Search Results (728)

In this present study, sodium- and strontium-modified bismuth titanate—Bi_0.5Na_0.5TiO₃ (BNT) and Bi_0.5Sr_0.5TiO₃ (BST)—were synthesized using the auto-combustion technique with citric acid (C₆H₈O₇) and glycine (C₂H₅NO₂) as fuels in an optimized ratio of 1.5:1. The resulting powders were characterized using X-ray diffraction (XRD), energy-dispersive X-ray (EDX) spectroscopy, UV–Visible diffuse reflectance spectroscopy (DRS), and Fourier-transform infrared (FT-IR) spectroscopy. The electrical behavior of the samples was studied using an LCR meter. XRD analysis confirmed the formation of a single-phase perovskite structure with average crystallite sizes of 18.60 nm for BNT and 22.03 nm for BST, attributed to the difference in ionic radii between Na⁺ and Sr²⁺. An increase in crystallite size was accompanied by a corresponding increase in lattice parameters and unit-cell volume. The Williamson–Hall analysis further validated the strain-size contributions. EDX (Energy-Dispersive X-ray analysis) results confirmed successful incorporation of Na⁺ and Sr²⁺ without detectable impurity phases. Optical studies revealed distinct absorption peaks at 341 nm for BNT and 374 nm for BST, and the optical bandgap (E_g), calculated using Tauc’s relation, was found to be 2.6 eV and 2.0 eV, respectively. FT-IR spectra exhibited characteristic Ti-O vibrational bands in the range of 420–720 cm⁻¹, consistent with the perovskite structure. For electrical characterization, the powders were pelletized under 3-ton pressure and sintered at 1000 °C for 3 h. The dielectric constant (ε_r), dielectric loss (tan δ), and ac conductivity (σ) of both samples increased with frequency. The combined structural, optical, and electrical results indicate that the optimized compositions of BNT and BST possess properties suitable for use in capacitors and other energy-storage applications. Full article

The interfacial behavior between lattice reinforcement and aluminum matrix plays an important role in determining the mechanical and tribological properties of lattice-reinforced aluminum matrix composites. In this study, 316L lattices with different aspect ratios were prepared by laser powder bed elting (LPBF) technology, and LY12 aluminum alloy was infiltrated under vacuum conditions. The effects of lattice aspect ratio on the interfacial reaction, microstructure, hardness, compressive strength, and wear resistance of the composites were systematically studied. First-principles calculations show that FeAl₂ and FeAl₃ intermetallic compounds are preferentially formed at the interface, showing good thermodynamic stability and mechanical properties. The microstructure analysis shows that the increase in aspect ratio promotes the formation of coarse FeAl₃ phase and network AlCu, while a too-large aspect ratio leads to the instability of microstructure and the generation of microcracks. When the lattice constant is 10 mm and the diameter of the support is 1 mm (BCC-10-1), the composite material has the best wear resistance, and the specific wear rate is 3.07 × 10⁻⁴ mm³/(N·m). These findings provide valuable insights into the design of high-performance lattice-reinforced aluminum matrix composites with customized interface properties. Full article

Indium-doped SnTe (Sn_1−xIn_xTe) provides a model platform for exploring the emergence of superconductivity within a topological crystalline insulator. Here, we present a systematic investigation of the structural, transport, and thermodynamic properties of high-quality single crystals with 0.0 ≤ x ≤ 0.5. All compositions up to x = 0.4 form a single-phase cubic structure, enabling a controlled study of the superconducting state. Electrical resistivity and specific heat measurements reveal a bulk, fully gapped s-wave superconducting phase whose transition temperature increases monotonically with In concentration, reaching Tc ≈ 4.7 K at x = 0.5. Analysis of the electronic specific heat and McMillan formalism shows that the electron–phonon coupling constant λ_el-ph systematically increases with doping, while the Debye temperature systematically decreases, resulting in the lattice softening. This behavior, together with the observed evolution of the normal-state resistivity exponent from Fermi-liquid (n ≈ 2.04) toward non-Fermi-liquid values (n ≈ 1.72), demonstrates a clear crossover from weak to strong interaction with increasing In content. These results establish Sn_1−xIn_xTe as a tunable superconducting system in which coupling strength can be continuously controlled, offering a promising platform for future studies on the interplay between phonon-mediated superconductivity and crystalline topological band structure. Full article

Precise control over defect structures is essential for tuning the functional properties of lithium niobate (LiNbO₃) crystals. Although the threshold effect of Hf⁴⁺ doping is well recognized, its underlying atomic-scale mechanism, especially in systems co-doped with luminescent rare earth ions, remains unclear. In this study, we combine experimental and theoretical approaches to elucidate the Hf⁴⁺ concentration-driven threshold behavior in Dy: LiNbO₃ crystals. A series of crystals with Hf⁴⁺ concentrations of 2, 4, 6, and 8 mol% were grown using the Czochralski method. Characterization through XRD and IR spectroscopy identified a threshold near 4 mol%, evidenced by an inflection in lattice constants and a pronounced blue shift of the OH⁻ absorption peak. UV–Vis–NIR absorption spectra revealed a systematic enhancement of Dy³⁺f–f transition intensities, linking the global defect structure to the local crystal field of the optical activator. First-principles calculations showed that Hf⁴⁺ ions preferentially occupy Li sites, repairing antisite Nb defects ($\mathrm{N}{\mathrm{b}}_{\mathrm{Li}}^{4+}$) below the threshold, and incorporate into Nb sites beyond it, inducing structural reorganization. Electron Localization Function analysis visualized strengthened Hf-O covalent bonding in the post-threshold regime. This work establishes a complete atomic-scale picture connecting dopant site preference, chemical bonding, and macroscopic properties, providing a foundational framework for the rational design of advanced LiNbO₃-based materials. Full article

This paper presents a theoretical study of the structural, electronic, and elastic properties of gallium-doped CuInSe₂ using the GGA exchange-correlation functional with the Hubbard correction for five Ga compositions: 0, 0.25, 0.5, 0.75, and 1. The found lattice parameters decrease with gallium composition and obey Vegard’s law. Traditional DFT calculations fail to explain the band structure of Copper Indium Gallium Selenide compounds (CIGS). The use of Hubbard corrections of d-electrons of copper, indium, gallium, and p-electrons of selenium opens the gap, showing a semiconductor’s behavior of CuInGaSe2 alloys in the range 1.04 eV to 1.88 eV, which are in good agreement with available experimental data and current theory using an expensive hybrid exchange-correlation functional. The obtained formation energies for the different gallium compositions are close to −1 eV/atom, and the phonon spectra indicate the thermodynamic stability of these alloys. The values of the elastic constant satisfy the Born elastic stability conditions, suggesting that these compounds are mechanically stable. Moreover, we compute the bulk modulus (B), shear modulus (G), Young’s modulus (E), Poisson ratio (p), Pugh’s ratio (r), and average Debye speed ($v$), and the Debye temperature (${\mathsf{\Theta }}_{\mathrm{D}}$) with the Ga composition. There is a symmetry between our results and the experimental data, as well as earlier simulation results. Full article

We introduce a BiHom-type skew-symmetric bracket on general linear Lie algebra $GL\left(V\right)$ built from two commuting inner automorphisms $\alpha =A{d}_{\psi }$ and $\beta =A{d}_{\varphi }$, with $\psi ,\varphi \in GL\left(V\right)$ and integers $i,j$. We prove that $(GL\left(V\right),{[·,·]}_{(\psi ,\varphi )}^{(i,j)},\alpha ,\beta )$ is a BiHom–Lie algebra, and we study the Lax equation obtained by replacing the commutator in the finite nonperiodic Toda lattice by this bracket. For the symmetric choice $\varphi =\psi$ with $(i,j)=(0,0)$, the deformed flow is equivariant under conjugation and becomes gauge-equivalent, via $\tilde{L}={\psi }^{-1}L\psi$, to a Toda-type Lax equation with a conjugated triangular projection. In particular, scalar deformations amount to a constant rescaling of time. On embedded $2\times 2$ blocks, we derive explicit trigonometric and hyperbolic formulae that make symmetry constraints (e.g., tracelessness) transparent. In the asymmetric hyperbolic case, we exhibit a trace obstruction showing that the right-hand side is generically not a commutator, which amounts to symmetry breaking of the isospectral property. We further extend the construction to the weakly coupled Toda lattice with an indefinite metric and provide explicit $2\times 2$ solutions via an inverse-scattering calculation, clarifying and correcting certain formulas in the literature. The classical Toda dynamics are recovered at special parameter values. Full article

The effects of Ge⁴⁺ substitution on the microwave dielectric properties of inverse spinel Mg₂SnO₄ ceramics were systematically investigated. A series of Mg₂(Sn_1−xGe_x)O₄ (x = 0.00–0.05) ceramics were synthesized via solid-state reaction and sintered at 1450–1600 °C. X-ray diffraction confirmed single-phase inverse spinel structures (Fd-3 m) for compositions up to x = 0.03, while minor MgSnO₃ secondary phases appeared at x = 0.05. Rietveld refinement revealed a linear decrease in lattice parameter from 8.6579 Å (x = 0) to 8.6325 Å (x = 0.05), consistent with Vegard’s law for the substitution of smaller Ge⁴⁺ (0.53 Å, Shannon ionic radius, octahedral coordination) for Sn⁴⁺ (0.69 Å, Shannon ionic radius, octahedral coordination) in octahedral sites. Optimal dielectric properties were achieved at x = 0.03 sintered at 1550 °C; the dielectric constant (ε_r) increased from 7.6 to 8.0, while the quality factor (Qf) improved by 19% from 56,200 to 67,000 GHz, which is attributed to reduced phonon scattering from Ge-induced lattice contraction. The temperature coefficient of resonant frequency (τ_f) remained stable (−64 to −68 ppm/°C) across all compositions. Property degradation at x = 0.05 correlated with the onset of Ge⁴⁺ solubility limit and MgSnO₃ formation. These results demonstrate that controlled Ge⁴⁺ substitution effectively enhances the microwave dielectric performance of Mg₂SnO₄ ceramics for communication applications. Full article

To explore the potential of new information transmission windows, this work presents a broadband plasmonic filter based on gold-deposited silicon photonic crystal fiber (PCF) operating in mid-infrared regime numerically, using the finite element method (FEM). The simulation results indicate that the interaction between the high-refractive-index pure silicon material and the gold layer can cause a shift of the resonance central point to the mid-infrared band, which provides the prerequisite for mid-infrared filtering. When the cladding holes’ diameter is 1.3 µm, the inner holes’ diameter is 1.04 µm, the diameter of the holes located on both sides of the core region is 2.08 µm, the gold-coated holes’ diameter is 2.08 µm, the lattice constant is 2 µm, and the gold thickness is 50 nm, this PCF can operate in the mid-infrared band near the central wavelength of 3 µm. The 1 mm long PCF polarizer exhibits a maximum extinction ratio (ER) of −43.5 dB at 3 µm and a broad operating bandwidth of greater than 820 nm with ER better than −20 dB. Additionally, it also possesses high fabrication feasibility. This in-fiber polarization filter, characterized by its comprehensive performance and ease of fabrication, aids in exploring the development potential of high-speed and large-capacity modern communication networks within new optical bands and contributes to new photonic computing and sensing. Full article

Vibration energy harvesting from ambient mechanical sources offers a sustainable alternative to batteries for powering low-power electronics in remote environments, yet challenges persist in achieving broadband efficiency, low-frequency operation, and concurrent vibration suppression. Here, we introduce a pyramidal piezoelectric sandwich beam (PPSB) with periodic elastic constraints, leveraging homogenized lattice truss cores for enhanced electromechanical coupling. Using Lagrange equations, we derive the coupled dynamics, validated against finite element simulations with resonant frequency errors below 3%. Compared to equivalent-stiffness uniform beams, the PPSB exhibits 3.42-fold higher voltage and 11.68-fold greater power output, attributed to optimized strain distribution and resonance amplification. Parametric analyses reveal trade-offs: increasing core thickness or spring stiffness elevates resonant frequencies but reduces voltage peaks due to stiffness–strain imbalances; conversely, a larger beam length, truss radius or tilt angle will reduce the natural frequency while increasing the output through inertia and shear enhancement. Piezoelectric constants and load resistance minimally affect mechanics but optimize electrical impedance matching. This single-phase, geometrically tunable design bridges gaps in multifunctional metamaterials, enabling self-powered sensors with vibration attenuation for aerospace, civil infrastructure, and biomedical applications, paving the way for energy-autonomous systems. Full article

Wearable robotic devices for rehabilitation and assistive applications face a critical challenge: discomfort induced by prolonged pressure at the human–robot interface. Conventional attachment systems with static straps or rigid cuffs frequently exceed pain tolerance thresholds, limiting clinical acceptance and patient adherence. This study presents a novel dynamic pressure modulation system using thermally activated Twisted and Coiled Artificial Muscles (TCAMs). The system integrates a lightweight lattice structure (0.1 kg) with biocompatible silicone coating incorporating two TCAMs fabricated from silver-coated nylon 6,6 fibers (Shieldex 235/36 × 4 HCB). Electrothermal activation via 2 A constant current induces axial contraction, dynamically regulating circumferential pressure from 0.05 kgf/cm² to 0.50 kgf/cm² within physiological comfort ranges. Experimental validation on a wrist-worn prototype demonstrates precise pressure control, rapid response (5–10 s), and thermal safety through 8 mm Ecoflex insulation. The system enables on-demand interface stiffening during robotic actuation and controlled pressure release during rest periods, significantly enhancing comfort and device tolerability. This approach represents a promising solution for clinically viable wearable robotic devices supporting upper limb rehabilitation and activities of daily living. Full article

The influence of vanadium substitution on the structure, elastic, mechanical, and magnetic behavior of lithium ferrite (Li_0.5+xV_xFe_2.5−2xO₄; x = 0.00–0.2) was systematically studied. X-ray diffraction (XRD) was used to investigate the crystal structure, and infrared spectroscopy (IR) was used to determine the cation distribution between the two ferrite sublattices, in addition to the elastic and mechanical behavior of Li_0.5+xV_xFe_2.5−2xO₄ ferrites. X-ray analysis revealed a monotonic decrease in lattice parameter from 8.344 Å to 8.320 Å with increasing V⁵⁺ content, confirming lattice contraction and stronger metal–oxygen bonding. Despite a moderate increase in porosity (from 6.9% to 8.9%), the elastic constants C₁₁ and C₁₂ increased, indicating improved stiffness and reduced compressibility. The derived Young’s, bulk, and rigidity moduli rose with the doping of V⁵⁺. Correspondingly, the longitudinal, shear, and mean velocities (V_l, V_s, and V_m) increased. The Debye temperature also showed a linear rise from 705 K to 723 K with V⁵⁺ doping, directly reflecting enhanced lattice stiffness and phonon frequency. Furthermore, both the saturation magnetization (M_S) and the initial permeability (μ_i) increased up to V⁵⁺ concentration x = 0.1 and then decreased. Curie temperature (T_C) decreased with increasing V⁵⁺ concentration, while both the saturation magnetization (M_S) and the initial permeability (μ_i) increased up to V⁵⁺ concentration x = 0.1 and then decreased, while the coercivity (H_C) showed the reverse trend. These results confirm that V⁵⁺ incorporation significantly enhances the Li ferrite, improving its elastic strength, lattice energy, thermal stability, and magnetically controlling properties and making them suitable for a variety of daily uses such as magneto-elastic sensors, high-frequency devices, and applications requiring mechanically robust ferrite materials. Full article

In this work, Ba_0.6Sr_0.4TiO₃ (BST) films were deposited on Si(100) and Pt(111)/Ti/SiO₂/Si(100) substrates using the pulsed laser deposition (PLD) technique. The effects of TiO₂ buffer layer thickness and preparation temperature on the microstructure and electrical properties of BST films were studied in detail. We intensively investigated the influence of the TiO₂ buffer layer on the microstructure of BST films by using X-ray diffraction and scanning electron microscopy. We found that anatase crystalline TiO₂ buffer layers within 15 nm thicknesses could significantly change the BST films from an irregular orientation to the (111) preferential orientation. The TiO₂ anatase layers could promote the growth of BST film grains for obtaining minimal stress and low lattice distortion, increase the nucleation density, and improve its surface morphology, resulting in higher dielectric constant and resistance voltage, and lower dielectric loss and leakage current density. The dielectric constant, dielectric loss, and dielectric tunability of the BST devices with 8 nm thick TiO₂ anatase buffer layers at 1 MHz were 856.5, 0.017, and 64.3%, respectively. The achieved high dielectric tunability indicates BST with TiO₂ anatase buffer layers as one of the encouraging candidates for RF and microwave tunable applications at room temperature. Full article

Metamaterials show perfect physics characteristics for controlling elastic wave propagation. Their potential offers a lot of useful applications in low-frequency sound absorption and vibration reduction systems. However, traditional materials have inherent deficiencies in terms of functionality. There are a few designs in both acoustic and solid-mechanics domains that simultaneously exhibit sound attenuation bands and vibration bandgaps. The question poses new challenges for metamaterial development. To address this, we propose a gradient-symmetric multilayered metamaterial. The structure is capable of concurrent sound and vibration absorption. First, we established an acoustic model based on Helmholtz resonators and a vibration model by spring-mass systems. This model can predict the sound attenuation frequencies and natural frequency positions accurately. Second, through a combined simulation and experimental approach, we investigated how variations in the number of structural layers affect sound attenuation bandwidth. In addition, we analyzed the mechanisms of sound pressure distribution inside and outside the bandgaps. Finally, we elucidated the influence of lattice constants on vibration bandgap positions, demonstrating possibilities for passive control of metamaterials. This research provides robust support for the dynamic design of acoustic and mechanical metamaterials, structural modeling methodologies, bandwidth regulation strategies, and the development of sound-absorbing and vibration-damping devices. Full article

The influence of M site substitution in MCr₂O₄ nanoceramics on their properties is examined in this research. This study is an attempt to correlate the structural, morphological, and optical properties of M-site-modified chromites. The MCr₂O₄ nanoceramics-CuCr₂O₄, CoCr₂O₄, and NiCr₂O₄ were synthesized using a wet chemical sol–gel auto-combustion method, and all three samples were annealed for 4 h at 900 °C. X-ray diffraction analysis showed that the XRD patterns of CuCr₂O₄, CoCr₂O₄, and NiCr₂O₄ correspond to single-phase cubic crystal structures with the space group Fd-3m. Using the Scherrer equation, the crystallite sizes were found to be 9.86 nm, 6.73 nm, and 10.73 nm for CuCr₂O₄, CoCr₂O₄, and NiCr₂O₄, respectively. Other parameters, including crystal structure, micro-strain, lattice constant, unit cell volume, X-ray density, packing factor, and the stacking fault of the calcined powder samples, were determined from data acquired from the X-ray diffractometer. Energy dispersive X-ray spectroscopy (EDX) was employed to confirm the appropriate chromite elements in their expected stoichiometric proportions, removed from other impurities. The identification of the functional groups of the samples was performed using Fourier Transform Infrared Spectroscopy (FTIR). The absorption bands characteristic of tetrahedral and octahedral coordination compounds of the spinel structure are found between 450 and 750 cm⁻¹ for all three samples in the spectrum. From the UV-absorption spectra, and using Tauc’s plot, the energy bandgap values for CuCr₂O₄, CoCr₂O₄, and NiCr₂O₄ were measured to be 1.66 eV, 1.82 eV, and 2.01 eV, respectively. The dielectric properties of the chromites were studied using an LCR meter. Frequency-dependent dielectric properties, including Dielectric constant and Tangent loss, were calculated. These findings suggest the feasibility of the use of these synthesized chromites for optical devices and other optoelectronic applications. Full article

Cholesterol (Chol) plays a crucial role in regulating membrane properties and biological processes such as membrane fusion, yet the molecular mechanisms underlying its function remain incompletely understood. In order to elucidate how sterol structure influences phospholipid organization relevant to membrane fusion, we compared the effects of Chol and its biosynthetic precursor lanosterol (Lan) on hydrated phosphatidylethanolamine (PE) assemblies using X-ray diffraction, the neutral flotation method, and osmotic stress measurements. Volumetric analyses revealed that Lan has a larger occupied molecular volume than Chol in the bilayers. These values were largely independent of differences between phospholipids (phosphatidylcholine and PE), indicating that sterols are deeply embedded within the bilayer. In palmitoyl-oleoyl-PE lamellar membranes, both sterols increased bilayer thickness. They both enhanced short-range repulsive hydration forces, but Chol suppressed fluctuation-induced repulsion more effectively, reflecting its greater stiffening effect. In bacterial PE systems forming the inverted hexagonal (H_II) phase, increasing sterol concentration decreased the lattice constant, with a more substantial effect for Lan, which also induced greater curvature of the water columns. These results suggest that while Chol enhances mechanical rigidity and membrane cohesion, Lan promotes molecular flexibility and curvature, properties associated with fusion intermediates. Full article