Search Results (19)

In the coal industry, miner safety is increasingly challenged by growing mining depths and complex environments. The failure to wear Personal Protective Equipment (PPE) is a frequent issue in accidents, threatening lives and reducing operational efficiency. Additionally, existing PPE datasets are inadequate for model training due to their small size, lack of diversity, and poor labeling. Current methods often struggle with the complexity of multi-scenario and multi-type PPE detection, especially under varying environmental conditions and with limited training data. In this paper, we propose a novel minersPPE dataset and an improved algorithm based on YOLOv8, enhanced with Dilated-CBAM (Dilated Convolutional Block Attention Module) and DBB (Diverse Branch Block) Detection Block (YOLOv8-DCDB), to address these challenges. The minersPPE dataset constructed in this paper includes 14 categories of protective equipment needed for various body parts of miners. To improve detection performance under complex lighting conditions and with varying PPE features, the algorithm incorporates the Dilated-CBAM module. Additionally, a multi-branch structured detection head is employed to effectively capture multi-scale features, especially enhancing the detection of small targets. To mitigate the class imbalance issue caused by the long-tail distribution in the dataset, we adopt a K-fold cross-validation strategy, optimizing the detection results. Compared to standard YOLOv8-based models, experiments on the minersPPE dataset demonstrate an 18.9% improvement in detection precision, verifying the effectiveness of the proposed YOLOv8-DCDB model in multi-scenario, multi-type PPE detection tasks. Full article

This study aims to report the dietary and daily management, clinical signs, complementary exams, and pathological findings related to an acute and fatal case of gastric dilatation and volvulus (GDV) in a captive Linnaeus’s two-toed sloth (Choloepus didactylus) in the Amazon Biome. An adult female sloth, rescued after being electrocuted, was housed at the Wildlife Section of the Veterinary Hospital (WSVH) of the Institute of Veterinary Medicine (IVM) at the Universidade Federal do Pará (UFPA). It was fed a diverse diet that included animal protein, fruits, vegetables, and greens, with vitamin and mineral supplementation. After five years, the sloth was found in its enclosure hyporesponsive, dehydrated, hypothermic, and hyperventilating, with an abdominal dilation of firm consistency. During emergency care, the animal died. Fecal samples collected two days before death were positive only for Clostridium perfringens type A. Necropsy findings included dilatation of the squamous gastric compartment due to gas accumulation, with necrotic and hemorrhagic mucosa, a 180–270° volvulus obstructing the gastroesophageal region, and intestinal mucosal hyperemia. Histopathology revealed marked congestion with hemorrhage and gastric mucosal necrosis, along with tertiary lymphoid follicles in the submucosa. To the authors’ knowledge, this is the first report of GDV in a sloth in Brazil. Further research is needed to develop appropriate approaches to GDV in captive sloths. Full article

At present, many offshore oil fields are facing problems, such as pollution-induced near-well zone blockage, poor inter-well connectivity, and strong vertical heterogeneity, which lead to insufficient formation energy and low production in the middle and late stages of development. It is necessary to develop a new technology to overcome these issues. In this regard, water-injection-induced dilation technology, which was already proven to have positive effects on loose sandstone reservoirs, was controversially applied to an offshore low-permeability reservoir. To investigate whether the water-injection-induced dilation technology is suitable, experiments were conducted to analyze the dilation potential of offshore low-permeability sandstone reservoirs, namely, X-ray diffraction, laser particle size analysis, physical simulation, computed tomography scan, and electron microscope scanning experiments. The X-ray diffraction experiments showed that the samples had more than 80% non-clay mineral content and a high brittleness index, which meant more complex microfractures under water injection. Particle size analysis experiments revealed that the particle size was mainly between 10 μm and 100 μm, and thus belonged to coarse silty sand. According to the sorting grade, the sample particle size distribution was uniform and the reservoir was more prone to dilation. The true triaxial physical simulation showed that a volumetric dilation zone occurred around the wellbore, where complicated microfractures occurred. This paper provides adequate evidence and mechanisms of dilation potential for an offshore low-permeability sandstone reservoir. Full article

Wood surface broken defects seriously damage the structure of wooden products, these defects have to be detected and eliminated. However, current defect detection methods based on machine vision have difficulty distinguishing the interference, similar to the broken defects, such as stains and mineral lines, and can result in frequent false detections. To address this issue, a multi-source data fusion network based on U-Net is proposed for wood broken defect detection, combining image and depth data, to suppress the interference and achieve complete segmentation of the defects. To efficiently extract various semantic information of defects, an improved ResNet34 is designed to, respectively, generate multi-level features of the image and depth data, in which the depthwise separable convolution (DSC) and dilated convolution (DC) are introduced to decrease the computational expense and feature redundancy. To take full advantages of two types of data, an adaptive interacting fusion module (AIF) is designed to adaptively integrate them, thereby generating accurate feature representation of the broken defects. The experiments demonstrate that the multi-source data fusion network can effectively improve the detection accuracy of wood broken defects and reduce the false detections of interference, such as stains and mineral lines. Full article

Unlike established coating formulations, functional particulate coatings often demand the omission of polymer dispersant so as to retain surface functionality. This results in heterogeneous complex rheology. We take an example from a novel development for an NO_x mitigation surface flow filter system, in which ground calcium carbonate (GCC), applied in a coating, reacts with NO₂ releasing CO₂. Inclusion of mesoporous ancillary mineral acts to capture the CO₂. The coating is applied as droplets to maximize gas-contact dynamic by forming a pixelated 2D array using a coating device consisting of protruding pins, which are loaded by submersion in the aqueous coating color such that the adhering droplets are transferred onto the substrate. The flow is driven by surface meniscus wetting causing lateral spread and bulk pore permeation. Filamentation occurs during the retraction of the pins. Stress-related viscoelastic and induced dilatancy in the suspension containing the ancillary mesoporous mineral disrupts processability. Adopting shear, oscillation and extensional rheometric methods, we show that the inclusion of an ancillary mineral that alone absorbs water, e.g., perlite (a naturally occurring porous volcanic glass), is rheologically preferable to one that in addition to absorbing water also immobilizes it on the mineral surface, e.g., sepiolite. When including micro-nanofibrillated cellulose (MNFC), critical for maintaining moisture to support NO₂ sorption, it is observed that it acts also as a flow modifier, enabling uniform coating transfer to be achieved, thus eliminating any possible detrimental effect on mineral surface activity by avoiding the use of soluble polymeric dispersant. Full article

Mercury’s peculiar orbit around the Sun (3:2 spin–orbit resonance) and lack of atmosphere result in one the widest temperature ranges experienced at the surface of a planetary body in the solar system. Temperature variations affect the physical and, therefore, spectral properties of minerals to varying degrees; thus, it is crucial to study them in the context of the upcoming arrival of the BepiColombo spacecraft in Mercury orbit in the fall of 2025. In this work, we heated and cooled analog materials (plagioclase and volcanic glasses) at temperatures representative of the hermean surface. With our experimental setup, we could measure near-infrared (1.0–3.5 $\mathsf{\mu }$m) and thermal infrared (2.0–14.3 $\mathsf{\mu }$m) reflectance spectra of our analogs at various temperatures during a heating (25–400 ${}^{\circ }$C) or cooling cycle (−125–25 ${}^{\circ }$C), allowing us to follow the evolution of the spectral properties of minerals. We also collected reflectance spectra in the visible domain (0.47–14.3 $\mathsf{\mu }$m) before and after heating. In the visible spectra, we identified irreversible changes in the spectral slope (reddening) and the reflectance (darkening or brightening) that are possibly associated with oxidation, whereas the temperature had reversible effects (e.g., band shifts of from ten to a hundred nanometers towards greater wavelengths) on the infrared spectral features of our samples. These reversible changes are likely caused by the crystal lattice dilatation during heating. Finally, we took advantage of the water and ice present on/in our samples to study the different components of the absorption band at 3.0 $\mathsf{\mu }$m when varying temperatures, which may be useful as a complement to future observations of the north pole of Mercury. The wavelength ranges covered by our measurements are of interest for the SIMBIO-SYS and MERTIS instruments, which will map the mineralogy of Mercury’s surface from spring 2026, and for which we selected useful spectral parameters that are proxies of surface temperature variations. Full article

With the depletion of shallow mineral resources, the sustainable development and utilization of deep mineral resources will become a normal activity. As a type of clean energy to promote sustainable development, gas in deep coal seams has attracted wide attention. A better understanding of the permeability evolution induced by mining disturbance and the geological environment is of great importance for underground coal exploitation and gas extraction. In order to analyze the evolution of the mechanical properties and permeability of deep coal that are induced by high ground temperature, coal of the Pingdingshan Coal Mine has been investigated, and the seepage tests were carried out by keeping the confining pressure constant and loading and unloading axial stress under different temperature conditions. The effect of temperature on the peak strength and the initial elastic modulus of coal samples is analyzed. The evolution of permeability, which is estimated with the transient pulse method, based on fractional derivative and fracture connectivity, are discussed by establishing the relationship between fracture connectivity and fractional derivative. Meanwhile, the damage variable that is caused by stress and temperature is introduced and the contribution of thermal damage on coal damage accumulation is discussed. A theoretical model is proposed regarding permeability evolution with temperature and stress based on the Cui–Bustin model, which is verified by experimental data. It has been found that the strength and elastic modulus of deep coal decrease nonlinearly with increasing temperature, which demonstrates that temperature has a weakening effect on the mechanical properties of coal. The fracture connectivity and permeability evolution trends with axial strain are consistent under different temperatures, which decrease slowly in the compaction and linear elastic stages, reach the minimum at the volumetric dilation point, gradually increase in the yield stage, then have a sharp increasing trend in the post-peak stage and, finally, become steady in the residual stage. The damage induced by temperature increases with rising temperatures under different external load conditions. When the external load increases gradually, the thermal damage still accumulates, but the thermal damage variable ratio decreases. The proposed permeability model considering temperature and stress can describe the trend of the experimental data. With axial stress increasing, the influence of temperature on permeability decreases, and its leading effect is mainly reflected in the compaction stage and the linear elastic stage of coal. Full article

The objective of this study was to evaluate the biocompatibility of trimethylsilane (TMS) plasma nanocoatings modified with NH₃/O₂ (2:1 molar ratio) plasma post-treatment onto cobalt chromium (CoCr) L605 alloy coupons and stents for cardiovascular stent applications. Biocompatibility of plasma nanocoatings was evaluated by coating adhesion, corrosion behavior, ion releasing, cytotoxicity, and cell proliferation. Surface chemistry and wettability were studied to understand effects of surface properties on biocompatibility. Results show that NH₃/O₂ post-treated TMS plasma nanocoatings are hydrophilic with water contact angle of 48.5° and have a typical surface composition of O (39.39 at.%), Si (31.92 at.%), C (24.12 at.%), and N (2.77 at.%). The plasma nanocoatings were conformal to substrate surface topography and had excellent adhesion to the alloy substrates, as assessed by tape test (ASTM D3359), and showed no cracking or peeling off L605 stent surfaces after dilation. The plasma nanocoatings also improve the corrosion resistance of CoCr L605 alloy by increasing corrosion potential and decreasing corrosion rates with no pitting corrosion and no mineral adsorption layer. Ion releasing test revealed that Co, Cr, and Ni ion concentrations were reduced by 64–79%, 67–69%, and 57–72%, respectively, in the plasma-nanocoated L605 samples as compared to uncoated L605 control samples. The plasma nanocoatings showed no sign of cytotoxicity from the test results according to ISO 10993-05 and 10993-12. Seven-day cell culture demonstrated that, in comparison with the uncoated L605 control surfaces, the plasma nanocoating surfaces showed 62 ± 7.3% decrease in porcine coronary artery smooth muscle cells (PCASMCs) density and had comparable density of porcine coronary artery endothelial cells (PCAECs). These results suggest that TMS plasma nanocoatings with NH₃/O₂ plasma post-treatment possess the desired biocompatibility for stent applications and support the hypothesis that nanocoated stents could be very effective for in-stent restenosis prevention. Full article

The Dayingezhuang orogenic gold deposit, located in the northwestern Jiaodong Peninsula, is hosted by the Zhaoping detachment fault, but the paleostress regime during the mineralization period remains poorly understood. In this study, a series of numerical modeling experiments with variable stress conditions were carried out using FLAC3D software to determine the orientation of paleostress and the fluid migration processes during the ore-forming period. The results show that the simple compression or tension stress model led to fluid downward or upward flow along the fault, respectively, accompanying the expansion deformation near the hanging wall or footwall of the Zhaoping fault, which is inconsistent with the known NE oblique mineralization distribution at Dayingezhuang. The reverse and strike-slip model shows that the shear stress was distributed in the gentle dip sites of the fault, and the expansion space occurred in the geometric depression sites of the fault, which is also inconsistent with the known mineralization distribution. The normal and strike-slip model shows that shear stress was distributed in the sites where the fault geometry transforms from steep to gentle. In addition, the expansion deformation zones appeared at sites with dip angles of 35~60° in the footwall and extended along with the NE-trending distribution from shallow to deep levels. The numerical results are quite consistent with the known mineralization, suggesting that the fault movement during the mineralization stage is a combination of the local strike-slip and the NW–SE extension in the Dayingezhuang deposit. Under this stress regime (σ₁ NE–SW, σ₂ vertical, σ₃ NW–SE), the NE dilation zones associated with fault deformation served as channels for the ore-forming fluid migration. Based on the numerical modeling results, the deeper NE levels of the No. 2 orebody in the Dayingezhuang deposit have good prospecting potential. Thus, our study not only highlights that gold mineralization at Dayingezhuang is essentially controlled by the detachment fault geometry associated with certain stress directions but also demonstrates that numerical modeling is a robust tool for identifying potential mineralization. Full article

This review paper summarizes the recent and past experimental findings to evaluate the damage characteristics of carbonate rocks subjected to thermal treatment (20–1500 °C). The outcomes of published studies show that the degree of thermal damage in the post-heated carbonate rocks is attributed to their rock fabric, microstructural patterns, mineral composition, texture, grain cementations, particle orientations, and grain contact surface area. The expressive variations in the engineering properties of these rocks subjected to the temperature (>500 °C) are the results of chemical processes (hydration, dehydration, deionization, melting, mineral phase transformation, etc.), intercrystalline and intergranular thermal cracking, the separation between cemented particles, removal of bonding agents, and internal defects. Thermally deteriorated carbonate rocks experience a significant reduction in their fracture toughness, static–dynamic strength, static–dynamic elastic moduli, wave velocities, and thermal transport properties, whereas their porous network properties appreciate with the temperature. The stress–strain curves illustrate that post-heated carbonate rocks show brittleness below a temperature of 400 °C, brittle–ductile transformation at a temperature range of 400 to 500 °C, and ductile behavior beyond this critical temperature. The aspects discussed in this review comprehensively describe the damage mechanism of thermally exploited carbonate rocks that can be used as a reference in rock mass classification, sub-surface investigation, and geotechnical site characterization. Full article

The accumulation of unknown polymorphic composites in the endocardium damages the endocardial endothelium (EE). However, the composition and role of unknown polymorphic composites in heart failure (HF) progression remain unclear. Here, we aimed to explore composite deposition during endocardium damage and HF progression. Adult male Sprague–Dawley rats were divided into two HF groups—angiotensin II-induced HF and left anterior descending artery ligation-induced HF. Heart tissues from patients who had undergone coronary artery bypass graft surgery (non-HF) and those with dilated cardiomyopathy (DCM) and ischemic cardiomyopathy (ICM) were collected. EE damage, polymorphic unknown composite accumulation, and elements in deposits were examined. HF progression reduced the expression of CD31 in the endocardium, impaired endocardial integrity, and exposed the myofibrils and mitochondria. The damaged endocardial surface showed the accumulation of unknown polymorphic composites. In the animal HF model, especially HF caused by myocardial infarction, the weight and atomic percentages of O, Na, and N in the deposited composites were significantly higher than those of the other groups. The deposited composites in the human HF heart section (DCM) had a significantly higher percentage of Na and S than the other groups, whereas the percentage of C and Na in the DCM and ICM groups was significantly higher than those of the control group. HF causes widespread EE dysfunction, and EndMT was accompanied by polymorphic composites of different shapes and elemental compositions, which further damage and deteriorate heart function. Full article

To investigate the influence of hydration on brittle deformation of oceanic crustal rocks, we conducted triaxial deformation experiments on gabbroic rocks with various degrees of hydration at a confining pressure of 20 MPa and room temperature, measuring elastic wave velocity. Hydrated olivine gabbros reached a maximum differential stress of 225–350 MPa, which was considerably less than those recorded for gabbros (~450 MPa), but comparable to those for serpentinized ultramafic rocks (250–300 MPa). Elastic wave velocities of hydrated olivine gabbros did not show a marked decrease even prior to failure. This indicated that the deformation of hydrated olivine gabbro is not associated with the opening of the stress-induced cracks that are responsible for dilatancy. Microstructural observations of the samples recovered after deformation showed crack damage to be highly localized to fault zones with no trace of stress-induced crack opening, consistent with the absence of dilatancy. These data suggest that strain localization of hydrated olivine gabbro can be caused by the development of shear cracks in hydrous minerals such as serpentine and chlorite, even when they are present in only small amounts. Our results suggest that the brittle behavior of the oceanic crust may considerably change due to limited hydration. Full article

The Pannonian basin is a major geothermal heat system in Central Europe. Its peripheral basin, the East Slovakian basin, is an example of a geothermal structure with a linear, directed heat flow ranging from 90 to 100 mW/m² from west to east. However, the use of the geothermal source is limited by several critical tectono-geologic factors: (a) Tectonics, and the associated disintegration of the aquifer block by multiple deformations during the pre-Paleogene, mainly Miocene, period. The main discontinuities of NW-SE and N-S direction negatively affect the permeability of the aquifer environment. For utilization, minor NE-SW dilatation open fractures are important, which have been developed by sinistral transtension on N–S faults and accelerated normal movements to the southeast. (b) Hydrogeologically, the geothermal structure is accommodated by three water types, namely, Na-HCO₃ with 10.9 g·L⁻¹ mineralization (in the north), the Ca-Mg-HCO₃ with 0.5–4.5 g·L⁻¹ mineralization (in the west), and Na-Cl water type containing 26.8–33.4 g·L⁻¹ mineralization (in the southwest). The chemical composition of the water is influenced by the Middle Triassic dolomite aquifer, as well as by infiltration of saline solutions and meteoric waters along with open fractures/faults. (c) Geothermally anomalous heat flow of 123–129 °C with 170 L/s total flow near the Slanské vchy volcanic chain seems to be the perspective for heat production. Full article

Multi-sensor satellite imagery data promote fast, cost-efficient regional geological mapping that constantly forms a criterion for successful gold exploration programs in harsh and inaccessible regions. The Barramiya–Mueilha sector in the Central Eastern Desert of Egypt contains several occurrences of shear/fault-associated gold-bearing quartz veins with consistently simple mineralogy and narrow hydrothermal alteration haloes. Gold-quartz veins and zones of carbonate alteration and listvenitization are widespread along the ENE–WSW Barramiya–Um Salatit and Dungash–Mueilha shear belts. These belts are characterized by heterogeneous shear fabrics and asymmetrical or overturned folds. Sentinel-1, Phased Array type L-band Synthetic Aperture Radar (PALSAR), Advanced Space borne Thermal Emission and Reflection Radiometer (ASTER), and Sentinel-2 are used herein to explicate the regional structural control of gold mineralization in the Barramiya–Mueilha sector. Feature-oriented Principal Components Selection (FPCS) applied to polarized backscatter ratio images of Sentinel-1 and PALSAR datasets show appreciable capability in tracing along the strike of regional structures and identification of potential dilation loci. The principal component analysis (PCA), band combination and band ratioing techniques are applied to the multispectral ASTER and Sentinel-2 datasets for lithological and hydrothermal alteration mapping. Ophiolites, island arc rocks, and Fe-oxides/hydroxides (ferrugination) and carbonate alteration zones are discriminated by using the PCA technique. Results of the band ratioing technique showed gossan, carbonate, and hydroxyl mineral assemblages in ductile shear zones, whereas irregular ferrugination zones are locally identified in the brittle shear zones. Gold occurrences are confined to major zones of fold superimposition and transpression along flexural planes in the foliated ophiolite-island arc belts. In the granitoid-gabbroid terranes, gold-quartz veins are rather controlled by fault and brittle shear zones. The uneven distribution of gold occurrences coupled with the variable recrystallization of the auriferous quartz veins suggests multistage gold mineralization in the area. Analysis of the host structures assessed by the remote sensing results denotes vein formation spanning the time–space from early transpression to late orogen collapse during the protracted tectonic evolution of the belt. Full article

Metal nanoparticles (NP) in minerals are an emerging field of research. Development of advanced analytical techniques such as Z-contrast imaging and mapping using high-angle annular dark field scanning transmission electron microscopy (HAADF STEM) allows unparalleled insights at the nanoscale. Moreover, the technique provides a link between micron-scale textures and chemical patterns if the sample is extracted in situ from a location of petrogenetic interest. Here we use HAADF STEM imaging and energy-dispersive X-ray spectrometry (EDX) mapping/spot analysis on focused ion beam prepared foils to characterise atypical Cu-As-zoned and weave-twinned hematite from the Olympic Dam deposit, South Australia. We aim to determine the role of solid-solution versus the presence of discrete included NPs in the observed zoning and to understand Cu-As-enrichment processes. Relative to the grain surface, the Cu-As bands extend in depth as (sub)vertical trails of opposite orientation, with Si-bearing hematite NP inclusions on one side and coarser cavities (up to hundreds of nm) on the other. The latter host Cu and Cu-As NPs, contain mappable K, Cl, and C, and display internal voids with rounded morphologies. Aside from STEM-EDX mapping, the agglomeration of native copper NPs was also assessed by high-resolution imaging. Collectively, such characteristics, corroborated with the geometrical outlines and negative crystal shapes of the cavities, infer that these are opened fluid inclusions with NPs attached to inclusion walls. Hematite along the trails features distinct nanoscale domains with lattice defects (twins, 2-fold superstructuring) relative to hematite outside the trails, indicating this is a nanoprecipitate formed during replacement processes, i.e., coupled dissolution and reprecipitation reactions (CDRR). Transient porosity intrinsically developed during CDRR can trap fluids and metals. Needle-shaped and platelet Cu-As NPs are also observed along (sub)horizontal bands along which Si, Al and K is traceable along the margins. The same signature is depicted along nm-wide planes crosscutting at 60° and offsetting (012)-twins in weave-twinned hematite. High-resolution imaging shows linear and planar defects, kink deformation along the twin planes, misorientation and lattice dilation around duplexes of Si-Al-K-planes. Such defects are evidence of strain, induced during fluid percolation along channels that become wider and host sericite platelets, as well as Cl-K-bearing inclusions, comparable with those from the Cu-As-zoned hematite, although without metal NPs. The Cu-As-bands mapped in hematite correspond to discrete NPs formed during interaction with fluids that changed in composition from alkali-silicic to Cl- and metal-bearing brines, and to fluid rates that evolved from slow infiltration to erratic inflow controlled by fault-valve mechanism pumping. This explains the presence of Cu-As NPs hosted either along Si-Al-K-planes (fluid supersaturation), or in fluid inclusions (phase separation during depressurisation) as well as the common signatures observed in hematite with variable degrees of fluid-mineral interaction. The invoked fluids are typical of hydrolytic alteration and the fluid pumping mechanism is feasible via fault (re)activation. Using a nanoscale approach, we show that fluid-mineral interaction can be fingerprinted at the (atomic) scale at which element exchange occurs. Full article