analysis represented the set of experimental testing performed within the target purpose. Satisfactory result values were stated within oil palm EFB fuel parameters, namely, moisture content Mc—7.07%, ash content Ac—9.41% and energy potential NCV—15.06 MJ∙kg−1. Mechanical analysis of the produced bio-pellet fuel proved outstanding results: Volume density ρ—1440.01 kg∙m−3 and mechanical durability DU—97.4% and 99.4% (according to ÖNORM M 7135 (2003) and ISO 17831-1 (2015)). Furthermore, results of compressive strength σ proved the requested high level; in simple pressure σp—10.83 MPa and in cleft σc—60.46 N·mm−1. Stereoscopic microscope measurements proved a prevalent proportion of fiber >97% within the feedstock content, and scanning electron microscopy (SEM) of bio-pellet samples diagnosed cracks purely on the outer surface, not within their internal structures, which indicated high quality compacted products. In conclusion, the overall evaluation indicates the production of environmental-friendly high quality bio-pellet fuel, thus, proving the suitability of oil palm EFB for the production of bio-pellet fuel. Full article
(This article belongs to the Section Energy Sustainability)
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