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37 pages, 15652 KB  
Review
Multi-Scale Structural Regulation of Boron-Doped Diamond via Doping, Modification, and Annealing for Water Pollutant Sensing
by Xue Wang, Shuxian Leng, Xiang Yu, Shengmao Lu and Junsheng Wang
Nanomaterials 2026, 16(13), 834; https://doi.org/10.3390/nano16130834 (registering DOI) - 7 Jul 2026
Abstract
This review covers literature published up to June 2026. Detecting various water pollutants quickly and reliably remains a challenge. Boron-doped diamond (BDD) electrodes, particularly when fabricated as nanostructured thin films such as nanocones or nanowalls, offer a wide electrochemical window, low background current, [...] Read more.
This review covers literature published up to June 2026. Detecting various water pollutants quickly and reliably remains a challenge. Boron-doped diamond (BDD) electrodes, particularly when fabricated as nanostructured thin films such as nanocones or nanowalls, offer a wide electrochemical window, low background current, and excellent chemical stability, making them promising tools for electrochemical sensing. However, unmodified BDD electrodes face an inherent trade-off among conductivity, active site density, and interfacial stability, a phenomenon termed herein the “sensitivity-selectivity-stability triangle bottleneck”, which severely limits practical performance. In this review, we demonstrate how multi-scale structural regulation can circumvent this bottleneck. Specifically, a triple strategy comprising boron doping, surface modification, and post-annealing treatment is proposed and evaluated. First, the effect of boron doping level on conductivity and active site density is discussed. Second, two common surface modification approaches are examined: carbon nanomaterials (which increase surface area and form conductive networks) and metal nanoparticles (which enhance catalytic activity and interfacial charge transfer). Third, post-annealing is highlighted as a key synergistic step that locks the modified layer and stabilizes the interface. Together, these three components form an integrated framework. To provide concrete guidance, the performance of each strategy is compared for representative water pollutants, including heavy metal ions, phenolic compounds, and emerging contaminants such as antibiotics and pesticides, with emphasis on sensitivity, selectivity, and stability. Representative detection limits achieved include 0.01 μg/L for Pb2+, 5 nM for acetaminophen, and 0.32 fM for PCB-77, demonstrating the effectiveness of the triple structural regulation strategy. Finally, in line with the theme of this Nanomaterials Special Issue on nanostructured thin films, current challenges in structural regulation are summarized, and future directions, including multi-parameter optimization, AI-assisted high-throughput screening, and real-world testing, are outlined. The goal is to offer practical structure-performance guidelines for designing BDD-based electrochemical sensors that are both high-performing and durable. Full article
(This article belongs to the Special Issue Preparation, Properties and Applications of Nanostructured Thin Films)
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33 pages, 65191 KB  
Article
Frequency-Adaptive Current Control with Kalman Filter-Based Observer for Multiple Grid-Connected Inverters Under Harsh Grid Distortion
by Seung-Yong Yeo, Min Kang, Luong Duc-Tai Cu and Kyeong-Hwa Kim
Energies 2026, 19(13), 3216; https://doi.org/10.3390/en19133216 (registering DOI) - 7 Jul 2026
Abstract
As renewable energy source-based distributed generation is more widely connected to the grid, stable current control and power quality improvement in grid-connected inverters (GCIs) become more important. To satisfy increasing power demand, multi-inverter systems connected to the grid in parallel are being widely [...] Read more.
As renewable energy source-based distributed generation is more widely connected to the grid, stable current control and power quality improvement in grid-connected inverters (GCIs) become more important. To satisfy increasing power demand, multi-inverter systems connected to the grid in parallel are being widely adopted. However, parallel operation may degrade current quality and stability because of inverter interactions under harsh grid conditions. In particular, grid voltage harmonics, voltage imbalance, and frequency variations can also impair current control performance and system stability. To address these concerns, a frequency-adaptive current controller integrated with a Kalman filter (KF)-based observer is developed to ensure a stable operation of multiple GCIs. Moreover, a stability evaluation is presented for multi-inverter systems by using admittance-based stability analysis. A Kalman filter-based state observer is applied to improve the estimation accuracy under noisy measurement conditions. In addition, a moving average filter-based phase-locked loop (MAF-PLL) is applied to improve the detection accuracy and reliability of the grid frequency and phase angle under harsh grid conditions to ensure an effective frequency-adaptive control design. The effectiveness and performance of the proposed current controller are assessed through the PSIM simulations. The simulation results show that the MAF-PLL reduces the maximum frequency fluctuation from ±7 Hz to ±1.1 Hz. In addition, the KF-based observer reduces the RMS estimation error to 0.0001 A. On the other hand, those values are 1.3 A with the conventional observer and 0.0003 A with the LQR-based observer, respectively. The practicality of the proposed scheme is also confirmed experimentally using 2 kW parallel multiple GCI prototype systems under harsh grid conditions. Full article
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16 pages, 9637 KB  
Article
Large Improvement of the Mechanical Strength of Carbon Nanotube Films by Joule Heating Dominated Post Treatments
by Zujia Hu, Yifan Feng, Heng Zhang, Kangfei Liu, Xinran Cheng, Yunxiao Du and Jiannong Wang
Materials 2026, 19(13), 2917; https://doi.org/10.3390/ma19132917 - 7 Jul 2026
Abstract
Carbon nanotube (CNT) films prepared via floating catalyst chemical vapor deposition generally suffer from residual iron impurities, structural defects, and weak inter-tube interfaces, which severely limit their mechanical performance. Here, we propose a post-treatment approach, which is dominated by Joule heating, to substantially [...] Read more.
Carbon nanotube (CNT) films prepared via floating catalyst chemical vapor deposition generally suffer from residual iron impurities, structural defects, and weak inter-tube interfaces, which severely limit their mechanical performance. Here, we propose a post-treatment approach, which is dominated by Joule heating, to substantially improve the mechanical properties of CNT films. Acid washing after Joule heating effectively removes iron catalyst and amorphous carbon, increasing the specific strength from 0.64 N/tex to 2.96 N/tex. Pre-stretching induces alignment of the CNTs along the stretching direction, further raising the specific strength to 5.57 N/tex. Subsequent Joule heating not only raises graphitization degree and repairs lattice defects but also transforms the weak van der Waals contacts between tubes into continuous carbon networks, leading to network densification and locking of the aligned structure. The final specific strength reaches 7.04 N/tex and true tensile strength 8.05 GPa, surpassing previous representative carbon materials. The purification mechanism of Joule heating depends on the initial iron content of the film: for high-iron films, iron melts, migrates and forms Fe/Fe3C@C core–shell particles, which can be converted into hollow carbon shells via acid etching; for low-iron films, iron is removed via atomic diffusion and evaporation. This work provides a fast, controllable and synergistic technical route for the preparation of high-performance CNT macrostructures. Full article
(This article belongs to the Section Advanced Nanomaterials and Nanotechnology)
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17 pages, 1030 KB  
Article
Resolved-GSERF: A Proficient NMR Approach for Identifying Accurate J-Coupling Constants of Targeted Peaks from Spectral Congestion
by Xiaoqing Lin
Molecules 2026, 31(13), 2386; https://doi.org/10.3390/molecules31132386 - 7 Jul 2026
Abstract
SElective ReFocusing (SERF)-based experiments present an effective tool for discerning proton–proton J-coupling constants of targeted spectral peaks. Nevertheless, the performance of SERF experiments highly relies on the selective excitation of isolated signals. The extraction of targeted peaks from spectral congestion, even from [...] Read more.
SElective ReFocusing (SERF)-based experiments present an effective tool for discerning proton–proton J-coupling constants of targeted spectral peaks. Nevertheless, the performance of SERF experiments highly relies on the selective excitation of isolated signals. The extraction of targeted peaks from spectral congestion, even from spectral overlap, generally poses a challenge to SERF-based experiments for accurate analysis of associated coupling constants due to the existence of redundant axial peaks and unwanted couplings. Herein, we propose an NMR method called resolved-GSERF to address this challenge and achieve accurate J-coupling measurements on targeted spectral peaks. In this approach, the selective magnetization transfer scheme with an appropriate spin-lock mixing time is employed to isolate the targeted peak signal from the spectral congestion region, thereby enhancing spectral sensitivity and resolution. The slice-selection-based GSERF refocusing encoding scheme is subsequently applied to extract J-coupling constant information of the targeted peak. The experimental results on complex chemical and biomedical samples suggest that the proposed approach offers a practical solution to the challenge of spectral congestion for identifying accurate J-couplings. Full article
(This article belongs to the Section Physical Chemistry)
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26 pages, 9045 KB  
Article
Remote Sensing-Based Identification of Spatial Spillovers and Transmission Pathways in the Heat–Energy–Carbon Nexus: Evidence from the Yangtze River Delta
by Gaoneng Lai, Lei Jiang, Yingbiao Chen, Shitai Bao, Jinxin Duan and Zuojie Zhu
Remote Sens. 2026, 18(13), 2222; https://doi.org/10.3390/rs18132222 - 6 Jul 2026
Abstract
The urban heat island (UHI) effect represents a critical urban climate phenomenon arising from the combined pressures of rapid urbanization and climate warming. Although its association with carbon emissions has received increasing scholarly attention, the underlying behavior-mediated pathways and cross-regional spillover patterns remain [...] Read more.
The urban heat island (UHI) effect represents a critical urban climate phenomenon arising from the combined pressures of rapid urbanization and climate warming. Although its association with carbon emissions has received increasing scholarly attention, the underlying behavior-mediated pathways and cross-regional spillover patterns remain insufficiently understood. Using multi-source geospatial data for the Yangtze River Delta urban agglomeration from 2014 to 2023, this study develops a multi-scale analytical framework integrating 1 km urban agglomeration exploratory analysis and 5 km spatial econometric modeling. Anthropogenic Energy Activity Intensity (AEAI) is constructed as a proxy for energy-related human activities, and a spatial Durbin model, combined with a spatial mediation approach, is employed to examine the spatial associations and statistically mediated pathways within the “heat-energy-carbon” nexus. The results indicate that: (1) carbon emissions exhibit significant positive spatial spillover effects, consistent with thermal diffusion processes and socioeconomic network interactions; (2) AEAI represents a substantial partial statistical mediation pathway in the association between UHI and carbon emissions, accounting for 44.63% of the total association. This suggests that the UHI–carbon emission linkage is partly embedded in spatial patterns of energy-intensive human activities rather than reflecting a purely direct thermal effect. These findings suggest that regional climate governance may need to move beyond single-city interventions and purely physical cooling strategies toward integrated approaches that combine cross-regional coordination with behavioral regulation. Promoting passive cooling-oriented urban planning and demand-side energy transitions may help reduce carbon lock-in risks and support the development of climate-resilient urban agglomerations. Full article
(This article belongs to the Section Urban Remote Sensing)
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30 pages, 17839 KB  
Article
Hysteresis and Optimal Pricing of Subscriptions with Cancellation Cost
by Dmitrii Rachinskii
Axioms 2026, 15(7), 506; https://doi.org/10.3390/axioms15070506 - 5 Jul 2026
Viewed by 60
Abstract
We develop a stochastic Stackelberg model of a subscription market with cancellation costs. A representative consumer chooses when to subscribe to and cancel a service as the utility derived from the subscription evolves according to a diffusion process, while the firm selects the [...] Read more.
We develop a stochastic Stackelberg model of a subscription market with cancellation costs. A representative consumer chooses when to subscribe to and cancel a service as the utility derived from the subscription evolves according to a diffusion process, while the firm selects the subscription fee and cancellation cost to maximize its expected payoff. The consumer’s problem is equivalent to the classical real-options model of entry and exit under uncertainty with adjustment costs and exhibits a two-threshold policy with an inaction band and hysteresis. Unlike the standard formulation, in which the optimal thresholds are characterized implicitly through a system of nonlinear equations, we derive an explicit parametric solution in closed form. This solution reduces the firm’s optimization problem to a two-dimensional unconstrained problem and yields a detailed characterization of the optimal pricing policy. We show that the firm’s strategy exhibits three qualitatively distinct regimes depending on the initial utility level. For small utility levels, the optimal cancellation cost is zero. In an intermediate regime, the firm’s optimal policy induces the consumer to set the entry threshold equal to the initial utility level, resulting in immediate subscription. For sufficiently large utility levels, the firm induces permanent lock-in by setting a high cancellation cost and a low subscription fee: the consumer subscribes immediately and never subsequently unsubscribes. The transition between the latter two regimes is discontinuous and results from competition between two local maxima of the firm’s payoff function. We then extend the model to a heterogeneous population of consumers. The superposition of individual two-threshold subscription strategies generates a Preisach hysteresis operator describing the aggregate dependence of the firm’s revenue on the utility dynamics. The discontinuous regime transition persists under heterogeneity, demonstrating the robustness of the underlying mechanism. The Preisach representation predicts complex history dependence and long-term effects of temporary utility shocks. For a gamma distribution of consumer preferences, the firm’s expected payoff is obtained in closed form in terms of incomplete gamma functions. Full article
11 pages, 2529 KB  
Article
Numerical Investigation of Transient Mode-Locking Dynamics in a SESAM-Based Yb-Doped Picosecond Fiber Laser
by Yufei Mao, Yuyan Zhao, Jiancheng Zheng and Chibiao Liu
Photonics 2026, 13(7), 651; https://doi.org/10.3390/photonics13070651 - 5 Jul 2026
Viewed by 116
Abstract
This study investigates the transient mode-locking dynamics and parameter-sensitive pulse evolution in a ytterbium-doped mode-locked fiber laser under near-zero net-dispersion conditions. The influence of gain saturation energy Es, modulation depth T0, saturation power Psat, and non-saturable loss [...] Read more.
This study investigates the transient mode-locking dynamics and parameter-sensitive pulse evolution in a ytterbium-doped mode-locked fiber laser under near-zero net-dispersion conditions. The influence of gain saturation energy Es, modulation depth T0, saturation power Psat, and non-saturable loss Pns on transient pulse evolution and mode-locking buildup is comparatively analyzed using the complex Ginzburg–Landau equation. Numerical results indicate that increasing the gain saturation energy Es weakens the gain saturation effect and prolongs the transient buildup process of stable mode locking, while simultaneously promoting intracavity energy accumulation and spectral broadening through enhanced nonlinear phase evolution. Increasing the modulation depth T0 accelerates mode-locking initiation through enhanced nonlinear transmission contrast, whereas saturation power Psat mainly affects the transient intracavity energy accumulation process during pulse evolution. Increasing the non-saturable loss Pns suppresses low-intensity fluctuations during pulse buildup and contributes to faster gain–loss stabilization inside the laser cavity. Under near-zero net-dispersion conditions, stable picosecond pulse evolution with consistent spectral and temporal characteristics is numerically obtained. The present results provide useful physical insight into gain–loss interaction mechanisms and transient dissipative-soliton dynamics in ultrafast fiber lasers. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
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29 pages, 1584 KB  
Article
Carbon-Neutrality Gap in Resource-Based Cities: STIRPAT Simulation and Cross-Validation of Carbon-Sink Models
by Xinlei Liu, Ya Yang, Ping Shen, Ying Lv, Liu Yang and Xingyu Liu
Sustainability 2026, 18(13), 6722; https://doi.org/10.3390/su18136722 - 2 Jul 2026
Viewed by 121
Abstract
Coal-dominated resource-based cities face a structurally embedded carbon-neutrality gap, shaped by the simultaneous pressures of industrial carbon lock-in and ecological fragility. China’s dual-carbon targets impose severe transition pressure on such regions, where carbon-intensive industries, strong path dependence, and limited decarbonization flexibility compound the [...] Read more.
Coal-dominated resource-based cities face a structurally embedded carbon-neutrality gap, shaped by the simultaneous pressures of industrial carbon lock-in and ecological fragility. China’s dual-carbon targets impose severe transition pressure on such regions, where carbon-intensive industries, strong path dependence, and limited decarbonization flexibility compound the challenge. Forest carbon sinks offer a cost-effective approach for offsetting residual emissions. However, water scarcity and restricted land-carrying capacity impose hard ecological ceilings on sink expansion in semi-arid areas such as the Loess Plateau. Existing studies have largely focused on national or provincial scales, with few addressing the coupled dynamics of industrial emissions and water-limited sink capacity at the county level. This study examines Shenmu, China’s largest coal-producing county-level city and a national energy-chemical industrial base. Using time-series data spanning 2010–2025, we project multi-scenario carbon emissions via an extended STIRPAT model with ridge regression, estimate forest carbon sink potential through a growing-stock (GS) gradient model cross-validated against GM(1,1), and systematically quantify the resulting carbon-neutrality gap. The results show that energy activities dominate total emissions throughout, consistently exceeding 90% of the aggregate. Under the baseline scenario, emissions reach 407.96 MtCO2eq in 2060 without peaking; under moderate mitigation, emissions peak at 269.39 MtCO2eq in 2050; under strengthened mitigation, emissions peak at 225.80 MtCO2eq before 2040 and subsequently decline. Forest carbon sinks are projected to offset 2.1–11.2% of emissions by 2060 under all scenarios, constrained by climatic aridity, finite afforestation potential, and water–soil carrying capacity thresholds. The carbon-neutrality gap remains structurally positive across every scenario, reflecting a fundamental asymmetry between rigid emission growth and ecologically bounded sink capacity. These findings indicate that only an integrated pathway combining industrial restructuring, energy decarbonization, diversified ecological sinks, and CCUS deployment can substantially narrow the gap; carbon neutrality by 2060 is unattainable through natural sinks alone. Full article
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30 pages, 14754 KB  
Article
GABA Regulates Ca2+ Oscillations and Synchronization in Pancreatic Beta Cells
by Vladimir Grubelnik and Marko Marhl
Metabolites 2026, 16(7), 462; https://doi.org/10.3390/metabo16070462 - 1 Jul 2026
Viewed by 300
Abstract
Background/Objectives: Gamma-aminobutyric acid (GABA) is increasingly recognized as an important modulator of pancreatic beta-cell function, but the mechanisms by which it regulates intracellular Ca2+ oscillations and coordinated beta-cell activity remain insufficiently understood. The aim of this study was to investigate how GABA [...] Read more.
Background/Objectives: Gamma-aminobutyric acid (GABA) is increasingly recognized as an important modulator of pancreatic beta-cell function, but the mechanisms by which it regulates intracellular Ca2+ oscillations and coordinated beta-cell activity remain insufficiently understood. The aim of this study was to investigate how GABA influences the amplitude, frequency, phase adjustment, entrainment, and synchronization of beta-cell Ca2+ oscillations. Methods: We developed a reduced ATP–Ca2+ oscillation model, based on established beta-cell oscillatory frameworks, and coupled it to the GABA-shunt subsystem derived from our previously established Dual Anaplerotic Model. The model incorporates explicit dynamics of cytosolic Ca2+, endoplasmic reticulum Ca2+, ATP, and a regulatory variable controlling Ca2+ influx, while the interstitial GABA signal is represented as a delayed feedback signal acting on cellular excitability. Single-cell and two-cell simulations were performed to analyze GABA-dependent oscillatory regulation and intercellular coupling. Results: The model reproduced key experimental observations under both control and GABA-deficient conditions, including reduced Ca2+-oscillation amplitude and a prolonged oscillation period when GABA production was suppressed. Mechanistically, GABA affected single-cell oscillations through two complementary pathways: metabolically, by modulating ATP production through PEP-related and TCA-related contributions linked to the GABA shunt, and as an interstitial/paracrine signal, by adjusting the phase of Ca2+ influx through fast and delayed inhibitory feedback. In the reduced two-cell model, delayed interstitial GABA signaling could phase-lock non-identical oscillators over finite ranges of parameter mismatch. When included as an additional weak effective term, electrical coupling broadened these ranges, consistent with a complementary interaction between GABA-mediated phase adjustment and established electrical coupling. Conclusions: GABA acts as a dual regulator of beta-cell dynamics, linking intracellular metabolism to Ca2+-oscillation patterning and promoting coordinated activity through intercellular phase adjustment. The model provides a mechanistic framework connecting GABA metabolism, ATP dynamics, Ca2+ signaling, and beta-cell synchronization in pancreatic islets. Full article
(This article belongs to the Section Cell Metabolism)
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35 pages, 770 KB  
Article
The Impact of Digital Government on Regional Scientific and Technological Innovation Capacity
by Zhengang Zhang and Defei Wang
Systems 2026, 14(7), 756; https://doi.org/10.3390/systems14070756 - 1 Jul 2026
Viewed by 205
Abstract
Background and Purpose: Contemporary digital government initiatives in China face a well-documented real-world paradox: massive fiscal outlays on digital governance coexist with marked disequilibrium in regional innovation returns. Two structural mismatches define this paradox. First, local governments overwhelmingly prioritize high-visibility hardware investments such [...] Read more.
Background and Purpose: Contemporary digital government initiatives in China face a well-documented real-world paradox: massive fiscal outlays on digital governance coexist with marked disequilibrium in regional innovation returns. Two structural mismatches define this paradox. First, local governments overwhelmingly prioritize high-visibility hardware investments such as data centers and large AI models, while neglecting deep-seated institutional reforms including cross-departmental business process reengineering and factor market liberalization. The pervasive phenomenon of “aggregated but non-interoperable data, and interoperable data left unused” reflects a severe asynchrony between rapid technological deployment and lagging institutional restructuring. Second, comparable digital investments yield vastly divergent innovation dividends across eastern, central, and western regions, with regional divergence entrenching into a rigid “higher in the east lower in the west, higher in the south lower in the north” pattern. Extant literature, largely confined to the lens of “instrumental rationality,” reduces digital government to an exogenous technological variable, leaving it unable to explain this core practical puzzle of “homogeneous inputs generating heterogeneous returns.” Moving beyond the narrow “technology-enabled governance” narrative, this study draws on the Digital-Era Governance (DEG) paradigm to investigate the actual impact of institutional restructuring on regional scientific and technological innovation capacity, aiming to provide empirical evidence to unlock the inefficiency lock-in prevalent in digital governance practices. Research Methods: This study uses 280 prefecture-level cities and above in China from 2018 to 2023 as the research sample and constructs a two-way fixed-effects model for benchmark regression analysis. To address endogeneity, the average level of digital government development in other cities within the same province is used as an instrumental variable, and the 2SLS method is employed to identify the causal effect. On this basis, a series of robustness checks are conducted, including excluding the special impact of the COVID-19 pandemic, substituting core variable measures, and decomposing the dimensions of the core explanatory variables, to ensure the reliability of the research conclusions. For mechanism identification, the Bootstrap sampling method is used to test the dual mediating effects of “digital industry agglomeration” and “resource misallocation alleviation”; furthermore, moderating effects and heterogeneity analysis models are introduced to reveal the boundary constraints of regional economic development levels and city types on the empowerment effect. Main Findings: Empirical results show that: (1) Digital government construction significantly improves regional scientific and technological innovation capacity, and this conclusion remains valid after endogeneity treatment and robustness checks. (2) Mechanism analysis demonstrates that digital government drives innovation through the dual paths of “promoting digital industry agglomeration” and “alleviating resource misallocation,” with the marginal contribution of alleviating resource misallocation being significantly higher than that of industrial agglomeration. This suggests that, in transitional economies, eliminating institutional frictions in factor mobility brings greater innovation dividends than simply building physical spatial clusters. (3) Moderating effects indicate that the higher the level of regional economic development, the stronger the innovation empowerment effect of digital government. (4) Heterogeneity analysis further reveals that the innovation dividends of digital government are significant only in non-resource-based cities, non-central cities, and large and medium-sized cities, while in resource-based cities, central cities, and small cities, the effects are systematically absorbed and not significant. Research Conclusions and Contributions: This study breaks through the ontological limitations of existing research that views digital government as a technological tool, grounding it within the DEG theoretical framework and confirming that digital government is an institutional force in the reconstruction of regional innovation ecosystems. The findings suggest to policymakers that digital government construction should promote a shift from a “technology-oriented” to an “institution-oriented” approach. The policy focus should shift from mere infrastructure expansion to the elimination of deep-seated institutional frictions, the improvement of factor allocation efficiency, and the advancement of gradients and the implementation of classified governance, all guided by regional economic foundations and heterogeneity characteristics. Full article
(This article belongs to the Topic Data Science and Intelligent Management)
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35 pages, 26337 KB  
Article
Mapping China’s New Materials Industry Chain for Sustainable Development: Evidence from Listed-Firm Investment-Based City Association Networks
by Wenjun Qiu, Tianyi Qin and Qingjian Zhao
Sustainability 2026, 18(13), 6597; https://doi.org/10.3390/su18136597 - 29 Jun 2026
Viewed by 314
Abstract
Understanding the spatial organization of the new materials industry chain is essential for promoting sustainable industrial development. However, existing research rarely examines it as an integrated intercity network spanning multiple segments and specialized sub-sectors. To address this gap, this study constructs the New [...] Read more.
Understanding the spatial organization of the new materials industry chain is essential for promoting sustainable industrial development. However, existing research rarely examines it as an integrated intercity network spanning multiple segments and specialized sub-sectors. To address this gap, this study constructs the New Materials City Association Network (NM-CityNet) using firm-level cross-regional equity investment data for 294 Chinese cities from 2010 to 2024. NM-CityNet includes two dimensions: segment networks (upstream, midstream, downstream) and sub-sector networks (advanced basic materials, critical strategic materials, and frontier new materials). A chain-lock model is applied, combined with social network analysis and the quadratic assignment procedure. Location quotients are integrated with weighted degree to capture specialized division-of-labour patterns. Using these methods, this study reveals the regional distribution, network structure, specialization patterns, and formation mechanisms of NM-CityNet. Results show that: (1) upstream core cities cluster in eastern China, midstream activities diffuse toward central and western regions, and downstream activities concentrate along the south-eastern coast; (2) NM-CityNet remains sparse and shows clear community structures, while different segments form differentiated spatial organization mechanisms; (3) sub-sectors exhibit clear specialization, with critical strategic materials showing broader spatial coverage; (4) drivers are heterogeneous: administrative proximity promotes link formation; government S&T financial-support differences are positively associated with link formation, although this association may partly reflect selective investment effects; economic and transport disparities inhibit link formation; innovation differences matter only in the midstream segment; and resource-endowment differences matter upstream and downstream. Full article
(This article belongs to the Section Economic and Business Aspects of Sustainability)
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32 pages, 2761 KB  
Article
Dominant-Mode-Based SCR-Adaptive SG-PSO Tuning for LVRT Recovery of PMSG Wind Turbines in Weak Grids
by Xiao Han, Xinghao Feng, Tong Huang, Zixuan Liu and Butian Chen
Energies 2026, 19(13), 3081; https://doi.org/10.3390/en19133081 - 29 Jun 2026
Viewed by 188
Abstract
Transient instability during the low-voltage ride-through (LVRT) recovery of permanent magnet synchronous generator (PMSG) wind turbines is strongly influenced by weak-grid interactions, while the quantitative relationship among grid strength, control parameters, and recovery performance remains insufficiently understood. This paper develops a small-signal transient [...] Read more.
Transient instability during the low-voltage ride-through (LVRT) recovery of permanent magnet synchronous generator (PMSG) wind turbines is strongly influenced by weak-grid interactions, while the quantitative relationship among grid strength, control parameters, and recovery performance remains insufficiently understood. This paper develops a small-signal transient recovery characteristic matrix for a grid-connected PMSG system by incorporating the dynamic interactions among the phase-locked loop (PLL), inner current loop, DC-link voltage loop, and grid-side inductance. Dominant-mode and root-locus analyses are employed to investigate how variations in the short-circuit ratio (SCR) affect dominant eigenvalue trajectories and the sensitivities of six PI control parameters. Based on the identified dynamic mechanisms, an SCR-adaptive sensitivity-guided particle swarm optimization (SG-PSO) method is proposed for coordinated PI parameter tuning. The proposed approach introduces SCR-dependent damping constraints and physical feasibility constraints, while normalized real-part eigenvalue sensitivities are utilized to guide the optimization process toward the most influential control parameters. Comparative simulation results demonstrate that, under SCR = 1.5, SG-PSO reduces the point of common coupling (PCC) voltage overshoot to 1.4% and shortens the recovery time to 58 ms, achieving better transient recovery indices than conventional PSO and OOBO-PI under the same simulation and constraint settings. Under SCR = 2.5, the recovery time is further reduced to 46 ms while maintaining a low overshoot of 0.9%. Additional robustness tests under parameter uncertainties and fault-condition variations further support the effectiveness and adaptability of the proposed method. The results indicate that the proposed SG-PSO framework provides an effective solution for enhancing LVRT recovery performance of PMSG wind turbines operating in weak-grid environments. Full article
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22 pages, 1194 KB  
Article
Anomalous Decline Patterns of Atlantic Meridional Overturning Circulation Driven by Arctic Oscillation
by Mian Liu, Yang Luo and Shuang Zhang
J. Mar. Sci. Eng. 2026, 14(13), 1197; https://doi.org/10.3390/jmse14131197 - 29 Jun 2026
Viewed by 130
Abstract
The Atlantic Meridional Overturning Circulation (AMOC), as the core component of the global thermohaline circulation, exerts a profound influence on the Northern Hemisphere climate. Recent observations show that AMOC intensity has weakened by approximately 15% over the past 40 years, yet the traditional [...] Read more.
The Atlantic Meridional Overturning Circulation (AMOC), as the core component of the global thermohaline circulation, exerts a profound influence on the Northern Hemisphere climate. Recent observations show that AMOC intensity has weakened by approximately 15% over the past 40 years, yet the traditional theoretical framework dominated by the North Atlantic Oscillation (NAO) cannot fully explain its spatial heterogeneity. This study systematically quantifies the independent driving mechanism of the Arctic Oscillation (AO) on AMOC decline for the first time by integrating multi-source reanalysis data (ERA5, ORAS5) and CMIP6 model output. Theoretical analysis shows that the AO positive phase regulates the stability of AMOC through two coupled pathways: (1) anomalous wind stress curl leads to the weakening of Ekman suction in the subpolar seas (contribution: 42 ± 6%), inhibiting deep-water formation in the Labrador Sea; and (2) increased freshwater flux through the Fram Strait triggers a negative salinity advection feedback, which leads to shoaling of the North Atlantic high-latitude mixed layer by up to 30 m. The cross-scale interaction reveals that the AO interannual variability amplifies the modulation of the AMOC interdecadal trend. This amplification occurs through the positive feedback of sea-ice albedo. When AO and NAO are locked in opposite phases (AO+/NAO−), the AMOC weakening rate increases to 1.8 Sv/decade (1 Sv = 106 m3/s), whereas the same-phase negative condition (AO−/NAO−) yields a moderate decline of 0.5 Sv/decade. This mechanism corrects the underestimation of the traditional wind-driven circulation theory for high-latitude processes and provides a physical attribution for the CMIP6 models’ systematic underestimation of AMOC sensitivity. The study further constructs the “Arctic Oscillation–subpolar basin–AMOC” three-pole coupling theoretical model and confirms that the Arctic amplification effect enhances the AO–AMOC coupling strength by a factor of 2.3 over the full study period (1979–2020; R2 = 0.71, p < 0.01), with an even more pronounced enhancement of 2.1 times during the recent two decades (2000–2020; R2 increased from 0.28 to 0.59). These findings have direct implications for coastal risk assessment, as AMOC weakening may accelerate sea-level rise along the North American East Coast and increase the frequency of extreme winter storm surges in European coastal areas. The results provide a dynamic basis for IPCC climate risk assessment and have practical application value for the early warning of extreme cold-wave events. Full article
(This article belongs to the Section Physical Oceanography)
19 pages, 14341 KB  
Article
Gravity Anomaly Characteristics and Tectonic Implications of the Tangshan Seismic Zone
by Minghui Zhang, Jiapei Wang, Guiju Wu, Hongbo Tan and Li Zhang
Sensors 2026, 26(13), 4113; https://doi.org/10.3390/s26134113 - 29 Jun 2026
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Abstract
A catastrophic Ms7.8 earthquake occurred in Tangshan in 1976 at a focal depth of approximately 12 km, resulting in severe casualties and substantial economic losses. Given its unique tectonic setting, the seismogenic structure and dynamic genesis of the Tangshan earthquake have long remained [...] Read more.
A catastrophic Ms7.8 earthquake occurred in Tangshan in 1976 at a focal depth of approximately 12 km, resulting in severe casualties and substantial economic losses. Given its unique tectonic setting, the seismogenic structure and dynamic genesis of the Tangshan earthquake have long remained a key research topic in seismotectonic studies. To better characterize the tectonic framework, seismogenic mechanisms, and deep–shallow dynamical coupling within the Tangshan seismic zone, we employ multi-scale wavelet decomposition on high-resolution residual gravity anomalies to isolate crustal structure signals across different depth ranges. Integrating these structural signatures with the spatial distribution of seismicity yields a comprehensive framework for interpreting the regional tectonic evolution. The Tangshan seismic zone is positioned within the intricate structural architecture of the Tangshan rhombic fault block, a system embedded within the broader context of the North China Craton (NCC) destruction. Seismicity displays a distinct preferred orientation, with events concentrated along block-bounding faults and gravity anomaly gradient zones. With increasing wavelet decomposition levels, the gravity anomalies exhibit a systematic transition from spatially dispersed patterns associated with shallow structures to more concentrated features reflecting deeper geological domains. Shallow anomalies from the first to third decomposition orders, which are primarily controlled by Quaternary sedimentary layers, show a fragmented distribution that corresponds well with the development of local flower structures and the occurrence of diffuse shallow seismicity. The fourth- to seventh-order anomalies clearly delineate the rhombic block and its bounding peripheral faults, highlighting the structural intersections that hosted the Tangshan mainshock and its associated aftershock sequence. In contrast, the eighth- to tenth-order deep-seated anomalies corresponding to deeper structural levels exhibit pronounced coalescence, effectively imaging mantle upwelling and large-scale density heterogeneities within the lithospheric mantle. These concentrated gravity highs are closely coupled with mantle thermal activity, whose upward ascent induces thermal weakening of the lower crust and facilitates progressive stress transfer toward shallower crustal levels. Concurrently, frictional locking of shallow high-angle faults promotes intense stress accumulation within the rigid basement. The interplay between deep-seated dynamic concentration and shallow structural confinement ultimately triggers the catastrophic coseismic rupture responsible for the Tangshan earthquake. By delineating the structural transition from deep-seated aggregation centers to shallow dispersed fracture zones, this study establishes a robust framework for assessing seismogenic environments and regional seismic hazard potential across the progressively destroyed NCC. Full article
(This article belongs to the Section Physical Sensors)
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Article
Research on the Mechanical Durability Performance and Action Mechanism of Basalt Fiber-Reinforced Concrete for Ship Lock Wall
by Benkun Lu, Jie Chen, Shuncheng Xiang, Zhe Peng, Changyu Liu, Haotian Yu and Yasi Ye
Polymers 2026, 18(13), 1587; https://doi.org/10.3390/polym18131587 - 26 Jun 2026
Viewed by 281
Abstract
To address early-age cracking in concrete walls of hydraulic structures such as ship locks, basalt fibers (BFs) were incorporated as a reinforcement strategy. The effects of varying BF dosages and lengths on the workability, mechanical strength, and crack resistance of concrete were systematically [...] Read more.
To address early-age cracking in concrete walls of hydraulic structures such as ship locks, basalt fibers (BFs) were incorporated as a reinforcement strategy. The effects of varying BF dosages and lengths on the workability, mechanical strength, and crack resistance of concrete were systematically evaluated. Furthermore, the internal microstructure was examined using scanning electron microscopy (SEM), and the durability performance, including impermeability, freeze–thaw resistance, and abrasion resistance, was assessed. The results indicate that workability decreased with increasing fiber content and length. The highest mechanical performance among tested mixes was achieved with 0.1% BF of 9 mm length, increasing 7-day and 28-day compressive strength by 17.47% and 22.59%, respectively, compared to plain concrete. The greatest crack resistance was observed with 0.2% BF of 18 mm length, delaying cracking by 150% and reducing crack width by 85%. Durability tests showed that a 0.2%-18 mm BF mix reduced water permeability depth by 47.37% and a 0.3% BF content optimized abrasion resistance. Freeze–thaw cycles indicated that a 0.3% fiber content effectively maintained the relative dynamic elastic modulus. SEM analysis revealed that BFs act as micro-bridges within the matrix, optimizing pore structure, inhibiting micro-crack propagation, and enhancing concrete density. This study evaluates BF-reinforced concrete and provides a practical reference for improving crack resistance and long-term durability in ship lock structures. Full article
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