Search Results (135)

This study discusses the frictional wear performance of three 3D-printed materials, acrylonitrile butadiene styrene (ABS), polylactic acid (PLA), and high-impact polystyrene (HIPS), while evaluating different layer thickness levels. The materials were subjected to wear volume and rate tests by ball-on-disc wear tests at various thickness levels (0.1, 0.2, and 0.3 mm) and sliding distances. Lastly, SEM analysis was carried out to study the wear tracks and debris developed during the testing. Quantitatively, ABS maintained a mean wear volume below 0.15 mm³ across all test conditions (e.g., 0.05 ± 0.01 mm³ at 0.1 mm layer thickness and 150 m sliding distance), whereas PLA and HIPS recorded much higher averages of 1.5 mm³ and 3.0 mm³, respectively. With the increase in layer thickness, which caused an upward trend in the obtained results, the wear volume of the investigated materials also increased. ABS exhibited the smallest material loss of all three polymers; for example, at 0.1 mm layer thickness and a 150 m sliding distance, the mean wear volume was only 0.05 mm³, and even under the harshest condition tested (0.3 mm layer thickness, 300 m), the value remained below 0.15 mm³. PLA and HIPS showed higher wear volumes, while HIPS had the lowest resistance among the three materials. The multifunctional wear behavior difference contributed by material type was 59.76%, as shown through ANOVA, and that by layer thickness was 21.32%. Among the parameters investigated, material type had the largest control in wear behavior due to inherent variation in the structural characteristics of the material such as interlayer adhesion, toughness, and brittleness. For instance, the amorphous nature of ABS and its good layer adhesion provided significantly superior wear resistance compared to the brittle PLA and the poorly adhered HIPS. It is highlighted in this research that selecting appropriate material and layer thickness combinations can improve the durability of 3D-printed components. Full article

Mesoporous silicon dioxide films have been shown to be well suited as adhesion-promoting interlayers for generating high-strength polymer–metal interfaces. These films can be fabricated via microwave plasma-enhanced chemical vapor deposition using the precursor hexamethyldisiloxane and oxygen as working gas. The resulting mesoporous structures enable polymer infiltration during overmolding, which leads to a nanoscale form-locking mechanism after solidification. This mechanism allows for efficient stress transfer across the interface and makes the resulting adhesion highly dependent on the morphology of the deposited film. To gain a deeper understanding of the underlying deposition mechanisms and improve process stability, this work investigates the growth behavior of mesoporous silica films using a multiple regression analysis approach. The seven process parameters coating time, distance, chamber pressure, substrate temperature, flow rate, plasma pulse duration, and pause-to-pulse ratio were systematically varied within a Design of Experiments framework. The resulting films were characterized by their free surface area, mean agglomerate diameter, and film thickness using digital image analysis, white light interferometry, and atomic force microscopy. The deposited films exhibit a wide range of morphological appearances, ranging from quasi-dense to dust-like structures. As part of this research, the free surface area varied from 15 to 55 percent, the mean agglomerate diameter from 17 to 126 nm, and the film thickness from 35 to 1600 nm. The derived growth model describes the deposition process with high statistical accuracy. Furthermore, all coatings were overmolded via injection molding and subjected to mechanical testing, allowing a direct correlation between film morphology and their performance as adhesion-promoting interlayers. Full article

MBenes, an emerging family of two-dimensional transition metal boride materials, are gaining prominence in alkali metal-ion battery research owing to their distinctive stratified architecture, enhanced charge transport properties, and exceptional electrochemical durability. This analysis provides a comprehensive examination of morphological characteristics and fabrication protocols for MBenes, with particular focus on strategies for optimizing energy storage metrics through controlled adjustment of interlayer distance and tailored surface modifications. The discussion highlights these materials’ unique capability to host substantial alkali metal ions, translating to exceptional longevity during charge–discharge cycling and remarkable high-current performance in both lithium and sodium battery systems. Current obstacles to materials development are critically evaluated, encompassing precision control in nanoscale synthesis, reproducibility in large-scale production, enhancement of thermodynamic stability, and eco-friendly processing requirements. Prospective research pathways are proposed, including sustainable manufacturing innovations, atomic-level structural tailoring through computational modeling, and expansion into hybrid energy storage-conversion platforms. By integrating fundamental material science principles with practical engineering considerations, this work seeks to establish actionable frameworks for advancing MBene-based technologies toward next-generation electrochemical storage solutions with enhanced energy density and operational reliability. Full article

Vanadium-based cathodes are promising for aqueous zinc-ion batteries (ZIBs) due to the large interlayer distance. However, the poor stability of electrode materials due to the dissolution effects has severely hindered the commercial development. To address this challenge, we propose an in situ NH₄⁺ pre-intercalation strategy to enhance the electrochemical performance of Na_0.76V₆O₁₅ (NaVO), thereby optimizing its structural stability and ionic conductivity. Moreover, NH₄⁺ pre-intercalation introduced a large number of oxygen vacancies and defects into the material, causing the reduction of V⁵⁺ to V⁴⁺. This transformation suppresses the dissolution and enhances its conductivity, thereby significantly improving the electrochemical performance. This modified NaNVO cathodes deliver a higher capacity of 456 mAh g⁻¹ at 0.1 A g⁻¹, with a capacity retention of 88% after 140 cycles and a long lifespan, maintaining 99% of its initial capacity after 2300 cycles. This work provided a new way to optimize the cathode for aqueous zinc-ion batteries. Full article

Three-dimensional concrete printing (3DCP) represents a paradigm shift in construction technology, enabling the automated, formwork-free fabrication of intricate geometries. Despite its rapid growth, successful implementation remains dependent on the precise control of material rheology and printing parameters. This review critically analyzes the foundational rheological properties of static yield stress, dynamic yield stress, plastic viscosity, and thixotropy and their influence on three core printability attributes, i.e., pumpability, extrudability, and buildability. Furthermore, it explores the role of critical process parameters, such as print speed, nozzle dimensions, layer deposition intervals, and standoff distance, in shaping interlayer bonding and structural integrity. Special emphasis is given to modeling frameworks by Suiker, Roussel, and Kruger, which provide robust tools for evaluating structural stability under plastic yield and elastic buckling conditions. The integration of these rheological and process-based insights offers a comprehensive roadmap for optimizing the performance, quality, and scalability of 3DCP. Full article

The salt layer, characterized by its low permeability and excellent damage self-healing properties, is an ideal geological body for CO₂ geological storage. However, the relatively high permeability of mudstone interlayers may reduce the safety of CO₂ long-term storage in bedded salt caverns. This study establishes a thermal–hydraulic–mechanical (THM) coupled physical and mathematical model for CO₂ geological storage in the Huaian salt cavern, analyzes the factors affecting CO₂ flow behavior, and proposes measures to enhance the safety of CO₂ storage in salt caverns. The results indicate that the permeability of both salt layers and mudstone interlayers is influenced by stress-induced deformation within the salt cavern. From the salt cavern edge to the simulation boundary, the permeability and volume strain exhibit a trend of rapid decline, followed by a gradual increase, and an eventual stabilization or slight reduction. The seepage velocity, pore pressure, and flow distance of CO₂ in the mudstone interlayer are significantly higher than those in the salt layer, leading to CO₂ migration along the interfaces between the mudstone and salt layer. With the increase in storage time, the permeability of the mudstone interlayer gradually decreases, while the permeability of the salt layer shows a general tendency to increase. The elevated storage pressure reduces the permeability of the mudstone interlayer, while increasing the permeability of the salt layer, and enhances the seepage velocity in both the mudstone and salt layers. To enhance the safety of CO₂ long-term storage in bedded salt caverns, it is recommended to minimize the presence of mudstone interlayers during site selection and cavern construction, optimize the storage pressure, and strengthen monitoring systems for potential CO₂ leakage. Full article

The explosive demand for high-performance secondary power sources in artificial intelligence (AI) has brought significant opportunities for low-voltage GaN devices. This paper focuses on research on high-efficiency and high-reliability low-voltage p-GaN gate HEMTs with a gate–drain distance, L_GD, of 1 to 3 μm in our pilot line, manufactured on 6-inch Si using a CMOS-compatible process, with extraordinary wafer-level uniformity. Specifically, these fabricated p-GaN gate HEMTs with an L_GD of 1.5 μm demonstrate a blocking voltage of over 180 V and a high V_TH of 1.6 V and exhibit a low R_ON of 2.8 Ω·mm. It is found that device structure optimization can significantly enhance device reliability. That is, through the dedicated optimization of source field plate structure and interlayer dielectric (ILD) thickness, the dynamic ON-resistance, R_ON, degradation of devices with an L_GD of 1.5 µm was successfully suppressed from 60% to 20%, and the V_TH shift was significantly reduced from 1.1 to 0.5 V. Further, the devices also passed preliminary gate bias stress and high-voltage OFF-state stress tests, providing guidance for preparing high-performance, low-voltage p-GaN gate HEMTs in the future. Full article

A numerical analysis model for sand-mudstone interbedded fracturing based on field application in South China is presented in this paper. The proposed model can analyze the influence laws of different longitudinal lithology changes, stress difference changes, different interlayer positions, and fracturing fluid construction parameters on fracture characteristics. Based on the study of fracture characteristics of low-modulus mudstone, a set of layered stress loading experimental devices was independently designed and developed. Experimental analysis shows that the stress difference has a limited limiting effect on the interlayer propagation of hydraulic fracturing fractures in the Weizhou Formation, and the fracture height is prone to interlayer propagation. The injection of high-rate and high-viscosity fracturing fluid has a significant impact on the hydraulic fracture surface penetration. Numerical simulation analysis shows that the smaller the elastic modulus of the mudstone interlayer and the lower the minimum horizontal principal stress compared to the sandstone layer, the more favorable it is for fracture propagation. Field application showed that the highest injection rate of the fracturing pump in well A was 7 m³/min for south-west Weizhou oilfield shale oil. The interpretation results of the acoustic logging after fracturing showed obvious response characteristics of the formation fractures, and the farthest detection fracture response well distance was 12 m, indicating a good fracturing transformation effect and providing technical support for subsequent offshore shale oil fracturing construction. Full article

Backfillembedded heat exchanger (BEHE) are used for stope cooling during the mining process and for geothermal energy recovery during the long-term heat extraction stage. This study develops a three-dimensional BEHE model to optimize the pipe arrangement, considering both the immediate requirements of stope cooling and the long-term objectives of geothermal energy exploitation. To evaluate the effects of geothermal energy extraction and stope cooling, heat extraction per meter and average temperature in the stope area are used as criterion parameters. The results indicate that the cooling efficiency is positively correlated with the number of pipe layers and pipe diameter, while it is negatively correlated with pipe spacing, interlayer spacing, and the distance from the bottom of the backfill-embedded heat exchanger (BEHE) to the cold radiation surface. Geothermal energy extraction, on the other hand, is positively correlated with the number of pipe layers, interlayer spacing, and the distance from the bottom of the BEHE to the cold radiation surface. Considering both objectives, the optimal pipe arrangement is determined to be PLS = 1.0 m, S = 500 mm, F = 3, D = 0.05 m, and DN = 50 mm. Additionally, based on a comprehensive analysis of extensive calculation results, an empirical correlation for heat extraction per meter as a function of pipe arrangement parameters was derived. Full article

The pursuit of efficient and sustainable hydrogen production is essential in the fight against climate change. One important method for achieving this is the electrolysis of water, particularly through the oxygen evolution reaction (OER). Recent studies indicate that trimetallic layered double hydroxides (LDHs) can enhance OER performance compared to bimetallic LDHs. This improvement occurs because the third cation alters the electronic structures of the other two cations, thereby increasing the intermediates’ binding energies and enhancing electrical conductivity. This study proposes an approach enabling the modulation of the electronic structures of all three cations involved in the synthesis of the trimetallic LDHs. It suggested intercalating sodium dodecyl sulfate (SDS) into the interlayer of the trimetallic NiFe-La-LDH. A successful intercalation of SDS has been confirmed through the XRD, FT-IR, EDS, and XPS. This has expanded the interlayer distance which was beneficial for the electrical conductivity. Furthermore, SDS generated sulphur, which modulated the electronic structures of all three cations enriching the active sites and improving electrical conductivity and OER performance compared to its counterparts. This approach is beneficial: 1. The interlayer can be further enlarged by using different doping ratios of SDS. 2. Sulphur can enrich the active sites and improve the OER performance. Full article

In order to study the instability characteristics of interlayer rock strata (IRS) in shallow buried close-distance coal seams under insufficient mining areas, based on the background of interval mining under goaf in Nanliang Coal Mine, this paper studies the instability characteristics of interlayer strata in interval mining under goaf by means of similar simulation, numerical simulation, and field measurement. The results indicated that the first weighting interval of the main roof during mining in the lower coal seam was 49 m, while small and large periodic weightings with intervals of 10–14 m and 15–19 m were identified. During periodic weighting, the support resistance ranged from 6813 to 10,935 kN, with a dynamic load factor of 1.07–1.74, and the peak abutment pressure in front of the working face was 5.85–9.85 MPa. The mining under the interval coal pillar (ICP) was the ‘stress increase zone’, and the mining under the temporary coal pillars (TCPs) and the interval goaf was the ‘stress release zone’. During the working face mining out of the ICP, the support resistance reached 10,934 kN, the dynamic load factor reached 1.74, and the abutment pressure (AP) reached 9.85 MPa, which was 60% higher than the AP mining under the “stress release zone”. Analysis suggests that the cutting instability of the IRS was the root cause of the increased AP in the working face of the lower coal seam. A numerical simulation was performed to verify the instability characteristics of the IRS in the interval goaf. The relationship between support strength and roof subsidence during the period of the working face leaving the coal pillar was established. A dynamic pressure prevention method involving pre-splitting and pressure relief of the ICP was proposed and yields superior field application performance. The findings of the study provide a reference for rock strata control during mining under the subcritical mining area in shallow and closely spaced coal seams. Full article

The mixture of hexamethylene diisocyanate (HDI) and butanol (BuOH) with the intercalation compound of 1,4-diazabicyclo[2.2.2]octane (DABCO) with α-zirconium phosphate (α-ZrP) has been evaluated as a latent thermal catalyst at varying temperatures. α-ZrP·DABCO did not show activity at 25 °C, but showed a high level of activity at a higher temperature of 80 °C. To clarify the reaction behavior of HDI-BuOH with α-ZrP·DABCO, a viscosity value of 1200 mPa·s·g/cm² was reached at 80 °C for 30 min. To investigate the deintercalation behavior of DABCO from the α-ZrP interlayer, it was investigated in BuOH and in HDI, respectively, under heated conditions. Interestingly, XRD patterns showed a reduction in α-ZrP·DABCO for the interlayer distance due to the deintercalation of DABCO in BuOH, while no changes associated with the deintercalation of DABCO were observed in HDI. Butanol was found to be important for the deintercalation of DABCO. To examine the reactivity of bifunctional monomers, the reaction of 1,4-butanediol (1,4-BDO) and HDI with α-ZrP·DABCO were investigated to show good reactivity at 80 °C and stability at 40 °C. Full article

Metasurfaces have shown great potential in achieving low-cost and low-complexity signal enhancement and redirection. Due to the low transmission power and high attenuation issues of current high-frequency communication technology, it is necessary to explore signal redirection technology based on metasurfaces. This paper presents an innovative metasurface for indoor signal enhancement and redirection, featuring thin thickness, high gain, and wide-angle deflection. The metasurface integrates the design principles of a Fabry–Perot cavity (FPC) theory with a Phase Gradient Partially Reflective Metasurface (PGPRM). Its unit is a fishnet structure with a substrate only 1/33 λ thin. Based on the precise phase control of the dual-layer PGPRM (with an inter-layer distance of 8 mm), the proposed metasurface can obtain phase coverage as small as 78° while achieving high-gain beam deflection as large as 47°. Simulation results show that within the band 8.6–9.2 GHz (6.7%), a single-layer metasurface can deflect the beam to 29° with a maximum gain of 16.9 dBi. In addition, it is also 360° polarization-insensitive in the xoy plane at 9 GHz with large-angle deflection characteristic retained. Moreover, cascading PGPRM can effectively improve the beam deflection angle. After analysis, the scheme with a double-layer spacing of 8 mm was ultimately selected. Simulation results show a double-layer metasurface can deflect the beam to 47° with a maximum gain of 16.4 dBi. This design provides an efficient and cost-effective solution for large-angle beam deflection with gain enhancement for indoor wireless communication. Full article

In this study, the topological properties of the shallow seismicity occurring in the area around the Lai Chau hydropower plant (Vietnam) are investigated by using visibility graph (VG) analysis, a well-known method to convert time series into networks or graphs. The relationship between the seismicity and reservoir water level was analyzed using Interlayer Mutual Information (IMI) and the Frobenius norm, both applied to the corresponding VG networks. IMI was used to assess the correlation between the two variables, while the Frobenius norm was employed to estimate the time delay between them. The total seismicity, which resulted in an $M\ge 0.8$ with a b-value of 0.86, is characterized by a $k-M$ slope of ≈9.1. Analyzing the variation of the seismological and topological parameters of the seismicity relative to the distance from the center of the Lai Chau reservoir revealed the following features: (1) the b-value fluctuates around a mean value of 1.21 at distances of up to 10–11 km, while, for distances larger than 25–30 km, it tends to the value of 0.86; (2) the maximum IMI between the monthly number of earthquakes and the monthly mean water level occurs at a distance of 9–11 km, showing a distance evolution similar to that of the b-value; (3) at these distances from the center of the reservoir, the time lag between the earthquake monthly counts and the monthly water level mean is 9–10 months; (4) the relationship between the b-value and the $k-M$ slope suggests that the $k-M$ slope depends on the number of earthquakes within a 22 km radius from the center of the dam. Our study’s findings offer new insights into the complex dynamics of seismicity occurring around reservoirs. Full article

In the present study, the feasibility to achieve localized induction heating and debonding of multi-material composite structures is assessed in testing coupons prepared by Automated Fiber Placement (AFP) and extrusion-based additive manufacturing (AM) technologies. Nano-compounds of Polyether-ketone-ketone (PEKK) with iron oxide nanoparticles acting as electromagnetic susceptors have been processed in a parallel co-rotating twin-screw extruder to produce filament feedstock for extrusion-based AM. The integration of nanocomposite interlayers as discrete debonding zones (DZ) by AFP-AM manufacturing has been investigated for two types of sandwich-structured laminate composites, i.e., laminate-DZ-laminate panels (Type I) and laminate-DZ-AM gyroid structures (Type II). Specimens were exposed to an alternating magnetic field generated by a radio frequency generator and a flat spiral copper induction coil, and induction heating parameters (frequency, power, heating time, sample standoff distance from coil) have been investigated in correlation with real-time thermal imaging to define the debonding process window without compromising laminate quality. For the optimized process parameters, i.e., 2–3 kW generator power and 20–25 mm standoff distance, corresponding to magnetic field intensities in the range of 3–5 kA m⁻¹, specimens were effectively heated above PEKK melting temperature, exhibiting high heating rates within the range of 5.3–9.4 °C/s (Type I) and 8.0–17.5 °C/s (Type II). The results demonstrated that localized induction heating successfully facilitated debonding, leading to full unzipping of the debonding zones in both laminate structures. Further insight on PEKK nanocomposites debonding performance was provided by thermal, morphological characterization and non-destructive inspection via X-ray micro-computed tomography at different processing stages. The developed framework aims to contribute to the development of rapid, on-demand joining, repair and disassembly technologies for thermoplastic composites, towards more efficient maintenance, repair and overhaul operations in the aviation sector and beyond. Full article