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Search Results (317)

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Keywords = low emissivity coating

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48 pages, 5229 KiB  
Article
Enhancing Ship Propulsion Efficiency Predictions with Integrated Physics and Machine Learning
by Hamid Reza Soltani Motlagh, Seyed Behbood Issa-Zadeh, Md Redzuan Zoolfakar and Claudia Lizette Garay-Rondero
J. Mar. Sci. Eng. 2025, 13(8), 1487; https://doi.org/10.3390/jmse13081487 - 31 Jul 2025
Viewed by 271
Abstract
This research develops a dual physics-based machine learning system to forecast fuel consumption and CO2 emissions for a 100 m oil tanker across six operational scenarios: Original, Paint, Advanced Propeller, Fin, Bulbous Bow, and Combined. The combination of hydrodynamic calculations with Monte [...] Read more.
This research develops a dual physics-based machine learning system to forecast fuel consumption and CO2 emissions for a 100 m oil tanker across six operational scenarios: Original, Paint, Advanced Propeller, Fin, Bulbous Bow, and Combined. The combination of hydrodynamic calculations with Monte Carlo simulations provides a solid foundation for training machine learning models, particularly in cases where dataset restrictions are present. The XGBoost model demonstrated superior performance compared to Support Vector Regression, Gaussian Process Regression, Random Forest, and Shallow Neural Network models, achieving near-zero prediction errors that closely matched physics-based calculations. The physics-based analysis demonstrated that the Combined scenario, which combines hull coatings with bulbous bow modifications, produced the largest fuel consumption reduction (5.37% at 15 knots), followed by the Advanced Propeller scenario. The results demonstrate that user inputs (e.g., engine power: 870 kW, speed: 12.7 knots) match the Advanced Propeller scenario, followed by Paint, which indicates that advanced propellers or hull coatings would optimize efficiency. The obtained insights help ship operators modify their operational parameters and designers select essential modifications for sustainable operations. The model maintains its strength at low speeds, where fuel consumption is minimal, making it applicable to other oil tankers. The hybrid approach provides a new tool for maritime efficiency analysis, yielding interpretable results that support International Maritime Organization objectives, despite starting with a limited dataset. The model requires additional research to enhance its predictive accuracy using larger datasets and real-time data collection, which will aid in achieving global environmental stewardship. Full article
(This article belongs to the Special Issue Machine Learning for Prediction of Ship Motion)
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24 pages, 1087 KiB  
Review
After-Treatment Technologies for Emissions of Low-Carbon Fuel Internal Combustion Engines: Current Status and Prospects
by Najunzhe Jin, Wuqiang Long, Chunyang Xie and Hua Tian
Energies 2025, 18(15), 4063; https://doi.org/10.3390/en18154063 - 31 Jul 2025
Viewed by 334
Abstract
In response to increasingly stringent emission regulations, low-carbon fuels have received significant attention as sustainable energy sources for internal combustion engines. This study investigates four representative low-carbon fuels, methane, methanol, hydrogen, and ammonia, by systematically summarizing their combustion characteristics and emission profiles, along [...] Read more.
In response to increasingly stringent emission regulations, low-carbon fuels have received significant attention as sustainable energy sources for internal combustion engines. This study investigates four representative low-carbon fuels, methane, methanol, hydrogen, and ammonia, by systematically summarizing their combustion characteristics and emission profiles, along with a review of existing after-treatment technologies tailored to each fuel type. For methane engines, unburned hydrocarbon (UHC) produced during low-temperature combustion exhibits poor oxidation reactivity, necessitating integration of oxidation strategies such as diesel oxidation catalyst (DOC), particulate oxidation catalyst (POC), ozone-assisted oxidation, and zoned catalyst coatings to improve purification efficiency. Methanol combustion under low-temperature conditions tends to produce formaldehyde and other UHCs. Due to the lack of dedicated after-treatment systems, pollutant control currently relies on general-purpose catalysts such as three-way catalyst (TWC), DOC, and POC. Although hydrogen combustion is carbon-free, its high combustion temperature often leads to elevated nitrogen oxide (NOx) emissions, requiring a combination of optimized hydrogen supply strategies and selective catalytic reduction (SCR)-based denitrification systems. Similarly, while ammonia offers carbon-free combustion and benefits from easier storage and transportation, its practical application is hindered by several challenges, including low ignitability, high toxicity, and notable NOx emissions compared to conventional fuels. Current exhaust treatment for ammonia-fueled engines primarily depends on SCR, selective catalytic reduction-coated diesel particulate filter (SDPF). Emerging NOx purification technologies, such as integrated NOx reduction via hydrogen or ammonia fuel utilization, still face challenges of stability and narrow effective temperatures. Full article
(This article belongs to the Special Issue Engine Combustion Characteristics, Performance, and Emission)
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33 pages, 5578 KiB  
Review
Underwater Drag Reduction Applications and Fabrication of Bio-Inspired Surfaces: A Review
by Zaixiang Zheng, Xin Gu, Shengnan Yang, Yue Wang, Ying Zhang, Qingzhen Han and Pan Cao
Biomimetics 2025, 10(7), 470; https://doi.org/10.3390/biomimetics10070470 - 17 Jul 2025
Viewed by 578
Abstract
As an emerging energy-saving approach, bio-inspired drag reduction technology has become a key research direction for reducing energy consumption and greenhouse gas emissions. This study introduces the latest research progress on bio-inspired microstructured surfaces in the field of underwater drag reduction, focusing on [...] Read more.
As an emerging energy-saving approach, bio-inspired drag reduction technology has become a key research direction for reducing energy consumption and greenhouse gas emissions. This study introduces the latest research progress on bio-inspired microstructured surfaces in the field of underwater drag reduction, focusing on analyzing the drag reduction mechanism, preparation process, and application effect of the three major technological paths; namely, bio-inspired non-smooth surfaces, bio-inspired superhydrophobic surfaces, and bio-inspired modified coatings. Bio-inspired non-smooth surfaces can significantly reduce the wall shear stress by regulating the flow characteristics of the turbulent boundary layer through microstructure design. Bio-inspired superhydrophobic surfaces form stable gas–liquid interfaces through the construction of micro-nanostructures and reduce frictional resistance by utilizing the slip boundary effect. Bio-inspired modified coatings, on the other hand, realize the synergistic function of drag reduction and antifouling through targeted chemical modification of materials and design of micro-nanostructures. Although these technologies have made significant progress in drag reduction performance, their engineering applications still face bottlenecks such as manufacturing process complexity, gas layer stability, and durability. Future research should focus on the analysis of drag reduction mechanisms and optimization of material properties under multi-physical field coupling conditions, the development of efficient and low-cost manufacturing processes, and the enhancement of surface stability and adaptability through dynamic self-healing coatings and smart response materials. It is hoped that the latest research status of bio-inspired drag reduction technology reviewed in this study provides a theoretical basis and technical reference for the sustainable development and energy-saving design of ships and underwater vehicles. Full article
(This article belongs to the Section Biomimetic Surfaces and Interfaces)
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35 pages, 2895 KiB  
Review
Ventilated Facades for Low-Carbon Buildings: A Review
by Pinar Mert Cuce and Erdem Cuce
Processes 2025, 13(7), 2275; https://doi.org/10.3390/pr13072275 - 17 Jul 2025
Viewed by 671
Abstract
The construction sector presently consumes about 40% of global energy and generates 36% of CO2 emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding [...] Read more.
The construction sector presently consumes about 40% of global energy and generates 36% of CO2 emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding and the insulated structure, address that challenge. First, the paper categorises VFs by structural configuration, ventilation strategy and functional control into four principal families: double-skin, rainscreen, hybrid/adaptive and active–passive systems, with further extensions such as BIPV, PCM and green-wall integrations that couple energy generation or storage with envelope performance. Heat-transfer analysis shows that the cavity interrupts conductive paths, promotes buoyancy- or wind-driven convection, and curtails radiative exchange. Key design parameters, including cavity depth, vent-area ratio, airflow velocity and surface emissivity, govern this balance, while hybrid ventilation offers the most excellent peak-load mitigation with modest energy input. A synthesis of simulation and field studies indicates that properly detailed VFs reduce envelope cooling loads by 20–55% across diverse climates and cut winter heating demand by 10–20% when vents are seasonally managed or coupled with heat-recovery devices. These thermal benefits translate into steadier interior surface temperatures, lower radiant asymmetry and fewer drafts, thereby expanding the hours occupants remain within comfort bands without mechanical conditioning. Climate-responsive guidance emerges in tropical and arid regions, favouring highly ventilated, low-absorptance cladding; temperate and continental zones gain from adaptive vents, movable insulation or PCM layers; multi-skin adaptive facades promise balanced year-round savings by re-configuring in real time. Overall, the review demonstrates that VFs constitute a versatile, passive-plus platform for low-carbon buildings, simultaneously enhancing energy efficiency, durability and indoor comfort. Future advances in smart controls, bio-based materials and integrated energy-recovery systems are poised to unlock further performance gains and accelerate the sector’s transition to net-zero. Emerging multifunctional materials such as phase-change composites, nanostructured coatings, and perovskite-integrated systems also show promise in enhancing facade adaptability and energy responsiveness. Full article
(This article belongs to the Special Issue Sustainable Development of Energy and Environment in Buildings)
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17 pages, 1170 KiB  
Article
Effect of Sulfur Poisoning During Worldwide Harmonized Light Vehicles Test Cycle on NOx Reduction Performance and Active Sites of Selective Catalytic Reduction Filter
by Zhou Zhou, Fei Yu, Dongxia Yang, Shiying Chang, Xiaokun He, Yunkun Zhao, Jiangli Ma, Ting Chen, Huilong Lai and He Lin
Catalysts 2025, 15(7), 682; https://doi.org/10.3390/catal15070682 - 14 Jul 2025
Viewed by 439
Abstract
Selective catalytic reduction filter (SDPF) technology constitutes a critical methodology for controlling nitrogen oxide (NOx) and particulate matter emissions from light-duty diesel vehicles. A series of SDPFs with different sulfur poisoning times and concentrations were prepared using the worldwide harmonized light [...] Read more.
Selective catalytic reduction filter (SDPF) technology constitutes a critical methodology for controlling nitrogen oxide (NOx) and particulate matter emissions from light-duty diesel vehicles. A series of SDPFs with different sulfur poisoning times and concentrations were prepared using the worldwide harmonized light vehicles test cycle (WLTC). Bench testing revealed that sulfur poisoning diminished the catalyst’s NH3 storage capacity, impaired the transient NOx reduction efficiency, and induced premature ammonia leakage. After multiple sulfur poisoning incidents, the NOx reduction performance stabilized. Higher SO2 concentrations accelerated catalyst deactivation and hastened the attainment of this equilibrium state. The characterization results for the catalyst indicate that the catalyst accumulated the same sulfur content after tail gas poisoning with different sulfur concentrations and that sulfur existed in the form of SO42−. The sulfur species in low-sulfur-poisoning-concentration catalysts mainly included sulfur ammonia and sulfur copper species, while high-sulfur-poisoning-concentration catalysts contained a higher proportion of sulfur copper species. Neither species type significantly altered the zeolite coating’s crystalline structure. Sulfur ammonia species could easily lead to a significant decrease in the specific surface area of the catalyst, which could be decomposed at 500 °C to achieve NOx reduction performance regeneration. In contrast, sulfur copper species required higher decomposition temperatures (600 °C), achieving only partial regeneration. Full article
(This article belongs to the Section Environmental Catalysis)
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14 pages, 3936 KiB  
Article
Atums Green Conjugated Polymer Heterojunction Films as Blue-Sensitive Photodiodes
by Zahida Batool, Razieh Firouzihaji, Mariia Babiichuk, Aria Khalili, John C. Garcia, Jau-Young Cho, Preeti Gahtori, Lukas Eylert, Karthik Shankar, Sergey I. Vagin, Julianne Gibbs and Alkiviathes Meldrum
Polymers 2025, 17(13), 1770; https://doi.org/10.3390/polym17131770 - 26 Jun 2025
Viewed by 467
Abstract
Conjugated polymers (CPs) offer many attractive features for photodiodes and photovoltaics, including solution processability, ease of scale-up, light weight, low cost, and mechanical flexibility. CPs have a wide range of energy gaps; thus, the choice of the specific polymer determines the optimum operational [...] Read more.
Conjugated polymers (CPs) offer many attractive features for photodiodes and photovoltaics, including solution processability, ease of scale-up, light weight, low cost, and mechanical flexibility. CPs have a wide range of energy gaps; thus, the choice of the specific polymer determines the optimum operational wavelength range. However, there are relatively few CPs with a strong absorption in the blue region of the spectrum where the human eye is most sensitive (440 to 470 nm) and none with an energy gap at 2.75 eV (450 nm), which corresponds to the peak of the CIE-1931 z(λ) color-matching function and the dominant blue light emission wavelength in computer and smartphone displays. Blue-light detectors in this wavelength range are important for light hazard control, sky polarization studies, and for blue-light information devices, where 450 nm corresponds to the principal emission of GaN-based light sources. We report on a new CP called Atums Green (AG), which shows promising characteristics as a blue-light photodetection polymer optimized for exactly this range of wavelengths centered around 450 nm. We built and measured a simple photodetector made from spin-coated films of AG and showed that its photosensitivity can be improved by the addition of asphaltene, a low-cost carbonaceous waste product. Full article
(This article belongs to the Section Polymer Membranes and Films)
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17 pages, 4222 KiB  
Article
Grooved High-Reflective Films for Ultraviolet Emission Enhancement
by Hengrui Zhang, Zhanhua Huang and Lin Zhang
Photonics 2025, 12(7), 644; https://doi.org/10.3390/photonics12070644 - 25 Jun 2025
Viewed by 286
Abstract
Conventional ultraviolet microplasma sources typically lack a back-reflection structure, resulting in radiative power loss from the backside. To enhance the emission efficiency of ultraviolet microplasma devices around 220 nm, we propose a multilayer reflective coating composed of alternating high- and low-refractive-index layers of [...] Read more.
Conventional ultraviolet microplasma sources typically lack a back-reflection structure, resulting in radiative power loss from the backside. To enhance the emission efficiency of ultraviolet microplasma devices around 220 nm, we propose a multilayer reflective coating composed of alternating high- and low-refractive-index layers of Al2O3 and SiO2, within a V-shaped groove. Key structural parameters, including the number of alternating film layer pairs, groove width, and light source position, are investigated to show their effects on ultraviolet reflection characteristics. The results show that reducing the groove width greatly enhances light reflection. When the groove width is 6.5 μm, the device exhibits a reflection efficiency of 47.82% and power enhancement of 91.66%, representing improvements of 2.5-fold and 4.2-fold, respectively, compared to non-optimized cases. Device performance is also influenced by the offset of the light source, which is more sensitive along the horizontal direction. This study provides a practical solution for developing high-efficiency ultraviolet emission devices. Full article
(This article belongs to the Special Issue Recent Progress in Integrated Photonics)
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18 pages, 8036 KiB  
Article
Research on High-Temperature Frictional Performance Optimization and Synergistic Effects of Phosphate-Based Composite Lubricating Coatings
by Yong Ding, Shengjun Wang, Youxin Zhou, Hongmei Lv and Baoping Yang
Coatings 2025, 15(6), 704; https://doi.org/10.3390/coatings15060704 - 11 Jun 2025
Viewed by 497
Abstract
In high-temperature, high-pressure, and corrosive industrial environments, frictional wear of metallic components stands as a critical determinant governing the long-term operational reliability of mechanical systems. To address the challenge of traditional lubricating coating failure under a broad temperature range (−50 to 500 °C), [...] Read more.
In high-temperature, high-pressure, and corrosive industrial environments, frictional wear of metallic components stands as a critical determinant governing the long-term operational reliability of mechanical systems. To address the challenge of traditional lubricating coating failure under a broad temperature range (−50 to 500 °C), this study developed a phosphate-based composite lubricating coating. Through air-spraying technology and orthogonal experimental optimization, the optimal formulation was determined as follows: binder/filler ratio = 6:4, 5% graphite, 15% MoS2, and 10% aluminum powder. Experimental results demonstrated that at 500 °C, the coating forms an Al–O–P cross-linked network structure, with MoS2 oxidation generating MoO3 and aluminum powder transforming into Al2O3, significantly enhancing density and oxidation resistance. Friction tests revealed that the composite coating achieves a friction coefficient as low as 0.12 at room temperature with a friction time of 260 min. At 500 °C, the friction coefficient stabilizes at 0.24, providing 40 min of effective protection. This technology not only resolves the high-temperature instability of traditional coatings but also ensures an environmentally friendly preparation process with no harmful emissions, offering a technical solution for the protection of high-temperature equipment such as thermal power plant boiler tubes and petrochemical reactors. Full article
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18 pages, 13426 KiB  
Article
Minimizing Color Difference in AAO-Based Coatings for Urban Camouflage
by Yichen Wang, Xiujuan Reng, Dong Wang, Haifeng Liu and Yu Wu
Nanomaterials 2025, 15(12), 890; https://doi.org/10.3390/nano15120890 - 9 Jun 2025
Viewed by 360
Abstract
We explored anodic aluminum oxide (AAO) stealth materials combining low infrared emissivity and visible structural coloration through multi-parameter modulation. Using DC ion gold sputtering and UHV magnetron chromium sputtering, we successfully prepared an AAO stealth material with high-saturation visible structural coloration and low [...] Read more.
We explored anodic aluminum oxide (AAO) stealth materials combining low infrared emissivity and visible structural coloration through multi-parameter modulation. Using DC ion gold sputtering and UHV magnetron chromium sputtering, we successfully prepared an AAO stealth material with high-saturation visible structural coloration and low infrared emissivity (ε < 0.17). Quantitative evaluation based on the CIE Lab color difference model indicated that the gold-coated samples had high matching accuracy with PANTONE standard colors (ΔEab* < 1.6). The chromium-coated samples had slightly lower matching accuracy (ΔEab* < 3.0), but still displayed rich coloration, with color difference within human-perceptible tolerance limits. Full article
(This article belongs to the Section Synthesis, Interfaces and Nanostructures)
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13 pages, 1744 KiB  
Article
Numerical Optimization of Metamaterial-Enhanced Infrared Emitters for Ultra-Low Power Consumption
by Bui Xuan Khuyen, Pham Duy Tan, Bui Son Tung, Nguyen Phon Hai, Pham Dinh Tuan, Do Xuan Phong, Do Khanh Tung, Nguyen Hai Anh, Ho Truong Giang, Nguyen Phuc Vinh, Nguyen Thanh Tung, Vu Dinh Lam, Liangyao Chen and YoungPak Lee
Photonics 2025, 12(6), 583; https://doi.org/10.3390/photonics12060583 - 7 Jun 2025
Viewed by 477
Abstract
This study addresses the challenges of high-power consumption and complexity in conventional infrared (IR) gas sensors by integrating metamaterials and gold coatings into IR radiation sources to reduce radiation loss. In addition, emitter design optimization and material selection were employed to minimize conduction [...] Read more.
This study addresses the challenges of high-power consumption and complexity in conventional infrared (IR) gas sensors by integrating metamaterials and gold coatings into IR radiation sources to reduce radiation loss. In addition, emitter design optimization and material selection were employed to minimize conduction loss. Our metasurface exhibited superior performance, achieving a narrower full width at half maximum at 4197 and 3950 nm, resulting in more confined emission spectral ranges. This focused emission reduced energy waste at unnecessary wavelengths, improving efficiency compared to traditional blackbody emitters. At 300 °C, the device consumed only 6.8 mW, while maintaining temperature uniformity and a fast response time. This enhancement is promising for the operation of such sensors in IoT networks with ultra-low power consumption and at suitably low costs for widespread demands in high-technology farming. Full article
(This article belongs to the Special Issue Emerging Trends in Metamaterials and Metasurfaces Research)
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18 pages, 5787 KiB  
Article
Use of Advanced Piston Ring Coatings on Agricultural Engines
by Xiaochao He, Bang Liu, Eduardo Tomanik, Grzegorz Koszalka and Anna Orlova
Lubricants 2025, 13(6), 239; https://doi.org/10.3390/lubricants13060239 - 26 May 2025
Viewed by 893
Abstract
The use of combustion engines on agricultural vehicles will persist much longer than on-road vehicles. Introducing new technologies in agricultural engines is crucial to mitigating emissions while accounting for customer cost-sensitivity, harsh operation conditions, and typically sub-optimal maintenance. This work describes the use [...] Read more.
The use of combustion engines on agricultural vehicles will persist much longer than on-road vehicles. Introducing new technologies in agricultural engines is crucial to mitigating emissions while accounting for customer cost-sensitivity, harsh operation conditions, and typically sub-optimal maintenance. This work describes the use of CrN and tetrahedral amorphous carbon (ta-C) DLC-coated rings in small agricultural diesel engines. Compared with the gas nitride rings, the CrN and the ta-C DLC coatings exhibited, respectively, 74% and 86% lower wear in rig tests. The DLC also presented a very low coefficient of friction and high resistance to scuffing. A similar wear trend was observed on durability engine tests, where the CrN top ring showed an 80% lower wear rate than the GNS used in a similar engine. Wear on the DLC oil ring was below the measurement capability. Liner radial wear was measured on the piston ring reversal points in four angular positions, and except for one position, was lower than 3 µm. At the end of the test, engine performance and emissions are nearly identical to those at the test’s start, demonstrating that the use of advanced tribological solutions can significantly contribute to emissions mitigation in agricultural engines. Full article
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15 pages, 2949 KiB  
Article
Evaluation of Temperature Regulation Efficiency of a Bilayer Coating on Glass with Evaporative and Radiative Cooling for Energy Management
by Huanying Zhang, Yonghang Yu, Dedong Ji, Chen Zhou and Shengyang Yang
Molecules 2025, 30(9), 2042; https://doi.org/10.3390/molecules30092042 - 3 May 2025
Viewed by 526
Abstract
With the increasing demand for energy-efficient and sustainable building materials, innovative cooling technologies have become a key focus in the construction industry. This study developed a double-layer cooling coating integrating evaporation and radiation mechanisms. The first layer consists of a TiO2/PUA [...] Read more.
With the increasing demand for energy-efficient and sustainable building materials, innovative cooling technologies have become a key focus in the construction industry. This study developed a double-layer cooling coating integrating evaporation and radiation mechanisms. The first layer consists of a TiO2/PUA radiation layer, where rutile TiO2 is incorporated into polyurethane acrylate (PUA) resin to enhance solar reflectivity. The second layer is a P(NVP-co-NMA) hydrogel, which evaporates water at high temperatures and absorbs moisture from the air at low temperatures, eliminating the need for additional water supply systems. The TiO2/PUA@P(NVP-co-NMA) coating demonstrates high solar reflectivity and infrared emissivity, effectively reducing indoor temperatures by dissipating heat through water evaporation and radiative cooling. Testing showed a temperature reduction of approximately 7.6 °C in a small house with this coating under simulated conditions. This material demonstrates favorable properties that may make it suitable for applications on building roofs and exterior walls, potentially addressing some limitations of conventional evaporative or radiative cooling systems. Its observed multi-effect cooling performance indicates promise for contributing to energy savings in sustainable building designs. Full article
(This article belongs to the Section Materials Chemistry)
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27 pages, 3097 KiB  
Article
An Improved Whale Optimization Algorithm for the Clean Production Transformation of Automotive Body Painting
by Qin Yang, Xinning Li, Teng Yang, Hu Wu and Liwen Zhang
Biomimetics 2025, 10(5), 273; https://doi.org/10.3390/biomimetics10050273 - 28 Apr 2025
Viewed by 425
Abstract
Research on clean production in automotive painting processes is a core component of achieving green manufacturing, addressing environmental regulatory challenges, and advancing sustainable development in the automotive industry by reducing volatile organic compound (VOC) emissions, optimizing resource utilization, and minimizing energy consumption. To [...] Read more.
Research on clean production in automotive painting processes is a core component of achieving green manufacturing, addressing environmental regulatory challenges, and advancing sustainable development in the automotive industry by reducing volatile organic compound (VOC) emissions, optimizing resource utilization, and minimizing energy consumption. To reduce pollutants generated by automotive painting processes and improve coating efficiency, this study proposes a clean production method for automotive body painting based on an improved whale optimization algorithm from the perspective of “low-carbon consumption and emission-reduced production”. A multi-level, multi-objective decision-making model is developed by integrating three dimensions of clean production: material flow (optimizing material costs), energy flow (minimizing painting energy consumption), and environmental emission flow (reducing carbon emissions and processing time). The whale optimization algorithm is enhanced through three key modifications: the incorporation of nonlinear convergence factors, elite opposition-based learning, and dynamic parameter self-adaptation, which are then applied to optimize the automotive painting model. Experimental validation using the painting processes of TJ Corporation’s New Energy Vehicles (NEVs) demonstrates the superiority of the proposed algorithm over the MHWOA, WOA-RBF, and WOA-VMD. Results show that the method achieves a 42.1% increase in coating production efficiency, over 98% exhaust gas purification rate, 18.2% average energy-saving improvement, and 17.9% reduction in manufacturing costs. This green transformation of low-carbon emission-reduction infrastructure in painting processes delivers significant economic and social benefits, positioning it as a sustainable solution for the automotive industry. Full article
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16 pages, 4986 KiB  
Article
Performance of 3D Network-Structured LiFePO4@Li3V2(PO4)3/Carbon Nanofibers via Coaxial Electrospinning as Self-Supporting Cathode for Lithium-Ion Batteries
by Ruixia Chu, Hongtao Zhang, Wanyou Huang, Fangyuan Qiu, Yan Wang, Zhenyu Li and Xiaoyue Jin
Materials 2025, 18(9), 1969; https://doi.org/10.3390/ma18091969 - 26 Apr 2025
Viewed by 608
Abstract
Lithium-ion batteries (LIBs) with high power, high capacity, and support for fast charging are increasingly favored by consumers. As a commercial electrode material for power batteries, LiFePO4 was limited from further wide application due to its low conductivity and lithium-ion diffusion rate. [...] Read more.
Lithium-ion batteries (LIBs) with high power, high capacity, and support for fast charging are increasingly favored by consumers. As a commercial electrode material for power batteries, LiFePO4 was limited from further wide application due to its low conductivity and lithium-ion diffusion rate. The development of advanced architectures integrating rational conductive networks with optimized ion transport pathways represents a critical frontier in optimizing the performance of cathode materials. In this paper, a novel self-supporting cathode material (designated as LFP@LVP-CES) was synthesized through an integrated coaxial electrospinning and controlled pyrolysis strategy. This methodology directly converts LiFePO4, Li3V2(PO4)3, and polyacrylonitrile (PAN)) into flexible, binder-free cathodes with a hierarchical structural organization. The 3D carbon nanofiber (CNF) matrix synergistically integrates LiFePO4 (Li/Fe/POx) and Li3V2(PO4)3 (Li/V/POx) nanoparticles, where CNFs act as a conductive scaffold to enhance electron transport, while the POx polyanionic frameworks stabilize Li+ diffusion pathways. Morphological characterizations (SEM and TEM) revealed a 3D cross-connected carbon nanofiber matrix (diameter: 250 ± 50 nm) uniformly embedded with active material particles. Electrochemical evaluations demonstrated that the LFP@LVP-CES cathode delivers an initial specific capacity of 165 mAh·g−1 at 0.1 C, maintaining 80 mAh·g−1 at 5 C. Notably, the material exhibited exceptional rate capability and cycling stability, demonstrating a 96% capacity recovery after high-rate cycling upon returning to 0.1 C, along with 97% capacity retention over 200 cycles at 1 C. Detailed kinetic analysis through EIS revealed significantly reduced Rct and increased Li+ diffusion. This superior electrochemical performance can be attributed to the synergistic effects between the 3D conductive network architecture and dual active materials. Compared with traditional coating processes and high-temperature calcination, the preparation of controllable electrospinning and low-temperature pyrolysis to some extent avoid the introduction of harmful substances and reduce raw material consumption and carbon emissions. This original integration strategy establishes a paradigm for designing freestanding electrode architectures through 3D structural design combined with a bimodal active material, providing critical insights for next-generation energy storage systems. Full article
(This article belongs to the Section Advanced Nanomaterials and Nanotechnology)
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21 pages, 22568 KiB  
Article
Properties Evaluation of a Novel Entropy-Stabilized Ceramic (La0.25Ce0.25Nd0.25Sm0.25)Ti2Al9O19 with Enhanced CMAS Corrosion Resistance for Thermal Barrier Coating Applications
by Fuxing Ye, Ziqi Song, Fanwei Meng and Sajid Ali
Materials 2025, 18(8), 1778; https://doi.org/10.3390/ma18081778 - 13 Apr 2025
Viewed by 511
Abstract
In this work, a novel potential thermal barrier coating material entropy-stabilized titanium–aluminum oxide (La0.25Ce0.25Nd0.25Sm0.25)Ti2Al9O19 (META) was successfully synthesized by the solid-state reaction method, and its thermophysical properties, phase stability, infrared [...] Read more.
In this work, a novel potential thermal barrier coating material entropy-stabilized titanium–aluminum oxide (La0.25Ce0.25Nd0.25Sm0.25)Ti2Al9O19 (META) was successfully synthesized by the solid-state reaction method, and its thermophysical properties, phase stability, infrared emissivity, mechanical properties, and CMAS corrosion resistance were systematically investigated. The results demonstrated that META exhibits low thermal conductivity at 1100 °C (1.84 W·(m·K)−1), with a thermal expansion coefficient (10.50 × 10−6 K−1, 1000–1100 °C) comparable to yttria-stabilized zirconia (YSZ). Furthermore, META displayed desirable thermal stability, high emissivity within the wavelength range of 2.5–10 μm, and improved mechanical properties. Finally, META offers superior corrosion resistance due to its excellent infiltration inhibiting. The bi-layer structure on the corrosion surface prevents the penetration of the molten CMAS. Additionally, doping small-radius rare-earth elements thermodynamically stabilizes the reaction layer. The results of this study indicate that (La0.25Ce0.25Nd0.25Sm0.25)Ti2Al9O19 has the potential to be a promising candidate for thermal barrier coating materials. Full article
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