Search Results (108)

Firstly, this paper reviews the fundamental theories of solid surface wettability and contact angle hysteresis. Subsequently, it further introduces four typical wettability-engineered surfaces with low hysteresis (superhydrophobic, superamphiphobic, super-slippery, and liquid-like smooth surfaces). Finally, it focuses on the latest research progress in the field of droplet manipulation on open planar surfaces with engineered wettability. To achieve droplet manipulation, the core driving forces primarily stem from natural forces guided by bioinspired gradient surfaces or the regulatory effects of external fields. In terms of bioinspired self-propelled droplet movement, this paper summarizes research inspired by natural organisms such as desert beetles, cacti, self-aligning floating seeds of emergent plants, or water-walking insects, which construct bioinspired special gradient surfaces to induce Laplace pressure differences or wettability gradients on both sides of droplets for droplet manipulation. Moreover, this paper further analyzes the mechanisms, advantages, and limitations of these self-propelled approaches, while summarizing the corresponding driving force sources and their theoretical formulas. For droplet manipulation under external fields, this paper elaborates on various external stimuli including electric fields, thermal fields, optical fields, acoustic fields, and magnetic fields. Among them, electric fields involve actuation mechanisms such as directly applied electrostatic forces and indirectly applied electrocapillary forces; thermal fields influence droplet motion through thermoresponsive wettability gradients and thermocapillary effects; optical fields cover multiple wavelengths including near-infrared, ultraviolet, and visible light; acoustic fields utilize horizontal and vertical acoustic radiation pressure or acoustic wave-induced acoustic streaming for droplet manipulation; the magnetic force acting on droplets may originate from their interior, surface, or external substrates. Based on these different transport principles, this paper comparatively analyzes the unique characteristics of droplet manipulation under the five external fields. Finally, this paper summarizes the current challenges and issues in the research of droplet manipulation on the open planar surfaces and provides an outlook on future development directions in this field. Full article

Highly over-mature marine shales are distributed worldwide with substantial resource potential, yet their pore structure characteristics and controlling mechanisms remain poorly understood, hindering accurate shale gas resource prediction and efficient development. This study focuses on the Cambrian Niutitang Formation shales in the Upper Yangtze region of South China. To decipher the multiscale pore network architecture and its genetic constraints, we employ scanning electron microscopy (SEM) pore extraction and fluid intrusion methods (CO₂ and N₂ adsorption, and high-pressure mercury intrusion porosimetry) to systematically characterize pore structures in these reservoirs. The results demonstrate that the shales exhibit high TOC contents (average 4.78%) and high thermal maturity (average Ro 3.64%). Three dominant pore types were identified: organic pores, intragranular pores, and intergranular pores. Organic pores are sparsely developed with diameters predominantly below 50 nm, displaying honeycomb, slit-like, or linear morphologies. Intragranular pores are primarily feldspar dissolution voids, while intergranular pores exhibit triangular or polygonal shapes with larger particle sizes. CO₂ adsorption isotherms (Type I) and low-temperature N₂ adsorption curves (H3-H4 hysteresis) indicate wedge-shaped and slit-like pores, with pore size distributions concentrated in the 0.5–50 nm range, showing strong heterogeneity. Pore structure shows weak correlations with TOC and quartz content but a strong correlation with feldspar abundance. This pattern arises from hydrocarbon generation exhaustion and graphitization-enhanced organic pore collapse under high compaction stress, which reduces pore preservation capacity. The aulacogen tectonic setting engenders proximal sediment provenance regimes that preferentially preserve labile minerals such as feldspars. This geological configuration establishes optimal diagenetic conditions for the subsequent development of meso- and macro-scale of dissolution pores. Our findings demonstrate that feldspar-rich shales, formed in a proximal depositional system with well-developed inorganic pores, serve as favorable reservoirs for the exploration of highly over-mature marine shale gas. Full article

Heterogeneity of pore and fracture structures has become an important factor affecting the migration of methane and water in coal reservoirs. However, controlling factors of pore and fracture structure collected from coal seam 10 in Taliqike Formation, Kubai Coalfield, Xinjiang need to be studied. In this paper, carbon dioxide adsorption, cryogenic liquid nitrogen, and high-pressure mercury intrusion, as well as coal microscopic components, were used to study pore volumes and characterize pore diameter distribution heterogeneity. By the theory of single weight and multiple fractal formations, the heterogeneity of the pore fracture structure of coal reservoir is expressed, and the influencing factors of the heterogeneity of the pore fracture structure and the pore volume are also discussed. The results are as follows. (1) Micro-pore distribution presents a distinct bidirectional state, with the main peak at approximately 0.6 nm and 0.85 nm. R_o,max has an obvious influence on micro-pore volume. The single-fractal dimension of micro-pore is not affected by a micro-pore volume but is influenced by other factors such as R_o,max and microscopic composition. The heterogeneity of the low-value area controls the heterogeneity of micro-pore diameter distribution. (2) For lower R_o,max samples, mesopores of these samples are ink bottle-shaped pores, and the pore connectivity is poor. In contrast, meso-pore of higher thermal evolution coal samples are mostly simple pores, such as parallel plates. The main mesopores are 10–100 nm pores, accounting for 75% of the total meso-pore volume. For the single fractal dimension, D₁ is greater than D₂, which also shows that the heterogeneity of a pore structure greater than 4 nm is much stronger than that of a pore structure less than 4 nm in these samples. (3) For lower R_o,max samples, double S-shaped curves with distinct hysteresis loop are obtained, while samples of higher R_o,max samples show parallel curves, suggesting that macro-pore of this type of sample develops parallel plate-like pore. There is a positive relationship between D₋₁₀–D₀ and D₋₁₀–D₁₀, while D₀–D₁₀ and D₋₁₀–D₀ have a weak correlation. With the increase of 2–10 nm pore volume, pore distribution heterogeneity of lower value area (D₋₁₀–D₀) weakens. This indicates that pore volume is an important factor affecting the multifractal variation. Full article

This study presents a pneumatic proportional pressure valve employing a silicon microfluidic chip (SMC) integrated with a V-shaped electrothermal microactuator, aiming to address the limitations of traditional solenoid-based valves in miniaturization and high-precision control. The SMC, fabricated via MEMS technology, leverages the thermal expansion of microactuator ribs to regulate pressure through adjustable orifices. A first-order transfer function between input voltage and displacement of the microactuator was derived through theoretical modeling and validated via COMSOL Multiphysics 5.2a simulations. Key geometric parameters of the actuator ribs—cross-section, number, inclination angle, width, span length and thickness—were analyzed for their influence on lever mechanism displacement, actuator displacement, static gain and time constant. AMESim 16.0-based simulations of single- and dual-chip valve structures revealed that increasing ζ shortens step-response rise time, while reducing τ improves hysteresis. Experimental validation confirmed the valve’s static and dynamic performance, achieving a step-response rise time of <40 ms, linearity within the 30–60% input voltage range, and effective tracking of sinusoidal control signals up to 8 Hz with a maximum pressure deviation of 0.015 MPa. The work underscores the potential of MEMS-based actuators in advancing compact pneumatic systems, offering a viable alternative to conventional solenoids. Key innovations include geometry-driven actuator optimization and dual-chip integration, providing insights into high-precision, low-cost pneumatic control solutions. Full article

Background: Myopia is a leading cause of visual impairment worldwide, and accumulating evidence suggests that biomechanics may be closely linked to its development. Understanding this relationship may help clarify the underlying mechanisms of myopia and guide treatment strategies. The aim of the study is to investigate the causal relationship between myopia and corneal biomechanics using the UK Biobank (UKB) database. Methods: Data from 11,064 eyes in the UKB, including refraction results and Ocular Response Analyzer (ORA) measurements, were analyzed. Eyes were categorized by spherical equivalent (SE) into emmetropia, mild myopia, moderate myopia, and high myopia. One-way ANOVA assessed differences in corneal biomechanical parameters across the varying myopia groups, while Quantile Regression (QR) explored the relationship between these parameters and myopia severity across the different quantiles. A Mendelian randomization (MR) analysis was employed to explore the causal relationships. Results: Significant differences in corneal biomechanical parameters and intraocular pressure (IOP) were observed across the myopia levels (p < 0.001). High myopia was associated with lower corneal hysteresis (CH), a lower corneal resistance factor (CRF), and increased IOP. The QR analysis demonstrated that lower corneal biomechanics were associated with higher degrees of myopia, with the impact of corneal biomechanics becoming more pronounced as the myopia severity increased. The MR analysis indicated that low CH (OR = 0.9943, p = 0.004) and CRF (OR = 0.9946, p = 0.002) values were risk factors for myopia, while no causal effect was found when the myopia was treated as the exposure and corneal biomechanics as the outcome. Conclusions: This study establishes a causal relationship where reduced corneal biomechanics contribute to myopia, while myopia itself does not directly affect biomechanics. Corneal biomechanics could serve as a biomarker for assessing high myopia risk. These findings offer new insights into high myopia’s pathological mechanisms and targeted prevention. Full article

This paper is about the characteristics of and a method to recognize the onset of limit cycle thermoacoustic oscillations in a gas turbine-like combustor with a premixed turbulent methane/air flame. Information on the measured time series data of the pressure and the OH* chemiluminescence is acquired and postprocessed. This is performed for a combustor with variation in two parameters: fuel/air equivalence ratio and combustor length. It is of prime importance to acknowledge the nonlinear dynamic nature of these instabilities. A method is studied to interpret thermoacoustic instability phenomena and assess quantitatively the transition of the combustor from a stable to an unstable regime. In this method, three-phase portraits are created on the basis of data retrieved from the measured acoustics and flame intensity in the laboratory-scale test combustor. In the path to limit cycle oscillation, the random distribution in the three-phase portrait contracts to an attractor. The phase portraits obtained when changing operating conditions, moving from the stable to the unstable regime and back, are analyzed. Subsequently, the attractor dimension is determined for quantitative analysis. On the basis of the trajectories from the stable to unstable and back in one run, a study is performed of the hysteresis dynamics in bifurcation diagrams. Finally, the onset of the instability is demonstrated to be recognized by the 0-1 criterion for chaos. The method was developed and demonstrated on a low-power atmospheric methane combustor with the aim to apply it subsequently on a high-power pressurized diesel combustor. Full article

Graphene-based textile pressure sensors are emerging as promising candidates for wearable sensing applications due to their high sensitivity, mechanical flexibility, and low energy consumption. This study investigates the design, fabrication, and electromechanical behaviour of graphene-coated nonwoven textile-based piezoresistive pressure sensors, focusing on the impact of different electrode materials and fabrication techniques. Three distinct sensor fabrication methods—drop casting, electrospinning, and electro-spraying—were employed to impregnate graphene onto nonwoven textile substrates, with silver-coated textile electrodes integrated to enhance conductivity. The fabricated sensors were characterised for their morphology (SEM), chemical composition (FTIR), and electromechanical response under cyclic compressive loading. The results indicate that the drop-cast sensors exhibited the lowest initial resistance (~0.15 kΩ) and highest sensitivity (10.5 kPa⁻¹) due to their higher graphene content and superior electrical connectivity. Electro-spun and electro-sprayed sensors demonstrated increased porosity and greater resistance fluctuations, highlighting the role of fabrication methods in sensor performance. Additionally, the silver-coated knitted electrodes provided the most stable electrical response, while spun-bonded and powder-bonded nonwoven electrodes exhibited higher hysteresis and resistance drift. These findings offer valuable insights into the optimisation of graphene-based textile pressure sensors for wearable health monitoring and smart textile applications, paving the way for scalable, low-power sensing solutions. Full article

The proliferation of flexible pressure sensors has generated new demands for high-sensitivity and low-cost sensors. Here, we propose an elegant strategy to address this challenge by taking a ridge-mimicking, gradient-varying, spatially ordered microstructure as the sensing layer, with laser processing and interdigitated electrodes as the upper and lower electrode layers. Simultaneously, the entire structure is encapsulated with polyimide (PI) tape for protection, and the fabrication process is relatively feasible, facilitating easy scaling. The presented results show that the flexible pressure sensor exhibits a sensitivity of 1.65 kPa⁻¹ across a pressure range of 0 to 1100 kPa. Furthermore, the sensor displays low hysteresis, as well as rapid response and recovery times of 62 ms and 83 ms, respectively. Finally, we demonstrate the application potential of the sensor for monitoring joint movements, especially for detecting pressure and direction in finger joints. This technology shows great potential for applications in smart robotics, wearable devices, health monitoring, and other emerging technologies. Full article

Flexible, wearable pressure sensors offer numerous benefits, including superior sensing capabilities, a lightweight and compact design, and exceptional conformal properties, making them highly sought after in various applications including medical monitoring, human–computer interactions, and electronic skins. Because of their excellent characteristics, such as simple fabrication, low power consumption, and short response time, capacitive pressure sensors have received widespread attention. As a flexible polymer material, polydimethylsiloxane (PDMS) is widely used in the preparation of dielectric layers for capacitive pressure sensors. The Young’s modulus of the flexible polymer can be effectively decreased through the synergistic application of sacrificial template and laser ablation techniques, thereby improving the functionality of capacitive pressure sensors. In this study, a novel sensor was introduced. Its dielectric layer was developed through a series of processes, including the use of a sacrificial template method using NaCl microparticles and subsequent CO₂ laser ablation. This porous PDMS dielectric layer, featuring an array of holes, was then sandwiched between two flexible electrodes to create a capacitive pressure sensor. The sensor demonstrates a sensitivity of 0.694 kPa⁻¹ within the pressure range of 0–1 kPa and can effectively detect pressures ranging from 3 Pa to 200 kPa. The sensor demonstrates stability for up to 500 cycles, with a rapid response time of 96 ms and a recovery time of 118 ms, coupled with a low hysteresis of 6.8%. Furthermore, our testing indicates that the sensor possesses limitless potential for use in detecting human physiological activities and delivering signals. Full article

Benefiting from its high thermal conductivity, simple structure, and light weight, the pulsating heat pipe (PHP) can meet the requirements for high efficiency, flexibility, and low cost in industrial heat transfer applications such as aerospace detector cooling and vehicle thermal management. Compared to a PHP working at room temperature, the mechanism of a PHP with hydrogen as the working fluid differs significantly due to the unique thermal properties of hydrogen. In this paper, a two-dimensional model of a hydrogen PHP with a filling ratio of 51% was established to study the flow characteristics and thermal performance. The volume of fluid (VOF) method was used to capture the phase distribution and interface dynamics, and the Lee model was employed to account for phase change. To validate the model, a comparison was conducted between the simulation results and experimental data obtained in our laboratory. The simulation results show that the pressure and temperature errors were within 25% and 5%, respectively. Throughout a pressure oscillation cycle, the occurrence of uniform flow velocity, acceleration, and flow reversal can be attributed to the changes in the vapor–liquid phase distribution resulting from the effect of condensation and evaporation. In addition, when the fluid velocity was greater than 0.6 m/s, dynamic contact angle hysteresis was observed in the condenser. The results contribute to a deeper understanding of the flow and heat transfer mechanism of the hydrogen PHPs, which have not been yet achieved through visualization experiments. Full article

Corneal biomechanics is a hot topic in ophthalmology. The biomechanical properties (BMPs) of the cornea have important implications in the management and diagnosis of corneal diseases such as ectasia and keratoconus. In addition, the characterization of BMPs is crucial to model the predictability of a corneal surgery intervention, the outcomes of refractive surgery or the follow-up of corneal diseases. The biomechanical behavior of the cornea is governed by viscoelastic properties that allow, among other structural implications, the damping of excess intraocular pressure and the reduction of damage to the optic nerve. Currently, the most versatile and complete methods to measure corneal viscoelasticity are based on air-puff corneal applanation. However, these methods lack the ability to directly measure corneal viscosity. The aim of this work is to propose a new methodology based on the analysis of corneal air-puff measurements through the standard linear solid model (SLSM) to provide analytical expressions to separately calculate the elastic and time-dependent (corneal retardation time and viscosity) properties. The results show the mean values of elasticity (E), viscosity (Ƞ) and corneal retardation time (τ) in a sample of 200 young and healthy subjects. The influence of elasticity and viscosity on viscoelasticity, high-order corneal aberrations and optical transparency is investigated. Finally, the SLSM fed back from experimental E and Ƞ values is employed to compare the creep relaxation response between a normal, an ocular hypertension patient and an Ortho-K user. Corneal biomechanics is strongly affected by intraocular pressure (IOP); however, corneal hysteresis (CH) analysis is not enough to be employed as a risk factor of glaucoma progression. Low values of CH can be accompanied by high or low corneal elasticity and viscosity depending on the IOP threshold from which the time-dependent biomechanical properties trends are reversed. Full article

Carbon-capture technologies are extremely abundant, yet they have not been applied extensively worldwide due to their high cost and technological complexities. This research studies the ability of polymerized fly ash to capture carbon dioxide (CO₂) under low-pressure and low-temperature conditions via physical adsorption. The research also studies the ability to desorb CO₂ due to the high demand for CO₂ in different industries. The adsorption–desorption hysteresis was measured using infrared-sensor detection apparatus. The impact of the CO₂ injection rate for adsorption, helium injection rate for desorption, temperature, and fly ash contact surface area on the adsorption–desorption hysteresis was investigated. The results showed that change in the CO₂ injection rate had little impact on the variation in the adsorption capacity; for all CO₂ rate experiments, the adsorption reached more than 90% of the total available adsorption sites. Increasing the temperature caused the polymerized fly ash to expand, thus increasing the available adsorption sites, thus increasing the overall adsorption volume. At low helium rates, desorption was extremely lengthy which resulted in a delayed hysteresis response. This is not favorable since it has a negative impact on the adsorption–desorption cyclic rate. Based on the results, the polymerized fly ash proved to have a high CO₂ capture capability and thus can be applied for carbon-capture applications. Full article

Introduction: Wetting affects chemical and physical properties. In aluminum, superhydrophobic surfaces keep fog, ice, and corrosion at bay. Biomimicry replicates natural processes. The high surface energy of aluminum limits its intrinsic dewetting properties. Existing surface modification methods have disadvantages, such as hazardous chemicals, high costs, and harsh processing conditions. This work is environmentally friendly and overcomes traditional limitations. Methods: Aluminum alloy plates (AA5083) of commercial grade (ASTM-B-209M) were used in the study. Stationary friction stir processing (sFSP) was carried out on a universal milling machine focused solely on surface characteristics using transition metal powders (99% purity). The prepared samples were polished with abrasive papers to 1000 grit after processing. In the microwave hot water treatment (mHWT), processed and unprocessed samples were processed for 10 min at 800 W. A silanization agent was vapor-deposited on the samples following mHWT at 55 °C for 60 min. Results: The low-strain-rate sFSP of aluminum alloys results in substantial grain refinement, reaching ~1 µm for processed samples and ~30 µm for unprocessed samples. Refined grains have a dense and networked nanostructure after mHWT. After silanization, the samples exhibit excellent contact angles (>155°), low tilt angles (10°), and low contact angle hysteresis (5°). The processed samples, featuring highly refined grains, demonstrate low water adhesion (~16 µN) compared to unprocessed samples (~50 μN), attributed to the high interfacial energy of the Cassie state, effectively entrapping air. These processed samples exhibit remarkable de-wetting properties and mechanical resilience, owing to the strong negative capillary pressure (>1100 kPa) generated by highly dense networked nanostructures. Conclusions: In conclusion, the research helps to develop sustainable and durable superhydrophobic aluminum surfaces. The environmentally friendly and cost-effective strategies explored have far-reaching implications for industrial applications, emphasizing opportunities for advancements and practical utilization across various industries. Full article

Hydrogen storage in general is an indispensable prerequisite for the introduction of a hydrogen energy-based infrastructure. In this respect, high-pressure metal hydride (MH) tank systems appear to be one of the most promising hydrogen storage techniques for automotive applications using proton exchange membrane (PEM) fuel cells. These systems bear the potential of achieving a beneficial compromise concerning the comparably large volumetric storage density, wide working temperature range, comparably low liberation of heat, and increased safety. The debatable term “unstable metal hydride” is used in the literature in reference to metal hydrides with high dissociation pressure at a comparably low temperature. Such compounds may help to improve the merits of high-pressure MH tank systems. Consequently, in the last few years, some materials for possible on-board applications in such tank systems have been developed. This review summarizes the state-of-the-art developments of these metal hydrides, mainly including intermetallic compounds and complex hydrides, and offers some guidelines for future developments. Since typical laboratory hydrogen uptake measurements are limited to 200 bar, a possible threshold for defining unstable hydrides could be a value of their equilibrium pressure of p_eq > 200 bar for T < 100 °C. However, these values would mark a technological future target and most current materials, and those reported in this review, do not fulfill these requirements and need to be seen as current stages of development toward the intended target. For each of the aforementioned categories in this review, special care is taken to not only cover the pioneering and classic research but also to portray the current status and latest advances. For intermetallic compounds, key aspects focus on the influence of partial substitution on the absorption/desorption plateau pressure, hydrogen storage capacity and hysteresis properties. For complex hydrides, the preparation procedures, thermodynamics and theoretical calculation are presented. In addition, challenges, perspectives, and development tendencies in this field are also discussed. Full article

Earthquakes impact the stability of municipal solid waste (MSW) landfills, especially those with high water levels, and may further lead to disastrous landslides. Numerical analysis offers an efficient and cost-effective way to study the seismic stability of a landfill. In this study, the finite difference nonlinear analysis method was employed to meticulously evaluate the dynamic response of landfills under varying water levels and seismic intensities. The analysis was guided by the seismic instability and centrifuge test outcomes. The rationality of the computational model was verified by examining the responses of acceleration and pore pressure. Subsequently, the time history curve of the dynamic safety factor was derived from the dynamic response of landfills. The results indicated that a landfill was more susceptible to large earthquake effects, and its stability decreased as the water level rose, with the safety factor decreasing to a critical point under the coupling effect of strong earthquakes and high water levels. In contrast, the stability of the landfill with low water levels was good under weak earthquake conditions, with only a slight decrease in the safety factor observed. The seismic stability of a landfill was significantly influenced by both accumulative deformation and negative excess pore pressure. A certain degree of hysteresis in the landfill’s instability was also observed compared to the earthquake loading process. The time history curve of the safety factor can offer a comprehensive insight into seismic stability under diverse conditions. Additionally, future research efforts are needed to better determine the values of strength parameters of MSW in seismic analysis. Full article