Search Results (117)

Four-dimensional (4D) printing integrates additive manufacturing with stimuli-responsive materials to fabricate biomedical implants and functional healthcare devices that undergo programmed, time-dependent changes in shape or function. Unlike static 3D-printed constructs, 4D-printed systems can respond to clinically relevant stimuli such as temperature, hydration, pH, light (including near-infrared), magnetic fields, or electrical inputs. These triggers drive defined actuation mechanisms, most commonly thermomechanical shape-memory recovery, swelling-induced morphing, and magnetothermal activation. This review synthesizes the principal material platforms used for biomedical 4D printing, including shape-memory polymers and alloys, hydrogels, liquid-crystal elastomers, and responsive composites, and links material choice to device behavior and translational feasibility. Applications are discussed across self-expanding stents, cardiac occluders, tissue-engineered constructs, implantable drug delivery systems, and adaptive wearables. Key translational challenges include sterilization compatibility, manufacturing reproducibility and quality control, safe stimulus delivery, predictable biodegradation and long-term biocompatibility, and regulatory pathway definition. Full article

In nature, avian species achieve remarkable aerodynamic efficiency by seamlessly coordinating flexible soft tissues to create continuous, adaptive wing surfaces, significantly minimizing drag and eliminating parasitic turbulence. Traditional shape morphing systems rely on bulky mechanical linkages that add excessive weight, often offsetting aerodynamic gains. The integration of soft active materials has emerged as a transformative solution for weight-efficient, seamless actuation. However, a significant disconnect remains between laboratory-scale research and practical aerospace implementation. This perspective evaluates three prominent classes of soft active materials, shape memory polymers (SMPs), dielectric elastomers (DEAs), and liquid crystal elastomers (LCEs), analyzing their actuation mechanisms and comparing their performance in load-bearing, response bandwidth, and energy efficiency. By addressing the necessity of structural-material synergy, we discuss the potential solution for bridging the gap between material synthesis and system-level flight performance to enable the successful deployment of soft active materials in future aerial platforms. Full article

Self-sustained oscillatory systems enable autonomous motion through continuous interaction with ambient energy sources, positioning them as promising candidates for soft robotic actuation, energy conversion, and biomedical applications. However, their utility is often limited by inherent vibrations and frictional losses, which can lead to impaired efficiency and generate noise. To overcome these limitations, a continuously rotating disc mechanism is proposed, which exploits the photothermal response of liquid crystal elastomers (LCEs) under uniform illumination. The resulting temperature field within the material is obtained via photothermal modeling of the LCE. The rotational actuation torque is generated through mass displacement resulting from light-induced LCE contraction. Based on the above conditions, we establish the equilibrium conditions and critical thresholds for continuous motion and reveal a synergy between the thermal field and torque. Through the interplay of the temperature field and the actuating rotating moment, the system ultimately attains steady self-rotation. Therefore, the absorbed energy offsets damping losses. Numerical simulations reveal that the steady-state self-spinning and translational velocity are influenced by multiple parameters including incident heat flux, gravitational field strength, material contraction coefficient, LCE element dimensions, illumination geometry, and resistive torque. The proposed LCE disc configuration exhibits exceptional operational stability and minimal damping, which has potential for implementation in advanced soft robotic systems and mechanical energy conversion applications. Full article

Fiber actuators underpin soft robots, artificial muscles, and smart textiles. A persistent bottleneck is the fabrication of monodomain liquid crystal elastomer (LCE) microfibers with narrow size distributions while preserving axial alignment. This work establishes a melt-centrifugal spinning (MCS) route with two-step UV fixation that separates flow-induced alignment from network crosslinking. High-speed rotation creates a long extensional jet; an obliquely incident, on-the-fly UV dose at touchdown locks the director, and a post-cure consolidates the network. The obtained LCE microfiber can achieve large reversible contraction (L/L₀ = 0.56), lift a weight, and trigger the tweezers. The method produces a new approach for the fabrication of device-ready LCE actuators, establishes a general design principle for diameter control via curing sequence, and opens a practical path toward artificial muscles and flexible micro robotics. Full article

Liquid Crystal Elastomers combine the elasticity of polymer networks with the anisotropic ordering of liquid crystals, thus enabling reversible shape modifications and stimulus responsive actuation. Unfortunately, manual LCE fabrication remains limited by operator-dependent variability, which can lead to inconsistent film thickness and manufacturing times inadequate for a mass production. This work presents a low-cost, automated manufacturing framework that redesigns the mechanical assembly steps of the traditional one-step LCE fabrication process. The design includes rubbing, slide alignment, spacer placement, and infiltration cell assembly to ensure consistent film quality and scalability. A customized Cartesian robot, built by adapting a modified X–Y core 3D printer, integrates specially designed manipulator systems, redesigned magnetic slide holders, automated rubbing tools, and supporting fixtures to assemble infiltration devices in an automated way. Validation tests demonstrate reproducible infiltration, improved mesogen alignment confirmed via polarized optical microscopy, and high geometric repeatability, although glass-slide thickness variability remains a significant contributor to deviations in final film thickness. By enabling parallelizable low-cost production, the designed hardware demonstrates its effectiveness in devising the scalable manufacturing of LCE films suited for advanced therapeutic and engineering applications. Full article

Liquid crystal elastomers (LCEs) are soft, stimuli-responsive materials capable of converting molecular-scale reorientation of mesogenic groups into macroscopic, reversible deformations. In this study, film-shaped LCEs were fabricated via a thiol–ene click reaction and characterized under varying electric-field strengths and tensile loads. The LCEs exhibited pronounced soft elasticity and large, reversible strains due to reorientation of mesogenic groups, in contrast to non-mesogenic elastomers. Dynamic viscoelastic measurements revealed fully reversible changes in storage modulus upon electric-field application, highlighting the critical role of mesogenic group alignment in electromechanical actuation. Electric-field-induced contraction increased with field strength and decreased with tensile load, reaching a maximum of 15% under minimal load, with additional enhancement resulting from mesogenic group reorientation along the thickness direction. Notably, unlike conventional light- or temperature-driven actuation, which is often limited by slow molecular relaxation or heat diffusion, the electric-field-driven LCE exhibited rapid, fully reversible deformation. These findings demonstrate the potential of electric-field-responsive LCEs for applications requiring fast, controllable, and large-strain actuation, and provide insights into the interplay between mesogenic group orientation, mechanical loading, and external stimuli in designing efficient soft actuators. Full article

Liquid crystal elastomers (LCEs), as a class of smart materials, have attracted significant attention across soft robotics, biomedical engineering, and intelligent devices because of their unique capabilities to undergo large, reversible, and anisotropic deformations under external stimuli. Over the years, fabrication methods have advanced from conventional molding and thin-film processing to additive manufacturing, with 4D printing emerging as a transformative approach by enabling time-dependent, programmable shape transformations. Among the available methods, direct ink writing (DIW) and vat photopolymerization are most widely adopted, with ink chemistry, rheology, curing, and printing parameters directly governing mesogen alignment and actuation performance. Recent advances in LCE actuators have demonstrated diverse functionalities in soft robotics, including bending, crawling, gripping, and sequential actuation, while biomedical applications span adaptive tissue scaffolds, wearable sensors, and patient-specific implants. This review discusses the conceptual distinction between 3D and 4D printing, compares different additive manufacturing techniques for LCE, and highlights emerging applications in the field of soft robotics and biomedical technologies. Despite rapid progress in LCE, challenges remain in biocompatibility, long-term durability and manufacturing scalability. Overall, innovations in 4D printing of LCEs underscores both the promise and the challenges of these materials, pointing toward their transformative role in enabling next-generation soft robotic and biomedical technologies. Full article

Using reactive atomistic molecular dynamics, we simulate the network formation and bulk properties of chemically identical liquid crystal elastomers (LCEs) and isotropic elastomers. The nematic elastomer is from a family of materials that have been shown to be auxetic at a molecular level. The network orientational order parameters and glass transition temperatures measured from our simulations are in strong agreement with experimental data. We reproduce, in silico, the magnitude and onset of strain-induced nematic order in isotropic simulations. Application of uniaxial strain to nematic LCE simulations causes biaxial order to emerge, as has been seen experimentally for these auxetic LCEs. At strains of ~1.0, the director reorients to be parallel to the applied strain, again as seen experimentally. The simulations shed light on the strain-induced order at a molecular level and allow insight into the individual contributions of the side-groups and crosslinker. Further, the agreement between our simulations and experimental data opens new possibilities in the computational design of high-molecular-weight liquid crystals, especially where an understanding of the properties under mechanical actuation is desired. Moreover, the simulation methodology we describe will be applicable to other combinations of orientational and/or positional order (e.g., smectics, cubics). Full article

Self-oscillating systems convert steady external stimuli into sustained motion, enabling diverse applications in robotics, energy absorption, optics, and logic. Inspired by the adhesion–detachment behavior of climbing plants, we propose a novel light-powered self-adhesion oscillator comprising an elastic strip–substrate structure and a weight suspended by a photo-responsive liquid crystal elastomer fiber. By integrating a nonlinear beam deformation model with Dugdale’s cohesive model, we develop a nonlinear dynamic framework to describe the self-adhesion behavior of the elastic strip. Quasi-static analysis reveals two distinct operating modes: a static mode and a self-adhesion mode. Under constant light exposure, the liquid crystal elastomer fiber undergoes light-induced contraction, increasing peeling force and triggering a sudden transition from adhesion-on to adhesion-off. Upon entering the adhesion-off state, the fiber recovers its contraction, leading to a sharp return to the adhesion-on state. This cycle sustains a four-stage oscillation: gradual peeling, abrupt adhesion-off, gradual adhering, and abrupt adhesion-on. Furthermore, we identify the critical conditions for initiating self-adhesion and demonstrate effective control over the oscillation period. The system exhibits key advantages including amplitude controllable oscillation, widely tunable frequency, well-defined motion trajectories, and structural simplicity. These characteristics suggest promising potential for applications in self-healing adhesion systems, rescue devices, military engineering, and beyond. Full article

Self-oscillations convert ambient energy into continuous periodic motion through feedback mechanisms, but their response to external periodic disturbances is not yet fully understood. Through the combination of a photothermally-responsive liquid crystal elastomer fiber and a mass block within a linear light field, we consider a liquid crystal elastomer self-oscillator. Following theoretical modeling of the light-driven self-oscillator under external periodic forcing and numerical simulations, three distinct phase-locking regimes are identified: in-phase, anti-phase, and quadrature synchronizations. Mechanisms are elucidated through time-domain, frequency-domain, and phase-space analyses. Moreover, approximate analytical expressions for the steady-state amplitude–frequency and phase–frequency responses of the self-oscillator under periodic forcing are derived using the multi-scale method. The impact of periodic forcing on the self-oscillator and its response regulation via system parameters is examined. A close correspondence exists between numerical and analytical results. This work investigates the response characteristics of a liquid crystal elastomer self-oscillator under periodic forcing, advances fundamental insights into disturbance rejection in self-oscillators, and delivers practical guidance for their robust operation in complex oscillatory settings. Full article

Self-oscillating systems are capable of transforming ambient energy directly into mechanical output, and exploring novel designs is of great value for energy harvesters, actuators, and engine applications. The inspiration for this study is drawn from the four-stroke engine; we designed a new self-rotating engine formed by a turnplate, a hinge, and an LCE fiber, operating with steady illumination applied. To analyze its rotation dynamics, a nonlinear theoretical framework was formulated constructed with the dynamic LCE model as a framework. The central discovery is that the light-driven LCE engine can operate in three distinct states under steady illumination—static equilibrium, pendulum-like oscillation and sustained self-rotation—switching between them through a supercritical Hopf bifurcation. The persistence of both the pendulum and rotary motions stems from an energy balance in which the positive work produced by photo-induced contraction of the LCE fiber is exactly offset by damping dissipation, while oscillation amplitude and rotation frequency are strongly governed by light intensity, contraction coefficient, damping coefficient, spring constant and turntable radius. Compared with many previously reported self-oscillating designs, the present self-rotating engine is distinctive for its lightweight and simple configuration, tunable size, and rapid operation. These features enable compact integration and broaden its potential applications in micro-scale systems and devices. The advancement in artificial muscles, medical instruments and micro sensors is strongly promoted by this, making it possible to create devices that are both smaller in size and superior in functionality. Full article

Traditional energy harvesting systems, such as photovoltaics and wind power, often rely on external environmental conditions and are typically associated with contact-based vibration wear and bulky structures. This study introduces light-fueled self-vibration to propose a self-harvesting system, consisting of liquid crystal elastomer fibers, two resistors, and two piezoelectric cantilever beams arranged symmetrically. Based on the photothermal temperature evolution, we derive the governing equations of the liquid crystal elastomer fiber–piezoelectric beam system. Two distinct states, namely a self-harvesting state and a static state, are revealed through numerical simulations. The self-oscillation results from light-induced cyclic contraction of the liquid crystal elastomer fibers, driving beam bending, stress generation in the piezoelectric layer, and voltage output. Additionally, the effects of various system parameters on amplitude, frequency, voltage, and power are analyzed in detail. Unlike traditional vibration energy harvesters, this light-fueled self-harvesting system features a compact structure, flexible installation, and ensures continuous and stable energy output. Furthermore, by coupling the light-responsive LCE fibers with piezoelectric transduction, the system provides a non-contact actuation mechanism that enhances durability and broadens potential application scenarios. Full article

Liquid crystal elastomers (LCEs) have shown great potential in the field of soft robotics due to their unique actuation capabilities. Despite the growing number of experimental studies in the soft robotics field, theoretical research remains limited. In this paper, a dynamic model of a bionic arm using an LCE fiber as artificial muscle is established, which exhibits periodic oscillation controlled by periodic illumination. Based on the assumption of linear damping and angular momentum theorem, the dynamics equation of the model oscillation is derived. Then, based on the assumption of linear elasticity model, the periodic spring force of the fiber is given. Subsequently, the evolution equations for the cis number fraction within the fiber are developed, and consequently, the analytical solution for the light-excited strain is derived. Following that, the dynamics equation is numerically solved, and the mechanism of the controllable oscillation is elucidated. Numerical calculations show that the stable oscillation period of the bionic arm depends on the illumination period. When the illumination period aligns with the natural period of the bionic arm, the resonance is formed and the amplitude is the largest. Additionally, the effects of various parameters on forced oscillation are analyzed. The results of numerical studies on the bionic arm can provide theoretical support for the design of micro-machines, bionic devices, soft robots, biomedical devices, and energy harvesters. Full article

Electroactive polymers (EAPs) represent a versatile class of smart materials capable of converting electrical stimuli into mechanical motion and vice versa, positioning them as key components in the next generation of actuators and sensors. This review summarizes recent developments in both electronic and ionic EAPs, highlighting their activation mechanisms, material architectures, and multifunctional capabilities. Representative systems include dielectric elastomers, ferroelectric and conducting polymers, liquid crystal elastomers, and ionic gels. Advances in fabrication methods, such as additive manufacturing, nanocomposite engineering, and patternable electrode deposition, are discussed with emphasis on miniaturization, stretchability, and integration into soft systems. Applications span biomedical devices, wearable electronics, soft robotics, and environmental monitoring, with growing interest in platforms that combine actuation and sensing within a single structure. Finally, the review addresses critical challenges such as long-term material stability and scalability, and outlines future directions toward self-powered, AI-integrated, and sustainable EAP technologies. Full article

The realization of broad-wavelength tunability of the structural color in Double layered Cholesteric Liquid Crystal Elastomers (DCLCEs), along with good flexibility and processability, presents a significant challenge. This research introduces a facile and effective fabrication technique, Solvent Evaporation-Induced Self-Assembly (SEISA), for the production of DCLCEs exhibiting broad wavelength tunability, superior flexibility, and robust mechanical characteristics. Focusing on initial color tuning, bubble defect minimization, UV photopolymerization, and coating procedures, this research systematically optimizes the fabrication process through experimental investigation of factors like chiral dopant amount, temperature, UV exposure duration, coating thickness, and speed. The method enabled the successful fabrication of DCLCEs with uniform and controllable coloration, demonstrating the effectiveness of this controlled synthesis approach in significantly enhancing structural color features. Upon stretching to 2.8 times its original length, the center wavelength shifted from 613 nm to 404 nm, yielding a tunable bandwidth of up to 209 nm across the visible spectrum. Full article