Search Results (25,497)

In the present paper, the interaction between metal oxide nanoparticles and carbon materials was studied, and the results showed a synergetic effect, leading to an improvement in the properties of the obtained hybrid composites. The In₂O₃ NPs were prepared by the precipitation method and thermal treatment at 550 °C. The composites were obtained using an ex situ method, by mixing the In₂O₃ NPs with reduced oxide graphene (rGO) in a ratio of 10:1. The structural, morphological, and chemical composition studies of the In₂O₃ NPs and In₂O₃-rGO composites were investigates by FTIR and EDX spectroscopy, SEM microscopy, and XRD analysis. These techniques have highlighted the obtaining of In₂O₃ of high purity, and crystallinity, with the mean particle size in the range of 8–25 nm, but also, the dispersion of In₂O₃ NPs onto rGO sheets. We examined the influence of the In₂O₃ nanostructure morphology and In₂O₃-rGO composites on the electrochemical properties using cyclic voltammetry. The surface properties of the In₂O₃ and composite films were studied by contact angles, which indicate the maintenance of the hydrophilic nature. The obtained results establish the synergy between the main components to form In₂O₃-rGO, which can be used for the development of biosensors to enhance the device performance. Full article

Controlling dry matter intake (DMI) is one strategy to reduce feed costs and increase efficiency. Including fat at a high concentrate level can increase the energy density of diets fed to ruminants, thus reducing DMI further. Therefore, the objective of this study was to evaluate the effects on fermentation and nutrient digestion of including different fat sources when high-concentrate diets with high-fat inclusion are used under simulating precision feeding in continuous culture. We hypothesized that incorporating different fat sources into the aforementioned program can improve nutrient utilization without affecting rumen fermentation. Four treatments were randomly assigned to eight continuous cultures in a randomized complete block design and ran for two periods of 10 d. Diets included a high concentrate level (HC; 65% DM) with high-fat inclusion starting with a 3% basal level of fat in the diet as the control (0% added fat; CON) and 9% fat in the diet (6% added poultry fat, PF; 6% added coconut oil, CO; and (6% added soybean oil, SO). Data were analyzed using the MIXED procedure of SAS with repeated measures. The DM, OM, NDF, and ADF digestibility coefficients (dCs) were higher for PF and CO, followed by SO and then CON. Starch and FA dCs were higher for different fat sources than for the CON. The total VFA concentration was higher for CON. There was a reduction in acetate and propionate with different fat sources. The mean culture pH and NH₃N were the highest for CO, followed by PF, then SO, and CON. The protozoa population was higher for CON than for the other fat treatments, followed by CO, PF, and SO. These results suggest that simulated precision feeding using continuous culture fermenters with high-concentrate diets up to 65% and high fat up to 6% can improve nutrient digestion approximately to 15% with changes in fermentation rate and profiles. Full article

Background: Outdoor and household PM_2.5 are established risk factors for chronic disease and early mortality. In China, high levels of outdoor PM_2.5 and solid fuel use for cooking and heating, especially in winter, pose large health risks to the country’s aging population. Hand grip strength is a validated biomarker of functional aging and strong predictor of disability and mortality in older adults. We investigated the effects of wintertime household and outdoor PM_2.5 on maximum grip strength in a rural cohort in Beijing. Methods: We analyzed data from 877 adults (mean age: 62 y) residing in 50 rural villages over three winter seasons (2018–2019, 2019–2020, and 2021–2022). Outdoor PM_2.5 was continuously measured in all villages, and household (indoor) PM_2.5 was monitored for at least two months in a randomly selected ~30% subsample of homes. Missing data were handled using multiple imputation. We applied multivariable mixed effects regression models to estimate within- and between-individual effects of PM_2.5 on grip strength, adjusting for demographic, behavioral, and health-related covariates. Results: Wintertime household and outdoor PM_2.5 concentrations ranged from 3 to 431 μg/m³ (mean = 80 μg/m³) and 8 to 100 μg/m³ (mean = 49 μg/m³), respectively. The effect of a 10 μg/m³ within-individual increase in household and outdoor PM_2.5 on maximum grip strength was 0.06 kg (95%CI: −0.01, 0.12 kg) and 1.51 kg (95%CI: 1.35, 1.68 kg), respectively. The household PM_2.5 effect attenuated after adjusting for outdoor PM_2.5, while outdoor PM_2.5 effects remained robust across sensitivity analyses. We found little evidence of between-individual effects. Conclusions: We did not find strong evidence of an adverse effect of household PM_2.5 on grip strength. The unexpected positive effects of outdoor PM_2.5 on grip strength may reflect transient physiological changes following short-term exposure. However, these findings should not be interpreted as evidence of protective effects of air pollution on aging. Rather, they highlight the complexity of air pollution’s health impacts and the value of longitudinal data in capturing time-sensitive effects. Further research is needed to better understand these patterns and their implications in high-exposure settings. Full article

Addressing the lack of dynamic monitoring methods for assessing the combined toxicity of mixed pesticides, this study developed a fluorescent probe, CCHL, specifically responsive to leucine aminopeptidase (LAP). The probe utilized Cy7-COOH (CCH) as the fluorophore, with fluorescence recovery triggered by enzymatic hydrolysis. Spectral characterization confirmed a linear response between the probe and LAP activity within a concentration range of 0–0.9 μg/mL (R² = 0.992), along with excellent selectivity in the presence of coexisting biomolecules. Application experiments demonstrated that the combination of chlorfenapyr and beta-cyfluthrin significantly reduced LAP activity, revealing a notable antagonistic effect. The novel sensing strategy developed here provides a real-time, visualized analytical tool for evaluating the combined effects of mixed pollutants, demonstrating significant potential for environmental toxicology monitoring. Full article

Anthropogenic disturbances interact with wildfire, altering successional dynamics across North America’s boreal forest. Linear disturbances, including seismic lines used for oil and gas exploration, dissect forests, while wildfire is a fundamental agent of forest succession. However, little is known about early succession dynamics after both seismic line creation and wildfire, especially across transitions from uplands to peatlands. To address this, we characterized and compared regeneration and recruitment after individual and successive disturbances in peatland, transitional, and mesic upland forests across the oil sands region of Alberta, Canada. We used non-metric multidimensional scaling to compare composition and mixed-effects generalized linear models to compare densities of trees and tall shrubs 10 to 24 years after disturbance. Compositionally, regeneration was similar within forest types and between transitional and peatland forests, while patterns in recruitment were more influenced by past disturbances. Overall, we found evidence of dominant, additive, and interactive effects on early successional patterns within linear disturbances in boreal forests. In transitional and peatland forests, disturbances influenced tree and tall shrub regeneration and recruitment in complex ways. Early successional dynamics after disturbance influence forest structure and composition and are vital to understanding recovery in boreal forests, especially across boreal forest transitions. Full article

Urban tree planting on single-family-home lots represents a critical yet underexplored component of municipal greening strategies. This study examines residents’ perceptions of tree planting in Westpointe, a diverse neighborhood in Salt Lake City, Utah, as part of the city’s Reimagine Nature Public Lands Master Plan development effort. Through a mixed-methods approach combining qualitative interviews (n = 24) and a tree signup initiative extended to 86 residents, with 51 participating, this research explores the complex interplay of demographic, economic, social, and infrastructure factors influencing residents’ willingness to plant trees on single-family-home lots. The findings reveal significant variations based on gender, with women expressing more positive environmental and aesthetic motivations, while men focused on practical concerns including maintenance and property damage. Age emerged as another critical factor, with older adults (65+) expressing concerns about long-term maintenance capabilities, while younger families (25–44) demonstrated future-oriented thinking about shade and property values. Property characteristics, particularly yard size, significantly influenced receptiveness, with owners of larger yards (>5000 sq ft) showing greater willingness compared to those with smaller properties, who cited space constraints. Additional barriers, i.e., maintenance, financial, and knowledge barriers, included irrigation costs, lack of horticultural knowledge, pest concerns, and proximity to underground utilities. Geographic analysis revealed that Spanish-speaking social networks were particularly effective in promoting tree planting. The study contributes to urban forestry literature by providing nuanced insights into single-family homeowners’ tree-planting decisions and offers targeted recommendations for municipal programs. These include gender-specific outreach strategies, age-appropriate support services, sliding-scale subsidy programs based on property size, and comprehensive education initiatives. The findings inform evidence-based approaches to increase urban canopy coverage through private property plantings, ultimately supporting climate resilience and environmental justice goals in diverse urban neighborhoods. Full article

This paper explores backchannels, short listener responses such as “mhm”, which play an important role in managing turn-taking and grounding in spontaneous conversation. While previous work has largely focused on their acoustic cues or listener’s behavior in isolation, this study investigates if and when backchannels occur by taking into account the prosodic characteristics together with the communicative functions of the interlocutor’s speech preceding backchannels. Using a corpus of spontaneous dyadic conversations in Austrian German annotated with continuous turn-taking labels, we analyze the distribution of backchannels across different turn-taking contexts and examine which acoustic features affect their occurrence and timing by means of Conditional Inference Trees and linear mixed-effects regression models. Our findings show that the turn-taking function of the interlocutor’s utterance is a significant predictor of whether a backchannel occurs or not: Backchannels tend to occur most frequently after longer and syntactically complete utterances by the interlocutor. Moreover, prosodic features such as utterance duration, articulation rate variability and rising or falling intensity affect the timing of listener responses, with significant differences across different turn-taking functions. These results highlight the value of using continuous turn-taking annotations to investigate conversational dynamics and demonstrate how turn-taking function and prosody jointly shape backchannel behavior in spontaneous conversation. Full article

This study examines the impact of renewable energy, economic growth, and trade openness on CO₂ emissions in the EU-15 countries over the period 1980–2022, employing the ARDL modeling framework. In addition, a panel PMG-ARDL model is employed as a robustness check. The analysis identifies cointegration among the variables in 11 out of the 15 countries studied. Economic growth is found to increase CO₂ emissions, highlighting the ongoing challenge of aligning economic expansion with environmental objectives. The estimated coefficients for economic growth range from 0.43 to 5.70, depending on the country. Renewable energy significantly reduces emissions, highlighting its critical role in achieving sustainability (the corresponding coefficient moves in the range −0.13 to −0.96). Trade openness generally shows a neutral impact on emissions across most cases. Overall, renewable energy contributes to reducing CO₂ emissions, whereas the effects of economic growth and trade openness remain mixed and country-specific. These findings highlight the need to promote cleaner technologies, enhance energy efficiency, and ensure broader access to environmentally friendly energy sources. Full article

Monitoring salt marsh vegetation in the Yellow River Delta (YRD) wetland is the basis of wetland research, which is of great significance for the further protection and restoration of wetland ecological functions. In the existing remote sensing technologies for wetland salt marsh vegetation classification, the object-oriented classification method effectively produces landscape patches similar to wetland vegetation and improves the spatial consistency and accuracy of the classification. However, the vegetation classes of the YRD are mixed with uneven distribution, irregular texture, and significant color variation. In order to solve the problem, this study proposes a fine-scale classification of dominant vegetation communities using color-enhanced aerial images. The color information is used to extract the color features of the image. Various features including spectral features, texture features and vegetation features are extracted from the image objects and used as inputs for four machine learning classifiers: random forest (RF), support vector machine (SVM), k-nearest neighbor (KNN) and maximum likelihood (MLC). The results showed that the accuracy of the four classifiers in classifying vegetation communities was significantly improved by adding color features. RF had the highest OA and Kappa coefficients of 96.69% and 0.9603. This shows that the classification method based on color enhancement can effectively distinguish between vegetation and non-vegetation and extract each vegetation type, which provides an effective technical route for wetland vegetation classification in aerial imagery. Full article

In turbine blade environments, the combination of blade curvature and accelerating flow gives rise to streamwise pressure gradients (SPGs), which substantially impact coolant–mainstream interactions. This study investigates the effect of SPGs on film cooling performance using Large Eddy Simulation (LES) for a shaped cooling hole at a density ratio of $\mathrm{DR}=1.5$ under two blowing ratios: $M=0.5$ and $M=1.6$. Both favorable pressure gradient (FPG) and zero pressure gradient (ZPG) conditions are examined. LES predictions are validated against experimental data in the high blowing ratio case, confirming the accuracy of the numerical method. Comparative analysis of the time-averaged flow fields indicates that, at $M=1.6$, FPG enhances wall attachment of the coolant jet, reduces boundary layer thickness, and suppresses vertical dispersion. Counter-rotating vortex pairs (CVRPs) are also compressed in this process, leading to improved downstream cooling. At $M=0.5$, however, the ZPG promotes greater lateral coolant spread near the hole exit, resulting in superior near-field cooling performance. Instantaneous flow structures are also analyzed to further explore the unsteady dynamics governing film cooling. The Q criterion exposes the formation and evolution of coherent vortices, including hairpin vortices, shear-layer vortices, and horseshoe vortices. Compared to ZPG, the FPG case exhibits a greater number of downstream hairpin vortices identified by density gradient, and this effect is particularly pronounced at the lower blowing ratio. The shear layer instability is evaluated using the local gradient $Ri$ number, revealing widespread Kelvin–Helmholtz instability near the jet interface. In addition, Fast Fourier Transform (FFT) analysis shows that FPG shifts disturbance energy to lower frequencies with higher amplitudes, indicating enhanced turbulent dissipation and intensified coolant mixing at a low blowing ratio. Full article

To achieve energy conservation, emission reduction, and green low-carbon goals for gas storage facilities, it is crucial to efficiently recover and utilize waste heat during gas injection while maintaining natural gas cooling rates. However, existing sensible and latent heat storage technologies cannot sustain long-term thermal storage or seasonal utilization of waste heat. Thermal chemical energy storage, with its high energy density and low thermal loss during prolonged storage, offers an effective solution for efficient recovery and long-term storage of waste heat in gas storage facilities. This study proposes a novel heat recovery method by combining a moving bed with mixed hydrated salts (CaCl₂·6H₂O and MgSO₄·7H₂O). By constructing both small-scale and full-scale three-dimensional models in Fluent, which couple the desorption and endothermic processes of hydrated salts, the study analyzes the temperature and flow fields within the moving bed during heat exchange, thereby verifying the feasibility of this approach. Furthermore, the effects of key parameters, including the inlet temperatures of hydrated salt particles and natural gas, flow velocity, and mass flow ratio on critical performance indicators such as the outlet temperatures of natural gas and hydrated salts, the overall heat transfer coefficient, the waste heat recovery efficiency, and the mass fraction of hydrated salt desorption are systematically investigated. The results indicate that in the small-scale model (1164 × 312 × 49 mm) the outlet temperatures of natural gas and mixed hydrated salts are 79.8 °C and 49.3 °C, respectively, with a waste heat recovery efficiency of only 33.6%. This low recovery rate is primarily due to the insufficient residence time of high-velocity natural gas (10.5 m·s⁻¹) and hydrated salt particles (2 mm·s⁻¹) in the moving bed, which limits heat exchange efficiency. In contrast, the full-scale moving bed (3000 × 1500 × 90 mm) not only accounts for variations in natural gas inlet temperature during the three-stage compression process but also allows for optimized operational adjustments. These optimizations ensure a natural gas outlet temperature of 41.3 °C, a hydrated salt outlet temperature of 82.5 °C, a significantly improved waste heat recovery efficiency of 94.2%, and a hydrated salt desorption mass fraction of 69.2%. This configuration enhances the safety of the gas injection system while maximizing both natural gas waste heat recovery and the efficient utilization of mixed hydrated salts. These findings provide essential theoretical guidance and data support for the effective recovery and seasonal utilization of waste heat in gas storage reservoirs. Full article

Background: The columellar strut and septal extension graft are two common techniques in modern rhinoplasty to enhance nasal tip projection and rotation, though their effectiveness varies. While numerous studies examine each technique individually, there is limited research directly comparing the two methods, especially regarding long-term outcomes. This study aims to clarify the roles of these grafting techniques and possibly compare their long-term effectiveness in reconstructing caudal nasal support structures with available evidence in the literature. Methods: A comparative study was conducted on 87 patients with structural and anatomical nasal defects who underwent rhinoplasty using either a columellar strut or a septal extension graft. Outcome variables included tip projection, tip rotation, and nasal length. Patients were evaluated pre-operatively and at intervals of 1 month, 6 months, 1 year, and 4 years post-operatively. A critical discussion was also conducted to define the roles of the two nasal grafts and assess their long-term effectiveness. Results: Although over 4000 publications address the use of grafts in rhinoplasty, only a few compare the two grafting techniques directly. Our analysis revealed mixed perspectives on the columellar strut: some argue it is unnecessary, while others suggest it is not superior to septo-columellar suturing techniques. Conversely, several studies highlight the septal extension graft’s importance in reconstructing nasal support, with some evidence indicating it outperforms the columellar strut in maintaining long-term structure. Conclusions: Both grafts contribute to increased nasal projection; however, the septal extension graft provides more stable, long-term tip position support. The columellar strut appears non-essential for enhancing tip projection and should be used selectively, as it increases projection only when specifically designed for that purpose by the surgeon. Full article

Mixing hydrogen into natural gas pipelines for transportation is an effective solution to the imbalance between the supply and demand of hydrogen energy. Studying the influence of bent pipes in hydrogen-mixed natural gas explosion accidents can enhance the safety of hydrogen energy storage and transportation. Through experiments and LES, the influence of pipe spacing configuration on the vented explosion of this mixed gas in pipes with a large length-to-diameter ratio was analyzed. The maximum explosion pressure (Pmax) of the straight pipe is 21.7 kPa and the maximum pressure rise rate ((dp/dt)max) is 1.8 MPa/s. After adding the double elbow, Pmax increased to 65.2 kPa and (dp/dt)max increased to 3.7 MPa/s. By increasing the distance (D1) from bent pipe-1 to the ignition source, the flame shape changes from “finger-shaped” to “concave-shaped” to “wrinkled-shaped.” When D1 is at its minimum, the explosion reaction is the most intense. However, as D1 increases, each characteristic parameter decreases linearly and the flame propagation speed significantly reduces, the flame area decays more severely, and the flame acceleration effect is also suppressed. When the distance between the two bent pipes (D2) was gradually increased, the flame transformed from “finger-shaped” to “tongue-shaped” to “wrinkled-shaped”. The flame area curve exhibited a unique evolutionary process of “hitting bottom” to “rebounding” to “large-scale flame backflow”. This paper explores the development process of various characteristic parameters, which is of great reference value for preventing explosions in hydrogen-blended natural gas pipelines in underground pipe galleries. Full article

The concept of governance has gained increasing attention across various fields of study. However, its application within the specific context of educational policies, particularly within compulsory public education, remains fragmented and underexplored. To answer the questions “How is governance conceptualized in the context of the compulsory public education system?” and “What contributions to future research emerge from this review?”, 32 peer-reviewed articles published in open-access journals between 2019 and 2023 were extracted from the Web of Science, Scopus, and ERIC databases and selected following PRISMA guidelines. Results from this systematic literature review analysis suggest a sustained yet moderate interest in the field, as evidenced by the reviewed publications, different theoretical and conceptual approaches, and research themes that illustrate different aspects of educational systems. Research gaps include the lack of a consolidated and integrated theoretical–conceptual framework on educational governance; the under-representation of specific actors, contexts, and points of view about how educational policies intentions are interpreted and enacted; insufficient critical analyses of, among others, educational leadership, digital transformation, and non-state actors’ influence in educational governance; and limited discussion of governance’s effects on educational justice, equity and quality. The main limitations relate to geographic, linguistic, and cultural biases of the analyzed studies, the exclusion of non-open-access articles, and the predominance of qualitative methodological approaches, which restrict generalizability. To address these challenges, future research should follow the adoption of interdisciplinary approaches, longitudinal and context-sensitive studies, and the use of mixed methodologies. These findings could contribute to a more informed discussion, avoiding reductionist interpretations and more open and critical perspectives on how educational governance transcends organizational and technical structures by incorporating political, ethical, and contextual dimensions that challenge the quality of educational systems. Full article

Intensified by climate change and anthropogenic activities, flood disasters necessitate rapid and accurate mapping for effective disaster management. This study develops an integrated framework leveraging synthetic aperture radar (SAR) and cloud computing to enhance flood monitoring, with a focus on a 2024 extreme rainfall event in Liaoning Province, China. Utilizing the Google Earth Engine (GEE) platform, we combine three complementary techniques: (1) Otsu automatic thresholding, for efficient extraction of surface water extent from Sentinel-1 GRD time series (154 scenes, January–October 2024), achieving processing times under 2 min with >85% open-water accuracy; (2) random forest (RF) classification, integrating multi-source features (SAR backscatter, terrain parameters from 30 m SRTM DEM, NDVI phenology) to distinguish permanent water bodies, flooded farmland, and urban areas, attaining an overall accuracy of 92.7%; and (3) Fuzzy C-Means (FCM) clustering, incorporating backscatter ratio and topographic constraints to resolve transitional “mixed-pixel” ambiguities in flood boundaries. The RF-FCM synergy effectively mapped submerged agricultural land and urban spill zones, while the Otsu-derived flood frequency highlighted high-risk corridors (recurrence > 10%) along the riverine zones and reservoir. This multi-algorithm approach provides a scalable, high-resolution (10 m) solution for near-real-time flood assessment, supporting emergency response and sustainable water resource management in affected basins. Full article