Search Results (283)

Refuse-derived fuel (RDF) presents a viable strategy to concurrently address the challenges of municipal solid waste management and the need for alternative energy. In this context, the present review systematically synthesizes recent advances in RDF preparation, combustion behavior, and efficient utilization technologies. The study examines the full chain of RDF production—including waste selection, mechanical/optical/magnetic sorting, granulation, briquetting, and chemical modification—highlighting how pretreatment technologies influence fuel homogeneity, calorific value, and emissions. The thermochemical conversion characteristics of RDF are systematically analyzed, covering the mechanism differences among slow pyrolysis, fast pyrolysis, flash pyrolysis, pyrolysis mechanisms, catalytic pyrolysis, fragmentation behavior, volatile release patterns, and kinetic modeling using Arrhenius and model-free isoconversional methods (e.g., FWO). Special attention is given to co-firing and high-efficiency combustion technologies, including ultra-supercritical boilers, circulating fluidized beds, and rotary kilns, where fuel quality, ash fusion behavior, slagging, bed agglomeration, and particulate emissions determine operational compatibility. Integrating recent findings, this review identifies the key technical bottlenecks—feedstock variability, chlorine/sulfur release, heavy-metal contaminants, ash-related issues, and the need for standardized RDF quality control. Emerging solutions such as AI-assisted sorting, catalytic upgrading, optimized co-firing strategies, and advanced thermal conversion systems (oxy-fuel, chemical looping, supercritical steam cycles) are discussed within the broader context of carbon reduction and circular economy transitions. Overall, RDF represents a scalable, flexible, and high-value waste-to-energy pathway, and the review provides insights into future research directions, system optimization, and policy frameworks required to support its industrial deployment. Full article

The accelerating global demand for sustainable energy, driven by population growth, industrialization, and environmental concerns, has intensified the search for renewable alternatives to fossil fuels. Biofuels, including bioethanol, biodiesel, biogas, and biohydrogen, offer a viable and practical pathway to reducing net carbon dioxide (CO₂) emissions. Yet, their large-scale production remains constrained by biomass recalcitrance, high pretreatment costs, and the enzyme-intensive nature of conversion processes. Recent advances in enzyme immobilization using magnetic nanoparticles (MNPs), covalent organic frameworks, metal–organic frameworks, and biochar have significantly improved enzyme stability, recyclability, and catalytic efficiency. Complementary strategies such as cross-linked enzyme aggregates, carrier-free immobilization, and site-specific attachment further reduce enzyme leaching and operational costs, particularly in lipase-mediated biodiesel synthesis. In addition to biocatalysis, nanozymes—nanomaterials exhibiting enzyme-like activity—are emerging as robust co-catalysts for biomass degradation and upgrading, although challenges in selectivity and environmental safety persist. Green synthesis approaches employing plant extracts, microbes, and agro-industrial wastes are increasingly adopted to produce eco-friendly nanomaterials and bio-derived supports aligned with circular economy principles. These functionalized materials have demonstrated promising performance in esterification, transesterification, and catalytic routes for biohydrogen generation. Technoeconomic and lifecycle assessments emphasize the need to balance catalyst complexity with environmental and economic sustainability. Multifunctional catalysts, process intensification strategies, and engineered thermostable enzymes are improving productivity. Looking forward, pilot-scale validation of green-synthesized nano- and biomaterials, coupled with appropriate regulatory frameworks, will be critical for real-world deployment. Full article

The development of sustainable catalysts from renewable resources is a key challenge for reducing the cost of industrial catalytic processes and waste valorization. In this work, low-cost heterogeneous active catalysts were prepared based on pyrolyzed forest residues, forming valuable porous support materials (Biochar) able to efficiently accommodate the highly active heteropolyacid HPW₁₂. Further, magnetic functionality was incorporated in the novel catalytic materials by the impregnation of NiFe₂O₄. The resulting magnetic composites were characterized by FTIR-ATR, SEM-EDS, ICP-OES, BET, XRD, potentiometric titration and magnetometry. The novel HPW₁₂@NiFe₂O₄@Biochar composites were able to valorize the glycerol to produce the fuel additive solketal with high conversion and high selectivity after only 3 h of reaction via acetalization reaction with acetone. The biochar catalytic composite prepared from cork presented higher pore size than the same prepared from forest biomass. This property was crucial to achieve the best conversion (89%) and the highest solketal selectivity (96%). Additionally, reusability capacity was verified, supporting the potential of the cork-pyrolyzed-based composites as potential low-cost catalytic material to produce fuel additives, such as solketal, under sustainable conditions. This may contribute one step further toward a future with greener energy, increasing the viability of biodiesel industry waste. Full article

Active propelled micro robots (MRs) represent a transformative shift in biomedical engineering, engineered to navigate physiological environments by converting chemical, acoustic, or magnetic energy into mechanical propulsion. Unlike passive delivery systems limited by diffusion and systemic clearance, MRs offer autonomous mobility, enabling precise penetration and retention in hard-to-reach tissues. This review provides comprehensive analysis of MR technologies within urology, a field uniquely suited for microrobotic intervention due to the urinary tract’s anatomical accessibility and fluid-filled nature. We explore how MRs address critical therapeutic limitations, including the high recurrence of kidney stones and the rapid washout of intravesical bladder cancer therapies. The review categorizes propulsion mechanisms optimized for the urinary environment, such as urea-fueled nanomotors and magnetic swarms. Furthermore, we detail emerging applications, including bioresorbable acoustic robots for tumor ablation and magnetic grippers for minimally invasive biopsies. Finally, we critically assess the path toward clinical translation, focusing on challenges in biocompatibility, real-time tracking (MRI, MPI, photoacoustic imaging), and the regulatory landscape for these advanced combination products. Full article

The integration of bioethanol into transportation fuels requires efficient purification methods to overcome the ethanol–water azeotrope, which cannot be separated by conventional distillation. Pervaporation has become an attractive alternative, offering high selectivity while minimising energy consumption. To further improve membrane performance, this study analyses sodium alginate-based hybrid membranes containing binary mixtures of chromite selenides with varying magnetic properties (ZnCr₂Se₄, CdCr₂Se₄, and CuCr₂Se₄). Pairwise combinations of these fillers were introduced to create complex magnetic structures that can influence polymer–filler interactions and molecular transport. Structural, magnetic, and functional characterisation showed that membrane properties were strongly dependent on the type and proportion of fillers. In particular, the CdCr₂Se₄ with CuCr₂Se₄ combination exhibited the most favourable balance between permeation flux and selectivity, achieving the highest parameters, including pervaporation separation index (PSI) reaching 747 kg·m⁻²·h⁻¹. This superior performance is attributed to the synergistic interaction of these two magnetic fillers, which enhances membrane selectivity while maintaining its integrity. This work presents a novel approach to membrane-based separation, advancing the development of energy-efficient, environmentally sustainable bioethanol purification technologies. Full article

Oil and its derivatives affect marine ecosystems due to pollution. Analytical methods for detecting oils and greases in saline water can identify oil-derived pollutants in seas and oceans, supporting the preservation and recovery of water quality. This study describes a methodology based on Raman spectroscopy to quantify oil in saline water. Specific seriate volumes of synthetic lubricating oil (SLO) and diesel fuel oil (DFO) were added to a beaker containing 1000 mL of saline water. A magnetic stirrer was used to create vortex, where the added oil dispersed uniformly over the surface and created a thin film. Raman spectra of the surface’s film were obtained by a spectrometer (830 nm, 350 mW) at a fixed position with reference to the beaker border, in triplicate. Two spectral models were developed; one based on the intensity of the peak at ~1400–1500 cm⁻¹ and another based on partial least squares regression (PLSR). Both spectral models enabled the quantification of SLO and DFO at concentrations ranging from 25.6 to 307 mg/L, and from 16.8 to 205 mg/L, respectively, with correlation coefficients as high as r = 0.99. The results highlight the potential of using Raman spectroscopy for analyzing oil in environmental water samples. Full article

This study examines the swelling behaviour of nitrile-butadiene rubber (NBR) when interacting with tyre pyrolysis oils (TPO), with a focus on the chemical composition of TPO and their interaction with rubber matrices. Initially, a comparative analysis with conventional diesel fuel (DF) was performed using advanced analytical techniques, including two-dimensional gas chromatography coupled to mass spectrometry (2D-GC/MS), infrared (IR) spectroscopy, and nuclear magnetic resonance (¹H-NMR) spectroscopy. The analysis revealed that TPO contains a significantly higher proportion of aromatic hydrocarbons than DF, along with unsaturated and oxygen-containing compounds not present in DF. Based on these compositional differences, blends of TPO and DF were formulated and evaluated for their suitability as liquid energy carriers according to the specifications of DF. In principle, blends with an addition of up to 5 vol% TPO in DF are technically suitable for use as fuel. Subsequently, the sorption behaviour of TPO, DF, and their blends in NBR was investigated. The swelling potential was determined based on mass, density, and volume, and the changes in the hardness and tensile strength of NBR were recorded. The results demonstrate that TPO induces pronounced swelling in NBR, as evidenced by a marked increase in mass uptake and volume expansion. A linear increase was observed between the degree of swelling and the increasing TPO content in the blends. Mechanical property assessments revealed a corresponding decrease in the hardness and tensile strength of NBR upon exposure to TPO, with the most severe effects associated with neat TPO. This work provides a comprehensive assessment of TPO as a potential blend component for DF. It highlights the need for careful consideration of material compatibility in practical applications. Full article

With the growth in global energy demand and increasing concern over the environmental issues associated with fossil fuels, magnetic confinement fusion (MCF) has gained widespread attention as a clean and sustainable energy solution. The superconducting magnet systems in MCF devices operate under liquid helium temperature of 4.2 K and strong magnetic fields, requiring structural materials to possess exceptional high strength, high toughness, and non-magnetic properties. This paper reviews recent research advances in cryogenic high-strength and high-toughness austenitic stainless steels (ASSs) for MCF devices, focusing on modified grades like 316LN and JK2LB used in the International Thermonuclear Experimental Reactor (ITER) project, as well as China’s CHN01 steel developed for the China Fusion Engineering Test Reactor (CFETR) project. The mechanical properties at 4.2 K (including yield strength (R_p0.2), fracture toughness (K(J)_Ic), and Elongation (e)), microstructural evolutions, weldability, and manufacturing challenges of these materials are systematically analyzed. Finally, the different technical approaches and achievements in material development among Japan, the United States, and China are compared, the current limitations of these materials in terms of weld integrity and manufacturability are discussed, and future research directions are outlined. Full article

In scaled laser-driven magnetized liner inertial fusion (MagLIF), externally applied magnetic fields improve energy coupling by suppressing electron thermal conduction, enhancing Joule heating, and increasing $\alpha$-particle energy deposition. However, confinement can be significantly degraded by magnetic flux transport, dominated by resistive diffusion, and more critically, the Nernst effect. One-dimensional magnetohydrodynamic simulations demonstrate that increasing the applied field generally enhances neutron yield, but when the Nernst effect is included, the benefit of stronger magnetization diminishes. Stagnation is achieved at 2.72 ns, yielding a peak temperature of 2.17 keV and a neutron production of $1.2\times {10}^{12}$. When the Nernst effect is taken into account, the neutron yield decreases by 57.3% compared with the case without it under an initial magnetic field of 10 T. During the implosion, the magnetic field in the fuel gradually diffuses outward into the outer liner. By stagnation, the magnetic flux of fuel has decreased by 33.8%. Based on the characteristics of the Nernst effect, an optimized initial magnetic field of approximately 6 T is identified, which yields an about 2.5 times higher neutron yield than the unmagnetized case. These findings emphasize the key role of magnetic–energy coupling in target performance and provide guidance for the design and scaling of magnetized targets. Full article

Amorphous cobalt-phosphorous (CoP) coatings are a candidate to replace hard chromium and other traditional coatings. Here, electrodeposition of both amorphous and crystalline CoP coatings was performed at room temperature and in an air environment. The bath composition and deposition conditions were optimized to offer a low cost, low maintenance, and safe process. The effects of various deposition variables such as solution composition, pH, duration, and mixing parameters were studied, and the reproducibility of the process was demonstrated. Selected coatings were then thoroughly characterized by a variety of techniques. The best amorphous/nanocrystalline coating contained ca. 6.4 wt.% P after 1.2 h of deposition, and 7.2 wt.% P after 4 h of deposition. The best crystalline coating contained ca. 2.7 wt.% P after 1.2 h of deposition and between 2.3 and 5.5 wt.% P after 4 h of deposition. The amorphous coating had excellent mechanical properties: a high hardness (7.8 ± 0.7 GPa), high Young’s modulus (153 ± 9 GPa), and surprisingly low coefficient of dry friction (between 0.11 ± 0.02 and 0.17 ± 0.01). The coating could not be scraped from the substrate using a diamond scalpel blade. In a standard adhesion test, the sample failed neither cohesively within the coating nor adhesively between the coating and the substrate. In the as-deposited conditions, the structure was uniform, nanocrystalline, or had nanocrystals embedded in an amorphous matrix. The crystallization temperature of the amorphous alloy was 284 °C, and the phase transformation occurred only between 300 and 400 °C. The coatings developed and comprehensively characterized herein may be considered for aerospace, magnetic storage, fuel cells, water splitting, and other applications. Full article

Acrylonitrile–butadiene–styrene (ABS) has been widely used as an engineering thermoplastic, and the increasing post-consumer waste of ABS plastics calls for efficient and sustainable recycling technologies. The recent advances in ABS recycling technologies were investigated to enhance material recovery, purity, and environmental performance. Thermo-oxidative degradation compromises mechanical integrity during reprocessing, while minor reductions in molecular weight increase melt flow rates. Surface modification techniques such as boiling treatment, Fenton reaction, and microwave-assisted flotation facilitate the selective separation of ABS from mixed plastic waste by enhancing its hydrophilicity. Dissolution-based recycling using solvent and anti-solvent systems enables the recovery of high-purity ABS, though some additive losses may occur during subsequent molding. Magnetic levitation and triboelectrostatic separation provide innovative density and charge-based sorting mechanisms for multi-plastic mixtures. Thermochemical routes, including supercritical water gasification and pyrolysis, generate fuel-grade gases and oils from ABS blends. Mechanical recycling remains industrially viable when recycled ABS is blended with virgin resin, whereas plasma-assisted mechanochemistry has emerged as a promising technique to restore mechanical properties. These recycling technologies contribute to a circular plastic economy by improving efficiency, reducing environmental burden, and enabling the reuse of high-performance ABS materials. Full article

The improved biomass-derived aldehyde compounds represent a valuable route to the production of high-value-added fuels and chemicals. However, the majority of mature catalytic systems exhibit low hydrodeoxygenation (HDO) activity, even under harsh reaction conditions. In this study, it was observed that a Pd/Fe magnetic bimetallic catalyst, in conjunction with formic acid (FA) as a hydrogen source and nitrogen-containing carbon material as a support, exhibited remarkable catalytic performance for the conversion of phenyl aldehydes in oxygenates derived from crude lignin. In the hydrogenation of vanillin, the Pd/Fe@N/C catalyst demonstrated superior catalytic activity under mild reaction conditions of 80 °C. When ethyl acetate was used as the solvent, the product was vanillyl alcohol (VA), and when cyclohexane was employed as the solvent, the product was p-methyl guaiacol (MMP). The yields achieved were 84.5% and 92.3%, respectively. It is recommended that further exploration of the FLOW reactor system be considered at a later stage due to the magnetic and easily separable characteristics of the catalyst. The excellent mass transfer and heat transfer performance of the FLOW reactor system will further ensure that the reaction conditions are moderate and will strive to achieve normal-temperature conversion. Full article

This paper presents a novel diagnostic method that employs the fuel injection system as a sensor for monitoring internal combustion engine pressure, analysing series resistance to detect connector degradation, and evaluating needle movement within the injector’s magnetic core. Experimental results showed that reducing the injector needle opening from 100% to 20% of its maximum displacement caused up to a 35% reduction in peak current amplitude and a 0.2 ms delay in coil charging. Increasing fuel pressure from 0.3 bar to 2.5 bar resulted in a rise in peak current by approximately 35% and an extension of coil charging delay by 0.4 ms. Furthermore, increasing the series resistance from 0.2 Ω to 2.0 Ω reduced the current amplitude by nearly 50% and significantly distorted the waveform, simulating connector oxidation or wear. Comparative analysis of reference and fault current waveforms confirmed that variations in electrical parameters correlate with injector needle displacement, fuel pressure, and resistance changes. Finally, an automated diagnostic system was developed that achieved over 90% accuracy in independently detecting injector faults based on current waveform characteristics. Full article

The permanent magnetic synchronous motor (PMSM) is of significant use for the centrifugal hydrogen compressor (CHC) in the hydrogen fuel cell system. In order to satisfy the demand for improving the CHC’s performance, including higher accuracy, higher response speed, and wider speed range, this paper proposes a novel adaptive super-twisting sliding mode observer (ASTSMO)-based position sensorless control strategy for the highspeed PMSM. Firstly, the super-twisting algorithm (STA) is introduced to the sliding mode observer (SMO) to reduce chattering and improve the accuracy of position estimation. Secondly, to increase the convergence speed, the ASTSMO is extended with a linear correction term, where an extra proportionality coefficient is used to adjust the stator current error under dynamic operation. Finally, a novel adaptive law is designed to solve the PMSM’s problems of wide speed change, wide current variation, and inevitable parameters fluctuation, which are caused by the CHC’s complex working environment like frequent load changes and significant temperature variations. In the experimental verification, the position accuracy and dynamic performance of the PMSM are both improved. It is also proved that the proposed strategy can guarantee the stable operation and fast response of the CHC, so as to maintain the reliability and the hydrogen utilization of the hydrogen fuel cell system. Full article

Wave energy is a highly concentrated energy resource with five times higher energy density than wind and at least ten times the power density of solar energy. It is expected to make a major contribution to addressing climate change and to help end our dependency on fossil fuels. Many ingenious wave energy conversion methods have been put forward, and a large number of wave energy converters (WECs) have been developed. However, to date, wave energy conversion technology is still in the demonstration application stage. Key issues such as survivability, reliability, and efficient conversion still need to be solved. The major hurdle is the fact that ocean waves provide a slow-moving, high-magnitude force, whereas most electric generators operate at high rotary speed and low torque. Coupling the slow-moving, high-magnitude force of ocean waves normally requires conversion to a high-speed, low-magnitude force as an intermediate step before a rotary generator is applied. This, in general, tends to severely limit the overall efficiency and reliability of the converter and drives the capital cost of the converter well above an acceptable commercial target. Magnetohydrodynamic (MHD) wave energy conversion makes use of MHD generators in which a conducting fluid passes through a very strong magnetic field to produce an electric current. In contrast to alternatives, the relatively slow speed at which the fluid traverses the magnetic field makes it possible to directly couple to ocean waves with a high-magnitude, slowly moving force. The MHD generator provides an excellent match to the mechanical impedance of an ocean wave, and therefore, an MHD WEC has no rotating mechanical parts with high speeds, no complex control process, and has good response to low sea states and high efficiency under all working conditions. This review introduces the system composition, working process, and technical features of WECs based on MHD generators first. Then, the research development, key points, and issues of wave energy conversion technology based on MHD generators are presented in detail. Finally, the problems to be solved and the future research directions of wave energy conversion based on MHD generators are pointed out. Full article