Search Results (126)

Understanding the development characteristics and controlling factors of organic-rich shales in carbonate platform settings is essential for predicting their distribution and assessing their natural gas exploration potential. However, the mechanisms governing the accumulation of such shales in these specific sedimentary environments remain poorly constrained, and the lack of integrated petrological and geochemical studies limits accurate evaluation of their resource potential. The key objective of this study is to investigate the development characteristics and formation mechanisms of organic-rich shales within intraplatform depressions. To address this objective, we conducted a comprehensive petrological and geochemical analysis of the Cambrian Shuijingtuo Formation organic-rich shale deposits deposited in a carbonate platform setting, particularly from Well EYY3 in Western Hubei, Central Yangtze region. The obtained results indicate that total organic carbon (TOC) contents in the Shuijingtuo Formation can reach up to 4.77%, with a thickness of approximately 9.5 m for shales containing over 2% TOC. Vertically, TOC content exhibits a rapid increase at the base, followed by a gradual decline toward the top, reflecting the evolution of depositional environments. The characteristics of organic-rich shale indicate a significant presence of carbonate minerals, which increase in concentration, alongside tuff lenticular bodies and lithological transition surfaces between tuff and shale. While the longitudinal variation of SiO₂ content in shale is subtle, there is a slight increase in land-sourced clasts and excess silica, and TOC has a significant positive correlation. At the base of the Shuijingtuo Formation, redox parameters, including U-EF and Mo-EF, display a rapid increase followed by a gradual decrease. Conversely, changes in Ni-EF, which indicate paleoproductivity, are less pronounced, and their correlation with TOC is relatively poor. These findings suggest that rapid sea-level rise associated with Cambrian transgressions was the main factor influencing organic matter enrichment in the carbonate platform depressions. This rise supplied nutrients and silica-rich organisms, altering the biological landscape and fostering anoxic conditions in the intraplatform depressions, promoting organic-rich shale formation. As sea levels declined, water circulation became restricted, leading to oxidation of shallow water bodies, decreased paleoproductivity, and shale deposits transitioned to tuff. Therefore, organic-rich shale can also be developed on carbonate platforms, with its formation primarily controlled by fluctuations in sea level. During highstand periods, intraplatform depressions may serve as favorable zones for shale gas exploration. Full article

Deep shale of the Lower Cambrian Qiongzhusi Formation in the Sichuan Basin represents a critical frontier for shale gas exploration in China. However, systematic understanding of the multi-scale links among lamination type, mechanical anisotropy, and fracture complexity remains limited. Based on lamination characteristics and total organic carbon (TOC) content, core samples were classified into four types. Using a multi-scale approach (uniaxial compression, Brazilian splitting, in situ CT scanning, QEMSCAN, and SEM), this study elucidates how lamination structure controls mechanical anisotropy, failure modes, and fracture mechanisms. The novelties of this work are threefold: (1) quantitatively linking specific lamination types (ORM, OPM, PAFC, PAF) to anisotropic mechanical responses; (2) introducing 3D fractal dimensions to evaluate fracture network complexity; and (3) integrating micro- (SEM) and macro-scale tests to reveal the coupled control of weak planes and brittle minerals on fracture propagation. Results indicate that laminated shales exhibit pronounced mechanical anisotropy. Loading parallel to laminations induces tensile splitting along weak planes, significantly reducing strength. Conversely, perpendicular loading generates complex fracture networks of horizontal secondary fractures along laminae and vertical main fractures through the matrix. Furthermore, 3D fractal dimension analysis quantifies fracture network complexity as follows: organic-poor clay-feldspar laminated shale > organic-poor clay-feldspar-calcareous laminated shale > organic-rich massive shale. Microscopic observations confirm that fracture propagation is jointly governed by weak plane systems and brittle mineral content, which collectively determine macroscopic failure patterns. These findings clarify how lamination type controls the laboratory mechanical response and fracture morphology of deep shale and provide a laboratory-scale framework for comparing lamination-related differences in mechanical anisotropy and fracture complexity in the Qiongzhusi Formation. Full article

Phosphatic deposits from the Lower Cambrian Pedroche Formation (Sierra de Córdoba, Spain) provide key insights into early diagenetic mineralization processes during the Cambrian radiation. This study applies an integrated multi-analytical approach combining Raman spectroscopy, SEM–EDS, LA-ICP-MS, and ToF-SIMS to investigate mineralogical, elemental, and molecular signatures of phosphatized bioclastic carbonates and associated siliciclastic facies from the Los Lagares-1 borehole. Results reveal a systematic phosphatization gradient from carbonate-dominated skeletal rims to phosphate-rich interiors composed of carbonate fluorapatite with variable carbonate and hydroxyl substitution. Trace-element systematics and REE patterns indicate seawater-influenced phosphogenesis under suboxic porewater conditions, coupled to iron reduction and early diagenetic clay mineral formation. In contrast, the siliciclastic siltstone facies preserves poorly crystalline phosphate phases associated with detrital aluminosilicates and chlorite, reflecting distinct porewater chemistry and crystallization kinetics. ToF-SIMS mapping demonstrates spatial coupling between fluorine and phosphate within fossil structures, confirming fluorapatite formation and localized organic matter entombment. These results highlight the strong control of host lithology on phosphate crystallization pathways and trace-element redistribution, and provide new constraints on microbially mediated phosphogenesis in restricted Early Cambrian reef–lagoon systems along the northern Gondwanan margin. Full article

Recent deep exploration in the northern Sichuan Basin has advanced our understanding of Lower Cambrian Canglangpu Formation carbonate reservoirs. However, the characteristics, genesis, and distribution of the reservoir, as well as future exploration targets, remain unclear. Specifically, core and thin-section analyses indicate that these reservoirs are notably tight, with virtually no visible macroporosity and low permeability (0.01–1 mD). However, helium porosity measurements reveal values of 2–5%, suggesting significant storage potential. An integrated approach utilizing optical and scanning electron microscopy (SEM), high-pressure mercury injection capillary pressure (MICP), nuclear magnetic resonance (NMR), and micro-computed tomography (micro-CT) was employed to characterize the pore systems. Quantitative thin-section analysis reveals visible areal porosity markedly lower than helium porosity, indicating predominance of micropores; mercury intrusion and NMR demonstrate that intragranular and intergranular micropores constitute most pore volume, although effectively connected throat sizes remain below 1 µm. Comparative stratigraphic evaluations show that porosity is more developed in the dolomite-rich upper and middle intervals of the depositional cycles, whereas the lower intervals are less porous. Early subaerial exposure promoted dolomitization and dissolution, which facilitated pore development. However, the influence of sediment mixing led to a reduction in porosity. And deep burial subjected the rocks to intense compaction and cementation, destroying most of the primary pore space. Consequently, reservoir quality is ultimately governed by the interplay between the original depositional environment and the later diagenetic history, with paleotopographic highs identified as the most promising exploration targets. These findings establish a predictive framework for reservoir quality in tight carbonate rocks, which holds significant implications for analogous plays worldwide. Full article

Permeability is affected by nanopores and pore structure, and anisotropic permeability is the result of shale lamination, orientation, and stratification of minerals. To understand the reasons for permeability anisotropy, the pore networks of over-mature shale has been studied. The mineral compositions, petrophysical properties, and pore structures of the Lower Cambrian Niutitang Formation shales were analyzed using subcritical gas adsorption, field-emission scanning electron microscopic, and X-ray micro-computed tomographic methods. Quartz, clay minerals, and carbonate are the dominant minerals in the shales. The bedding-parallel and bedding-perpendicular permeabilities are 1.25–46.21 × 10⁻² and 1.38–6.62 × 10⁻² mD, respectively. The anisotropy of permeability, which is the ratio between the bedding-parallel and bedding-perpendicular permeability, is 0.21–26.87. The micropore and Barrett–Joyner–Halenda pore volumes are 0.54–3.62 and 0.05–0.69 mL/100 g, respectively. The bedding-parallel permeability is correlated positively with the micropore and Barrett–Joyner–Halenda pore volumes. Thin-section observations indicate the shales exhibit a bedding-parallel alignment of phyllosilicate minerals and planar deformation bands. The scanning electron microscopy shows deformation of the lamination and parallel alignment of the clay minerals due to compaction or differential compaction over coarser-grained quartz grains. The scanning electron microscopy images and subcritical gas adsorption data indicate that the pore fracture system is parallel to bedding and formed after diagenesis. Furthermore, X-ray micro-computed tomographic analysis shows that the micro-fractures are also preferentially oriented, parallel to bedding. Full article

Based on data from core observations, thin-section petrography, scanning electron microscopy, whole-rock X-ray diffraction, organic geochemical analysis, and element analysis, in this study, we characterized the mineralogical–petrological features and sedimentary environment of the Lower Cambrian Qiongzhusi Formation shale in Western Hubei Province, and we clarified their relationships with organic matter enrichment. The results are as follows: (1) Five dominant rock types were identified in the Qiongzhusi Formation, namely, siliceous shale, argillaceous–siliceous mixed shale, argillaceous–calcareous shale, calcareous–siliceous shale, and calcareous shale. Vertically, the lithofacies transition follows the sequence of siliceous shale facies → mixed shale facies → calcareous shale facies. Laterally, from the marine trough to the trough margin, the thicknesses of the siliceous shale, argillaceous–siliceous mixed shale, and calcareous–siliceous mixed shale gradually decrease, whereas the thickness of the argillaceous–calcareous mixed shale increases progressively. (2) From the early to late sedimentary periods of the Qiongzhusi Formation and from the marine trough to the trough margin, a consistent evolutionary trend can be observed: gradual shallowing of the water depth, intensified hydrodynamic conditions, increased dissolved oxygen content of the bottom water, weakened upwelling currents, reduced paleoproductivity in the surface water, enhanced water mass stagnation, increased terrigenous input, and a corresponding gradual decrease in the total organic carbon (TOC) content. (3) The formation of the late-stage organic-rich shale was comprehensively controlled by the terrigenous input, redox conditions, paleoproductivity, water mass stagnation, and upwelling activity. Among these factors, the redox conditions, water mass stagnation, and paleoproductivity were the primary drivers responsible for the difference in the TOC contents in the Western Hubei marine trough and its margin, while the terrigenous input played a secondary role. Full article

The Middle Cambrian salt–anhydrite succession in the Tarim Basin has been regarded as an effective regional cap-rock. However, numerous Ordovician hydrocarbon reservoirs have been discovered above the anhydrite, and recent drilling has identified industrial oil and gas flows beneath anhydrite-bearing intervals. These findings call into question the sealing effectiveness of anhydrite rocks in deep subsalt settings. In this study, X-ray diffraction (XRD), petrographic analysis, scanning electron microscopy (SEM), and triaxial compression tests were conducted to investigate the mineral composition, deformation behavior, and failure mechanisms of anhydrite rocks. The results indicate that: (1) dolomite-bearing anhydrite undergoes plastic deformation at depths greater than 4400~4600 m (~70 MPa confining pressure), whereas dolomitic anhydrite enters the plastic deformation regime below 5200~5400 m (~80 MPa confining pressure); (2) the deformation evolution of the cap rocks can be divided into four stages. Stages I–III are dominated by brittle deformation, with plasticity progressively increasing with confining pressure, whereas Stage IV is characterized by pervasive plastic deformation and strong sealing capacity, representing an effective cap rock during the critical period of hydrocarbon accumulation; (3) Middle Cambrian reservoirs in the eastern Tazhong area were destroyed by reverse faults that cut through brittle Middle Cambrian cap rocks. In contrast, Lower Cambrian gas reservoirs were charged during the Himalayan period, when the cap rocks remained intact, and exhibited strong sealing capacity. This study demonstrates the temporal variability in the sealing effectiveness of Middle Cambrian anhydrite cap rocks in the eastern Tazhong area and provides a methodological basis for deep and ultra-deep subsalt hydrocarbon exploration. Full article

In recent years, oil and gas exploration in the Lower Cambrian of the central–northern Sichuan Basin, China, has demonstrated enormous resource potential. As a potential interval of high-quality hydrocarbon source rocks, the Canglangpu Formation of the Lower Cambrian remains underdeveloped in exploration and lacks in-depth research. Affected by tectonics, sedimentary environment, and diagenesis, the genetic mechanisms and genetic models of carbonate reservoirs in the Canglangpu Formation within the study area need further clarification. This study utilizes petrological characteristics of dolomite and geochemical data to clarify diagenetic fluids of different reservoir rocks and identifies the main controlling factors and development models of the reservoirs. The results show that the dolomites in Member 1 of the Canglangpu Formation (Cang-1 Member) in central–northern Sichuan are mainly classified into three types: silty–fine crystalline dolomite (D1), granular dolomite (D2), and residual-texture dolomite (D3). The reservoir spaces are dominated by intercrystalline pores, intergranular pores, and structural fractures. The porosity of the Cang-1 Member in the area is relatively low, with an average porosity of 5% or lower. The reservoir porosity average is 3.63%, belonging to low-porosity reservoirs. The permeability average is 2.94 × 10⁻³ mD. Analysis of different geochemical indicators indicates that the diagenetic fluids of the three dolomite types are mainly syndepositional seawater. D1 is formed by penecontemporaneous dolomitization, while both D2 and D3 are formed during the shallow-to-middle burial stage. The main controlling factors of dolomite reservoirs include sedimentary facies, diagenesis, and tectonic movement. This study clarifies the genesis and development model of dolomite reservoirs in the Cang-1 Member, aiming to provide reliable and valuable references for the exploration of dolomite reservoirs in the Canglangpu Formation of the Sichuan Basin. Full article

Determining the age and origin of the “Huoshan Sandstone” holds significant geological implications for the stratigraphic division and correlation of Precambrian sequences in the North China Craton, provenance analysis, reconstruction of tectonic–sedimentary patterns, and paleogeographic settings restoration. This paper investigates the petrology, zircon U-Pb dating, Hf isotopes analysis, and zircon microzonation geochemistry of the “Huoshan Sandstone”. The “Huoshan Sandstone” is grayish-white, light gray, light yellow, purplish-red quartzitic sandstone and quartz sandstone, with a quartz content ranging from 85.5% to 97.8%. The quartz grains exhibit relatively straight contact edges, characteristic of low-grade metamorphosed quartzite. The protolith of the “Huoshan Sandstone” is a medium-grained quartz sandstone with dominant grain sizes of 0.30~0.50 mm, exhibiting well-rounded to subrounded grains and highly developed siliceous cementation characterized by secondary overgrowth. The zircon Th/U ratio confirms that the zircons in the “Huoshan Sandston” are mainly magmatic zircons. Most zircons exhibit extreme HREE enrichment and left-sloping REE patterns, and show significant positive Ce anomalies (Ce/Ce* of 1.06~290.68) and negative Eu anomalies (Eu/Eu* of 0.065~0.61). The age range of zircon ²⁰⁷Pb/²⁰⁶Pb is 1770 ± 20~2732 ± 16 Ma, and there are two obvious peaks at 1800 and 2500 Ma in the U-Pb age frequency histogram, the age of the intersection point on the concordia line is 2521 ± 31 Ma, and the age of the intersection point on the lower part of the line is 1829 ± 22 Ma. These two ages correspond to the timing of Neoarchean TTG gneiss formation through oceanic crust partial melting in the central North China Craton, and the ~1.85 Ga Paleoproterozoic thermal metamorphic event recorded in the Zhongtiao Group of the same region, respectively. The maximum depositional age of the “Huoshan Sandstone”, constrained by the youngest detrital zircon U-Pb ages at 1770 ± 20 Ma, indicates that its sedimentation occurred after 1770 ± 20 Ma (Late Late Paleoproterozoic). Furthermore, as it underlies the red shales of the Cambrian Mantou Formation as a distinct tectonic layer, it must have formed prior to the deposition of the Cambrian Mantou Formation. In addition, in situ Lu-Hf isotopic analyses of these zircons yielded two-stage model ages, mainly between 2.5 and 2.8 Ga, suggesting the provenance to be the Precambrian basement of the Zhongtiao Mountain region in the central North China Craton. It is inferred that the Precambrian strata in the Zhongtiao Mountain area were involved in the process of subduction, collage, and collision of the two continental blocks of the eastern and western parts of the North China Craton, and further confirmation is provided that the final collision of the two continental blocks to form the central orogenic belt occurred in the late Palaeoproterozoic. Full article

The ocean constitutes the largest actively exchangeable carbon reservoir in Earth’s surface system, with the ocean–atmosphere system functioning as an integrated entity that modulates atmospheric CO₂ concentrations over geological timescales. While carbonate and organic-rich sedimentary carbon sinks have been the subject of extensive research, their synergistic roles in long-term carbon–climate feedback loops, as well as the degree to which microbial mediation links ocean hydrographic states to basin-scale carbon sequestration efficiency, remain poorly synthesized. Here, we develop a mechanistic framework comprising five intercoupled components: (1) driving factors (tectonic–climatic forcing and anthropogenic analogs); (2) ocean state controls (basin restriction, water column stratification, and redox conditions); (3) microbial processes (microbial carbon pump-mediated transformation of dissolved organic carbon and the modulating influence of microbial carbonate formation); (4) sedimentary carbon sinks (carbonate platforms versus organic-rich shales underpinning organo-mineral stabilization); and (5) Earth system feedback expressions (e.g., carbon isotope excursions and sustained perturbations in atmospheric CO₂ levels). This framework is validated across three contrasting sedimentary basins, including the Western Tethys rift basins, the Cambrian South China platform system, and the Toarcian Lower Saxony restricted basin, and via three falsifiable propositions. Converging evidence from these case studies corroborates three key conclusions: (1) basin restriction and diminished water mass renewal foster water column stratification and hypoxic/anoxic conditions, thereby enhancing organic carbon preservation (P1); (2) the tectonic and depositional setting of a basin modulates the relative predominance of carbonate and organic carbon sinks (P2); and (3) post-extinction anachronistic facies record amplified microbial control over carbon burial pathways (P3). By emphasizing the context dependence of carbon sequestration processes and the significance of organo-mineral stabilization alongside particulate organic carbon export, this synthesis provides a transferable analytical framework for interpreting deep-time carbon cycle transitions and for contextualizing the impacts of modern ocean warming and deoxygenation on natural carbon sinks. Full article

The Cambrian Period represents a critical yet debated interval in the global transition from “Aragonite Seas” to “Calcite Seas”. This study reconstructs the physicochemical evolution of paleoseawater through microstructural analysis and trace element geochemistry of Cambrian oolitic rocks in the northern Sichuan Basin, South China. Our results demonstrate that micrite envelopes on ooid margins and early submarine cements (Stage 1) effectively least-altered signals, resisting diagenetic alteration. Consequently, the maximum values of trace element in these fabrics serve as reliable proxies for paleoseawater reconstruction. Ooids from the upper Canglangpu Formation to the Longwangmiao Formation (Lower Cambrian, Series 2) are characterized by concentric laminations with tangential ultrastructures, high Sr contents (up to 1536 ppm), and high seawater molar Mg/Ca ratios (hereafter mMg/Ca, up to 5.02). These features contrast sharply with the radial fabrics, low Sr contents (<400 ppm), and low seawater mMg/Ca ratios (<0.4) observed in the Xixiangchi Formation (Upper Cambrian, Furongian). Integrating regional data with global correlations, this study confirms that Aragonite Sea conditions persisted on the northern margin of the Yangtze Block until at least the late Early Cambrian (Stage 4). The Middle Cambrian (Miaolingian) represents a pivotal transitional interval, leading to a complete shift to a stable Calcite Sea by the Late Cambrian (Furongian). These findings provide crucial regional constraints for refining the Phanerozoic model of seawater chemical evolution. Full article

Despite complex geological conditions and limited exploration activity, the South Yellow Sea Basin has not yet yielded a commercial hydrocarbon discovery. Recent studies indicate substantial hydrocarbon potential within the Upper Sinian–Lower Silurian strata; however, the mechanisms controlling hydrocarbon accumulation in these sequences remain poorly understood. In this study, outcrop, drilling, organic geochemical, and seismic data from the Yangtze Plate are integrated using a land–sea comparison approach to evaluate petroleum geological conditions, identify key controlling factors, and predict hydrocarbon accumulation in the Upper Sinian–Lower Silurian sequences of the Laoshan Uplift. The results indicate that the Upper Sinian–Lower Silurian strata possess favorable petroleum geological conditions, including two effective source–reservoir–seal assemblages. Key controls on deep hydrocarbon accumulation include high-quality Lower Cambrian source rocks, early development of the Laoshan paleo-uplift, structural stable zones, and Lower Silurian detachment layers. Three hydrocarbon accumulation evolution models are proposed: (1) early stage lateral hydrocarbon supply from adjacent depressions, (2) early stage lower-source–upper-reservoir charging, and (3) late-stage deep-burial cracking with structural adjustment. These findings provide important guidance for deep hydrocarbon exploration the Upper Sinian–Lower Silurian sequences of the Laoshan Uplift in the South Yellow Sea Basin. Full article

Many small-size ore deposits occur in the Lower Paleozoic strata along the ENE-trending imbricate thrust fault in NW Tarim Basin. Based on field investigations and petrographic examinations, sulfur-related deposits mainly occur within the paleo-karst cavities and are composed of elemental sulfur and anhydrite. Elemental sulfur is extensively present, whereas anhydrite is limited to the Topulang area. The over-dispersed δ³⁴S values (−25.2 to +7.4‰ VCDT) suggest that elemental sulfur and anhydrite typically originate from a multi-phase process involving bacterial sulfate reduction (BSR) superimposed stepwise sulfur disproportionation. The source of sulfate most likely derived from the subsurface Cambrian evaporites. The lower δ¹³C (−6.43 to −3.10‰ VPDB) and δ¹⁸O values (−13.49 to −10.30‰ VPDB) and the higher ⁸⁷Sr/⁸⁶Sr ratios (>0.7105) further suggest that the calcite cements precipitated from near surface aquifer with significant meteoric water influx and were associated with southeastward propagation since the Cenozoic in response to the remote effects of the India–Eurasia collision. This regional tectonic uplift and meteoric water influx created favorable anoxic environments (“sulfur springs”) for subsequent BSR and sulfur disproportionation along the Kepingtage overthrust fault front, resulting in the mineralization of sulfur-bearing species. This study provides a useful example for understanding the repeated processes of BSR and sulfur disproportionation for deep-buried evaporites associated with tectonic-driven mineralization within the Tarim Basin and elsewhere. Full article

The Upper Cambrian–Lower Silurian sediments of the Baltic Basin represent organic-rich clastic and carbonate rocks that are a key exploration target for hydrocarbons in northern Pomerania, Poland. The source rocks contain an average total organic carbon (TOC) content of 4.1 wt% (range: 0.7–9.6 wt%). The organic matter is primarily in the early to mid-oil window; however, both more mature and overmature organic matter also occur (average Tmax: 445 °C; range: 427–488 °C; average Ro: 1.3%; range: 1.0%–1.8%). These organic-rich rocks were mostly deposited under dysoxic rather than anoxic conditions. Fossils of oxygen-dependent benthic fauna are widely distributed, even in the darkest (black shale) lithologies. Nevertheless, short intervals lacking benthic fossils indicate episodes of anoxic bottom-water conditions. The Furongian–Lower Llandovery source rocks exhibit a low sedimentation rate, ranging from 1 to 19 m/Ma. Geochemically, the organic matter is dominated by type II kerogen. Petrographically, the kerogen consists mainly of graptolites and algae. Due to the predominance of planktonic-origin fauna and thermal maturity, the kerogen is relatively hydrogen depleted (average Hydrogen Index, HI: 169 mg HC/g TOC; range: 1–340 mg HC/g TOC). The present day petroleum potential of these source rocks varies from fair to good and very good. Bitumen analysis revealed a dominance of kerogen components, with only minor admixtures of light and heavy oils. Full article

The Lower Cambrian Niutitang Formation was deposited precisely during the Cambrian Explosion period, a short-lived interval marked by drastic shifts in oceanic chemistry and climate. This stratigraphic sequence preserves a comprehensive record of early-ocean evolution and constitutes a world-class reservoir for rare and precious metals, widely termed the “poly-metallic enrichment layer”. Despite its metallogenic prominence, the genetic model for metal enrichment in the Niutitang Formation remains contentious. In this study, we employed inductively coupled plasma mass spectrometry (ICP-MS), carbon and sulfur analyzer, and X-ray fluorescence spectrometry (XRF) to quantify trace-metal abundances, redox-sensitive element distribution patterns, rare-earth element signatures, and total organic carbon contents. Results reveal that metal enrichment in the Niutitang Formation was governed by temporally distinct mechanisms. Member I records extreme enrichment in As, Ag, V, Re, Ba, Cr, Cs, Ga, Ge, Se and In. This anomaly was driven by the Great Oxidation Event and intensified upwelling that oxidized surface waters, elevated primary productivity and delivered abundant organic matter. Subsequent microbial sulfate reduction generated high H₂S concentrations, converting the water column to euxinic conditions. Basin restriction imposed persistent anoxia in bottom waters, establishing a pronounced redox stratification. Concurrent vigorous hydrothermal activity injected large metal fluxes, leading to efficient scavenging of the above metals at the sulfidic–anoxic interface. In Members II and III, basin restriction waned, permitting enhanced water-mass exchange and a concomitant shift from euxinic to anoxic–suboxic conditions. Hydrothermal metal fluxes declined, yet elevated organic-matter fluxes continued to sequester Ag, Mo, Ni, Sb, Re, Th, Ga, and Tl via carboxyl- and thiol-complexation. Thus, “organic ligand shuttling” superseded “sulfide precipitation” as the dominant enrichment mechanism. Collectively, the polymetallic enrichment in the Niutitang Formation reflects a hybrid model controlled by seawater redox gradients, episodic hydrothermal metal supply, and organic-complexation processes. Consequently, metal enrichment in Member I was primarily governed by the interplay between vigorous hydrothermal flux and a persistently sulfidic water column, whereas enrichment in Members II and III was dominated by organic-ligand complexation and fluctuations in the marine redox interface. This study clarifies the stage-dependent metal enrichment model of the Niutitang Formation and provides a theoretical basis for accurate prediction and efficient exploration of polymetallic resources in the region. Full article