Search Results (466)

Biothiols, including cysteine (Cys), homocysteine (Hcy), and glutathione (GSH), are crucial for physiological regulation and their imbalance poses severe health risks. Herein, we developed a pH-responsive liquid crystal (LC)-based sensing platform for detection of biothiols by doping 4-n-pentylbiphenyl-4-carboxylic acid (PBA) into 4-n-pentyl-4-cyanobiphenyl (5CB). Urease catalyzed urea hydrolysis to produce OH⁻, triggering the deprotonation of PBA, thereby inducing a vertical alignment of LC molecules at the interface corresponding to dark optical appearances. Heavy metal ions (e.g., Hg²⁺) could inhibit urease activity, under which condition LC presents bright optical images and LC molecules maintain a state of tilted arrangement. However, biothiols competitively bind to Hg²⁺, the activity of urease is maintained which enables the occurrence of urea hydrolysis. This case triggers LC molecules to align in a vertical orientation, resulting in bright optical images. This pH-driven reorientation of LCs provides a visual readout (bright-to-dark transition) correlated with biothiol concentration. The detection limits of Cys/Hcy and GSH for the PBA-doped LC platform are 0.1 μM and 0.5 μM, respectively. Overall, this study provides a simple, label-free and low-cost strategy that has a broad application prospect for the detection of biothiols. Full article

The motivation for increasing the efficiency of renewable energy sources is the basic problem of ongoing research. Currently, intensive research is underway in technology based on the use of dye-sensitized solar cells (DSSCs). The aim of this work is to investigate the effect of modifying the iodide electrolyte with liquid crystals (LCs) known for the self-organization of molecules into specific mesophases. The current–voltage (I-V) and power–voltage (P-V) characteristics were determined for the ruthenium-based dyes N3, Z907, and N719 to investigate the influence of their structure and concentration on the efficiency of DSSCs. The addition of a nematic LC of 4-n-pentyl-4-cyanobiphenyl (5CB) to the iodide electrolyte influences the I-V and P-V characteristics. A modification of the I-V characteristics was found, especially a change in the values of short circuit current (I_SC) and open circuit voltage (V_OC). The conversion efficiency for cells with modified electrolyte shows a complex dependence that first increases and then decreases with increasing LC concentration. It may be caused by the orientational interaction of LC molecules with the titanium dioxide (TiO₂) layer on the photoanode. A too high concentration of LC may lead to a reduction in total ionic conductivity due to the insulating effect of the elongated polar molecules. Full article

A novel reflective metasurface (RMS) is proposed in this paper. The MS measures 128 × 128 × 2.794 mm³ and consists of a six-layer vertically stacked structure, with a liquid crystal (LC) cavity in the middle layer. A dual fan-shaped direct current (DC) bias circuit is designed to minimize the interaction between the radio frequency (RF) signal and the DC source, allowing control of the LC dielectric constant via bias voltage. This enables multi-band operation to improve communication capacity and quality for x-band devices. The polarization conversion (PC) structure employs an orthogonal anisotropic design, utilizing logarithmic functions to create two pairs of bowtie microstrip patches for linear-to-circular polarization conversion (LCPC). Simulation results show that for x-polarized incident waves, with an LC dielectric constant of ε_r = 2.8, left- and right-handed circularly polarized (LHCP and RHCP) waves are achieved in the frequency ranges of 8.15–8.46 GHz and 9.84–12.52 GHz, respectively. For ε_r = 3.9, LHCP and RHCP are achieved in 9–9.11 GHz and 9.86–11.81 GHz, respectively, and for ε_r = 4.6, they are in 8.96–9.11 GHz and 9.95–11.51 GHz. In the case of y-polarized incident waves, the MS reflects the reverse CP waves within the same frequency ranges. Measured results show that at ε_r = 2.8, the axial ratio (AR) is below 3 dB in the frequency ranges 8.16–8.46 GHz and 9.86–12.48 GHz, with 3 dB AR relative bandwidth (ARBW) of 3.61% and 23.46%, respectively. For ε_r = 4.6, the AR < 3 dB in the frequency range of 9.78–11.34 GHz, with a 3 dB ARBW of 14.77%. Finally, the measured and simulated results are compared to validate the proposed design, which can be applied to various applications within the corresponding operating frequency band. Full article

The temperature-dependent polarization performance of super-twisted nematic liquid crystals (STN-LCs) when used as polarizers has garnered considerable scholarly attention. In this study, the transmittance of an STN-LC cell was measured under incident light wavelengths of 650 nm, 532 nm, and 405 nm over the temperature range of 30 °C to 100 °C. The STN-LC cell was employed both as the sample under test and as an analyzer in a rotational measurement setup to investigate how its polarization properties vary with temperature. The results indicate that the LC cell exhibits the characteristics of a linear polarizer under red light (650 nm) and violet laser (405 nm) across the full temperature range. However, under green laser (532 nm), when the temperature exceeds 60 °C, its extinction ratio is poor, suggesting its unsuitability for polarization applications under such conditions. A birefringence inversion formula was derived using the transmittance difference method, which effectively eliminates the influence of the glass substrates on the measured transmittance of the LC layer. Utilizing this method, a simple optical setup consisting of a polarizer and photodetector was constructed to accurately extract the birefringence of the LC. The birefringence of super-twisted nematic liquid crystal can be obtained by the transmittance difference method, which is low-cost, has a simple optical path, and is convenient for temperature-controlled experimental measurements of the liquid crystal cell. The findings of this study provide methodological support for the precise determination of birefringence in LCs exhibiting linear polarization characteristics. Full article

Liquid crystals exhibit unique properties that can be tailored in response to external stimuli. Significant research is directed toward the development of luminescent materials exhibiting liquid crystallinity for various applications. The present work reports Au(I) complexes featuring N-heterocyclic carbene and phenyl acetylide ligands. Metal complexes enable the utilization of the triplet excitons through their inherent spin–orbit coupling, promoting intersystem crossing from singlet (S_n) to triplet (T_n) states to observe room-temperature phosphorescence (RTP). The strong bonds between carbene and Au enhance the thermal stability, and the substituted benzimidazole ring alters the thermodynamic and photophysical properties of the complexes. Incorporating the acetylide ligands with long alkoxy chains led to the formation of liquid crystalline (LC) phases, which exhibited stability over a wide temperature range. Additionally, the luminescence behavior was affected by the ethynyl ligands, and high quantum yields of RTP were observed. This study establishes the development of LC Au(I) complexes with a thermodynamically stable LC mesophase over a wide temperature range for applications in the field of light-emitting functional materials. Full article

In this paper, a capacitively coupled-fed reconfigurable wideband bandpass filter (BPF) is proposed based on liquid crystal (LC) technology, which achieved three transmission poles across varying bias voltages (V_B). An open-ended stepped impedance resonator configuration enables multi-mode resonance, offering significantly wider bandwidth compared to uniform-impedance resonators. The fractional bandwidth (FBW) and transmission pole positions are determined by the impedance ratio of the two resonators, allowing the filter to meet specific design requirements. An analytical methodology employing multilayer transmission line formulations and resonant frequency ratios was used to predict the modal stability of transmission poles under dielectric constant variation, which was subsequently validated through simulation. Experimental results show that the center frequency can be adjusted from 10.76 to 9.47 GHz with a maximum V_B of 30 V, achieving a tuning range of 12.71%. The normalized 3 dB FBW exceeds 64.66%, and the return loss remains above 10 dB from 0 to 30 V, offering the widest FBW among the reported LC BPFs without pole merging or mode collapse. The frequency response of the fabricated filter shows good agreement with the simulation results. Full article

Fluorescent liquid crystals (LCs) have attracted considerable interest owing to their unique combination of fluidity, anisotropy, and intrinsic emission. However, most reported fluorescent LCs exhibit high phase transition temperatures and/or smectic phases, limiting their practical applications. To address this, we designed and synthesized a series of 2,1,3-benzothiadiazole (BTD)-based fluorescent nematic liquid crystals incorporating donor (D) or acceptor (A) groups to form D–A–D or D–A–A structures. Most of the synthesized derivatives exhibited supercooled nematic phases at room temperature. They composed various functional groups, such as secondary alkylamine, branched alkyl chain, and trifluoroacetyl groups, which are rarely used in calamitic nematic LCs. Notably, dimethylamine- and carbonyl-substituted derivatives exhibited relatively high fluorescence quantum yields (Φ_fl) in both solid and mesophase states, demonstrating their potential as efficient fluorescent materials. Our findings underscore the versatility of BTD-based mesogenic skeletons for designing room-temperature fluorescent nematic LCs with various functional groups. These materials offer promising opportunities for next-generation display technologies, optical sensors, and photonic applications. Full article

Shaping or splitting of a Gaussian beam is often desired to optimise laser–material interactions, improving throughput and quality. This can be achieved holographically using liquid crystal-on-silicon spatial light modulators (LC-SLMs). Until recently, maximum exposure has been limited to circa 120 W average power with a Gaussian profile, restricting potential applications due to the non-linear (NL) phase response of the liquid crystal above this threshold. In this study, we present experimental tests of a new SLM device, demonstrating high first-order diffraction efficiency of η = 0.98 ± 0.01 at 300 W average power and a phase range Δφ > 2π at P = 383 W, an exceptional performance. The numerically calculated device temperature response with power closely matches that measured, supporting the higher power-handling capability. Surface modification of mild steel and molybdenum up to P = 350 W exposure is demonstrated when employing a single-mode (SM) fibre laser source. Exposure on mild steel with a vortex beam (m = +6) displays numerous ringed regions with varying micro-structures and clear elemental separation created by the radial heat flow. On molybdenum, with multi-spot Gaussian exposure, both MoO₃ films and recrystallisation rings were observed, exposure-dependent. The step change in device capability will accelerate new applications for this LC-SLM in both subtractive and additive manufacturing. Full article

The micro-phase segregation of two incompatible components on a nanometer scale results in a unique solvent-induced extended anisotropic arrangement. With the addition of a chiral dopant, lyotropic liquid crystals can be induced to adopt a helical structure, forming lyotropic cholesteric liquid crystals capable of reflecting incident light. In this study, to prevent fluid leakage in lyotropic materials, we encapsulated a series of hydrogel-stabilized lyotropic liquid crystals, presenting tunable structural colors visible in all directions, mimicking the color-changing characteristics of living organisms. Hydrogel scaffolds with controllable swelling behaviors were engineered by incorporating crosslinking monomers. To ensure stable integration of lyotropic liquid crystals, high-boiling-point ethylene glycol was employed as a fluid during the fabrication process. This study extensively explores the relationship between tensile force, temperature, and pressure and the color changes in lyotropic liquid crystals (LC). The results indicate that lyotropic LC membranes, stabilized by ethylene glycol and PDMS encapsulation, exhibit long-term stability, rendering them suitable for applications in temperature and pressure sensing. This approach ensures the continuous presence and stability of lyotropic liquid crystals within the hydrogel matrix. Full article

Microswimmers are key for unveiling new physical phenomena underlying their propulsion, especially when driven inside complex fluids. Liquid crystals are anisotropic complex fluids that feature long-range orientational order. The propulsion of non-charged dielectric particles can be accomplished in these systems by breaking the particles’ fore-aft symmetry thanks to anisotropies in the conductivity and dielectric permittivity parameters of the liquid crystal. Under the application of an AC electric field, asymmetric osmotic flows are generated to propel non-spherical particles, whose direction of motion depends on the orientational order of the liquid crystal molecules around the inclusions. This means that, by controlling the LC orientation, one will be able to steer driven colloidal inclusions. In this experimental work, we show that a homogeneous magnetic field that is able to control the orientation of the liquid crystal molecules also allows us to determine the direction of motion of driven particles without significant changes in the propulsion mechanism. Additionally, we show that a radial configuration of the magnetic field lines can be used to generate topological defects in the liquid crystal orientational field that attract colloidal particles, leading to their clustering as rotating mills. The generated clusters were tested to study the collective motion of particles, suggesting the presence of particle–particle interactions. Full article

Micro-nano measurement represents a critical engineering focus in the advancement of micro-nano fabrication technologies. Exploring advanced micro-nano measurement methods is a key direction for driving progress in micro-nano manufacturing. This study proposes a confocal measurement method utilizing a liquid crystal spatial light modulator (LC-SLM) to simulate a binary Fresnel lens for 3D focusing, enabling the non-mechanical measurement of spatial positions on sample surfaces. Specifically, it introduces a 3D focusing method based on LC-SLM, constructs a confocal microscopy 3D focusing system, and conducts lateral focusing experiments and axial focusing experiments. Experimental results demonstrate that the system can freely adjust lateral focusing positions. Within an axial focusing range of 900 μm, it achieves axial measurement accuracy exceeding 1 μm, with a maximum resolution capability of approximately 16.667 nm. Compared to similar confocal microscopy systems, this method allows rapid adjustment of lateral focusing positions without regenerating phase grayscale maps, achieves comparable axial measurement accuracy, and enhances measurement speed. Full article

Free ion impurities in liquid crystals significantly impact the dynamic electro-optic performance of liquid crystal displays, leading to slow switching times, short-term flickering, and long-term image sticking. These ionic contaminants originate from various sources, including LC cell fabrication, electrode degradation, and organic alignment layers. This study demonstrates that doping LCs with a small concentration of helical carbon nanotubes effectively reduces free ion concentrations by approximately 70%. The resulting reduction in ionic impurities lowers the rotational viscosity of the LC, facilitating faster electro-optic switching. Additionally, the purified LC exhibits enhanced dielectric anisotropy, further improving its performance in display applications. These findings suggest that helical carbon nanotubes doping offers a promising approach for mitigating ion-related issues in liquid crystals without the need for additional chemical treatments, paving the way for an efficient liquid crystal display technology. Full article

Polymer-dispersed liquid crystals (PDLCs) are composite materials, in which LCs are dispersed in the form of microdroplets in a polymer matrix. As a composite material, its electro-optical properties are affected by many factors such as molecular structure, composition, and the microstructure of the LCs and polymers. In this work, PDLC films were prepared based on the thiol-ene click reaction, and effects of refractive indexes of polymers and LCs on their electro-optical properties were studied. The refractive indexes of the polymer matrix are adjusted by controlling the content of sulfur element, and those of the LCs are adjusted by adding multi-fluorinated LCs with high refractive index. By regulating the refractive indexes of the polymer matrix and LCs, the maximum transmittance of the film is raised and the viewing angle of the film is also extended. This work could afford some ideas for the directional regulation of the viewing angles and the electro-optical properties of the PDLC film. Full article

This study presents the uniform alignment of liquid crystal (LC) molecules on silver (Ag)-doped nickel oxide (NiO) films. The films were fabricated using a solution brush coating process, with Ag doping concentrations of 0, 10, and 20 wt%. X-ray photoelectron spectroscopy confirmed the successful formation of the films, while atomic force microscopy revealed nano/microgroove anisotropic structures, attributed to brush hair movement during coating. X-ray diffraction analysis indicated the films’ amorphous nature. Optical transmittance measurements demonstrated their suitability for electronic display applications. Polarized optical microscopy verified uniform LC molecular alignment and effective optical control. The fabricated LC cells exhibited increased LC polar anchoring energy, improving device stability. The polar anchoring energy increased by 1159.02% after Ag doping. Additionally, reduced residual charge was observed, suggesting minimized image sticking. These findings indicate that Ag-doped NiO films are a promising alternative for LC alignment layers in functional LC systems. Full article