Search Results (97)

This paper presents a novel, non-contact method for measuring capillary water uptake in porous materials based on the phenomenon of moisture-induced expansion. The proposed approach establishes a quantitative relationship between the amount of water absorbed by the material and the deformations measured on its surface. Digital Image Correlation (DIC) was used to track the displacements of reference points on gypsum specimens during capillary rise. The absorbed water mass was determined from the recorded displacements using a mechanical model that incorporates the moisture expansion coefficient. The method was validated by comparison with conventional continuous gravimetric measurements. The results demonstrate that the displacement-based approach accurately captures the capillary rise process, particularly in the initial phase, where the gravimetric method suffers from significant measurement errors due to surface tension effects. The proposed method eliminates these limitations, providing higher accuracy and temporal resolution. In addition, it enables the testing of larger samples and offers the potential for spatially resolved moisture analysis. The findings confirm that the method is suitable for studying moisture transport in porous materials and may serve as a valuable alternative to traditional gravimetric techniques. Full article

Salinity and clay mineral types have been shown to influence the migration and settlement efficiency of microplastics (MPs) under restrictive experimental conditions. However, current research is limited to deep trenches or laboratory conditions, and studies in the semi-enclosed sea area of the continental shelf are still lacking. We investigated the effects of bottom seawater salinity and clay mineral types on MPs distribution in surface sediments using the western part of the North Yellow Sea as an example, where current conditions are complex and salinity changes rapidly over short distances. Under detection conditions with a minimum detection limit of 10 μm, the abundance range of MPs in the investigated sea area reached 24–1134 items/(g dry weight). The distribution of MPs was in good agreement with the isohaline of the bottom seawater, and MPs tended to converge in the high salinity area. However, there is an exceptional case in which the temperature and salinity difference caused by the cold water mass can create a frontal flow that blocks the transport of terrigenous materials to the middle of the cold water mass. This phenomenon causes MPs to settle at the edge of the cold water mass. A significant positive correlation exists between montmorillonite with expansive properties and fragment MPs and MPs with particle size > 100 μm, which have a larger surface area (p < 0.05). The negative charges on the surface of MPs and clay minerals are neutralized, promoting the heterogeneous aggregation between clay minerals and MPs and accelerating the sedimentation process of MPs in the ocean. This is another important reason for the accumulation of MPs in the high-salinity region. This study provides a basis for pollution prevention and control of MPs in the shallow sea, supplying new insights into the effects of bottom seawater salinity and clay mineral type on the distribution of MPs. Full article

Moisture phase change (MPC), a key process in bread baking, significantly impacts heat and mass transfer, as confirmed by experiments. However, existing models poorly characterize this phenomenon, and its quantitative impact on baking needs systematic study. This research develops a coupled multiphase model for heat and mass transfer with large deformation, employing both equilibrium and nonequilibrium approaches to describe MPC in closed and open pores, respectively. Experimentally calibrated pore-opening functions and viscosity variations revealed that pore-opening primarily occurs at 71–81 °C, whereas dough solidification occurs at 50–110 °C. Model-based analysis indicates that in closed pores, evaporation–diffusion–condensation is the primary mode of moisture transport and heat transfer with contributing approximately 60% of the total effective thermal conductivity, and when pores open, water vapor evaporates or condenses on pore walls, forming an ‘evaporation front’ and ‘condensation front’. The content of liquid water increases at the ‘condensation front’ and decreases at the ‘evaporation front’. Bread deformation is predominantly governed by pressure differentials between closed pores and the ambient environment, with the partial pressure of water vapor emerging as the principal driver because its average content exceeds 70% within closed pores. These findings demonstrate that MPC governs heat and mass transfer and deformation during bread baking. Full article

The central Mediterranean and nearby regions were affected by extreme wildfires during the summer of 2021. During the crisis, Türkiye, Greece, Italy, and other countries faced numerous challenges ranging from the near-complete destruction of landscapes to human losses. The crisis also resulted in reduced air quality levels due to increased emissions of pollutants linked to biomass-burning processes. In the Mediterranean Basin, observation sites perform continuous measurements of chemical and meteorological parameters meant to track and evaluate greenhouse gas and pollutant emissions in the area. In the case of wildfires, CO (carbon monoxide) and formaldehyde (HCHO) are effective tracers of this phenomenon, and the integration of satellite data on tropospheric column densities with surface measurements can provide additional insights on the transport of air masses originating from wildfires. At the Lamezia Terme (code: LMT) World Meteorological Organization–Global Atmosphere Watch (WMO/GAW) observation site in Calabria, Southern Italy, a new multiparameter approach combining different methodologies has been used to further evaluate the effects of the 2021 wildfires on atmospheric measurements. A previous study focused on wildfires that affected the Aspromonte Massif area in Calabria; in this study, the integration of surface data, tropospheric columns, and backtrajectories has allowed pinpointing additional contributions from other southern Italian regions, as well as North Africa and Greece. CO data were available for both surface and column assessments, while continuous HCHO data at the site were only available through satellite. In order to correlate the observed peaks with wildfires, surface BC (black carbon) was also analyzed. The analysis, which focused on July and August 2021, has allowed the definition of three case studies, each highlighting distinct sources of emission in the Mediterranean; the case studies were further evaluated using HYSPLIT backtrajectories and CAMS products. The LMT site and its peculiar local wind patterns have been demonstrated to play a significant role in the detection of wildfire outputs in the context of the Mediterranean Basin. The findings of this study further stress the importance of assessing the effects of wildfire emissions over wide areas. Full article

Nanofluids, with their enhanced thermal properties, provide innovative solutions for improving heat transfer efficiency in renewable energy systems. This study investigates a numerical simulation of bioconvective flow and heat transfer in a Williamson nanofluid over a stretching wedge, incorporating the effects of chemical reactions and hydrogen diffusion. The system also includes motile microorganisms, which induce bioconvection, a phenomenon where microorganisms’ collective motion creates a convective flow that enhances mass and heat transport processes. This mechanism is crucial for improving the distribution of nanoparticles and maintaining the stability of the nanofluid. The unique rheological behavior of Williamson fluid, extensively utilized in hydrometallurgical and chemical processing industries, significantly influences thermal and mass transport characteristics. The governing nonlinear partial differential equations (PDEs), derived from conservation laws and boundary conditions, are converted into dimensionless ordinary differential equations (ODEs) using similarity transformations. MATLAB’s bvp4c solver is employed to numerically analyze these equations. The outcomes highlight the complex interplay between fluid parameters and flow characteristics. An increase in the Williamson nanofluid parameters leads to a reduction in fluid velocity, with solutions observed for the skin friction coefficient. Higher thermophoresis and Williamson nanofluid parameters elevate the fluid temperature, enhancing heat transfer efficiency. Conversely, a larger Schmidt number boosts fluid concentration, while stronger chemical reaction effects reduce it. These results are generated by fixing parametric values as $0.1<\varpi <1.5, 0.1<\mathit{Nr}<3.0, 0.2<\mathrm{Pr}<0.5, 0.1<\mathit{Sc}<0.4, \mathrm{and} 0.1<\mathit{Pe}<1.5.$ This work provides valuable insights into the dynamics of Williamson nanofluids and their potential for thermal management in renewable energy systems. The combined impact of bioconvection, chemical reactions, and advanced rheological properties underscores the suitability of these nanofluids for applications in solar thermal, geothermal, and other energy technologies requiring precise heat and mass transfer control. This paper is also focused on their applications in solar thermal collectors, geothermal systems, and thermal energy storage, highlighting advanced experimental and computational approaches to address key challenges in renewable energy technologies. Full article

The microwave sintering of various materials is a promising technology, which has received much attention for its demonstrated potential. Both the conventional (furnace) and microwave sintering rely on thermal activation for particle bonding, for which a high temperature environment is essential. In comparison, microwave treatment achieves the same degree of densification as furnace sintering in a time shorter by a factor of two or higher and at a temperature lower by 5% to 15%. However, this is a phenomenon not yet fully understood and is commonly referred to as a non-thermal effect. Its understanding is a subject of both physics and practical interest. The non-thermal effect has been studied under years of research in order to broaden the applicability of microwave sintering. Here, we first present an overview of experimentally demonstrated advantages of microwave sintering. To facilitate further studies, we then review the literature and put together four commonly recognized interpretations of the non-thermal effects: the ponderomotive force-driven mass transport, magnetism-created cohesive forces, polarization charge-enhanced wave electric field, and polarization charge-induced attractive force among the sintered particles, with an emphasis on recent development. Full article

Microreactors have the advantages of high heat and mass transfer efficiency, strict control of reaction parameters, easy amplification, and good safety performance, and have been widely used in various fields such as chip manufacturing, fine chemicals, and biomanufacturing. However, narrow microchannels in microreactors often become filled with catalyst particles, leading to blockages. To address this challenge, this study proposes a multiphase flow heat transfer model based on the lattice Boltzmann method (LBM) to investigate the dynamic changes during the bubble collapse process and temperature distribution regularities. Based on the developed three-phase flow dynamics model, this study delves into the shock dynamic evolution process of bubble collapse and analyzes the temperature distribution regularities. Then, the flow patterns under different particle density conditions are explored. The study found that under the action of shock wave, the stable structure of the liquid film of the bubble is destroyed, and the bubble deforms and collapses. At the moment of bubble collapse, energy is rapidly transferred from the potential energy of the bubble to the kinetic energy of the flow field. Subsequently, the kinetic energy is converted into pressure waves. This results in the rapid generation of extremely high pressure in the flow field, creating high-velocity jets and intense turbulent vortices, which can enhance the mass transfer effects of the multiphase flows. At the moment of bubble collapse, a certain high temperature phenomenon will be formed at the collapse, and the high temperature phenomenon in this region is relatively chaotic and random. The pressure waves generated during bubble collapse have a significant impact on the motion trajectories of particles, while the influence on high-density particles is relatively small. The results offer a theoretical basis for understanding mass transfer mechanisms and particle flow patterns in three-phase flow. Moreover, these findings have significant practical implications for advancing technologies in industrial applications, including chip manufacturing and chemical process transport. Full article

Periodic pattern formation is a prominent phenomenon in chemical, physical, and geochemical systems. This phenomenon can arise from various processes, such as the reaction and mass transport of chemical species, solidification, or solvent evaporation. We investigated the formation of ring-banded spherulites of l-menthol using a thin liquid film in a Petri dish. We found that the film thickness and cooling rate strongly influence the generation of crystallization patterns. We performed two-dimensional numerical simulations using the Cahn–Hilliard model to support the experimentally observed trend on the dependence of the layer thickness on the periodicity of the generated macroscopic patterns. In a specific scenario, we observed the formation of rings consisting of needle-like crystals on the cover of the Petri dish. This phenomenon was due to the evaporation of the menthol and its subsequent crystallization. In addition to these findings, we created crystallization patterns by solvent evaporation (using tert-butyl alcohol, methyl alcohol, and acetone). Full article

The migration of acid gases through the pressure sheath of flexible pipes may induce a corrosive environment that can lead to steel armors’ failure by SCC (stress corrosion cracking). This permeation process depends on temperature, partial pressures, materials, and the pipe’s geometry. However, there are few works related to permeation modeling in flexible pipes, and these works usually contain significant simplification in pipes’ geometry. Hence, this work proposes two finite element (FE) permeation models and discusses the effects of the pipe’s characteristics. The models were developed in Ansys^®, considering two- (2DFE) and three-dimensional (3DFE) approaches, and rely on gas fugacities instead of concentrations to describe the mass transport phenomenon. A radial temperature gradient is also considered, and the heat transfer is uncoupled from the mass transfer. Dry and flooded annulus analyses were conducted with the proposed models. In dry conditions, the results obtained with the 2DFE and the 3DFE approaches showed no significant differences, demonstrating that 3D effects are irrelevant. Hence, the permeation phenomenon is ruled by the permeation properties of the polymeric layers (pressure and outer sheaths) and possible shield effects promoted by the metallic armors. In contrast, the flooded annulus analyses resulted in a non-uniform fugacity distribution in the annulus with significant differences between the 2DFE and the 3DFE approaches, showing the importance of modeling the helical geometries of the metallic armors in this condition. Finally, a conservative 2DFE approach, which neglects the contribution of the pressure sheath, is proposed to analyze the flooded annulus condition, aiming to overcome the high computational cost demanded by the 3DFE approach. Full article

One of the major challenges for crop breeding scientists is climate change. Their task is to develop new crop varieties that can withstand this phenomenon. For this study, a new Egyptian paddy variety called Giza 183, which is designed to adapt to mitigate the effects of climate change, was chosen. We focused on examining the physical and engineering properties of this variety in order to design strategies for storage, handling, transportation, drying, parboiling, and processing equipment in rice mills. The goal was to minimize post-harvest losses during the milling process, thereby maximizing high-quality yields while reducing losses. The physical properties of the rice grains, such as the length, width, and thickness, were measured at an average moisture content of 13.7% ± 0.25% (wet basis). The results reveal that the mean values of length, width, and thickness averaged 7.50 mm, 3.18 mm, and 2.19 mm, respectively. Additionally, the geometric mean diameter, the equivalent mean diameter, surface area, arithmetic mean diameter, and volume were approximately 3.74 mm, 2.38 mm, 37.37 mm², 4.29 mm, and 28.23 mm³, respectively. The mean of sphericity was 49.9%, and the grain shape (length/width) was 2.19. The true density was measured at 1218.28 kgm⁻³, while the bulk density was 572.17 kgm⁻³. The porosity was found to be 53.03%. Furthermore, the milling production rates for brown rice, hull, white rice, and broken rice were determined to be 76.83%, 23.15%, 67.97%, and 17.36%, respectively. The average weight of one thousand grains was 25.49 g. A linear regression model for describing the mass of rough rice grain was investigated. The mass was estimated with the single variable of the grain aspect ratio (width/length) with a determination coefficient of 0.9908. Information gained from the current study will be useful in designing post-harvest processing and storage structures in rice processing industries. Full article

For monitoring capillary moisture conduction, the most important parameter is the moisture conductivity coefficient, which is a material characteristic; however, its use in practical calculations is not very common. For further development in the field of liquid moisture propagation, an automated measuring apparatus has been developed and granted a European patent. Its essence lies in detecting the liquid water content based on a well-known physical phenomenon: electromagnetic radiation in the microwave range. The determination of the spatiotemporal moisture field is the first and fundamental step for describing transportation phenomena. The moisture field thus created allows for the viewing of the moisture conductivity coefficient, which is one of the most important parameters in describing transportation phenomena as a function of moisture. The presence of water in building materials can significantly affect their physical properties, such as mechanical or thermal–technical characteristics. This may lead to unacceptable consequences, which might only manifest after a certain period of time. In the case of multi-layered structures, moisture can transfer from one material to another. Therefore, it is essential to address this process. The advantage of the software solution described by the methodology is the use of an open communication protocol in the form of a synchronized array, which is not common in typical applications of this type. The principle of separating hardware modules is also unusual for devices of this type, as it requires the independent communication of each module with the control software. Mutual communication is handled exclusively at the software level, making it possible to modify, optimize, or parameterize the procedures as needed. Upon closer examination of the wetting curves of various materials, anomalies were revealed in some of their structures. This can be advantageously utilized in the research of newly developed composite materials. The assembled system of measuring instruments, their software integration, and control provide a foundation for the practical application of the described procedures and methods for determining the moisture field of building materials. The parameterization of individual processes, as well as the open access to data, allows for the optimization of the methodology, as materials of entirely different characteristics may require an individual approach, which will certainly contribute to the advancement of science and research in this area. Currently, this work is being followed by further extensive studies, not yet published by the authors, focusing on the application of the described moisture field to evaluate the moisture conductivity coefficient as a function dependent on the material’s mass moisture content. Their application requires specific mathematical and programming approaches due to the significant volume of data involved. Full article

The specific energy of lithium-ion batteries (LIBs) can be enhanced through various approaches, one of which is increasing the proportion of active materials by thickening the electrodes. However, this typically leads to the battery having lower performance at a high cycling rate, a phenomenon commonly known as rate capacity retention. One solution to this is perforating the electrode, by creating channels or corrugations in the active electrode material, either as holes or as channels. This is known to reduce the rate capacity retention effect, but in order to engineer this better, a simplified transport process analysis needs to be established. In this paper, we propose a classic electrochemical analysis based on voltage–charge cycling measurements in order to obtain a classical mass transport coefficient, $h_m$, that is further used as a main indicator for electrode design quality assessment. We also demonstrate theoretically and experimentally how the mass transfer coefficient, $h_m$, can be determined and how it changes as the electrode layer thickness increases, with and without electrode corrugations. Full article

Phthalic acid esters (PAEs) are a class of common environmental endocrine disruptors (EEDs), capable of causing considerable pollution to water, soil, and air and producing a range of adverse health impacts in humans. Although various studies have investigated the pollution characteristics and health hazards of PAEs in different media, a systematic review of PAEs in the broader environmental context is still lacking. In order to comprehensively explore current issues and suggest prospects, the current status, detection technology, toxicity, and health hazards of PAEs were investigated. The results suggest that PAE pollution is a widespread and complex global phenomenon, transported over long distances. The traditional techniques used for determination include high-performance liquid chromatography–mass spectrometry (HPLC-MS), gas chromatography–mass spectrometry (GC-MS), and high-performance liquid chromatography (HPLC). Various detection techniques offer distinct advantages and disadvantages. Moreover, PAEs can cause differing extents of harm to the nervous and reproductive systems of mammals. In the future, it is imperative to improve the detection of PAEs, establish rapid identification approaches, refine toxicological research methods, and investigate more comprehensive health risk assessment methods. These efforts will provide scientific support for the prevention and management of the resulting contaminants. Full article

Silt removal is crucial for maintaining navigable waterways in harbors. Jet pumps, without moving parts, are highly suitable for underwater operations such as channel dredging in port environments. Despite their structural advantages in slurry handling, the prolonged transport of solid–liquid two-phase flows can lead to wear on the wall materials, resulting in decreased efficiency and potential pump failure. The wear characteristics of the jet pump walls due to sand particles of varying grain sizes were experimentally investigated. The characteristic of the sands having a higher distribution above the axis as they enter the jet pump was captured by a high-speed camera. The experiment recorded the variations in mass loss at different sections of the jet pump over a period of 120 h, identifying that backflow within the throat region is a significant contributor to wall wear. Scanning electron microscopy was employed to examine the microstructure of the abraded pump surfaces. It was found that there are noticeable differences in the surface wear microstructure across various pump areas, and that particles of different grain sizes result in distinct wear patterns on the pump surfaces. The underlying causes of this phenomenon were discussed from the perspective of particle motion. Full article

The results from a wide-ranging parametric investigation into the behavior of the collisionless partially magnetized plasma discharge of three propellants—xenon, krypton, and argon—are reported in this two-part article. These studies are performed using high-fidelity reduced-order particle-in-cell (PIC) simulations in a 2D configuration that represents an axial–azimuthal cross-section of a Hall thruster. In this part I paper, we discuss the effects of discharge voltage and current density (mass flow rate). Our parametric studies assess the spectra of the resolved instabilities under various plasma conditions. We evaluate the ability of the relevant theories from the literature to explain the variations in the instabilities’ characteristics across the studied plasma parameter space and for various propellants. Moreover, we investigate the changes in the electrons’ cross-magnetic-field transport, as well as the significance of the contribution of different momentum terms to this phenomenon across the analyzed cases. In terms of salient observations, the ion acoustic instability (IAI)-related modes are found to be dominant across the simulation cases, with the ion transit time instability also seen to develop at low current density values. Across the explored parameter space, the instabilities have the main contributions to the electrons’ transport within the plume region. The peak of the electric momentum force term, representing the effect of the instabilities, overall shifts toward the plume as either the current density or the discharge voltage increases. The numerical findings are compared against relevant experimental observations reported in the literature. Full article