Search Results (21)

This study utilized the FVCOM model to establish a hydrodynamic model for the waters from Haikou to Danzhou. Based on this framework, a numerical model for oil spill drift and diffusion was developed using the Lagrangian particle method, incorporating processes such as advection, diffusion, spreading, emulsification, dissolution, volatilization, and shoreline adsorption. Sea experiments involving drifters and dye were conducted to validate the oil spill model. The model was subsequently applied to analyze the impacts of tidal phases and wind fields on oil spill trajectories, predict affected areas, and assess risks to environmentally sensitive zones. The results demonstrate that the hydrodynamic model accurately reproduces the tidal current characteristics of the study area. Validation using drifter and dye experiments confirmed that the model’s predictive error remains within 20%, meeting operational forecasting standards. Potential sources of error include uncertainties in wind–wave–current interactions and discrepancies in windage coefficients between oil spills and drifters. Tidal currents and wind fields were identified as the dominant drivers of oil spill drift and diffusion. Under southerly wind conditions, the oil spill exhibited the largest spatial extent, covering 995.25 km² with a trajectory length of 226.92 km. A sensitivity analysis highlighted the Lingao Silverlip Pearl Oyster Marine Protected Area and Shatu Bay Beach as high-risk regions. The developed model provides critical technical support for oil spill emergency response under diverse environmental conditions, enabling proactive pathway forecasting and preventive measures to mitigate ecological damage. Full article

Oil spills represent a critical environmental hazard with far-reaching ecological and economic consequences, necessitating the development of sophisticated modelling approaches to predict, monitor, and mitigate their impacts. This study presents a computationally efficient and physically grounded modelling framework for simulating oil spill drift in marine environments, developed using Python coding. The proposed model integrates core physical processes—advection, diffusion, and degradation—within a simplified partial differential equation system, employing an integrator for numerical simulation. Building on recent advances in marine pollution modelling, the study incorporates real-time oceanographic data, satellite-based remote sensing, and subsurface dispersion dynamics into an enriched version of the simulation. The research is structured in two phases: (1) the development of a minimalist Python model to validate fundamental oil transport behaviours, and (2) the implementation of a comprehensive, multi-layered simulation that includes NOAA ocean currents, 3D vertical mixing, and support for inland and chemical spill modelling. The results confirm the model’s ability to reproduce realistic oil spill trajectories, diffusion patterns, and biodegradation effects under variable environmental conditions. The proposed framework demonstrates strong potential for real-time decision support in oil spill response, coastal protection, and environmental policy-making. This paperwork contributes to the field by bridging theoretical modelling with practical response needs, offering a scalable and adaptable tool for marine pollution forecasting. Future extensions may incorporate deep learning algorithms and high-resolution sensor data to further enhance predictive accuracy and operational readiness. Full article

A detailed analysis of high-resolution (3.5 kHz) chirp seismic profiles acquired in the Gunsan Basin of the central Yellow Sea revealed that hydrocarbon gases are actively seeping via the formation of many plumes. The uppermost sedimentary layer was acoustically confirmed to be fully or partially charged with gases. Somewhat favored by the low-tide period, episodic gas seepage is mainly associated with the underlying fault systems of Cretaceous-Cenozoic sedimentary strata in the southwestern part of the basin. Catastrophic gas expulsion seems to have formed a crater at the sidewall of a sedimentary ridge and two diapirs. Here, methane is poorly concentrated but rich in the heavy carbon isotope (δ¹³C, −52.6‰ to −44.7‰ The Vienna Peedee Belemnite [VPDB]), indicating that methane formed mainly through biodegradation of heavy oils at depth remains in the shallow sediments following its expulsion. Episodic rapid upward advection of porewater is also manifest by unmixed heavy methane trapped in the upper part of the primary biogenic methane (δ¹³C, about −90‰ VPDB)-filled sediment core. These findings imply that the Gunsan Basin fulfills the requirements for possible generation and preservation of oil and gas, like the petroliferous basins of eastern China and the Yellow Sea. Full article

A quantitative and qualitative assessment using molecular markers derived from compound-specific indices for indicating groundwater impacted by petroleum spills in an oil field was recently undertaken and demonstrated serious contamination, with both high total petroleum hydrocarbons (TPH) (3.68–7.32 mg/L) and hazardous compounds in the groundwater. A petroleum source was identified, and the analysis revealed a decreasing trend of fresh petroleum input, along with groundwater advection and an increasing trend of biodegradation potential at locations farther from the source. This was confirmed via microbial analysis with both biodegrading microorganisms and diversity indices (Shannon, Simpson, and Pielou) and the principal component analysis (PCA) modeling approach, which classified the field samples into three types according to the distribution correlations between different organic compounds. Biodegradation was believed to be the dominant sink of hydrocarbons due to the increasing Pr/C17 and Ph/C18 values with seasonal changes. Raised temperatures activated the microbial degradation process; specifically, low-weight hydrocarbons degraded more rapidly than high-weight hydrocarbons, resulting in the accumulation of an unresolved complex mixture of bioproducts at locations that were farther away. Spatially, the Pr/C17 and Ph/C18 values increased from the upstream to the downstream areas, showing substantial biodegradation. The relationships between the molecular markers and chemical indices were quantified via canonical correlation analysis (CCA) to visually explain the interactive reaction processes. It was also demonstrated that the biodegradation of petroleum organics can be characterized by the consumption of dissolved oxygen and a decreasing Pr/Ph ratio, due to system reduction. These results demonstrate that compound-specific molecular markers, coupled with biochemical parameters, can effectively support a better understanding and effective fingerprinting of the fate and transport of petroleum organic contaminants, thus offering valuable technical support for a cost-effective remediation strategy. Full article

In the Lagrangian approach, the transport processes in the ocean and atmosphere are studied by tracking water or air parcels, each of which may carry different tracers. In the ocean, they are salt, nutrients, heat, and particulate matter, such as plankters, oil, radionuclides, and microplastics. In the atmosphere, the tracers are water vapor, ozone, and various chemicals. The observation and simulation reveal highly complex patterns of advection of tracers in turbulent-like geophysical flows. Transport barriers are material surfaces across which the transport is minimal. They can be classified into elliptic, parabolic, and hyperbolic barriers. Different diagnostics in detecting transport barriers and the analysis of their role in the dynamics of oceanic and atmospheric flows are reviewed. We discuss the mathematical tools, borrowed from dynamical systems theory, for detecting transport barriers in simple kinematic and dynamic models of vortical and jet-like flows. We show how the ideas and methods, developed for simple model flows, can be successfully applied for studying the role of barriers in oceanic and atmospheric flows. Special attention is placed on the significance of transport barriers in important practical issues: anthropogenic and natural pollution, advection of plankton, cross-shelf exchange, and propagation of upwelling fronts in coastal zones. Full article

We analyzed the soil at the site of a former coking wastewater treatment plant on redeveloped land in Taiyuan, northern China, in an attempt to detect the presence of 16 types of priority polycyclic aromatic hydrocarbons (PAHs) listed by the United States Environmental Protection Agency (US EPA) and evaluate the potential pollution risks. The results show that the total proportion of PAHs in the surface soil of the redeveloped land ranged from 0.3 to 1092.57 mg/kg, with an average value of 218.5 mg/kg, mainly consisting of high-ring (5–6 rings) components. Characteristic ratio analysis indicated that the pollution was mainly related to the combustion of petroleum, coal, and biomasses. The wastewater treatment units operated according to the following treatment train: advection oil separation tank, dissolved air flotation tank, aerobic tank, secondary sedimentation tank, and sludge concentration tank. Our study found that pollution resulting from low-ring PAHs mainly appeared in the advection oil separation tank during the pre-wastewater treatment stage, while medium-ring PAH contamination mainly occurred in the dissolved air floatation tank, aerobic tank, and secondary sedimentation tank during the middle stages of wastewater treatment. High-ring PAH contamination primarily appeared in the sludge concentration tank in the latter stage of wastewater treatment. Based on our assessment of the ecological risk using the Nemerow Comprehensive Pollution Index and the toxicity equivalent factor (TEF) method, we determined that individual PAHs in the study area exceeded acceptable levels and the total amount of pollution was potentially harmful to the ecological environment. In addition, the comprehensive lifetime cancer risk for different populations resulting from exposure to the soil in the study area was determined to be within acceptable limits based on the average PAH concentrations. Full article

Decarbonisation of heat is essential to meeting net zero carbon targets; however, fluctuating renewable resources, such as wind or solar, may not meet peak periods of demand. Therefore, methods of underground thermal energy storage can aid in storing heat in low demand periods to be exploited when required. Borehole thermal energy storage (BTES) is an important technology in storing surplus heat and the efficiency of such systems can be strongly influenced by groundwater flow. In this paper, the effect of groundwater flow on a single deep borehole heat exchanger (DBHEs) was modelled using OpenGeoSys (OGS) software to test the impact of varying regional Darcy velocities on the performance of heat extraction and BTES. It is anticipated that infrastructure such as ex-geothermal exploration or oil and gas development wells approaching the end of life could be repurposed. These systems may encounter fluid flow in the subsurface and the impact of this on single well deep BTES has not previously been investigated. Higher groundwater velocities can increase the performance of a DBHE operating to extract heat only for a heating season of 6 months. This is due to the reduced cooling of rocks in proximity to the DBHE as groundwater flow replenishes heat which has been removed from the rock volume around the borehole (this can also be equivalently thought of as “coolth” being transported away from the DBHE in a thermal plume). When testing varying Darcy velocities with other parameters for a DBHE of 920 m length in rock of thermal conductivity 2.55 W/(m·K), it was observed that rocks with larger Darcy velocity (1e-6 m/s) can increase the thermal output by up to 28 kW in comparison to when there is no groundwater flow. In contrast, groundwater flow inhibits single well deep BTES as it depletes the thermal store, reducing storage efficiency by up to 13% in comparison to models with no advective heat transfer in the subsurface. The highest Darcy velocity of 1e-6 m/s was shown to most influence heat extraction and BTES; however, the likelihood of this occurring regionally, and at depth of around or over 1 km is unlikely. This study also tested varying temporal resolutions of charge and cyclicity. Shorter charge periods allow a greater recovery of heat (c. 34% heat injected recovered for 1 month charge, as opposed to <17% for 6 months charge). Full article

The drainage and cultivation of peatlands will lead to subsidence and mineralisation of organic matter, increasing carbon (C) loss as more CO₂ is emitted. There is little information about carbon emissions from bare peat soil. A study was undertaken to measure the CO₂ emissions from a logged-over peat swamp area that was purposely vegetation-free. We aimed to report CO₂ emissions from a bare, drained peatland developed for an oil palm plantation. For 12 months, we used eddy covariance (EC), closed chambers, and soil subsidence measurements to derive CO₂ emissions from a logged-over peat swamp area. Significant variations in the estimated soil CO₂ efflux were observed in the three tested measurement techniques. The average CO₂ flux rate measured by the EC technique was 4.94 ± 0.12 µmol CO₂ m⁻² s⁻¹ (or 68.55 tonnes CO₂ ha⁻¹ year⁻¹). Meanwhile, the soil CO₂ efflux rate measured by the closed chamber technique was 4.19 ± 0.22 µmol CO₂ m⁻² s⁻¹ (or 58.14 tonnes CO₂ ha⁻¹ year⁻¹). Subsidence amounted to 1.9 cm year⁻¹, corresponding to 36.12 tonnes CO₂ ha⁻¹ year⁻¹. The estimation of the C loss was found to be highest by the EC technique, lower by the soil chamber technique, and lowest by the peat subsidence rate technique. The higher CO₂ emission rate observed in the EC technique could be attributed to soil microbial respiration and decomposing woody residues in the nearby stacking rows due to the large EC footprint. It could also be affected by CO₂ advection from oil palms adjacent to the study site. Despite the large differences in the CO₂ emission rates by the different techniques, this study provides valuable information on the soil heterotrophic respiration of deep peat in Sarawak. Carbon emissions from a bare peat area cover only a fraction of the soil CO₂ respiration component, i.e., the soil heterotrophic respiration. Further investigations are needed to determine the CO₂ emissions by soil microbial activities and plant roots from other peat areas in Sarawak. Full article

In this study, we investigate the air quality improvement effect in Busan, the largest port city in South Korea, caused by the implementation of International Maritime Organization (IMO) sulfur regulations. Currently, the Korean government is struggling with problems related to PM_2.5, and ships are one of the major sources of PM_2.5 generation in South Korea. Therefore, we tried to estimate how much the PM_2.5 levels in South Korea could be improved via low-sulfur regulation. According to the Clean Air Quality Policy Support System (CAPSS; National Emission Inventory) in 2016, ship emissions in Busan accounted for 39%, 71%, and 39% of PM_2.5, SO₂, and NO₂ emissions, respectively. To simulate the effect of the IMO’s 0.5 percent sulfur regulation, SOx and PM_2.5 emissions from oil-fueled cargo ships were reduced. Via ship fuel regulation, the PM_2.5 concentration was improved by up to 19% at a site near the port in 2020. In addition, in the case of sulfate, the reduction rate was higher on the downwind side of the Busan port and not near the port, which can be considered as the cause of advection and secondary formation. The PM_2.5 contributions from ships to each of the sub-regions in Busan also decreased by an average of 47% because of IMO sulfur regulation. Although there were limitations in terms of emission estimations because of the application of low-sulfur regulation, we expect that the results of this paper can be used for additional PM_2.5 improvement plans developed by the Korean government and by the local government as well. Full article

 Forced and spontaneous imbibition of water is performed to displace oil from strongly water-wet Gray Berea (~130 mD) and Bentheimer (~1900 mD) sandstone core plugs. Two nonpolar oils (n-heptane and Marcol-82) were used as a non-wetting phase, with viscosities between 0.4 and 32 cP and brine (1 M NaCl) for the wetting phase with viscosity 1.1 cP. Recovery was measured for both imbibition modes, and pressure drop was measured during forced imbibition. Five forced imbibition tests were performed using low or high injection rates, using low or high oil viscosity. Seventeen spontaneous imbibition experiments were performed at four different oil viscosities. By varying the oil viscosity, the injection rate and imbibition modes, capillary and advective forces were allowed to dominate, giving trends that could be captured with modeling. Full numerical simulations matched the experimental observations consistently. The findings of this study provide better understanding of pressure and recovery behavior in strongly water-wet systems. A strong positive capillary pressure and a favorable mobility ratio resulting from low water relative permeability were main features explaining the observations. Complete oil recovery was achieved at water breakthrough during forced imbibition for low and high oil viscosity and the recovery curves were identical when plotted against the injected volume. Analytical solutions for forced imbibition indicate that the pressure drop changes linearly with time when capillary pressure is negligible. Positive capillary forces assist water imbibition, reducing the pressure drop needed to inject water, but yielding a jump in pressure drop when the front reaches the outlet. At a high injection rate, capillary forces are repressed and the linear trend between the end points was clearer than at a low rate for the experimental data. Increasing the oil viscosity by a factor of 80 only increased the spontaneous imbibition time scale by five, consistent with low water mobility constraining the imbibition rate. The time scale was predicted to be more sensitive to changes in water viscosity. At a higher oil-to-water mobility ratio, a higher part of the total recovery follows the square root of time. Our findings indicate that piston-like displacement of oil by water is a reasonable approximation for forced and spontaneous imbibition, unless the oil has a much higher viscosity than the water.  Full article

Over the past century, the demand for petroleum products has increased rapidly, leading to higher oil extraction, processing and transportation, which result in numerous oil spills in coastal-marine environments. As the spilled oil can negatively affect the coastal-marine ecosystems, its transport and fates captured a significant interest of the scientific community and regulatory agencies. Typically, the environment has natural mechanisms (e.g., photooxidation, biodegradation, evaporation) to weather/degrade and remove the spilled oil from the environment. Among various oil weathering mechanisms, biodegradation by naturally occurring bacterial populations removes a majority of spilled oil, thus the focus on bioremediation has increased significantly. Helping in the marginal recognition of this promising technique for oil-spill degradation, this paper reviews recently published articles that will help broaden the understanding of the factors affecting biodegradation of spilled oil in coastal-marine environments. The goal of this review is to examine the effects of various environmental variables that contribute to oil degradation in the coastal-marine environments, as well as the factors that influence these processes. Physico-chemical parameters such as temperature, oxygen level, pressure, shoreline energy, salinity, and pH are taken into account. In general, increase in temperature, exposure to sunlight (photooxidation), dissolved oxygen (DO), nutrients (nitrogen, phosphorous and potassium), shoreline energy (physical advection—waves) and diverse hydrocarbon-degrading microorganisms consortium were found to increase spilled oil degradation in marine environments. In contrast, higher initial oil concentration and seawater pressure can lower oil degradation rates. There is limited information on the influences of seawater pH and salinity on oil degradation, thus warranting additional research. This comprehensive review can be used as a guide for bioremediation modeling and mitigating future oil spill pollution in the marine environment by utilizing the bacteria adapted to certain conditions. Full article

Water-capped tailings technology (WCTT) is a key component of the reclamation strategies in the Athabasca oil sands region (AOSR) of northeastern Alberta, Canada. The release of microbial methane from tailings emplaced within oil sands pit lakes, and its subsequent microbial oxidation, could inhibit the development of persistent oxygen concentrations within the water column, which are critical to the success of this reclamation approach. Here, we describe the results of a four-year (2015–2018) chemical and isotopic (δ¹³C) investigation into the dynamics of microbial methane cycling within Base Mine Lake (BML), the first full-scale pit lake commissioned in the AOSR. Overall, the water-column methane concentrations decreased over the course of the study, though this was dynamic both seasonally and annually. Phospholipid fatty acid (PLFA) distributions and δ¹³C demonstrated that dissolved methane, primarily input via fluid fine tailings (FFT) porewater advection, was oxidized by the water column microbial community at all sampling times. Modeling and under-ice observations indicated that the dissolution of methane from bubbles during ebullition, or when trapped beneath ice, was also an important source of dissolved methane. The addition of alum to BML in the fall of 2016 impacted the microbial cycling in BML, leading to decreased methane oxidation rates, the short-term dominance of a phototrophic community, and longer-term shifts in the microbial community metabolism. Overall, our results highlight a need to understand the dynamic nature of these microbial communities and the impact of perturbations on the associated biogeochemical cycling within oil sands pit lakes. Full article

Due to its dire impacts on marine life, public health, and socio-economic services, oil spills require an immediate response. Effective action starts with good knowledge of the ocean dynamics and circulation, from which Lagrangian methods derive key information on the dispersal pathways present in the contaminated region. However, precise assessments of the capacity of Lagrangian methods in real contamination cases remain rare and limited to large slicks spanning several hundreds of km. Here we address this knowledge gap and consider two medium-scale (tens of km wide) events of oil in contrasting conditions: an offshore case (East China Sea, 2018) and a recent near-coastal one (East Mediterranean, 2021). Our comparison between oil slicks and Lagrangian diagnostics derived from near-real-time velocity fields shows that the calculation of Lagrangian fronts is, in general, more robust to errors in the velocity fields and more informative on the dispersion pathways than the direct advection of a numerical tracer. The inclusion of the effect of wind is also found to be essential, being capable of suddenly breaking Lagrangian transport barriers. Finally, we show that a usually neglected Lagrangian quantity, the Lyapunov vector, can be exploited to predict the front drifting speed, and in turn, its future location over a few days, on the basis of near-real-time information alone. These results may be of special relevance in the context of next-generation altimetry missions that are expected to provide highly resolved and precise near-real-time velocity fields for both open ocean and coastal regions. Full article

River oil spills are generally more frequent and pose greater environmental and public health risk than coastal and offshore oil spills. However, the river oil spill research has received a negligible amount of academic attention in the past three decades, while at the same time the coastal and offshore oil spill research has expanded and evolved tremendously. This paper provides the state-of-the-art review of river oil spill modeling and summarizes the developments in the field from 1994 to present. The review has revealed that the majority of the gaps in knowledge still remain. Thus, there is a need for (i) experimental studies in order to develop and validate new models and better understand the main physicochemical processes, (ii) studies on inter-linking of the governing processes, such as hydrodynamics, advection–dispersion, and weathering processes, (iii) adaptation and validation of coastal and offshore oil spill models for applications in riverine environments, and (iv) development of river oil spill remote sensing systems and detection techniques. Finally, there is a need to more actively promote the importance of river oil spill research and modeling in the context of environmental and public health protection, which would form the basis for obtaining more research funding and thus more academic attention. Full article

Accidental oil spills not only deteriorate biodiversity but also cause immediate threats to coastal environments. This study quantitatively investigates the initial dispersion of spilled oil using the environmental fluid dynamics code (EFDC) model, loosely coupled with an endorsed oil spill model (MEDSLIK-II) accounting for time-dependent advection, diffusion, and physiochemical weathering of the surface oil slick. Focusing on local contributing factors (i.e., construction activities) to oil dispersion, the current model is applied to likely oil spills occurring at three different phases of the Songdo LNG terminal construction on a reclaimed site in South Korea. Applied phases pose detailed ship collision scenarios generated based on a proposed construction plan of the terminal. The effects of permeable revetments, required for reclamation, on the currents were also investigated and applied in subsequent oil spill modeling. For each scenario, the simulated results showed distinct patterns in the advection, dispersion, and transformation of the oil slick. Oil absorption into the coast, which causes immense damage to the coastal communities, is found to be highly dependent on the tidal currents, volume of oil spilled, and nearby construction activities. Full article