Search Results (504)

To investigate the evolution of the optothermal properties of lithium niobate with ion beam irradiation parameters, the thermal effect theory was analyzed, and ion beam irradiation technology was used to modify lithium niobate samples. The transmittance of lithium niobate crystals after ion beam irradiation and the relationship between their optothermal properties and transmittance were studied. The results show that the average surface optothermal signal of lithium niobate exhibits a significant dependence on ion beam parameters. When the ion beam voltage is 800 V, the ion beam current is 30 mA, and the irradiation time is 60 s, a distinct absorption peak is observed on the surface of lithium niobate, with an average surface optothermal signal of 5377.34 ppm, demonstrating potential for all-optical modulation. Full article

We propose a simulation-based design for a flexible color filter (FCF) using a lithium niobate metamaterial (LNM) to investigate its color filtering potential. The FCF is composed of three periodically arranged half-ellipse LN arrays on a polydimethylsiloxane (PDMS) substrate, denoted as LNM-1, LNM-2, and LNM-3. The electromagnetic responses of the FCF can be controlled by adjusting the periods of the LNMs. Our simulations predict high-quality (Q) factors in transmission spectra, ranging from 100 to 200 for LNM-1, 290 to 360 for LNM-2, and 140 to 300 for LNM-3. When the FCF is exposed to the surrounding environments with different refractive indexes, it exhibits a theoretical figure of merit (FOM) up to 900 RIU⁻¹ and a sensitivity reaching 130 nm/RIU. The electromagnetic field distributions reveal strong confinement within the LNM nanostructures, confirming an efficient light–matter interaction. These results indicate that the proposed LNM-based FCF presents a promising design concept for high-performance color sensing and filtering applications. Full article

This study explores the impact of graphene integration on lithium niobate (LiNbO₃, LN) ridge waveguides and directional couplers, focusing on coupling efficiency, polarization-dependent light absorption, and temperature sensitivity. Experimental and simulation results reveal that graphene loading significantly alters the effective mode refractive index and enhances waveguide coupling, enabling precise control over light transmission and power distribution. The temperature-dependent behavior of graphene–LN structures demonstrates strong thermal sensitivity, with notable changes in output power ratios between cross and through ports under varying temperatures. These findings highlight the potential of graphene–LN hybrid devices for compact, high-performance photonic circuits and temperature sensing applications. This study provides valuable insights into the design of advanced integrated photonic systems, paving the way for innovations in optical communication, sensing, and quantum technologies. Full article

In the field of modern optical communication, radar signal processing and optical sensors, true time delay technology, as a key means of signal processing, can achieve the accurate control of the time delay of optical signals. This study presents a novel design that integrates a 2 × 2 Multi-Mode Interference (MMI) structure with a Mach–Zehnder modulator on a silicon nitride–lithium niobate (SiN-LiNbO₃) heterogeneous integrated optical platform. This configuration enables the selective interruption of optical wave paths. The upper path passes through an ultralow-loss Archimedes’ spiral waveguide delay line made of silicon nitride, where the five spiral structures provide delays of 10 ps, 20 ps, 40 ps, 80 ps, and 160 ps, respectively. In contrast, the lower path is straight through, without introducing an additional delay. By applying an electrical voltage, the state of the SiN-LiNbO₃ switch can be altered, facilitating the switching and reconfiguration of optical paths and ultimately enabling the combination of various delay values. Simulation results demonstrate that the proposed optical true delay line achieves a discrete, adjustable delay ranging from 10 ps to 310 ps with a step size of 10 ps. The delay loss is less than 0.013 dB/ps, the response speed reaches the order of ns, and the 3 dB-EO bandwidth is broader than 67 GHz. In comparison to other optical switches optical true delay lines in terms of the parameters of delay range, minimum adjustable delay, and delay loss, the proposed optical waveguide digital adjustable true delay line, which is based on an optical switch and an Archimedes’ spiral structure, has outstanding advantages in response speed and delay loss. Full article

Thin-film lithium niobate (TFLN) electro-optic modulators serve as critical components in microwave photonic systems. To improve device performance, we developed a U-T double-layer traveling-wave electrode configuration. Using finite element analysis, we systematically simulated and optimized both modulation efficiency and radiofrequency characteristics, ultimately realizing a low half-wave voltage-length product of 1.77 V·cm, a minimal optical loss of 0.022 dB/cm, and an ultra-wide modulation bandwidth surpassing 100 GHz. Full article

As photonic integrated circuits (PICs) gain prominence in quantum communication and quantum computation, the development of efficient and stable cryogenic packaging technologies becomes paramount. This paper presents a robust and scalable cryogenic packaging method for thin-film lithium niobate (TFLN) photonic chips. The packaged fiber-to-chip interface shows a coupling efficiency of 15.7% ± 0.3%, with minimal variation of ±0.5% as the temperature cools down from 295 K to 1.5 K. Furthermore, the packaged chip exhibits outstanding stability over multiple thermal cycling, highlighting its potential for practical applications in cryogenic environments. Full article

The degenerate optical parametric oscillator (OPO) is demonstrated to generate high-power, broadband mid-infrared MgO-doped periodically poled lithium niobate (MgO:PPLN) femtosecond laser at 151 MHz, synchronously pumped by a commercial Kerr-lens mode-locked Yb:KGW oscillator at 1028 nm. The average power of the degenerate OPO centered at 2056 nm is as high as 740 mW, which is the highest output power from a reported 2 μm degenerate femtosecond OPO, pumped by a bulk solid-state laser. The full width at half maximum (FWHM) spectral bandwidth of the degenerate OPO is 87.4 nm, corresponding to a theoretical, Fourier-limited pulse duration of 51 fs. These remarkable results indicate that degenerate OPO is a great potential candidate technology for generating high-power and few-cycle femtosecond pulses around 2 μm. Such mid-infrared sources are well-suited for high harmonic generation, a pumping source for mid- to far-infrared OPO. Full article

Optically triggering the core coalescence of double-emulsion droplets remains challenging. Herein, we utilize a photovoltaic field generated by laser illumination on LiNbO₃ crystals to trigger the core coalescence in a high-throughput manner. The synergy between the interfacial pressure of the shell droplet and the internal flow induced by the photovoltaic field facilitates the core coalescence. With an increase in the core number, the illumination intensity required for the core coalescence is found to increase initially, whereas it tends to saturate at 5 × 10⁷ W/m², an intensity that does not cause a large temperature increase (<4 °C). The effective mixing of the substances contained in two core droplets after their coalescence is also verified. The proposed technique provides a precise, non-thermal and electrodeless strategy for high-throughput biochemical microreactions. Full article

In this paper, we report on the growth and characterization of high doping concentration (2.1 at%) ytterbium (Yb) doped lithium niobate (Yb:LiNbO₃) crystal. By using a slightly modified Czochralski method, we have successfully grown a usable size (2 mm × 2 mm × 30 mm) Yb:LiNbO₃ single crystal. We also conducted the energy-dispersive X-ray spectroscopy (EDS) and the X-ray diffraction (XRD) analyses, which experimentally confirm that the grown crystal is a Yb:LiNbO₃ single crystal. We also measured the absorption and emission spectra of the grown crystal. It was found out that there is a near-flat broad emission within a spectral range of 1004–1030 nm when excited at 980 nm for this high doping concentration Yb:LiNbO₃ crystal. Such a near-flat broad emission can be very useful for realizing high slope efficiency ultrafast (femtosecond) lasing in the Yb:LiNbO₃ crystal due to the low quantum defect of the Yb:LiNbO₃ crystal. We also investigated the electro-optic effect of the Yb:LiNbO₃. The experimental result confirms that the electro-optic (EO) effect of a highly doped (2.1 at%) lithium niobate crystal is close to the EO value of the pure lithium niobate. Thus, the highly doped Yb:LiNbO₃ crystal can still be an effective electrically tunable lasing medium. It can enable electrically tunable, high slope efficiency femtosecond lasing due to the combined features, including (1) a near flat broad emission spectrum at the spectral range of 1004–1030 nm, (2) a non-compromised electro-optic effect at high doping concentration Yb:LiNbO₃ crystal, and (3) a low quantum defect. Full article

Niobium-based oxides are being increasingly evaluated as materials for energy storage applications. Additionally, the use of these oxides as cathodes in aqueous electrolytes has shown promise. Based on this, the pseudocapacitive behavior of protonic niobate nanowires in an aqueous acidic electrolyte (1 M H₂SO₄) was evaluated for the first time. The material was obtained in two simple sequential steps. First, hydrothermal synthesis resulted in sodium niobate; second was ionic exchange (in two concentrations of 2 M and 0.1 M HNO₃), where the protonic niobate was obtained. The resulting protonic niobate was characterized by FEG-SEM, the results demonstrated that the morphology of the oxide was concentration-dependent in the ionic exchange step, and EDS analysis was used to validate the procedure. Using DRX, Raman spectroscopy, and FTIR analysis, the transformation of sodium niobate to protonic niobate was evidenced. The electrochemical tests demonstrated that the protonic niobate presented pseudocapacitive behavior when employed as the cathode in 1 M H₂SO₄, and the ionic exchange in 2 M HNO₃ promoted a better specific capacitance, reaching 119.8 mF·cm⁻² at a 1 mA·cm⁻² current density. Full article

With the increasing communication frequencies in 6G networks, high-speed terahertz (THz) modulation signal generation has become a critical research area. This study first proposes an on-chip high-speed THz modulation signal generation system based on lithium niobate (LN), which integrates a pair of racetrack resonator-integrated Mach–Zehnder modulators (RMZMs) with a chirped periodically poled lithium niobate (CPPLN) waveguide. The on-chip system combines near-infrared electro-optic modulation and cascaded difference-frequency generation (CDFG) for high-speed THz modulation signal generation. At 300 K, utilizing two input optical waves at frequencies of 193.55 THz and 193.14 THz, this on-chip system enables high-speed THz modulation signal generation at 0.41 THz, with a 1 Gbit/s modulation rate and a 0.25 V modulation voltage. During the simulation, when the intensity of the input optical waves is 1000 MW/cm², the generated 0.41 THz signal reaches a peak intensity of 21.24 MW/cm². Furthermore, based on theoretical analysis and subsequent simulation, the on-chip system is shown to support a maximum modulation signal generation rate of 7.75 Gbit/s. These results demonstrate the potential of the proposed on-chip system as a compact and efficient solution for high-speed THz modulation signal generation. Full article

Copper niobate (CuNb₂O₆) is an important compound due to its low cost and polymorphism, presenting monoclinic and orthorhombic phases, which leads to unique physical–chemical properties. The electrochemical performance of efficient electrocatalysts for the oxygen evolution reaction (OER) is of importance in order to produce hydrogen gas from water. In this context, this work reports the synthesis of CuNb₂O₆ particles by high-energy milling for 5 and 10 h, and subsequent thermal treatment at 900 °C for 3 h. The samples were characterized by XRD, XRF, FESEM, RAMAN, UV–Vis, and FT-IR techniques, and were applied as electrocatalysts for the OER. The samples had both monoclinic and orthorhombic crystalline phases. The band gaps were in the range of 1.92 to 2.06 eV. In the application for the OER, the particles obtained by 5 and 10 h of milling exhibited overpotentials of 476 and 347 mV vs. RHE at 10 mA cm⁻², respectively. In chronopotentiometry experiments for 15 h, the samples exhibited excellent chemical stability. The electrochemical performance of the sample milled for 10 h showed superior performance (347 mV vs. RHE) when compared with electrocatalysts of the same type, demonstrating that the methodology used to synthesize the samples is promising for energy applications. Full article

Despite significant progress, fabricating two-dimensional (2D) lithium niobate (LN)-based photonic crystal (PhC) cavities integrated with tapered and PhC waveguides remains challenging, due to structural imperfections. Notable, especially, are variations in hole radius (r) and inclination angle (°), which induce bandgap shifts and degrade quality factors (Q-factor). These fabrication errors underscore the critical need to address nanoscale tolerances. Here, we systematically investigate the impacts of key geometric parameters on optical performance and optimize a 2D LN-based cavity integrated with taper and PhC waveguide system. Using a 3D Finite-Difference Time-Domain (FDTD) and varFDTD simulations, we identify stringent fabrication thresholds. The a must exceed 0.72 µm to sustain Q > ${10}^7$; reducing a to 0.69 µm collapses Q-factors below ${10}^4$, due to under-coupled modes and bandgap misalignment, which necessitates ±0.005 µm precision. When an r < 0.22 µm weakens confinement, Q plummets to 2 × ${10}^4$ at r = 0.20 µm (±0.01 µm etching tolerance). Inclination angles < 70° induce 100× Q-factor losses, requiring ±2° alignment for symmetric modes. Air slot width (s) variations shift resonant wavelengths and require optimization in coordination with the inclination angle. By optimizing s and the inclination angle (at 70°), we achieve a record Q-factor of 6.21 ×${10}^6$, with, in addition, C-band compatibility (1502–1581 nm). This work establishes rigorous design–fabrication guidelines, demonstrating the potential for LN-based photonic devices with high nano-fabrication robustness. Full article

A 90° optical hybrid employing an MMI coupler was fabricated on a thin-film lithium niobate (TFLN) platform that can be used for integrated coherent transceivers. The fabricated 90° optical hybrid exhibited a CMRR greater than 20 dB, a phase error below ±7.5°, and an excess loss less than 1.8 dB (including contributions from the 90° hybrid, a 1 × 2 MMI coupler, and an optical delay line, after subtracting the losses from the coupler and delay line, the 90° optical hybrid introduced less than 0.9 dB of loss) over the C-band with a compact footprint of 13.8 × 250 μm², facilitating the future development of high-bandwidth optical coherent transceivers heterogeneously integrated on TFLN. Full article

Based on the B-site modification strategy, excellent energy storage properties were achieved in this work by substituting Nb with Ta of the same valence in niobate-based glass ceramics. Ta substitution was found to lead to the transformation of crystal structures, and the space point group evolved from the non-centrosymmetric P4bm to the centrosymmetric P4/mbm, resulting in a transition from relaxor ferroelectric to paraelectric glass ceramics. Furthermore, the addition of Ta led to a significant decrease in grain size and interfacial activation energy, as well as an increase in the optical band gap, resulting in a dramatic increase in BDS from 800 kV/cm to 1300 kV/cm. The KBSN-4.0mol%Ta₂O₅ glass ceramic exhibited optimal energy storage properties, including a discharge energy density of ~5.62 J/cm³ and a superfast discharge rate of ~9.7 ns, resulting in an ultrahigh discharge power density of about ~1296.9 MW/cm³ at 1300 kV/cm. Furthermore, this KBSN-Ta glass ceramic also displayed good thermal stability over a temperature range of 20–120 °C, with the W_d decreasing by 9.0% at 600 kV/cm. B-site modification engineering in glass ceramics has proved to be an important way to effectively optimize energy storage performance. Full article