Catalysis: The Key to Valorizing Crude Glycerol

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalysis for Sustainable Energy".

Deadline for manuscript submissions: 30 September 2025 | Viewed by 1484

Special Issue Editors


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REQUIMTE/LAQV and Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal
Interests: heterogeneous catalysts; polyoxometalates; catalytic metal–organic frameworks; sustainable catalytic processes; oxidation catalysis; hydrogen peroxide; desulfurization; glycerol oxidation; deep-eutectic solvents
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Laboratório de Catálise, Department of Chemistry, Federal University of Vicosa, Viçosa 36570-900, Brazil
Interests: homogeneous and heterogeneous catalysts; Keggin heteropolyacids; polyoxometalates; metal catalysts; sustainable catalytic processes; oxidation catalysis; hydrogen peroxide; glycerol chemistry; biofuels and bioadditives

Special Issue Information

Dear Colleagues,

The valorization of the large amount of crude glycerol formed in the biodiesel industry is of primary necessity. There is no doubt that biodiesel is a non-toxic, biodegradable, and renewable fuel, allowing for safer handling and reduced carbon, sulfur, and particulate matter emissions. Industrial biodiesel is one of the most promising ways to replace fossil fuel. Biodiesel is obtained through the transesterification reaction of triglycerides, and glycerol is the by-product of this reaction, originating as 10% in weight in relation to biodiesel. As such, there is an excess of crude glycerol in the fuel industry, owing to the increased interest in biodiesel production. To increase biodiesel’s own sustainability, it is extremely important to develop strategies capable of reutilizing the crude glycerol obtained as waste. Glycerol has many different uses, but most are effective only in its pure form. This Special Issue intends to report effective processes for the purification and transformation of crude glycerol into valuable products with high economic and industrial viability.

Dr. Salete Balula
Prof. Dr. Márcio José da Silva
Guest Editors

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Keywords

  • crude glycerol
  • biodiesel production
  • sustainable catalytic processes
  • purification methodologies
  • effective glycerol usage
  • catalytic esterification
  • catalytic etherification
  • catalytic acetalization
  • catalytic oxidation
  • deep eutectic solvents

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Published Papers (1 paper)

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Research

19 pages, 10340 KiB  
Article
Hydrogenolysis of Bio-Glycerol over In Situ Generated Nanosized Cu-ZnO Catalysts
by Iuliana Porukova, Vadim Samoilov, Vladimir Lavrentev, Dzhamalutdin Ramazanov and Anton Maximov
Catalysts 2024, 14(12), 908; https://doi.org/10.3390/catal14120908 - 10 Dec 2024
Viewed by 1087
Abstract
Due to the growth of biodiesel production, utilization of the glycerol formed as a by-product is still of considerable importance. This study is devoted to a novel approach for glycerol hydrogenolysis with use of in situ generated Cu-ZnO catalysts. The main product formed [...] Read more.
Due to the growth of biodiesel production, utilization of the glycerol formed as a by-product is still of considerable importance. This study is devoted to a novel approach for glycerol hydrogenolysis with use of in situ generated Cu-ZnO catalysts. The main product formed is 1,2-propanediol, with the by-products being lactic acid and ethylene glycol. The Cu-ZnO catalysts are characterized by AAS, XRD, XPS, SEM, TEM, EDX, BET, and chemisorption N2O. The proportion of ZnO turns out to have a significant effect on the activity and selectivity of the catalyst formed. Increasing the ZnO content enables one to obtain more dispersed, active, selective, and agglomeration-resistant catalysts. The transition from monometallic Cu catalysts to Cu-ZnO with a ZnO content of 65 wt% allows one to increase selectivity from 74 to 86%, TOF from 0.136 to 0.511 s−1, and SCu from 1.9 to 7.1 m2/g-Cu. The morphology of the synthesized Cu-ZnO catalysts resembles the structure of oxide/metal inverse catalysts. Full article
(This article belongs to the Special Issue Catalysis: The Key to Valorizing Crude Glycerol)
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