Search Results (236)

The novel industrial trial is conducted to investigate the effect of argon injection into the down-leg of the RH degasser on the inclusion removal. The ‘cold steel plate dipping’ is used to take samples of molten steel and argon bubbles from the RH ladle. The industrial CT detection and electron microscope observation are applied to analyze the bubble characteristics. The results show that the size of bubbles generated by argon injection in the down-leg ranges from 7 to 1430 μm. Among them, the number density of bubbles with a diameter of 60 μm is the largest, reaching 0.1 per mm³. After adopting the down-leg argon injection technology, the average oxygen activity at the end of the RH process decreases by 2.35 ppm, and the surface defects of cold-rolled sheets of all grades are reduced. Based on the theoretical analysis of bubble collision and adhesion to inclusions, the small-sized bubbles have a relatively high capture probability for inclusions smaller than 10 μm. Comprehensively analyzing the experimental results, it is found that the down-leg argon injection technology has an obvious effect on removing inclusions. Full article

In this paper, the influence of the novel design of a ladle shroud (LS) on the liquid steel flow structure inside the working volume of a two-strand slab tundish was assessed, determining the best solutions for LS use to achieve the optimal level of active flow zones and protect the tundish lining. A 0.33 scale water model was used for physical experiments. Numerical simulations were carried out in the Ansys-Fluent 12.1 software for a 1:1 scale tundish. The effect of the influence of LS type, LS immersion depth, LS side ports position, LS misalignment and casting speed was examined. Finally, the use of the “umbrella” ladle shroud allows stable hydrodynamics to be maintained even with shroud misalignment. Moreover, the “umbrella” ladle shroud effectively decreases the average velocity of liquid steel inside the tundish and significantly decreases shear stresses and dynamic pressure at the tundish lining in the tundish pouring area. Full article

This study investigates the potential of producing zero-clinker, alkali-activated binders and concrete entirely from industrial by-products—ladle furnace slag (LFS), coal ash (CA), and cement kiln dust (CKD). The incorporation of CKD enhanced the workability and compressive strength properties of the alkali-activated mixtures, with the highest mechanical properties at 20% CKD addition. XRD, FTIR, and SEM analyses confirmed the formation of hydrocalumite, indicating improved hydration and microstructural densification. Mortar and concrete produced using the eco-cement reached 28-day strengths of 34.5 MPa and 32.6 MPa, corresponding to concrete class C20/25. These findings demonstrate the feasibility of manufacturing 100% waste-based construction materials suitable for sustainable, non-reinforced applications. Full article

Ladle furnace (LF) refining is one of the most widely used secondary refining processes for producing clean steel and constitutes a key process in the steelmaking–continuous casting section. The properties of slag play a decisive role in determining molten steel quality and refining efficiency. In this study, based on the composition of refining slag from a steelmaking plant in China, the properties of a CaO-SiO₂-MgO-Al₂O₃ slag system were investigated with respect to five aspects, the liquid phase region, sulphide capacity, melting properties, slag viscosity, and mineralogical phase precipitation, at varying temperatures, basicity, w(MgO) and w(Al₂O₃) using FactSage and the KTH model. Analysis of the slag properties indicates that the CaO-SiO₂-MgO-Al₂O₃ slag system performs better when basicity ranges from 3 to 4, w(MgO) is between 6% and 8%, and w(Al₂O₃) is 15%–25%. These findings provide theoretical support and guidance for optimizing the refining slag system in plant trials. Full article

Ladle slag (LF slag) is a by-product of secondary steelmaking that presents unique valorization challenges compared to BOF or EAF slags due to its distinctive chemical composition (high Al₂O₃ and CaO content) and uncontrolled hydraulic activity. While other steelmaking slags can be reused as supplementary cementitious materials or aggregates, LF slag is predominantly landfilled, with over 2 million tons discarded annually in Europe alone. This study introduces a novel pyrometallurgical valorization strategy that, unlike conventional approaches focused solely on mineral recovery, simultaneously recovers both metallic and mineral value through aluminothermic reduction. This process utilizes end-of-waste aluminum scrap rather than virgin materials to reduce Fe and Si oxides, creating a circular economy solution that addresses two waste streams simultaneously. The process generates two valuable products with low liquidus temperatures: a ferrosilicon alloy (FeSi15-50 grade) and a residual oxide rich in calcium and magnesium aluminates suitable for cementitious or ceramic applications. Through the integration of FactSage thermodynamic simulations with experimental validation, it is possible to predict and control phase evolution during equilibrium cooling, an approach not previously applied to LF slag valorization. Experimental validation using industrial slags confirms the theoretical predictions and demonstrates the process operates in a near-energy-neutral, self-sustaining mode by recovering both chemical and sensible thermal energy (50–100 kWh per ton of slag). This represents approximately 90% lower energy consumption compared to conventional ferrosilicon production. The work provides a comprehensive and scalable approach to transform a problematic waste material into valuable products, supporting circular economy principles and low-carbon metallurgy objectives. Full article

This article uses a water model with a ratio of 1:5.75 to study the influence of factors such as the position and flow rate of top and bottom composite argon blowing on the mixing time of molten steel in a 300t ladle at a certain factory. Using engine oil to simulate steel slag, the mass transfer velocity of molten steel under different bottom and top blowing positions and flow rates of the ladle was compared. At the same time, numerical simulation was used to analyze the changes in the flow field of molten steel under different ladle blowing modes. The optimal ladle composite bottom argon process was proposed and industrial experiments were conducted on site. The research results show that the stirring effect of top–bottom composite argon blowing in the ladle is significantly better than that of the pure bottom blowing mode. When the top blowing gun is located 300 mm at the bottom of the ladle, the mixing time of the molten steel is shortest and the stirring efficiency is highest. The higher the insertion depth of the top blowing gun, the faster the flow rate of the molten steel, and the smaller the proportion of dead zones. Top and bottom blowing can improve the mass transfer rate between steel slag and promote the formation of refined slag. Through industrial experiments, it was found that the S content in the molten steel decreased by approximately 22.3% and the total oxygen content decreased by 25% before and after 10 min of composite argon blowing at the top and bottom of the ladle. Full article

Optimizing the operational parameters of an RH degasser is essential for increasing the production of high-quality steel while reducing energy and resource consumption. This paper presents a study on the impact of different injection gas flow rates on the mixing characteristics of an industrial-scale RH degasser and evaluates the optimal flow rate for achieving the lowest mixing time. A 3D simulation model was developed using a VOF–DPM framework, with gas flow rates being varied from 18 to 72 SCFM to assess mixing time and associated flow behavior. The results indicate that the mixing time has a non-linear relationship with the gas flow rate, and increasing the flow rate does not always lead to a reduced mixing time. A flow rate of 45 SCFM (a 1.5-fold increase from 18 SCFM) provided the best mixing efficiency, reducing the mixing time by 52%. Additionally, beyond 36 SCFM, a saturation limit was observed in the circulation rate, where further increases in the gas flow rate resulted in a less than 5% improvement in steel flowing through the snorkels. These findings highlight the need for careful evaluation of injection gas flow rates in RH operations to identify the optimal value that maximizes mixing efficiency, minimizes resource consumption, and enhances productivity by enabling greater steel output in less time. Full article

Background: In September of 2024, the 2nd annual meeting of the Strategic Advances in Sarcoma Science (SASS) convened at the National Institutes of Health. This gathering of national sarcoma experts focused on preclinical studies, clinical trials, opportunities, challenges, and future directions in sarcoma biology and clinical care with a focus on immunotherapy. The Immunology in Sarcoma breakout group conducted a dedicated discussion focused on the current and future implementation of adoptive cellular therapies (ACTs) in sarcomas. The current manuscript summarizes these discussions and provides a comprehensive resource for researchers and clinicians. Results: Adoptive cell therapy (ACT) has shown encouraging results in sarcomas with afami-cel achieving durable responses in synovial sarcoma and early TCR-T trials against NY-ESO-1 and MAGE-A4 demonstrating meaningful response rates. Building on these outcomes will require discovering new targets, selecting optimal cell types, refining conditioning regimens, combining with alternative treatment strategies such as TKIs, and leveraging predictive biomarkers informed by a deeper understanding of the tumor microenvironment. Conclusions: Sarcomas are promising targets for adoptive cell therapy (ACT), as shown by afami-cel’s success in synovial sarcoma, but broader impact requires new target discovery, optimal cell selection, improved conditioning, combination treatments, deeper tumor microenvironment understanding, and predictive biomarkers to achieve more durable responses for more patients. Full article

The entrainment behavior of solid particles from the top liquid surface into molten steel exerts a crucial influence on rapid slagging and efficient desulfurization during the refining process. A Euler–Euler mathematical model was established to describe the multiphase flow field and the entrainment behavior of solid particles in a bottom-blown ladle. This model was validated by comparison with water model experiments. The effects of bottom-blowing tuyere number, gas flow rate, and solid particle size on the flow field and particle entrainment behavior were investigated. It was found that increasing the gas flow rate enhances the participation of particles in the ladle; however, the entrainment effect changes minimally when the gas flow rate exceeds 192 Nm³/h. Increasing the number of tuyeres adversely affects particle entrainment and mixing efficiency, while simultaneously expanding the size of the “open eyes”. The particle size of the refining slag has a significant impact on the entrainment effect: when the particle size exceeds 10 mm, the particles are hardly entrained in the ladle. Reducing the particle size is more conducive to increasing the entrainment amount, but excessively small particles will significantly enlarge the size of the “open eyes”. Full article

Stuffing sand, as a critical auxiliary material, plays an important role in ladle teeming during the continuous casting process and is closely related to steel cleanliness. Based on thermodynamic calculations, a melting test in a vacuum induction furnace, and industrial statistical data analysis, the reoxidation of IF steel caused by conventional Cr₂O₃-based stuffing sand was investigated. The results show that Cr₂O₃-based stuffing sand is one of the main factors resulting in the reoxidation of IF steel. [Al] and [Ti] in IF steel can be oxidized by FeO, Cr₂O₃, and SiO₂ from the Cr₂O₃-based stuffing sand, which leads to the mass burning loss of [Al] and [Ti], thus resulting in the deterioration of steel cleanliness. After reoxidation caused by Cr₂O₃-based stuffing sand, the [Cr] content in IF steel increases by 70 ppm on average. To avoid reoxidation pollution by conventional Cr₂O₃-based stuffing sand, a new kind of Al₂O₃-based stuffing sand with low reactivity was developed and applied in industrial production. After adopting this new kind of stuffing sand, the burning loss of [Al] and [Ti] decreases by 41.3% and 24.2%, respectively, and the total oxygen content (T.[O]) of the steel in the tundish decreases by 35.2% compared with the conventional Cr₂O₃-based stuffing sand. Full article

This paper presents the changes in microstructure and mechanical properties that occurred across the wall cross-section of a massive slag ladle casting due to service conditions. The slag ladle was made of low-carbon cast steel. Based on the test results, it was shown that the working environment influenced the macro-segregation of C and S on the cross-section of the wall and, consequently, had an effect on the changes in microstructure. A pearlitic–ferritic microstructure was found in the central part, while in the outer and inner parts of the wall, the microstructure was of a ferritic–pearlitic type. This change mainly influenced the impact energy—the lowest values were obtained at the centre of the wall (24 J at +20 °C). In the remaining areas tested on the wall cross-section at +20 °C, the impact energy exceeded the minimum required value of 27 J in the Charpy test. The tests revealed the presence of a network of cracks in areas adjacent to the inner surface of the ladle wall, which had a negative impact on the impact energy values, as did the presence of non-metallic inclusions. The changes found in the microstructure as a result of the ladle operation caused significant differences in properties such as impact energy and hardness, while also affecting, though to a lesser extent, the mechanical properties (UTS = 397–434 MPa; YS = 222–236 MPa). Full article

Vacuum degassing (VD) is a critical refining step in electric arc furnace (EAF) steelmaking for producing clean steel with reduced nitrogen and hydrogen content. This study develops an Effective Equilibrium Reaction Zone (EERZ) model focused on denitrogenation (de-N) by simulating interfacial reactions at the bubble–steel interface (Z1). The model incorporates key process parameters such as argon flow rate, vacuum pressure, and initial nitrogen and sulfur concentrations. A robust empirical correlation was established between de-N efficiency and the mass of Z1, reducing prediction time from a day to under a minute. Additionally, the model was further improved by incorporating a dynamic surface exposure zone (Z_eye) to account for transient ladle eye effects on nitrogen removal under deep vacuum (<10 torr), validated using synchronized plant trials and Python-based video analysis. The integrated approach—combining thermodynamic-kinetic modeling, plant validation, and image-based diagnostics—provides a robust framework for optimizing VD control and enhancing nitrogen removal control in EAF-based steelmaking. Full article

Alkali-activated building materials have attracted the interest of many researchers due to their low cost and eco-efficiency. Different binders with different chemical compositions can be used for their production, so the reaction mechanism can become complex and the results of studies can vary widely. In this work, several alkali-activated mortars based on marginal by-products as binders, such as high calcium fly ash and ladle furnace slag, are investigated. Their mechanical (flexural and compressive strength, ultrasonic pulse velocity, and modulus of elasticity) and physical (porosity, absorption, specific gravity, and pH) properties were determined. After evaluating the mechanical performance of the mortars, the optimum mixture containing fly ash, which reached 15 MPa under compression at 90 days, was selected for the production of precast compressed slabs. Steel or glass fibers were also incorporated to improve their ductility. To reduce the density of the slabs, 60% of the siliceous sand aggregate was also replaced with recycled polyethylene terephthalate (PET) plastic aggregate. The homogeneity, density, porosity, and capillary absorption of the slabs were measured, as well as their flexural strength and fracture energy. The results showed that alkali activation can be used to improve the mechanical properties of weak secondary binders such as ladle furnace slag and hydrated fly ash. The incorporation of recycled PET aggregates produced slabs that could be classified as lightweight, with similar porosity and capillary absorption values, and over 65% achieved strength compared to the normal weight slabs. Full article

To realize accurate ladle pouring, an analytical model of the constant flow rate pouring was established. By integrating a user-defined function (UDF), a CFD simulation model of the constant flow rate pouring was established to investigate the liquid steel pouring behavior under different inner wall inclination angle α, initial liquid volume V_c, and target flow rate q. Finally, the accuracy of the analytical model and the simulation model was verified through experiments. The results show that the experimental results agree well with the theoretical and simulation results, which verify the accuracy of the analytical model and the simulation model. Moreover, the simulation results indicate that increasing both α and V_c leads to an increase in the pouring flow rate. To achieve a stable pouring process and a constant flow rate value, a proper α, V_c and q_t should be selected. In this study α = 7.5° V_c = 70% V_capacity and q in the range of 0.10–0.12 m³/s are proper. To realize constant flow rate pouring, a time-variant ladle angular velocity is obtained and it can be adjusted by the motor speed. Therefore, different constant flow rates could be acquired by adjusting the motor speed, which provide guidance to the casting technology. Full article

Nodular cast iron is one of the most widely used materials in the machine building industry. The main reasons for this are its strength, elongation, and competitive price compared to other steels and metals. The possibility to have a high strength and elongation together is thanks to the spheroidal shape of the graphite inserts in the metal structure of the iron. To exploit these advantages, special treatments such as adding magnesium are used after the melting process but before pouring the metal in the casting mold. Classic technology is called tundish/sandwich technology when ferrosiliconmagnesium alloy in bulk is placed at the bottom of a ladle before filling it with liquid cast iron. In the present article, an alternative technology will be presented where a fesimg alloy is filled in a steel wire and inserted automatically into a ladle. The advantages of this technology will be described in detail. Full article