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23 pages, 7821 KiB  
Article
The Multiple Stages of Regional Triassic Crustal Reworking in Eastern Tianshan, NW China: Evidence from the Xigebi Area
by Ming Wei, Haiquan Li, Wenxiao Zhou, Mahemuti Muredili, Ernest Chi Fru and Thomas Sheldrick
Minerals 2025, 15(8), 829; https://doi.org/10.3390/min15080829 (registering DOI) - 4 Aug 2025
Abstract
The eastern Tianshan region in the Central Asian Orogenic Belt (CAOB) is characterized by multiple complex tectonic activity of uncertain historical contribution to the construction of the CAOB. This study utilizes a multi-proxy geochemical approach to characterize I-type monzogranite pluton rocks and their [...] Read more.
The eastern Tianshan region in the Central Asian Orogenic Belt (CAOB) is characterized by multiple complex tectonic activity of uncertain historical contribution to the construction of the CAOB. This study utilizes a multi-proxy geochemical approach to characterize I-type monzogranite pluton rocks and their associated hornblende-rich dioritic enclaves to decipher the tectonic and magmatic evolution of the Xigebi area, eastern Tianshan. Zircon geochronology indicates a Triassic and Permian crystallization age of ca. 224.2 ± 1.7 Ma and ca. 268.3 ± 3.0 Ma for the host monzogranites and the dioritic enclaves, respectively. Major, trace and rare earth element distribution, together with Hf isotope systematics displaying noticeable positive εHf(t) anomalies for both rock types, point to partial melting of meta-mafic rocks in an intraplate extensional setting. The diorite was formed by the melting of lower crustal meta-igneous rocks mixed with mantle melts, and the monzogranite, predominantly from deep crustal meta-basalts contaminated by shallow metasedimentary rocks, with some degree of mixing with deeply sourced mantle magma. While both the host monzogranites and their dioritic enclaves are the products of upwelling magma, the younger Triassic monzogranites captured and preserved fragments of the dioritic Permian lower continental crust during crystallization. These multiple stages of magmatic underplating and crustal reworking associated with vertical stratification of the juvenile paleo-continental crust suggest the monzogranites and diorites indicate a change from a post-collisional setting to a regional intraplate regime on the southern margin of the CAOB. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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26 pages, 6611 KiB  
Article
The Geochronology, Geochemical Characteristics, and Tectonic Settings of the Granites, Yexilinhundi, Southern Great Xing’an Range
by Haixin Yue, Henan Yu, Zhenjun Sun, Yanping He, Mengfan Guan, Yingbo Yu and Xi Chen
Minerals 2025, 15(8), 813; https://doi.org/10.3390/min15080813 (registering DOI) - 31 Jul 2025
Viewed by 157
Abstract
The southern Great Xing’an Range is located in the overlap zone of the Paleo-Asian Ocean metallogenic domain and the Circum-Pacific metallogenic domain. It hosts numerous Sn-polymetallic deposits, such as Weilasituo, Bianjiadayuan, Huanggang, and Dajing, and witnessed multiple episodes of magmatism during the Late [...] Read more.
The southern Great Xing’an Range is located in the overlap zone of the Paleo-Asian Ocean metallogenic domain and the Circum-Pacific metallogenic domain. It hosts numerous Sn-polymetallic deposits, such as Weilasituo, Bianjiadayuan, Huanggang, and Dajing, and witnessed multiple episodes of magmatism during the Late Mesozoic. The study area is situated within the Huanggangliang-Ganzhuermiao metallogenic belt in the southern Great Xing’an Range. The region has witnessed extensive magmatism, with Mesozoic magmatic activities being particularly closely linked to regional mineralization. We present petrographic, zircon U-Pb chronological, lithogeochemical, and Lu-Hf isotopic analyses of the Yexilinhundi granites. The results indicate that the granite porphyry and granodiorite were emplaced during the Late Jurassic. Both rocks exhibit high SiO2, K2O + Na2O, differentiation index (DI), and 10,000 Ga/Al ratios, coupled with low MgO contents. They show distinct fractionation between light and heavy rare earth elements (LREEs and HREEs), exhibit Eu anomalies, and have low whole-rock zircon saturation temperatures (Tzr), collectively demonstrating characteristics of highly fractionated I-type granites. The εHf(t) values of the granites range from 0.600 to 9.14, with young two-stage model ages (TDM2 = 616.0~1158 Ma), indicating that the magmatic source originated from partial melting of Mesoproterozoic-Neoproterozoic juvenile crust. This study proposes that the granites formed in a post-collisional/post-orogenic extensional setting associated with the subduction of the Mongol-Okhotsk Ocean, providing a scientific basis for understanding the relationship between the formation of Sn-polymetallic deposits and granitic magmatic evolution in the study area. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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13 pages, 5465 KiB  
Article
Molybdenite Re-Os Isotopic Ages of Two Late Mesozoic Giant Mo Deposits in the Eastern Qinling Orogenic Belt, Central China
by Yuanshuo Zhang, Li Yang, Herong Gui, Dejin Wang, Mengqiu He and Jun He
Minerals 2025, 15(8), 800; https://doi.org/10.3390/min15080800 - 30 Jul 2025
Viewed by 247
Abstract
Precise Re-Os isotopic ages of the Jinduicheng and Donggou Mo deposits in the East Qinling orogenic belt can shed light on the controversies about multiple-stage pulses of mineralization and further elucidate the genesis and metallogenic process of the deposits. In this study, we [...] Read more.
Precise Re-Os isotopic ages of the Jinduicheng and Donggou Mo deposits in the East Qinling orogenic belt can shed light on the controversies about multiple-stage pulses of mineralization and further elucidate the genesis and metallogenic process of the deposits. In this study, we propose two major events of Mo mineralization in this orogenic belt occurring during the Late Mesozoic: the early stage of 156–130 Ma and late stage of 122–114 Ma. Results of molybdenite Re-Os isotopic analysis reveal that the Jinduicheng deposit formed at 139.2 ± 2.9 Ma, while the Donggou deposit exhibited two-stage mineralization at 115.4 ± 1.6 Ma and 111.9 ± 1.3 Ma. These isotopic ages align with the spatiotemporal evolution of coeval ore-barren granites exposed in eastern Qinling, pointing to a close genetic relationship between the magmatism and mineralization that was controlled by the same tectonic activity, likely in a post-collisional setting. This highlights the multiple-stage Mo mineralization and provides evidence for further understanding the geodynamics and metallogenic process in the eastern Qinling orogenic belt. Full article
(This article belongs to the Section Mineral Deposits)
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43 pages, 20293 KiB  
Article
Volcanic Stratigraphy, Petrology, Geochemistry and Precise U-Pb Zircon Geochronology of the Late Ediacaran Ouarzazate Group at the Oued Dar’a Caldera: Intracontinental Felsic Super-Eruptions in Association with Continental Flood Basalt Magmatism on the West African Craton (Saghro Massif, Anti-Atlas)
by Rachid Oukhro, Nasrrddine Youbi, Boriana Kalderon-Asael, David A. D. Evans, James Pierce, Jörn-Frederik Wotzlaw, Maria Ovtcharova, João Mata, Mohamed Achraf Mediany, Jihane Ounar, Warda El Moume, Ismail Hadimi, Oussama Moutbir, Moulay Ahmed Boumehdi, Abdelmalek Ouadjou and Andrey Bekker
Minerals 2025, 15(8), 776; https://doi.org/10.3390/min15080776 - 24 Jul 2025
Viewed by 594
Abstract
The Ouarzazate Group in the Anti-Atlas Belt of southern Morocco, part of the West African Craton (WAC), is a significant Proterozoic lithostratigraphic unit formed during the late Ediacaran period. It includes extensive volcanic rocks associated with the early stages of Iapetus Ocean opening. [...] Read more.
The Ouarzazate Group in the Anti-Atlas Belt of southern Morocco, part of the West African Craton (WAC), is a significant Proterozoic lithostratigraphic unit formed during the late Ediacaran period. It includes extensive volcanic rocks associated with the early stages of Iapetus Ocean opening. Zircon U-Pb dating and geochemical analyses of the Oued Dar’a Caldera (ODC) volcanic succession in the Saghro Massif reveal two major eruptive cycles corresponding to the lower and upper Ouarzazate Group. The 1st cycle (588–563 Ma) includes pre- and syn-caldera volcanic succession characterized by basaltic andesite to rhyolitic rocks, formed in a volcanic arc setting through lithospheric mantle-derived mafic magmatism and crustal melting. A major caldera-forming eruption occurred approximately 571–562 Ma, with associated rhyolitic dyke swarms indicating a larger caldera extent than previously known. The 2nd cycle (561–543 Ma) features post-caldera bimodal volcanism, with tholeiitic basalts and intraplate felsic magmas, signaling a shift to continental flood basalts and silicic volcanic systems. The entire volcanic activity spans approximately 23–40 million years. This succession is linked to late Ediacaran intracontinental super-eruptions tied to orogenic collapse and continental extension, likely in association with the Central Iapetus Magmatic Province (CIMP), marking a significant transition in the geodynamic evolution of the WAC. Full article
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50 pages, 33914 KiB  
Article
Radiation Assessment and Geochemical Characteristics of 238U, 226Ra, 232Th, and 40K of Selected Specialized Granitic Occurrences, Saudi Arabia, Arabian Shield
by Mohamed Tharwat S. Heikal, Aya S. Shereif, Árpád Csámer and Fatma Deshesh
Toxics 2025, 13(8), 612; https://doi.org/10.3390/toxics13080612 - 22 Jul 2025
Viewed by 319
Abstract
Between approximately 725 and 518 Ma, a suite of specialized felsic plutons and granitic stocks were emplaced across the Arabian Shield, many of which are now recognized as highly mineralized prospects enriched in rare earth elements (REEs), rare metals, and radioactive elements bearing [...] Read more.
Between approximately 725 and 518 Ma, a suite of specialized felsic plutons and granitic stocks were emplaced across the Arabian Shield, many of which are now recognized as highly mineralized prospects enriched in rare earth elements (REEs), rare metals, and radioactive elements bearing mineralizations. The current investigation focused on the radiological and geochemical characterization of naturally occurring radionuclides, specifically 238U, 226Ra, 232Th, and 40K, within three strategically selected granitic prospects, namely, J. Tawlah albite granite (TW), J. Hamra (HM), and J. Abu Al Dod alkali feldspar syenite and granites (AD). Concerning the radioactivity levels of the investigated granitic stocks, specifically the activity concentrations of 238U, 226Ra, 232Th, and 40K, the measured average values demonstrate significant variability across the TW, HM, and AD stocks. The average 238U concentrations are 195 (SD = 38.7), 88.66 (SD = 25.6), and 214.3 (SD = 140.8) Bq/kg for TW, HM, and AD granitic stocks, respectively. Corresponding 226Ra levels are recorded at 172.4 (SD = 34.6), 75.62 (SD = 25.9), and 198.4 (SD = 139.5) Bq/kg. For 232Th, the concentrations are markedly elevated in TW at 5453.8 (SD = 2182.9) Bq/kg, compared to 77.16 (SD = 27.02) and 160.2 (SD = 103.8) Bq/kg in HM and AD granitic stocks, respectively. Meanwhile, 40K levels are reported at 1670 (SD = 535.9), 2846.2 (SD = 249.9), and 3225 (SD = 222.3) Bq/kg for TW, HM, and AD granitic plutons, respectively. Notably, these values exceed the global average background levels, indicating an anomalous enrichment of the studied granitic occurrences. The mean radiological hazard indices for each granitic unit generally exceed global benchmarks, except for AEDEout in the HM and AD stocks, which remain below international limits. The geochemical disparities observed are indicative of post-magmatic alteration processes, as substantiated by the interpretation of remote sensing datasets. In light of the significant radiological burden presented by these granitic stocks, it is essential to implement a rigorous precautionary framework for any future mining. These materials must be categorically excluded from uses that entail direct human exposure, especially in residential construction or infrastructure projects. Full article
(This article belongs to the Section Metals and Radioactive Substances)
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29 pages, 14630 KiB  
Article
Tectonic Evolution of the Eastern Central Asian Orogenic Belt: Evidence from Magmatic Activity in the Faku Area, Northern Liaoning, China
by Shaoshan Shi, Yi Shi, Xiaofan Zhou, Nan Ju, Yanfei Zhang and Shan Jiang
Minerals 2025, 15(7), 736; https://doi.org/10.3390/min15070736 - 15 Jul 2025
Viewed by 265
Abstract
The Permian–Triassic magmatic record in the eastern Central Asian Orogenic Belt (CAOB) provides critical insights into the terminal stages of the Paleo-Asian Ocean (PAO) evolution, including collisional and post-collisional processes following its Late Permian closure. The northeastern China region, tectonically situated within the [...] Read more.
The Permian–Triassic magmatic record in the eastern Central Asian Orogenic Belt (CAOB) provides critical insights into the terminal stages of the Paleo-Asian Ocean (PAO) evolution, including collisional and post-collisional processes following its Late Permian closure. The northeastern China region, tectonically situated within the eastern segment of the CAOB, is traditionally known as the Xingmeng Orogenic Belt (XOR). This study integrates zircon U-Pb geochronology, whole-rock geochemistry, and zircon Hf isotopic analyses of intermediate-acid volcanic rocks and intrusive rocks from the former “Tongjiatun Formation” in the Faku area of northern Liaoning. The main objective is to explore the petrogenesis of these igneous rocks and their implications for the regional tectonic setting. Zircon U-Pb ages of these rocks range from 260.5 to 230.1 Ma, indicating Permian–Triassic magmatism. Specifically, the Gongzhuling rhyolite (260.5 ± 2.2 Ma) and Gongzhuling dacite (260.3 ± 2.4 Ma) formed during the Middle-Late Permian (270–256 Ma); the Wangjiadian dacite (243 ± 3.0 Ma) and Wafangxi rhyolite (243.9 ± 3.0 Ma) were formed in the late Permian-early Middle Triassic (256–242 Ma); the Haoguantun rhyolite (240.9 ± 2.2 Ma) and Sheshangou pluton (230.1 ± 1.7 Ma) were formed during the Late Middle-Late Triassic (241–215 Ma). Geochemical studies, integrated with the geochronological results, reveal distinct tectonic settings during successive stages: (1) Middle-Late Permian (270–256 Ma): Magmatism included peraluminous A-type rhyolite with in calc-alkaline series (e.g., Gongzhuling) formed in an extensional environment linked to a mantle plume, alongside metaluminous, calc-alkaline I-type dacite (e.g., Gongzhuling) associated with the subduction of the PAO plate. (2) Late Permian-Early Middle Triassic (256–242 Ma): Calc-alkaline I-type magmatism dominated, represented by dacite (e.g., Wangjiadian) and rhyolite (e.g., Wafangxi), indicative of a collisional uplift environment. (3) Late Middle-Late Triassic (241–215 Ma): Magmatism transitioned to high-K calc-alkaline with A-type rocks affinities, including rhyolite (e.g., Haoguantun) and plutons (e.g., Sheshangou), formed in a post-collisional extensional environment. This study suggests that the closure of the PAO along the northern margin of the North China Craton (NCC) occurred before the Late Triassic. Late Triassic magmatic rocks in this region record a post-orogenic extensional setting, reflecting tectonic processes following NCC-XOR collision rather than PAO subduction. Combined with previously reported age data, the tectonic evolution of the eastern segment of the CAOB during the Permian-Triassic can be divided into four stages: active continental margin (293–274 Ma), plate disintegration (270–256 Ma), final collision and closure (256–241 Ma), and post-orogenic extension (241–215 Ma). Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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19 pages, 2647 KiB  
Article
Geological, Mineralogical, and Alteration Insights of the Intermediate-Sulfidation Epithermal Mineralization in the Sidi Aissa District, Northern Tunisia
by Jamel Ayari, Maurizio Barbieri, Tiziano Boschetti, Ahmed Sellami, Paolo Ballirano and Abdelkarim Charef
Geosciences 2025, 15(7), 269; https://doi.org/10.3390/geosciences15070269 - 12 Jul 2025
Viewed by 463
Abstract
The Sidi Aissa Pb-Zn-(Ag) District, located within the Nappe Zone of northern Tunisia, has been reinterpreted as a typical intermediate-sulfidation (IS) epithermal mineralization system based on field observations and lithogeochemical analyses. Previously described as vein-style Pb-Zn deposits, the local geological framework is dominated [...] Read more.
The Sidi Aissa Pb-Zn-(Ag) District, located within the Nappe Zone of northern Tunisia, has been reinterpreted as a typical intermediate-sulfidation (IS) epithermal mineralization system based on field observations and lithogeochemical analyses. Previously described as vein-style Pb-Zn deposits, the local geological framework is dominated by extensional normal faults forming half-grabens. These faults facilitated the exhumation of deep Triassic autochthonous rocks and the extrusion of 8-Ma rhyodacites and Messinian basalts. These structures, functioning as pathways for magmatic-hydrothermal fluids, facilitated the upward migration of acidic fluids, which interacted with the surrounding wall rocks, forming a subsurface alteration zone. The mineralization, shaped by Miocene extensional tectonics and magmatic activity, occurred in three stages: early quartz-dominated veins, an intermediate barite-rich phase, and late-stage supergene oxidation. Hydrothermal alteration, characterized by silicification, argillic, and propylitic zones, is closely associated with the deposition of base metals (Pb, Zn) and silver. The mineral assemblage, including barite, galena, sphalerite, and quartz, reflects dynamic processes such as fluid boiling, mixing, and pressure changes. Full article
(This article belongs to the Section Geochemistry)
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23 pages, 81584 KiB  
Article
GNSS-Based Models of Displacement, Stress, and Strain in the SHETPENANT Region: Impact of Geodynamic Activity from the ORCA Submarine Volcano
by Belén Rosado, Vanessa Jiménez, Alejandro Pérez-Peña, Rosa Martín, Amós de Gil, Enrique Carmona, Jorge Gárate and Manuel Berrocoso
Remote Sens. 2025, 17(14), 2370; https://doi.org/10.3390/rs17142370 - 10 Jul 2025
Viewed by 405
Abstract
The South Shetland Islands and Antarctic Peninsula (SHETPENANT region) constitute a geodynamically active area shaped by the interaction of major tectonic plates and active magmatic systems. This study analyzes GNSS time series spanning from 2017 to 2024 to investigate surface deformation associated with [...] Read more.
The South Shetland Islands and Antarctic Peninsula (SHETPENANT region) constitute a geodynamically active area shaped by the interaction of major tectonic plates and active magmatic systems. This study analyzes GNSS time series spanning from 2017 to 2024 to investigate surface deformation associated with the 2020–2021 seismic swarm near the Orca submarine volcano. Horizontal and vertical displacement velocities were estimated for the preseismic, coseismic, and postseismic phases using the CATS method. Results reveal significant coseismic displacements exceeding 20 mm in the horizontal components near Orca, associated with rapid magmatic pressure release and dike intrusion. Postseismic velocities indicate continued, though slower, deformation attributed to crustal relaxation. Stations located near the Orca exhibit nonlinear, transient behavior, whereas more distant stations display stable, linear trends, highlighting the spatial heterogeneity of crustal deformation. Stress and strain fields derived from the velocity models identify zones of extensional dilatation in the central Bransfield Basin and localized compression near magmatic intrusions. Maximum strain rates during the coseismic phase exceeded 200 νstrain/year, supporting a scenario of crustal thinning and fault reactivation. These patterns align with the known structural framework of the region. The integration of GNSS-based displacement and strain modeling proves essential for resolving active volcano-tectonic interactions. The findings enhance our understanding of back-arc deformation processes in polar regions and support the development of more effective geohazard monitoring strategies. Full article
(This article belongs to the Special Issue Antarctic Remote Sensing Applications (Second Edition))
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21 pages, 5597 KiB  
Article
40Ar-39Ar Chronometry Supports Multi-Stage Tectonic Thermal Events in the Bayan Obo Fe-Nb-REE Deposit
by Xinke Gao, Dongsheng Wang, Hongying Li, Yike Li, Hongquan She, Jianjun Yang, Li Zhang, Changhui Ke, Jian Zhao, Shouxian Ma, Chenghao Ren and Futing Yin
Minerals 2025, 15(7), 683; https://doi.org/10.3390/min15070683 - 26 Jun 2025
Viewed by 332
Abstract
The Bayan Obo deposit, located on the northern margin of the North China Plate (NCP), is the world’s largest comprehensive Fe-REE-Nb deposit. After its formation, this deposit was affected by multiple tectonic thermal events, but the ages of these geological events are controversial. [...] Read more.
The Bayan Obo deposit, located on the northern margin of the North China Plate (NCP), is the world’s largest comprehensive Fe-REE-Nb deposit. After its formation, this deposit was affected by multiple tectonic thermal events, but the ages of these geological events are controversial. To determine the evolutionary history of the Bayan Obo deposit, we conducted a detailed study of the macroscopic and microscopic deformation characteristics of the ore district and selected representative minerals, such as riebeckite and biotite, which are widely present in the banded rocks of the deposit, for an 40Ar-39Ar isotopic analysis. The results show that a large number of deformation structures have developed in the carbonatite and surrounding rocks, including mineral bands, boudins, tight folds, and rotated porphyroclasts, suggesting that the region has undergone intense compression and shearing and that the deformation temperature can reach ~550 °C. 40Ar-39Ar plateau ages of 414.9 ± 1.4 Ma and 264.5 ± 2.5 Ma were obtained for the riebeckite and biotite, respectively. Using these results in conjunction with regional geological data and considering the closure temperature of the mineral isotope system, it was inferred that these two ages corresponded to two distinct reworking events experienced by the deposit during the Early Paleozoic and Late Paleozoic following its initial formation. These events corresponded to the collision between the Bainaomiao Arc and the NCP and the magmatic activity induced by a continental–continental collision during the closure of the Paleo-Asian Ocean (PAO), respectively. Full article
(This article belongs to the Special Issue Mineralization and Metallogeny of Iron Deposits)
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34 pages, 12770 KiB  
Article
Immiscibility in Magma Conduits: Evidence from Granitic Enclaves
by Ya Tian, Guanglai Li, Yongle Yang, Chao Huang, Yinqiu Hu, Kai Xu and Ji Zhang
Minerals 2025, 15(7), 664; https://doi.org/10.3390/min15070664 - 20 Jun 2025
Viewed by 312
Abstract
Many granitic enclaves are developed in the volcanic channel of the Xiangshan volcanic basin. To explore their genesis, this study examined the petrography, geochemistry, LA-ICP-MS zircon U–Pb chronology, and zircon Hf isotopes of the granitic enclaves and compared them with the porphyroclastic lavas. [...] Read more.
Many granitic enclaves are developed in the volcanic channel of the Xiangshan volcanic basin. To explore their genesis, this study examined the petrography, geochemistry, LA-ICP-MS zircon U–Pb chronology, and zircon Hf isotopes of the granitic enclaves and compared them with the porphyroclastic lavas. In general, the granitic enclaves and porphyroclastic lavas have similar structures, and the rock-forming minerals and accessory minerals have relatively close compositions. In terms of rock geochemical characteristics, the granitic enclaves are richer in silicon and alkalis but have lower abundances of aluminum, magnesium, iron, and calcium than the porphyroclastic lavas. Rb, Th, K, Sm, and other elements are more enriched, whereas Ba, Ti, Nb, P, and other elements are more depleted. The granitic enclaves have lower rare earth contents (195.53 × 10−6–271.06 × 10−6) than the porphyroclastic lavas (246.67 × 10−6–314.27 × 10−6). The rare earth element distribution curves of the two are generally consistent, both right-leaning, and enriched with light rare earth patterns. The weighted average zircon U–Pb ages of two granitic enclave samples were 135.45 ± 0.54 Ma (MSWD = 0.62, n = 17) and 135.81 ± 0.60 Ma (MSWD = 0.40, n = 20), respectively, which are consistent with the weighted average age of a single porphyroclastic lava sample of 134.01 ± 0.53 Ma (MSWD = 2.0, n = 20). The zircons of the two kinds of rocks crystallize at almost the same temperature. The consistent trend of the rare earth element distribution curve of zircons in the granitic enclaves and the porphyroclastic lava samples indicates that the zircons of the two samples were formed in the same stage. The formation process of granitic enclaves may be that the lower crustal melt is induced to rise, and the crystallization differentiation occurs in the magma reservoir and is stored in the form of crystal mush, forming a shallow crystal mush reservoir. The crystal mush reservoir is composed of a large number of rock-forming minerals such as quartz, feldspar, and biotite, as well as accessory mineral crystals such as zircon and flowable intergranular melt. In the later stage of magma high evolution, a small and short-time magmatic activity caused a large amount of crystalline granitic crystal mush to pour into the volcanic pipeline. In the closed system of volcanic pipeline, the pressure and temperature decreased rapidly, and the supercooling degree increased, and the immiscibility finally formed pale granitic enclaves. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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24 pages, 40890 KiB  
Article
Contrasts in Two-Stage Superimposed Magmatism of the Shizhuzi Magmatic Complex-Mo-Cu-Au System, Liaodong Peninsula, North China Craton
by Jinjian Wu, Jinzhong Yang, Jinhui Yang and Qingdong Zeng
Minerals 2025, 15(6), 631; https://doi.org/10.3390/min15060631 - 10 Jun 2025
Viewed by 413
Abstract
The North China Craton (NCC) experienced extensive destruction and modification of its subcontinental lithospheric mantle during the Mesozoic, a period marked by intensive tectonism, magmatism, and mineralization. Among the key manifestations of this event are the Shizhuzi magmatic complex (SMC) and related Mo-Cu-Au [...] Read more.
The North China Craton (NCC) experienced extensive destruction and modification of its subcontinental lithospheric mantle during the Mesozoic, a period marked by intensive tectonism, magmatism, and mineralization. Among the key manifestations of this event are the Shizhuzi magmatic complex (SMC) and related Mo-Cu-Au deposits in the Liaodong Peninsula. This study presents new zircon U-Pb ages and Hf isotope data, along with whole-rock major and trace element geochemical data. Meanwhile, by incorporating published datasets, the magmatism and mineralization of the SMC are discussed. Two-stage magmatic activity is identified in the SMC as follows: (1) Stage I (130–126 Ma) associated with mineralization, and (2) Stage II (121–117 Ma), both corresponding to the peak destruction of the NCC. The mineralized granitoids exhibit I-type affinities and formed in an extension setting. Quartz diorites within this suite were derived from the partial melting of an enriched mantle source, and the high-temperature thermal underplating associated with this process subsequently triggered partial melting of the basaltic lower crust, leading to the generation of granodiorites and monzonitic granites. These rocks experienced limited fractional crystallization (dominated by plagioclase + biotite) and are linked to Mo-Cu-Au mineralization. In contrast, the non-mineralized granitoids are high-K calc-alkaline, peraluminous A-type granites, which developed in an extremely extensional tectonic setting. They were derived from partial melting of ancient lower crust and display characteristics of highly fractionated granites, having undergone extensive crystallization differentiation involving plagioclase + K-feldspar during magmatic evolution. The mineralized and non-mineralized granitoids exhibit distinct differences in lithology, major/trace element characteristics, Hf isotopes, and degree of fractional crystallization. Our proposed two-stage magmatic model—coupled with a mineralization phase—provides significant insights into both magmatic processes and metallogenesis in the Liaodong Peninsula. It further offers key perspectives into the Early Cretaceous decratonization of the NCC in terms of its tectonic–magmatic–mineralization evolution. Full article
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22 pages, 6644 KiB  
Article
Geochronology, Geochemistry, and Tectonic Significance of Early Carboniferous Volcanic Rocks from the Ulanhot Region in the Central Great Xing’an Range
by Yanqing Zang, Tao Qin, Cheng Qian, Chao Zhang, Jingsheng Chen and Wei Sun
Minerals 2025, 15(6), 610; https://doi.org/10.3390/min15060610 - 5 Jun 2025
Viewed by 389
Abstract
The attributes of Late Paleozoic magmatic events are of paramount significance in elucidating the tectonic evolution of the Ulanhot region, which is located in the middle of the Hegenshan–Heihe tectonic belt (HHTB). This study undertook a comprehensive investigation of the petrography, LA–ICP–MS zircon [...] Read more.
The attributes of Late Paleozoic magmatic events are of paramount significance in elucidating the tectonic evolution of the Ulanhot region, which is located in the middle of the Hegenshan–Heihe tectonic belt (HHTB). This study undertook a comprehensive investigation of the petrography, LA–ICP–MS zircon U–Pb dating, whole rock geochemistry, and zircon Hf isotopes of the Early Carboniferous volcanic rocks. The volcanic rocks are predominantly composed of andesite, schist (which protolith is rhyolitic tuff), and rhyolitic tuff. The results of zircon U–Pb dating reveal that the formation ages of volcanic rocks are Early Carboniferous (343–347.4 Ma). Geochemical characteristics indicate that the andesites possess a comparatively elevated concentration of Al2O3, alongside diminished levels of MgO and TiO2, belonging to the high-K calc-alkaline series. The zircon εHf(t) of the andesites range from −13 to 9.4, while the two-stage Hf model ages span from 697 to 1937 Ma. The felsic volcanic rocks have high contents of SiO2 and Na2O + K2O, low contents of MgO and TiO2, and belong to high-K to normal calc-alkaline series. The zircon εHf(t) values of the felsic volcanic rocks range from −12.8 to 10, while the two-stage Hf model ages span from 693 to 2158 Ma. The Early Carboniferous volcanic rocks exhibit a notable enrichment in large ion lithophile elements (LILEs, such as Rb, K, Ba) and light rare earth elements (LREEs), depletion in high-field-strength elements (HFSEs, including Nb, Ta, Ti, Hf), as well as heavy rare earth elements (HREEs). The distribution patterns of the rare earth elements (REEs) demonstrate a conspicuous right-leaning tendency, accompanied by weak negative Eu anomalies. These characteristics indicate that the andesites represent products of multistage mixing and interaction between crustal and mantle materials in a subduction zone setting. The felsic volcanic rocks originated from the partial melting of crustal materials. Early Carboniferous igneous rocks formed in a volcanic arc setting are characteristic of an active continental margin. The identification of Early Carboniferous arc volcanic rocks in the Central Great Xing’an Range suggests that this region was under the subduction background of the oceanic plate subduction before the collision and amalgamation of the Erguna–Xing’an Block and the Songnen Block in the Early Carboniferous. Full article
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22 pages, 12129 KiB  
Article
Metallogenic Age and Tectonic Setting of the Haigou Gold Deposit in Southeast Jilin Province, NE China: Constraints from Magmatic Chronology and Geochemistry
by Zhongjie Yang, Yuandong Zhao, Cangjiang Zhang, Chuantao Ren, Qun Yang and Long Zhang
Minerals 2025, 15(6), 582; https://doi.org/10.3390/min15060582 - 29 May 2025
Viewed by 376
Abstract
Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily [...] Read more.
Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily occurs within the monzonite granite and monzonite rock mass in the Haigou area and is controlled by fault structures trending northeast, northwest, and near north-south. In order to constrain the age and tectonic setting of quartz vein-type gold mineralization, we conducted a detailed underground investigation and collected samples of monzonite granite and pyroxene diorite porphyrite veins related to quartz-vein-type gold mineralization for LA-ICP-MS zircon U-Pb dating and whole-rock main trace element data testing to confirm that monzonite granite is closely related to gold mineralization. Pyroxene diorite porphyry and gold mineralization were found in parallel veins. The zircon U-Pb weighted mean ages of monzonite and pyroxene diorite porphyrite veins are 317.1 ± 3.5 Ma and 308.8 ± 3.0 Ma, respectively, indicating that gold mineralization in monzonite, pyroxene diorite porphyrite veins, and quartz veins occurred in the Late Carboniferous. The monzonite granite and pyroxene diorite porphyrite veins associated with quartz vein-type gold mineralization have high SiO2, high K, and high Al2O3 and are all metaluminous high-potassium calc-alkaline rock series. Both of them are relatively enriched in light rare earth elements (LREE) and macroionic lithophile elements (LILE: Rb, Ba, K, etc.), but deficient in heavy rare earth elements (HREE) and high field strength elements (HFSE: Nb, Ta, P, Ti, etc.), the monzonitic granite Eu is a weak positive anomaly (δEu = 1.15–1.46), the pyroxene diorite porphyre dyke Eu is a weak positive anomaly (δEu = 1.09–1.13), and the Nb and Ta are negative anomalies. The Th/Nb values are 0.28–0.73 and 1.48–2.05, and La/Nb are 2.61–4.74 and 4.59–5.43, respectively, suggesting that diagenetic mineralization is the product of subduction in an active continental margin environment. In recent years, scholarly research on Sr, Nd, and Pb isotopes in Haigou rock masses has indicated that the magmatic source region in the Haigou mining areas is complex. It is neither a singular crustal source nor a mantle source but rather a mixed crust-mantle source, primarily resulting from the partial melting of lower crustal materials, with additional contributions from mantle-derived materials. In summary, the metallogenic characteristics, chronology data, geochemical characteristics, and regional tectonic interpretation indicate that at least one phase of magmatic-hydrothermal gold mineralization was established in the Late Carboniferous as a result of the subduction of the Paleo-Asian ocean plate at the northern margin of the North China Craton. Full article
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37 pages, 17692 KiB  
Article
Geological, Mineralogical, Geochemical, and Petrogenetic Characteristics of Plutonic Rocks in Çiftehan (Ulukışla-Niğde) Area, South-Central Türkiye: Implication for Genetic Link with Fe-Zn Skarn Mineralization
by Emmanuel Daanoba Sunkari and Abdurrahman Lermi
Minerals 2025, 15(6), 578; https://doi.org/10.3390/min15060578 - 29 May 2025
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Abstract
Globally, most skarn deposits show a direct relationship with magmatic activity, indicating a genetic link between the geochemical composition of causative plutons and the metal content of associated skarns. Therefore, this study investigated the Early–Middle Eocene plutonic rocks and their relationship with Fe-Zn [...] Read more.
Globally, most skarn deposits show a direct relationship with magmatic activity, indicating a genetic link between the geochemical composition of causative plutons and the metal content of associated skarns. Therefore, this study investigated the Early–Middle Eocene plutonic rocks and their relationship with Fe-Zn skarn deposits in the Esendemirtepe-Koçak and Horoz areas of south-central Türkiye. Despite the regional significance, previous studies have not adequately addressed the petrogenetic evolution of these intrusions and the geochemical characteristics of the related skarns. In particular, the fluid-aided mobility of elements at the contact between the causative plutons and the volcano-sedimentary country rocks remains poorly understood. Therefore, in this study, field studies, petrographic and mineralogical analysis, and whole-rock geochemical analysis were conducted to investigate the genetic link between the plutonic rocks and the skarn deposits. Field studies reveal that the skarn zones are within volcano-sedimentary sequences and marble-schist units intruded by four distinct plutonic bodies: (1) Esendemirtepe diorite, (2) Koçak diorite, (3) Horoz granodiorite, and (4) Çifteköy monzogabbro. These rocks exhibit calc-alkaline, I-type, and metaluminous signatures, except for the Çifteköy monzogabbro, which shows I-type, tholeiitic, and alkaline characteristics. All the plutonic rocks associated with the skarn formation display steep LREE-enriched REE patterns with minor positive Eu anomalies (Eu/Eu* = 0.98–1.35), suggesting a subduction-related volcanic arc setting similar to other granitoids in the Ulukışla Basin. The Horoz skarn exhibits both endoskarn and exoskarn features, while the Esendemirtepe-Koçak deposit is characterized by typical exoskarn features. Dominant ore minerals in both skarn deposits include magnetite, hematite, sphalerite, chalcopyrite, and pyrite, with minor arsenopyrite, galena, and cobaltite. The mineral composition of the skarn also shows the dominance of Na-rich and Mg-rich minerals in both locations. The geochemical compositions of the I-type, metaluminous Esendemirtepe-Koçak, and Horoz plutonic rocks are compatible with Fe-Zn skarn type deposits based on the moderate MgO (0.36–4.44 wt.%) and K2O (1.38–7.99 wt.%), and Rb/Zr and Sr/Zr ratios. They also show typical volcanic arc features, and the variation in various trace element concentrations shows similarity with Fe-Zn skarn type granitoids. These findings support a strong genetic relationship between the mineralization and the geochemical and mineralogical characteristics of the associated plutonic rocks. Full article
(This article belongs to the Special Issue Igneous Rocks and Related Mineral Deposits)
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19 pages, 9898 KiB  
Article
Seismic Tomography in the Târgu Jiu Region (Romania): Relationships with Seismic Velocity Anomalies and Fault Activity
by Bogdan Zaharia, Andrei Mihai, Raluca Dinescu, Mihai Anghel, Cristian Neagoe, Mircea Radulian and Christian Schiffer
Appl. Sci. 2025, 15(11), 6084; https://doi.org/10.3390/app15116084 - 28 May 2025
Viewed by 646
Abstract
This study presents a seismic tomography analysis of the Târgu Jiu region in southwestern Romania, an area that experienced an unusual earthquake sequence in 2023. Using P- and S-wave arrival times local earthquakes, we applied the LOTOS algorithm to produce high-resolution 3D crustal [...] Read more.
This study presents a seismic tomography analysis of the Târgu Jiu region in southwestern Romania, an area that experienced an unusual earthquake sequence in 2023. Using P- and S-wave arrival times local earthquakes, we applied the LOTOS algorithm to produce high-resolution 3D crustal seismic velocities models. High Vp and Vs values in the northern and northeastern areas suggest the presence of dense, rigid geological formations, likely associated with consolidated magmatic or metamorphic units. In contrast, the central region exhibits low Vs values, coinciding with an active seismic zone and intersecting major fault structures. This suggests the presence of highly fractured and weakly consolidated rocks, potentially saturated with fluids. The Vp/Vs ratio in the central region reached values of ≥1.8–1.9, indicating fluid-filled fractures that may influence fault dynamics and earthquake occurrence. In the southern region, velocity anomalies suggest weakly consolidated sedimentary units with a high degree of fracturing. These findings contribute to a better understanding of the geodynamic behavior of the Târgu Jiu area and its seismic hazard potential. Full article
(This article belongs to the Special Issue Earthquake Engineering: Geological Impacts and Disaster Assessment)
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