Search Results (10,255)

Soil moisture critically governs terrestrial energy and water cycles. Precise monitoring of soil water content is essential for precision agriculture, drought early warning, and water resource management. Ground-based observations offer limited spatial coverage, and satellite remote sensing generally lacks high spatial resolution. Unmanned aerial vehicle (UAV) remote sensing, which provides centimeter-level spatial detail, can effectively address this gap and has therefore attracted considerable attention in soil moisture inversion research. Using CiteSpace, we performed a bibliometric analysis of 97 Chinese papers from the China National Knowledge Infrastructure (CNKI) and 321 English papers from the Web of Science Core Collection (2014–2025). The field has expanded rapidly since 2018, with China occupying a leading role. Domestically, Northwest A&F University represents a major research cluster, while the Chinese Academy of Sciences leads internationally. Key research topics include UAVs, soil moisture, machine learning, hyperspectral sensing, canopy temperature, and precision agriculture. Research themes have progressed from reliance on vegetation indices and temperature data toward the integration of hyperspectral and thermal infrared measurements, and toward the use of machine learning approaches to improve inversion models and achieve more accurate estimations. This study delineates the classification and developmental context of a knowledge system for soil moisture inversion using UAV remote sensing. Current work concentrates on integrating multi-sensor data with machine learning, while future efforts will emphasize coupling physical mechanisms with deep learning. These findings offer researchers a clear view of the field’s frontiers and a basis for planning future studies. Full article

Industrial tunnel pasteurizers are widely used for bottled liquid products because they provide a robust and continuous thermal treatment. However, operating conditions are often conservatively selected to ensure microbiological safety, which may result in excessive energy consumption and limited thermal efficiency. This study experimentally investigates the thermal behavior and energy performance of an industrial tunnel pasteurizer used for a sealed bottled herbal-based high-viscosity liquid formulation under both nominal and modified operating conditions. An instrumented bottle was developed to measure temperature evolution at different locations inside the bottle, including the product core. In parallel, the overall heat capacity of the bottle–product system was determined by differential scanning calorimetry, enabling the estimation of the thermal energy absorbed by the bottles. Mass and energy balances were applied to quantify the heat exchanged in each process stage and to estimate phase-specific and overall heat-transfer efficiencies. Under nominal conditions, the pasteurization requirement, defined as a temperature above 72 °C for at least 12 min at the coldest point, was fully satisfied, with the temperature remaining above 72 °C for approximately 22 min near the bottle wall and 17–18 min at the product core. The energy analysis showed that overall process efficiency was limited, indicating room for improvement. Three additional experimental tests were therefore carried out under modified temperature and flow-rate conditions. In all cases, the pasteurization target was maintained. The results demonstrate that the process complies with the prescribed pasteurization target while offering significant opportunities for energy savings through optimization of the operating parameters. Full article

Wear remains a dominant cause of performance loss and premature failure in mechanical components, motivating the development of environmentally benign surface-engineering solutions. Among thermal spray systems, high-velocity oxy-fuel (HVOF)-sprayed WC-Co coatings are widely applied under severe wear conditions. The development of nanophase coatings offers the potential for enhanced mechanical performance. However, retaining the nanostructure and limiting decarburization during deposition remain key challenges. In this study, nanophase WC-12Co feedstocks with two particle size ranges, together with Al-modified nanophase powders, were used to deposit coatings under optimized HVOF spraying conditions (spray distance 200 mm, reduced O₂/fuel ratio, and high particle velocity) and were benchmarked against a conventional WC-12Co (12 wt.% Co) coating. The coatings were characterized in terms of microstructure and phase constitution (OM, SEM/EDS, XRD) as well as thickness, porosity (0.5–3.6%), adhesion strength (up to 65 MPa), and microhardness (~1040–1210 HV). Tribological behavior was assessed by ASTM G99 pin-on-disk testing and counterbody wear was quantified via geometric volume loss estimations. The use of larger nanophase particles enabled effective nanostructure retention with limited decarburization, whereas reducing particle size intensified decarburization, promoting increased W₂C formation, and markedly reduced coating cohesion, despite lower porosity and higher hardness. Aluminum additions enhanced coating microhardness and suppressed Co₃W₃C formation, indicating improved phase stability with minimal additional decarburization. Although coating wear remained negligible for all systems, Al-containing coatings exhibited increased friction (up to 35%) and significantly higher counterbody wear (up to sevenfold) compared to the Al-free nanophase coating, which was found to correlate with coating microhardness. Overall, the results demonstrate that optimizing nanophase WC-Co coatings requires balancing competing mechanisms between microstructural stability, cohesive integrity, and tribological response, highlighting the critical role of feedstock design in tailoring coating performance. Full article

As demand for energy-efficient buildings grows, the use of expanded polystyrene (EPS) insulation is expected to increase, intensifying the need for material-efficient strategies such as recycling and reuse. This study investigates the technical feasibility, chemical safety, and climate implications of reusing EPS insulation recovered from building and infrastructure applications. EPS boards with service lives exceeding 20 years were collected from demolition sites and characterised for density, compressive strength, thermal conductivity, and hazardous substance content. Measured material properties were compared with historical test reports from 1976 to 2009 to assess long-term performance. The thermal conductivity and compressive strength of the used EPS samples fell within or close to the 95% prediction intervals for the corresponding products at the time of production, indicating limited long-term degradation. No brominated flame retardants or other substances of concern were detected above the detection limits. Life cycle assessment (LCA) results showed that reuse provides greater greenhouse gas (GHG) emission reduction potential than improved recycling alone, primarily through avoided virgin EPS production and reduced processing needs. An important insight from this study is that key material properties of used EPS can be reliably estimated from simple measurements of density, dimensions, and weight, and that direct reuse is feasible for less demanding applications. Additionally, further work is needed to test additional samples from diverse demolition sites across various applications and climates to establish a consistent basis for reuse. Full article

Cermet tools possess favorable mechanical and tribological properties and are widely adopted for machining hard-to-cut materials. However, their performance can further be enhanced with different cooling and lubrication techniques. In this study, the tool wear mechanisms of cermet tools during hard turning of AISI 4340 alloy steel are investigated under dry and minimum quantity lubrication (MQL) environments to identify the prevalent causes of tool failure through comprehensive analysis of tool wear progression, chip temperature, and chip morphological analysis. The results revealed that the application of MQL exhibited prolonged and stable steady-state tool wear progression with retained cutting-edge geometry, thus demonstrated 30.27% improvement in tool life compared to dry cutting. On the contrary, a rapid increase in tool wear due to excessive friction and higher thermal load is noticed with dry cutting in the absence of any heat-dissipating medium. Chip temperature measurements supported these observations, as chip temperature increases sharply from 358 °C (with a fresh tool) to about 1090 °C (with a worn tool) under a dry environment. Conversely, with MQL, the corresponding increase was in the range between 294 °C and 843 °C with a fresh and worn tool, respectively. Chip analysis revealed a serrated type of chip morphology. Dry cutting exhibited intensified feed marks, indicative of severe tool–chip friction, whereas MQL demonstrated smoother morphology with closely spaced saw-tooth patterns. Tool wear mechanisms indicate abrasion, adhesion, and edge chipping as dominant wear mechanisms under both environments; however, in the absence of any lubricant, these mechanisms were more intensified with higher crater formation. Full article

With the capacity of generators continuing to increase, higher demands are placed on the heat dissipation of epoxy resin (EP), the main insulation material used in stator bars and windings. To overcome its low thermal conductivity, a multiscale hybrid filler strategy was adopted to investigate the effects of spherical Al₂O₃ (10 and 1 μm), platelet BN (1 μm), and SiO₂ (50 nm) on the thermal and insulating properties of EP composites. Unlike conventional studies focusing on individual fillers, this work highlights the synergistic design of fillers with different sizes and morphologies. The filler ratios were optimized by finite element simulation, and the composites were prepared by melt blending. The results show that, at a total filler loading of 38.5 wt%, the EP composite filled with spherical Al₂O₃ particles of 10 and 1 μm, platelet BN of 1 μm, and nano-SiO₂ of 50 nm achieves a thermal conductivity of 0.5497 W/(m·K), corresponding to an increase of 158.2% compared with pure EP (0.2129 W/(m·K)). This enhancement is attributed to the synergistic effect of multiscale and multishape fillers, where large Al₂O₃ particles form the main thermally conductive framework, small Al₂O₃ particles fill the gaps, platelet BN acts as a bridging filler, and nano-SiO₂ improves the interfacial region. In addition, the composite exhibits low relative permittivity and dissipation factor tanδ in the frequency range of 10⁻²–10⁶ Hz, and its breakdown strength reaches 65.99 kV/mm. These results demonstrate that simulation-guided multiscale hybrid filler design is an effective strategy for improving the thermal conductivity of EP while maintaining acceptable insulating performance. Full article

Polyester resin biocomposites containing biochar have attracted attention for improving mechanical strength and thermal stability while promoting sustainability. The pyrolysis temperature of biochar and its proportion in the polymer matrix are key factors affecting biocomposite performance. This study examined how biochar pyrolysis temperatures (400, 600, 800 °C) and incorporation levels (10, 20, 30 wt.%) influence the physical, chemical, mechanical, flammability, and morphological properties of polyester-based biocomposites. The samples were analyzed for density, water absorption, FTIR, XRD, flexural and tensile strength, ignition time, structural degradation, volumetric loss, and SEM microstructure. Biocomposites with 30 wt.% biochar produced at 800 °C showed the best mechanical properties, with a flexural strength of 95.3 MPa and an elastic modulus of 4417.4 MPa, representing increases of 14.5% and 45.7%, respectively, over the control. FTIR and XRD results revealed decreased aliphatic groups and increased aromaticity at higher pyrolysis temperatures, improving interactions between the matrix and biochar. These biocomposites also demonstrated enhanced thermal stability, with an ignition time of approximately 963 s, delayed structural degradation, and reduced volumetric loss (~19.3%). Overall, pyrolysis temperature and biochar content significantly influence the structural, mechanical, and thermal properties of polyester biocomposites, showing that biochar serves as a sustainable, performance-enhancing component in thermoset polymer matrices. Full article

In this work, Ce-doped ZnO thin films at various contents of cerium were deposited on glass substrates by thermal vacuum evaporation to study the influence of Ce concentration on their optical, structural, morphological, and photocatalytic behavior. Pure ZnO and Ce-doped ZnO films doped with 2% and 5% Ce were characterized by SEM, XRD, AFM, UV–VIS spectroscopy, and ellipsometry. The XRD analysis confirmed that all the films retained the hexagonal wurtzite structure, while Ce incorporation induced lattice strain and reduced crystallite size, particularly at higher doping levels. SEM and AFM studies showed that films with 2% Ce exhibited smaller grain size and lower roughness, whereas 5% Ce-doped films showed grain growth and increased roughness. Pure ZnO films displayed high transparency (>90%), whereas Ce incorporation caused a red shift in the absorption edge and narrowing of the optical band gap due to defect-related states and lattice distortion. Photocatalytic experiments revealed that Ce doping improved charge carrier separation and increased the number of oxygen vacancies. Among all samples, the 2% Ce-doped ZnO film demonstrated the highest photocatalytic efficiency. These findings highlight the importance of controlled Ce doping in tuning the microstructure, optical properties, and photocatalytic performance of ZnO thin films, making them suitable for environmental remediation and optoelectronic applications. Full article

Eucommia ulmoides gum (EUG), a sustainable plant-derived natural polymer, was functionalized via three distinct routes, including vulcanization, epoxidation, and hydroxylation to yield vulcanized (VEUG), epoxidized (EEUG), and hydroxylated EUG (HEUG), respectively. We systematically characterized the effects of modification route and degree on the chemical structure, crystallization behavior, thermal stability, hydrophilicity, and mechanical properties of functionalized EUG and further evaluated the high/low-temperature performance, microstructure, and mechanical properties of the corresponding modified asphalt binders (VEMA, EEMA, HEMA) as a function of modifier type and loading. For VEUG, C-S cross-linking networks formed during vulcanization suppress EUG crystallization, enabling a rigid-plastic to elastic transition, while high-temperature cleavage of C-S bonds reduces its initial thermal stability. For EEUG, epoxidation breaks C=C double bonds and introduces epoxy groups to strengthen intermolecular interactions; subsequent ring-opening grafting of hydroxyl groups onto EEUG yields HEUG, which forms additional cross-links via dynamic hydrogen bonds. Increasing modification degree for both EEUG and HEUG reduces their number- and weight-average molecular weights with narrower distribution, diminishes crystallinity, enhances thermal stability and hydrophilicity, and drives a rigid-plastic to elastic transition, characterized by decreased strength (0.65 MPa < σ_HEUG < σ_EEUG < 10.18 MPa) and markedly improved ductility (143.6% < ε_EEUG < 262.0%, 679.9% < ε_HEUG < 1360.3%). In asphalt binders, VEUG’s cross-linked network endows VEMA with refined more abundant bee-like microstructures, drastically boosting high- and low-temperature performance: relative to pristine EUG-modified asphalt (EUGMA), VEMA’s DMT modulus decreases by 94%, and adhesion increases by 87%. EEMA forms covalent bonds with polar asphalt components via epoxy groups, while HEMA constructs a hydrogen-bonded cross-linked network; both effectively inhibit asphaltene aggregation. With increasing modifier loading, EEMA and HEMA exhibit increased modulus, reduced adhesion, and gradually improved high- and low-temperature performance, except for the non-significant high-temperature enhancement of HEMA at higher loadings. Full article

Thermoacoustic power generation holds significant promise for applications such as solar thermal utilization, industrial waste heat recovery, and distributed energy systems, owing to its high efficiency and reliability. Conventional standing-wave and traveling-wave thermoacoustic generators, however, are often limited by bulky resonators and substantial acoustic power dissipation. Replacing the resonator with a linear alternator (LA) offers an effective means to improve system compactness and output performance. Nonetheless, under standing-wave acoustic conditions, the LA’s large piston swept volume increases the device size, thereby constraining overall compactness. To address this limitation, a novel moving-magnet LA with electromagnetic components integrated into the moving piston is proposed. Compared to conventional configurations, this design significantly reduces the size and weight of the alternator. Furthermore, the influence of different magnetic circuit configurations on output performance is systematically investigated, enabling optimization of the alternator design. Results demonstrate that the proposed alternator achieves a more compact structure while delivering output performance comparable to that of conventional external magnetic-circuit designs, thereby validating the feasibility of the proposed approach. Full article

The sustainable renovation of ageing industrial buildings presents both a challenge and an opportunity to enhance energy efficiency while preserving architectural and structural integrity. This study develops an integrated methodological framework for assessing and optimising multilayer wall systems in such conversions, combining thermal, environmental, and durability analyses. Six composite wall configurations were designed and numerically evaluated using steady-state 2D heat conduction and vapour-diffusion models. The results reveal substantial thermal improvement compared to the reference uninsulated brick wall (U = 1.41 W/m²·K). The proposed systems achieved U-values between 0.351 and 0.172 W/m²·K, meeting or surpassing European energy standards. The BP–EPS wall exhibited the lowest U-value (0.172 W/m²·K), while the FC–EPSR configuration achieved superior corner performance with a 2D surface temperature (Tsi) of 17.99 °C and the highest surface temperature factor (fRsi = 0.943), along with a reduced condensation risk, indicating more balanced overall performance. Weight and thickness reductions of up to 80.5% and 52%, respectively, were observed, enhancing retrofit feasibility and space efficiency. Life Cycle Assessment results indicated that optimised wall configurations reduced embodied carbon (A1–A3) by up to 78% and total life cycle emissions (A1–A3 + B6) by over 86% relative to the reference case. Vapour-diffusion analysis confirmed the FC–EPSR wall’s lowest condensation fraction, indicating excellent hygrothermal durability. Multi-criteria evaluation using the simple additive weighting method and Monte Carlo robustness analysis verified FC–EPSR as the most balanced and reliable system. Overall, the findings present a validated and replicable pathway for the sustainable renovation of industrial buildings, supporting the goals of European carbon neutrality and the circular economy. Full article

Per- and polyfluoroalkyl substances (PFAS) have found wide application in proton exchange membrane fuel cells (PEMFCs) and water electrolysers (PEMELs), thanks to their exceptional chemical and thermal stability. However, their environmental persistence and growing regulatory pressure—particularly from the European Union—have made the transition to PFAS-free components a priority. This work reviews current advancements in alternative materials that can guarantee the same performance or maybe improve it. Although several non-fluorinated materials have demonstrated initial performance close to PFAS-based benchmarks, significant challenges remain. These include limited long-term stability, difficulties for new materials to fit into existing stack architectures, and the lack of standardized testing protocols. Nevertheless, recent efforts have successfully demonstrated a PFAS-free PEM electrolyser stack at TRL 4, validating the technical feasibility of full PFAS substitution. Achieving commercial readiness will require parallel progress in materials development and industrial scalability. This review highlights the possibility that hydrogen technologies, such as fuel cells and electrolysers, which are called upon to support the energy transition towards a more sustainable future, are themselves truly environmentally friendly, thus making their use as green as possible. Full article

This study addresses the optimal scheduling of a proton exchange membrane fuel cell (PEMFC)-based building combined cooling, heating, and power (CCHP) system, aiming to improve operational efficiency and flexibility under coupled electricity–thermal–cooling demands and load uncertainty. A physics-informed scheduling environment was developed using component models and multi-energy balance constraints, including a PEMFC with waste-heat recovery, a lithium bromide absorption chiller, a reversible heat pump with condenser heat recovery to thermal storage, a battery energy storage system, and a hot-water thermal storage tank. The dispatch problem was formulated as a Markov decision process and solved using deep reinforcement learning with TD3; performance was evaluated on typical summer and winter days, and robustness was tested by generating 100 scenarios with 30% demand perturbations. The results show that TD3 learns coordinated multi-energy dispatch patterns consistent with seasonal operation and reduces hydrogen consumption relative to a rule-based strategy under uncertainty while requiring millisecond-level inference time. Dynamic programming achieved slightly lower hydrogen consumption but incurred orders-of-magnitude higher computation time. Overall, TD3 provides a practical trade-off between near-optimal performance, robustness, and real-time applicability for PEMFC-based building CCHP scheduling. Full article

With the accelerated transformation of green shipping and the advancement of ship electrification, lithium-ion batteries have become the core solution for ship propulsion due to their advantages of high energy density and zero emission. Efficient thermal management serves as a key technical support to ensure the safe and stable operation of batteries, extend their service life, and mitigate the risk of thermal runaway. Lithium-ion batteries accumulate heat during discharge, and pure phase change material (PCM) cooling systems are limited by low thermal conductivity, leading to excessive battery temperature rise and poor temperature uniformity. To address this problem, RT42 (a paraffin-based PCM with a melting temperature range of 311.15–316.15 K) was selected as the PCM in this study. The battery thermal management system (BTMS) coupling RT42 with a three-dimensional fin network structure was designed. Numerical simulations were conducted via ANSYS Fluent, and the enthalpy-porosity method was adopted to simulate the PCM phase change process. The effects of fin distribution, spacing and layer number on BTMS performance were systematically investigated and compared. Results show that the heat transfer process in the PCM can be significantly improved due to the three-dimensional fin network, and the battery maximum temperature can be reduced by 7.53 K compared with the pure PCM system. This study provides theoretical support for the design and optimization of high-efficiency BTMS. Full article

Bone tissue plays a vital role in the human body and possesses intrinsic self-repair mechanisms; however, large defects or pathological fractures may exceed its natural healing capacity. Bone tissue engineering provides promising strategies to restore bone integrity through the use of scaffolds, growth factors, and stem cells. While calcium phosphate (CaP)-based ceramics, such as hydroxyapatite (HAp) and tricalcium phosphate (TCP), represent the current benchmark, their limitations, including slow degradation (HAp) and limited osteoinductivity (TCP), have driven the development of alternative biomaterials. In this context, magnesium phosphate (MgP)-based materials have gained increasing attention due to their tunable resorption rate, improved biodegradability, and ability to stimulate osteogenesis and angiogenesis through the release of magnesium (Mg²⁺) ions. This study reports on composite scaffolds based on electrospun poly(ε-caprolactone) (PCL) fibres coated with MgP layers doped with lithium (Li) and zinc (Zn), designed to mimic the nanofibrous architecture of the extracellular matrix. Lithium and zinc were selected due to their known ability to modulate cellular response, with lithium promoting osteogenic activity and zinc contributing to improved cell proliferation and antibacterial potential. The phosphate phases obtained by coprecipitation were deposited onto the PCL fibres using Matrix-Assisted Pulsed Laser Evaporation (MAPLE), enabling controlled surface functionalization. Following thermal treatment, the formation of the crystalline magnesium pyrophosphate (Mg₂P₂O₇) phase was confirmed by chemical and structural characterization. The combination of a slowly degrading PCL matrix, providing sustained structural support, and a bioactive MgP coating, enabling rapid and controlled ion release, results in improved scaffold performance in terms of biocompatibility, biodegradability, and bioactivity. While the slow degradation rate of PCL ensures mechanical stability over an extended period, the surface-deposited MgP phase allows immediate interaction with the biological environment, facilitating faster ion release and enhancing cell–material interactions. These findings highlight the potential of the developed composites as promising candidates for trabecular bone regeneration and as viable alternatives to conventional CaP-based scaffolds in regenerative medicine. Full article