Search Results (57)

High-Andean páramo ecosystems regulate streamflow and water quality through water storage, subsurface flow, and natural hydrogeochemical buffering. However, increasing land-use pressures may generate early water-quality signals that are difficult to distinguish from natural geogenic variability in protected headwater catchments. This study evaluated the spatiotemporal variability of water quality in the Diablo Sacha River, located within the Quinllunga Water Protection Area, Ecuador. Water samples were collected at ten monitoring stations during six bimonthly campaigns from March 2024 to January 2025, generating 60 spatiotemporal observations per parameter. An integrated hydrogeochemical and multivariate framework was applied, combining Piper diagrams, Spearman correlation analysis, independent principal component analyses for hydrogeochemical and anthropogenic variables, and two-way PERMANOVA. Results showed a predominant Ca–Mg–HCO₃ hydrochemical facies, indicating that water chemistry is mainly controlled by natural mineral weathering, water–rock interaction, and longitudinal solute accumulation. The hydrogeochemical PCA explained 52.75% of the variance and identified a mineralization gradient associated with EC, HCO₃⁻, SO₄²⁻, Ca²⁺, Mg²⁺, and hydrological dilution. The anthropogenic PCA explained 61.77% of the variance and revealed secondary signals related to nutrients, organic matter, suspended solids, oils and grease, and microbiological indicators. PERMANOVA confirmed significant spatiotemporal structuring for hydrogeochemical variables and seasonal modulation for anthropogenic indicators. Overall, the Diablo Sacha River functions as a hydrogeochemically buffered high-Andean headwater system, where natural páramo processes maintain water-quality stability, while emerging anthropogenic signals act as early-warning indicators of ecosystem pressure. Full article

Groundwater is a critical lifeline for ecosystems and human settlements in arid and semi-arid regions, yet it is increasingly vulnerable to the dual pressures of extreme climatic conditions and intensifying anthropogenic activities. This study investigated 24 groundwater and 4 river water samples to discuss the hydrogeochemical evolution and water quality suitability in the Tianjun Basin, a typical high-altitude arid basin on the northeastern Tibetan Plateau. The results indicate that groundwater is mildly alkaline (pH: 7.65–8.35) and predominantly fresh (TDS: 233.77–1061.42 mg/L). Hydrochemical facies evolve from HCO₃-Ca type in upstream areas to Mixed HCO₃-Na·Ca and Cl-Na types. Hydrochemical analysis suggests that silicate weathering and carbonate dissolution are the dominant natural processes, while cation exchange further modifies the ionic composition. Notably, anthropogenic nitrogen (NO₃⁻ and NH₄⁺) contamination, primarily from domestic sewage in the Tianjun Basin, has significantly impacted groundwater quality. Health risk assessment shows that infants are the most vulnerable group, with 16.67% of samples posing a non-carcinogenic risk via the oral pathway. Regarding irrigation suitability, while sodium hazards are generally low, a significant salinity hazard is identified due to elevated electrical conductivity in the arid environment. This poses a substantial risk of secondary soil salinization, necessitating strict salt management strategies to preserve long-term land productivity. These findings provide critical insights for the sustainable management of fragile groundwater resources in extreme arid environments. Full article

Uranium exploration in southeastern Mongolia remains constrained by fragmented Soviet-era datasets and limited modern synthesis. This study addresses the problem of integrating historical geological records with contemporary exploration methods to evaluate uranium mineralization potential. A comprehensive GIS-based database was compiled from Soviet reports legally acquired from the Mineral Resources Authority of Mongolia and expanded with geological, geophysical, and drilling data collected between 2006 and 2011. Methodological advances included remote sensing detection of anomalous radioactivity in arid environments, stratigraphic modeling, and hydrogeochemical surveys. The dataset encompasses more than 1100 radioactive anomalies and approximately 300 mineralized zones, with emphasis on the Han Bogd granite massif, Ail Bayan coal deposit, Suujin Tal structural system, Zuunbayan depression, and Naarst structural complex. Results indicate that most anomalous zones are sub-economic, commonly associated with organic-rich facies such as coal seams, while the continuity of mineralized bodies remains uncertain. Nevertheless, the dual consideration of granitic source terrains and coal-bearing sedimentary traps provides new insights into uranium mobility and deposition. The significance of this work lies in its systematic integration of historical and modern data, offering a refined geological framework and highlighting key areas for future investigation, thereby contributing to ongoing discussions on sedimentary uranium resources in Mongolia. Results indicate that most anomalous zones are sub-economic, commonly associated with organic-rich facies such as coal seams, while the continuity of mineralized bodies remains uncertain. Importantly, the study highlights granitic intrusions and volcanic complexes as the primary uranium sources, with coal-bearing and sedimentary basins acting as secondary depositional environments. The dual consideration of source terrains and depositional traps provides new insights into uranium mobility and deposition. Full article

The hydrogeochemical characterization of shallow volcanic lakes at the Sete Cidades Volcano (São Miguel, Azores) provides new insights into the processes controlling water chemistry in low-depth lacustrine systems within active volcanic environments. Fourteen lakes (0.6–4 m deep) were sampled during two campaigns (winter 2024 and spring/summer 2025), combining in situ physicochemical measurements and major ion analyses along vertical profiles. The lakes are holomictic, cold (11.3–17.6 °C), slightly acidic (pH 5.66–5.95), and weakly mineralized (EC ~65–69 µS/cm), indicating dilute waters of predominantly meteoric origin. Hydrochemical facies are dominated by Na–Cl type, with strong correlations between chloride and conductivity (r = 0.857), supporting a major contribution from marine atmospheric deposition. To move beyond correlation-based interpretation, Gibbs diagrams and saturation indices (PHREEQC) were applied to constrain the dominant geochemical processes. Most samples plot within the precipitation dominance field, while all calculated saturation indices are negative (SI < 0), indicating undersaturation with respect to carbonate, evaporite, and silicate minerals. These results demonstrate that water chemistry is primarily controlled by atmospheric inputs, with only minor contributions from water–rock interaction and negligible influence of evaporation or mineral equilibrium processes. Seasonal increases in HCO₃⁻ and dissolved CO₂ at depth suggest enhanced organic matter decomposition during warmer periods, highlighting the role of biogeochemical processes in modulating carbon dynamics in shallow systems. The absence of a clear hydrothermal signature further distinguishes these lakes from deeper volcanic systems in the Azores. This study provides the first integrated hydrogeochemical framework for shallow volcanic lakes in the region, combining classical hydrochemistry with process-based tools. The results establish a quantitative baseline for assessing environmental change and improve the interpretation of external (atmospheric) versus internal (geochemical and biological) controls in volcanic lake systems. Full article

Thermal groundwater resources constitute valuable health-oriented georesources, particularly when integrated into regional strategies for wellness, balneotherapy, and therapeutic tourism. This study presents the first comprehensive and integrated hydrochemical, geospatial, and balneological characterization of thermal groundwater systems in Uruguay, enabling their classification from a medical hydrology perspective and supporting the assessment of their potential use in balneotherapy. Seven thermal groundwater sources located in northwestern Uruguay were investigated, mainly associated with the Guaraní Aquifer System (GAS), together with the singular Almirón spring, which represents a distinct hydrogeological setting. Field measurements and laboratory analyses were conducted to determine physicochemical parameters, major ions, and gases. Hydrogeochemical facies were identified using Piper and Gibbs diagrams, while multivariate statistical techniques, including Principal Component Analysis (PCA) and hierarchical clustering, were applied to discriminate water types and support their balneological classification. The results indicate that most thermal waters associated with the GAS are characterized by sodium–bicarbonate facies, weak to medium mineralization. Dry residue to 180 °C, (311–734 mg/L), and mesothermal to hyperthermal temperatures (36.3–44.5 °C), reflecting deep confined circulation and prolonged water–rock interaction. By comparison, the Almirón spring exhibits a chloride–sodium facies with strong mineralization. Dry residue to 180 °C, (6590 mg/L) and hypothermal (32 °C), consistent with a distinct hydrogeological origin involving crystalline basement and Devonian sedimentary units and reflecting more evolved geochemical conditions. Based on the obtained results, and by analogy with comparable international hydrothermal profiles, the main balneological indications of these waters include musculoskeletal and rheumatic disorders, dermatological disorders, and other emerging indications such as stress, sleep disorders, obesity, and Long COVID. In conclusion, this study reveals the hydrochemical diversity of Uruguay’s thermal groundwater and its possible use in balneology. Future research should focus on controlled clinical and balneological studies to validate specific therapeutic effects. Full article

Integrating an end member catchment offers a mechanistic foundation for interpreting large basin hydrology. This critical aspect is rarely evident in Malawi’s river basin studies. This study characterizes the hydrochemistry of surface and groundwater and stable isotopes of water to gain a regional picture of how the Ruo River Transboundary Catchment (RRC) influences the Shire–Zambezi River Basin. Hydrochemistry (2013 to 2024) and stable isotope (2020 to 2022) data are used. Both Gibbs and Piper diagrams were used to interpret surface and groundwater facies and hydrogeochemical processes controlling mineralization of water. SI biplots were used to trace water sources, mixing signals, and evaporation trends. Low to moderate mineralization is noted in surface and groundwater sources, and electrical conductivity varied between 19 and 622 µS/cm and 31 and 1930 µS/cm for surface (12 sites) and groundwater (151 boreholes), respectively. Piper diagram analysis reveals a Ca-Mg-HCO₃ water type dominance. Gibbs plots suggested dissolution of silicate minerals and interaction of surface and groundwater. Stable oxygen (δ¹⁸O) and hydrogen (δ²H) isotope ratios in precipitation, surface, and groundwater exhibit a similar pattern, indicating a common meteoric input, variability in moisture source, and significant interaction of surface water and groundwater. SI plots indicate mixing of precipitation, surface, and groundwater of RRC. Finally, the Ruo River at flood stage reverses the flow of the Shire River sub catchments, impacting the water quality and quantity of the Zambezi, and, therefore, should be considered an important mixing end member in the Lower Shire Basin. Full article

Groundwater contamination in chemical industrial parks (CIPs) is a significant threat to global water security due to spills, leaks, and discharges, as well as the complexity of concealing a diverse range of industrial pollutants. In this article, we collected 30 groundwater samples from zones of presumed influence across a CIP, including upstream background, within-park, periphery, and downstream, located in Luxian County, Sichuan, China. We employed excitation–emission matrix (EEM) fluorescence spectroscopy with parallel factor analysis (PARAFAC) coupled with comprehensive hydrochemical analysis to deconvolve the dissolved organic matter (DOM) signature and statistically link its fluorescent components to specific hydrogeochemical processes and anthropogenic sources. Results revealed that industrial activities have transformed the groundwater to Ca-HCO₃·Cl and Ca·Na-HCO₃·Cl types from the hydrochemical facies comprising Ca-HCO₃ and Ca·Mg-HCO₃ types. Hydrogeology and groundwater chemistry depend primarily on weathering and atmospheric precipitation, but industrial effluents and evaporation concentration also significantly affect them. EEM-PARAFAC identified three dominant fluorescent components: fulvic-like (C1), humic-like (C2), and tryptophan-like (C3), with the latter serving as a sensitive indicator of recent anthropogenic inputs. The spatial distribution of these components, particularly the enrichment of C3, is primarily governed by anthropogenic inputs (e.g., sewage leakage), modulated by local hydrological conditions. This work demonstrates the integration of optical spectroscopy with conventional hydrochemistry for source apportionment in complex industrial settings. It provides a mechanistic understanding of pollution propagation and a practical, rapid diagnostic tool for targeted groundwater protection in CIPs. Full article

Population growth and agricultural expansion are threatening groundwater resources in the Maze Zenti catchment, Southern Ethiopia. This study evaluated groundwater suitability for drinking and irrigation by analyzing 30 samples using an integrated approach. This approach included GIS-based IDW interpolation, hydrochemical characterization, drinking water quality index, entropy weight, pollution index of groundwater, multivariate statistics, Piper, Gibbs, and Wilcox diagrams, ANOVA, and irrigation indices based on WHO standards. The correlation matrix revealed strong associations between Na⁺-TDS (r = 0.77) and Na⁺-Ca²⁺ (r = 0.68), indicating mineral dissolution, ion exchange, and agricultural inputs as key factors. Weak correlations were found for NO₃⁻ and F⁻, reflecting localized anthropogenic and geogenic influences. Component analysis identified four components explaining 78.2% (wet season) and 81.2% (dry season) of the variance, highlighting mineralization and anthropogenic inputs. Hydrochemical facies were mainly Ca-Mg-HCO₃ with some localized Na-HCO₃, suggesting that rock–water interactions are the primary source of geochemical control. Drinking water quality assessment showed that, during the wet season, 52.8% of the catchment had excellent water quality, 45.8% was good, and 1.4% was poor–very poor. In the dry season, 51.6% was excellent, 47.4% was good, 0.8% was poor, and 0.2% was very poor. The results of the entropy-weighted analysis indicated seasonal improvement, with excellent areas increasing from 13.1% to 31.4% and poor zones decreasing from 7.5% to 3.4%. Irrigation indices (Na%, PI, MAR, SAR) and Wilcox analysis (86.4% C2S1) suggested low sodicity and salinity hazards. This study provides the first integrated seasonal mapping of drinking and irrigation water quality, entropy-weighted water quality, and pollution index for the Maze Zenti catchment, establishing a hydrogeochemical baseline. Overall, groundwater in the area is generally suitable for drinking and irrigation. However, localized monitoring and sustainable land-use practices are recommended to mitigate contamination risks. Full article

Salinization represents a significant threat to freshwater resources worldwide, compromising water quality and security. In the Vieira de Leiria–Marinha Grande aquifer, salinization mechanisms are a complex interaction between seawater intrusion and evaporite dissolution. Near the coast, groundwater is mainly influenced by seawater, evidenced by Na-Cl hydrochemical facies, high electrical conductivity, and Na⁺/Cl⁻, Cl⁻/Br⁻ and SO₄^2−/Cl⁻ molar ratios consistent with marine signatures. In areas affected by diapiric dissolution, besides elevated electrical conductivity, groundwater is enriched in SO₄²⁻ and Ca²⁺ and in minor elements like K⁺, Li⁺, B³⁺, Ba²⁺ and Sr²⁺, and high SO₄²⁻/Cl⁻ and Ca²⁺/HCO₃⁻ molar ratios, indicative of gypsum/anhydrite dissolution. The relationship between δ¹⁸O and electrical conductivity further supports the identification of distinct salinity sources. This study integrates hydrogeochemical tracers to investigate hydrochemical evolution in the aquifer with increasing residence time and influence of water–rock interaction, as well as the accurate characterization of salinization mechanisms in multilayer aquifers. A comprehensive understanding of these processes is essential for identifying vulnerable zones and developing effective management strategies to ensure the protection and sustainable use of groundwater resources. Full article

Sustainable groundwater management is critical in semi-arid coastal regions, where municipal landfills pose a severe threat to aquifer integrity and long-term water security. However, there is still a lack of seasonally resolved hydrogeochemical monitoring around newly established landfills, particularly in rapidly urbanizing Mediterranean settings. This study assesses the hydrogeochemical impact of the newly operational Tangier Landfill and Recovery Center on local groundwater resources to inform sustainable remediation strategies. A combined approach was applied to samples collected in dry and wet seasons, using Piper and Stiff diagrams to trace facies evolution together with a dual-index assessment based on the Canadian (CCME-WQI) and Weighted Arithmetic (WAWQI) Water Quality Indices. Results show that upgradient waters remain of Good–Excellent quality and are dominated by Ca–HCO₃ facies, whereas downgradient wells display extreme mineralization, with EC up to 15,480 µS/cm and Cl⁻ and SO₄²⁻ exceeding 1834 and 2114 mg/L, respectively. At hotspot sites P4 and P8, As reaches 0.065 mg/L and Cd 0.006 mg/L, far above the WHO drinking-water guidelines. While the CCME-WQI captures the general salinity-driven degradation pattern, the WAWQI pinpoints these acute toxicity zones as Very poor–Unsuitable. The study demonstrates that rainfall intensifies toxicity through a seasonal “Piston Effect” that mobilizes stored contaminants rather than diluting them, underscoring the need for seasonally adaptive monitoring to ensure the environmental sustainability of landfill-adjacent aquifers. Full article

To explore the hydrogeochemical characteristics and dominant water–rock interaction processes of thermal water in Lindian geothermal field (northern Songliao Basin, NE China), this study analyzed 16 thermal water samples (1900–3000 m depth) and 3 shallow groundwater samples using hydrochemical indices, water isotopes, and statistical methods (Pearson Correlation and Principle Component Analysis). Results show that the thermal water originates from precipitation and exhibits an “oxygen shift” indicating a long-time water–rock interaction under low to medium reservoir temperature. The thermal water is alkaline with a high TDS and dominated by Na⁺, Cl⁻, and HCO₃⁻, and its hydrochemical facies changes from HCO₃·Cl–Na to Cl·HCO₃–Na and Cl–Na along the groundwater flow path. Leaching of halite, silicates, and carbonates is the primary process controlling solute accumulation. The geothermal reservoir is in a relatively closed, strong reducing environment, and thermal water reached water–rock equilibrium with respect to Na-, K-, Ca-, and Mg-alumino silicates. Principle Component Analysis identifies three key controlling factors, including mineral leaching, organic matter degradation, and sulfate reduction/mineral precipitation. This study establishes a hydrogeochemical baseline for the initial exploitation stage, providing a scientific basis for predicting long-term water quality changes and formulating differentiated sustainable development strategies for the Lindian geothermal field. Full article

This study investigates the coupled relationship between groundwater chemistry, lithology, and structural features in the dry zone of Netiyagama, Sri Lanka, within a fractured crystalline basement. Groundwater chemistry fundamentally reflects geological conditions determined by rock-water interactions, we hypothesized that the specific spatial patterns of groundwater chemistry in heterogeneous fractured systems are distinctly controlled by integrated effects of lithological variations, structurally driven flow pathways, aquifer stratification, and geochemical processes, including cation exchange and mineral-specific weathering. To test this, we integrated hydrogeochemical signatures with mapped hydrogeological data and applied multi-stage multivariate analyses, including Piper diagrams, Hierarchical Cluster Analysis (HCA), and Principal Component Analysis (PCA), and various bivariate plots. Piper diagrams identified five distinct hydrochemical facies, but these did not correlate directly with specific rock types, highlighting the limitations of traditional methods in heterogeneous settings. Employing a multi-stage multivariate analysis, we identified seven clusters (C1–C7) that exhibited unique spatial distributions across different rock types and provided a more refined classification of groundwater chemistries. These clusters align with a three-unit aquifer framework (shallow weathered zone, intermittent fracture zone at ~80–100 m MSL, and deeper persistent fractures) controlled by a regional syncline and lineaments. Further analysis through bivariate diagrams revealed insights into dominant weathering processes, cation-exchange mechanisms, and groundwater residence times across the identified clusters. Recharge-type clusters (C1, C2, C5) reflect plagioclase-dominated weathering and short flow paths; transitional clusters (C3, C7) show mixed sources and increasing exchange; evolved clusters (C4, C6) exhibit higher mineralization and longer residence. Overall, the integrated workflow (facies plots + PCA/HCA + bivariate/process diagrams) constrains aquifer dynamics, recharge pathways, and flow-path evolution without additional drilling, and provides practical guidance for well siting and treatment. Full article

Groundwater quality in the semi-arid region of Oum El Bouaghi, Northeastern Algeria, was assessed for irrigation suitability using hydrogeochemical analyses, water quality indices, and GIS techniques. The study analyzed 23 groundwater samples during dry and wet seasons in 2022–2023, several physicochemical parameters were measured. Results revealed neutral to slightly alkaline pH levels, except for one acidic sample, with salinity (EC: 527–5001 µS·cm⁻¹) exceeding WHO guidelines, particularly during the dry season due to evaporation and anthropogenic activities. Hydrogeochemical facies showed dominance of Na⁺-HCO₃⁻ and Ca²⁺-Cl⁻/SO₄²⁻ water types, indicating rock–water interactions and evaporation control, as confirmed by Gibbs plots. The IWQI classified water into five categories, with severe restrictions (IWQI < 40) in 13% of samples during the dry season, improving slightly in the wet season. Indices such as SAR, Na%, and RSC indicated low to moderate sodium hazard, while KR and PS highlighted salinity risks in specific areas. Spatial analysis revealed localized pollution hotspots, with the (GPI) identifying minimal to high contamination levels, linked to agricultural and geogenic sources. These findings underscore needs for sustainable groundwater management, including monitoring, optimized irrigation practices, and mitigation of anthropogenic impacts, to ensure long-term agricultural viability in this water-scarce region. Full article

This study investigates geothermal waters in the Xinjiang region through hydrogeochemical methods, including cluster analysis, ionic ratios, and isotopic analysis. Cluster analysis categorized the geothermal water samples into three distinct groups (G1, G2, and G3). The predominant hydrochemical facies are SO₄-HCO₃-Na, SO₄-Cl-Na, and Cl-Na types, whose formation is controlled by multiple factors. Evidence from molar ratios of major ions suggests that geothermal waters in Group G1 are predominantly governed by water–rock interactions, whereas Groups G2 and G3 are mainly influenced by evaporative concentration. Hydrogen and oxygen isotopic signatures confirm that meteoric water serves as the primary recharge source for these geothermal waters. The spatial correlation between regional tectonic features and most geothermal discharge points demonstrates a consistent relationship between geothermal water occurrence and structural distribution in Xinjiang. Additionally, a conceptual circulation model is proposed wherein meteoric water undergoes deep circulation following local recharge, ascends along fault zones under tectonic pressure, and mixes with shallow groundwater. This research primarily elucidates the hydrogeochemical characteristics and recharge mechanisms of geothermal resources in Xinjiang, thereby providing a scientific basis for their future development and utilization. Full article

Compression of clayey sediments not only causes land subsidence but also results in geogenic high fluoride groundwater. The distribution characteristics and enrichment mechanisms of fluoride in alluvial−lacustrine facies clayey sediments in the land subsidence area of Cangzhou Plain, China, were investigated using sample collection, mineralogical research, and hydrogeochemical and isotopic analysis. The results show that F⁻ concentration of groundwater samples ranged from 0.31 to 5.54 mg/L in aquifers. The total fluoride content of clayey sediments ranged from 440 to 792 mg/kg and porewater F⁻ concentration ranged from 0.77 to 4.18 mg/L. Clay minerals containing fine particles, such as muscovite, facilitate the enrichment of fluoride in clayey sediments, resulting in higher total fluoride levels than those in sandy sediments. The clay porewater F⁻ predominantly originated from the dissolution of water-soluble F and the desorption of exchangeable F from sediments. The F⁻ concentration in porewater was further influenced by ionic interactions such as cation exchange. The stable sedimentary environment and intense compression promoted the dissolution of F–bearing minerals and the desorption of adsorbed F in deep clayey sediments. The similar composition feature of δ²H−δ¹⁸O in deep groundwater and clay porewater samples suggests a significant mixing effect. These findings highlight the joint effects of hydrogeochemical and mineralogical processes on F behavior in clayey sediments. Full article