Search Results (313)

Currently, the Longmaxi shale in the Sichuan Basin is the most successful stratum of shale gas production in China. However, because Longmaxi shale mostly has high over-maturity, a low-maturity sample cannot be obtained for gas generation thermal simulations, and as a result, a gas generation model has not yet been established for it. Therefore, models of other shales are usually used to calculate the amount of gas generated from Longmaxi shale, but they may produce inaccurate results. In this study, a Longmaxi shale sample with an equivalent vitrinite reflectance calculated from Raman spectroscopy (EqVR_o) of 1.26% was obtained from Well Yucan 1 in the Chengkou area, northeast Sichuan Province. This Longmaxi shale may have the lowest maturity in nature. Pyrolysis simulations based on gold tubes were performed on this sample, and the gas generation line was obtained. The amount of gas generated during the low-maturity stage was compensated by referring to gas generation data obtained from Lower Silurian black shale in western Lithuania. Thus, a gas generation model of the Longmaxi shale was built. The model showed that the gas generation process of Longmaxi shale could be divided into three stages: (1) First, there is the quick generation stage (EqVR_o 0.5–3.0%), where hydrocarbon gases were generated quickly and constantly, and the generation rate was steady. A maximum of 458 mL/g TOC was reached at a maturity of 3.0% EqVR_o. (2) Second, there is the stable stage (EqVR_o 3.0–3.25%), where the amount of generated gas reached a plateau of 453–458 mL/g TOC. (3) Third, there is the rapid descent stage (EqVR_o > 3.25%), where the amount of generated gas started to decrease, and it was 393 mL/g TOC at an EqVR_o of 3.34%. This model allows us to more accurately calculate the amount of gas generated from the Longmaxi shale in the Sichuan Basin. Full article

This paper reports on the failure of cells with lithium iron phosphate (LFP) chemistry tested under a range of conditions to understand their effect on the volume and composition of gas generated. Cells of the following formats, 26,650, pouch, and prismatic, and capacities ranging from 3 to 230 Ah, were subjected to external heat, overcharge, and nail penetration tests. Gas volume was calculated, and the following gases analysed: H₂, CO₂, CO, CH₄, C₂H₄, C₂H₆, C₃H₆, and C₃H₈. Cells that failed via external heating under inert conditions (N₂ or Ar atmosphere) at 100% state of charge (SoC) typically generated 0.7 L/Ah of gas; overcharged cells, 0.11–0.68 L/Ah; and nail penetration between 0.3 and 0.5 L/Ah. In general, for all test configurations, regardless of atmosphere, the total gas volume contained a 40% concentration of H₂, 15% of CO₂, and the remaining gas consisted of varying concentrations of CO and flammable hydrocarbons. This demonstrates that despite differences in gas volume, the failure gas composition of LFP cells remains similar. Full article

Significant uranium exploration breakthroughs have been achieved in the eolian deposits of the uranium reservoirs in the southwestern part of the Ordos Basin. The redox environment remains a crucial factor in controlling the migration and precipitation of uranium. This study, through rock mineralogical observations and hydrocarbon gas composition analysis, combined with the regional source rock and basin tectonic evolution history, reveals the characteristics of the reducing medium and the mineralization mechanisms involved in uranium ore formation. The Lower Cretaceous Luohe Formation uranium reservoirs in the study area exhibit a notable lack of common reducing media, such as carbonaceous debris and pyrite. However, the total hydrocarbon gases in the Luohe Formation range from 2967 to 20,602 μmol/kg, with an average of 8411 μmol/kg—significantly higher than those found in uranium reservoirs elsewhere in China, exceeding them by 10 to 100 times. Due to the absence of other macroscopically visible organic matter, hydrocarbon gases are identified as the most crucial reducing agent for uranium mineralization. These gases consist predominantly of methane and originate from the Triassic Yanchang Formation source rock. Faults formed during the Indosinian, Yanshanian, and Himalayan tectonic periods effectively connect the Cretaceous uranium reservoirs with the oil and gas reservoirs of the Triassic and Jurassic, providing pathways for the migration of deep hydrocarbon fluids into the Cretaceous uranium reservoirs. The multiphase tectonic evolution of the Ordos Basin since the Cenozoic has facilitated the development of faults, ensuring a sufficient supply of reducing media for uranium reservoirs in an arid sedimentary context. Additionally, the “Replenishment-Runoff-Drainage System” created by tectonic activity promotes a continuous supply of uranium- and oxygen-bearing fluids to the uranium reservoirs, resulting in a multi-energy coupling mineralization effect. Full article

This study investigates hazardous emissions from foundry binder systems, comparing organic resins (phenolic urethane, furan, and alkaline-phenolic) and clay-bonded green sand with inorganic alternatives (sodium silicate and geopolymer). The research was conducted at the Fundaciόn Azterlan pilot plant (Spain), involving controlled chamber tests for the production of 60 kg iron alloy castings in 110 kg sand molds. The molds were evaluated under two configurations: homogeneous systems, where both mold and cores were manufactured using the same binder (five trials), and heterogeneous systems, where different binders were used for mold and cores (four trials). Each mold was placed in a metallic box fitted with a lid and an integrated gas extraction duct. The lid remained open during pouring and was closed immediately afterward to enable efficient evacuation of casting gases through the extraction system. Although the box was not completely airtight, it was designed to direct most exhaust gases through the duct. Along the extraction system line, different sampling instruments were strategically located for the precise measurement of contaminants: volatile organic compounds (VOCs), polycyclic aromatic hydrocarbons (PAHs), phenol, multiple forms of particulate matter (including crystalline silica content), and gases produced during pyrolysis. Across the nine trials, inorganic binders demonstrated significant reductions in gas emissions and priority pollutants, achieving decreases of over 90% in BTEX compounds (benzene, toluene, ethylbenzene, and xylene) and over 94% in PAHs compared to organic systems. Gas emissions were also substantially reduced, with CO emissions lowered by over 30%, NO_x by more than 98%, and SO₂ by over 75%. Conducted under the Greencasting LIFE project (LIFE 21 ENV/FI/101074439), this work provides empirical evidence supporting sodium silicate and geopolymer binders as viable, sustainable solutions for minimizing occupational and ecological risks in metal casting processes. Full article

Solid oxide fuel cells (SOFCs) represent a pivotal technology in renewable energy due to their clean and efficient power generation capabilities. Their role in potential carbon mitigation enhances their viability. SOFCs can operate via a variety of alternative fuels, including hydrocarbons, alcohols, solid carbon, and ammonia. However, several solutions have been proposed to overcome various technical issues and to allow for stable operation in dry methane, without coking in the anode layer. To avoid coke formation thermodynamically, methane is typically reformed, contributing to an increased degradation rate through the addition of oxygen-containing gases into the fuel gas to increase the O/C ratio. The performance achieved by reforming catalytic materials, comprising active sites, supports, and electrochemical testing, significantly influences catalyst performance, showing relatively high open-circuit voltages and coking-resistance of the CH₄ reforming catalysts. In the next step, the operating principles and thermodynamics of methane reforming are explored, including their traditional catalyst materials and their accompanying challenges. This work explores the components and functions of SOFCs, particularly focusing on anode materials such as perovskites, Ruddlesden–Popper oxides, and spinels, along with their structure–property relationships, including their ionic and electronic conductivity, thermal expansion coefficients, and acidity/basicity. Mechanistic and kinetic studies of common reforming processes, including steam reforming, partial oxidation, CO₂ reforming, and the mixed steam and dry reforming of methane, are analyzed. Furthermore, this review examines catalyst deactivation mechanisms, specifically carbon and metal sulfide formation, and the performance of methane reforming and partial oxidation catalysts in SOFCs. Single-cell performance, including that of various perovskite and related oxides, activity/stability enhancement by infiltration, and the simulation and modeling of electrochemical performance, is discussed. This review also addresses research challenges in regards to methane reforming and partial oxidation within SOFCs, such as gas composition changes and large thermal gradients in stack systems. Finally, this review investigates the modeling of catalytic and non-catalytic processes using different dimension and segment simulations of steam methane reforming, presenting new engineering designs, material developments, and the latest knowledge to guide the development of and the driving force behind an oxygen concentration gradient through the external circuit to the cathode. Full article

The combustion of gaseous fuels in condensing boilers contributes to the greenhouse gas and toxic compound emissions in exhaust gases. Hydrogen, as a clean energy carrier, could play a key role in decarbonizing the residential heating sector. However, its significantly different combustion behavior compared to hydrocarbon fuels requires thorough investigation prior to implementation in heating systems. This study presents experimental and theoretical analyses of the co-combustion of natural gas with hydrogen in low-power-output condensing boilers (second and third generation), with hydrogen content of up to 50% by volume. The results show that mixtures of hydrogen and natural gas contribute to increasing heat transfer in boilers through convection and flue gas radiation. They also highlight the benefits of using the heat from the condensation of vapors in the flue gases. Other studies have observed an increase in efficiency of up to 1.6 percentage points compared to natural gas at 50% hydrogen content. Up to a 6% increase in the amount of energy recovered by water vapor condensation was also recorded, while exhaust gas losses did not change significantly. Notably, the addition of hydrogen resulted in a substantial decrease in the emission of nitrogen oxides (NOx) and carbon monoxide (CO). At 50% hydrogen content, NO_x emissions decreased several-fold to 2.7 mg/m³, while CO emissions were reduced by a factor of six, reaching 9.9 mg/m³. All measured NO_x values remained well below the current regulatory limit for condensing gas boilers, which is 33.5 mg/m³. These results highlight the potential of hydrogen blending as a transitional solution on the path toward cleaner residential heating systems. Full article

The production of gas and condensate from liquid-rich shale reservoirs, particularly within heterogeneous lacustrine systems, remains a critical challenge in unconventional hydrocarbon exploration due to intricate multiphase hydrocarbon partitioning, including gases (C₁–C₂), volatile liquids (C₃–C₇), and heavier liquids (C₇₊). This study investigates a 120-meter-thick interval dominated by lacustrine deposits from the Lower Cretaceous Shahezi Formation (K₁sh) in the Songliao Basin. This interval, characterized by high clay mineral content and silicate–pyrite laminations, was examined to identify the factors controlling hybrid shale gas condensate systems. We proposed the Hybrid Shale Condensate Index (HSCI), defined as the molar ratios of (C₁–C₇)/C₇₊, to categorize fluid phases and address shortcomings in traditional GOR/API ratios. Over 1000 samples were treated by geochemical pyrolysis logging, X-ray fluorescence (XRF) spectrum element logging, SEM-based automated mineralogy, and in situ gas desorption, revealing four primary controls: (1) Thermal maturity thresholds. Mature to highly mature shales exhibit peak condensate production and the highest total gas content (TGC), with maximum gaseous and liquid hydrocarbons at T_max = 490 °C. (2) Lithofacies assemblage. Argillaceous shales rich in mixed carbonate and clay minerals exhibit an intergranular porosity of 4.8 ± 1.2% and store 83 ± 7% of gas in intercrystalline pore spaces. (3) Paleoenvironmental settings. Conditions such as humid climate, saline water geochemistry, anoxic bottom waters, and significant input of volcanic materials promoted organic carbon accumulation (TOC reaching up to 5.2 wt%) and the preservation of organic-rich lamination. (4) Laminae and fracture systems. Silicate laminae account for 78% of total pore space, and pyrite laminations form interconnected pore networks conducive to gas storage. These findings delineate the “sweet spots” for unconventional hydrocarbon reservoirs, thereby enhancing exploration for gas condensate in lacustrine shale systems. Full article

Dissolved gas analysis (DGA) is one of the transformer testing methods that has been widely used for a long time because it does not require the transformer to be offline for testing. The inspection can be conducted while the transformer is operating normally, and it is cost-effective. In research on fault severity, thermodynamic theory has been applied to find the energy index of the hydrocarbon gases generated by faults, ${\mathrm{CH}}_4$, ${\mathrm{C}}_2{\mathrm{H}}_6$, ${\mathrm{C}}_2{\mathrm{H}}_4$ and ${\mathrm{C}}_2{\mathrm{H}}_2$, referred to as the Normalised Energy Intensity (NEI). This study examines the application of the Positive Cumulative Sum of Difference (CUSUM) method to hydrocarbon NEI and carbon dioxide NEI for fault severity assessment. The study demonstrates the effectiveness of this approach by means of case studies on the basis of DGA results from two steel plants. In the case of NEI from hydrocarbon gases (${\mathrm{NEI}}_{\mathrm{HC}}$), the positive CUSUM is compared with the NEI, the NEI score, and the cumulative NEI. In the case of NEI from carbon oxide gases (${\mathrm{NEI}}_{\mathrm{CO}}$), Positive CUSUM is compared with NEI and the ratio of ${\mathrm{CO}}_2$ to $\mathrm{CO}$. It was found that Positive CUSUM for ${\mathrm{NEI}}_{\mathrm{HC}}$ is a much better indicator of the severity of defects than the NEI, the NEI score, and the cumulative NEI. In contrast, Positive CUSUM for ${\mathrm{NEI}}_{\mathrm{CO}}$ gave excessively high values. However, combining NEI with the ${\mathrm{CO}}_2$/$\mathrm{CO}$ ratio gave better monitoring results. Therefore, from an online DGA perspective, Positive CUSUM can be used to effectively monitor fault severity. Full article

Owing to global energy demands and climate change resulting from fossil fuel use, technologies capable of converting greenhouse gases into renewable energy resources are needed. One such technology is photocatalytic CO₂ reduction, which utilises solar energy to transform CO₂ into value-added hydrocarbons. However, the application of photocatalytic CO₂ reduction is limited by the inefficiency of existing photocatalysts. In this study, we developed a nitrogen-deficient g-C₃N₄-confined PtCu dual-atom catalyst (PtCu/V_N-C₃N₄) for photocatalytic CO₂ reduction. Aberration-corrected high-angle annular dark-field scanning transmission electron microscopy and X-ray absorption fine structure spectroscopy confirmed the atomic-level anchoring of PtCu pairs onto the nitrogen-vacancy-rich g-C₃N₄ nanosheets. The optimised PtCu/V_N-C₃N₄ exhibited superior photocatalytic performance, with CO and CH₄ evolution rates of 13.3 µmol/g/h and 2.5 µmol/g/h, respectively, under visible-light irradiation. Mechanistic investigations revealed that CO₂ molecules were preferentially adsorbed onto the PtCu dual sites, initiating a stepwise reduction pathway. In situ diffuse reflectance infrared Fourier-transform spectroscopy identified the formation of a key intermediate (HCOO*), whereas interfacial wettability studies demonstrated efficient H₂O adsorption on PtCu sites, providing essential proton sources for CO₂ protonation. Photoelectrochemical characterisation further confirmed the enhanced charge-transfer kinetics in PtCu/V_N-C₃N₄, which were attributed to the synergistic interplay between the nitrogen vacancies and dual-atom sites. Notably, the dual-active-site architecture minimised the competitive adsorption between CO₂ and H₂O molecules, thereby optimising the surface reaction pathways. This study establishes a rational strategy for designing atomically precise dual-atom catalysts through defect engineering, achieving concurrent improvements in activity, selectivity, and charge carrier utilisation for solar-driven CO₂ conversion. Full article

Polycyclic aromatic hydrocarbons (PAHs), prevalent aquatic contaminants, arise from burning fossil fuels, a major source of greenhouse gases driving global warming. PAHs and warmer temperatures individually exert diverse negative effects on aquatic organisms. However, the effects of PAH exposure and/or rising temperature remain largely unknown. Liver in vitro models, like the rainbow trout (Oncorhynchus mykiss) RTL-W1 liver cell line, have been employed to unravel PAH-exposure effects, primarily on cell viability and enzymatic activity. Here, monolayer-cultured (2D) RTL-W1 cells were used to assess the co-exposure effects of temperature (18 and 21 °C) and two PAHs, benzo[a]pyrene (B[a]P) and benzo[k]fluoranthene (B[k]F), at 10 and 100 nM. After a 72 h exposure, the cell density and viability were evaluated using the trypan blue and LDH assays. The mRNA levels of the detoxification-associated genes aryl hydrocarbon receptor (AhR), cytochrome P450 (CYP)1A, CYP3A27, glutathione S-transferase omega 1 (GSTO1), uridine diphosphate–glucuronosyltransferase (UGT), catalase (CAT), and multidrug resistance-associated protein 2 (MRP2) were measured by RT-qPCR. Temperature influenced cell viability and LDH leakage. Both PAHs reduced the cell density and upregulated the mRNA levels of AhR, CYP1A, CYP3A27, and UGT, while GSTO1 and MRP2 were only augmented after the higher B[k]F concentration. Temperature influenced CAT and UGT expression. There was no interaction between temperature and the PAHs. Overall, the results show that B[k]F has more effects on detoxification targets than B[a]P, whereas a temperature increase mildly affects gene expression. The RTL-W1 in 2D seems useful for unravelling not only the liver effects of PAH but also the impact of temperature stress. Full article

Exploration practice has proved that preservation conditions are one of the critical factors contributing to shale gas enrichment in the Middle Yangtze area. Well Yidi2 is the discovery well of Cambrian shale gas in this area. The paleo-fluid evolution and its implication for preservation conditions of shale gas remains unclear, posing challenges for shale gas exploration and development. In this study, through systematic analysis of fluid inclusions in fractrue-filling vein of the entire core section of this well, combined with carbon and oxygen isotope tests of veins and host rocks, a paleo-fluid profile was established to explore the formation environment of Cambrian paleo-fluids and their implications for the preservation conditions of the Shuijingtuo Formation (SJT Fm.) shale gas. The results suggest that fractures in the SJT Fm. shale at the base of Cambrian Series 2 mainly formed during the deep burial hydrocarbon generation stage, trapping a large number of liquid hydrocarbon inclusions. Subsequently, numerous high-density methane inclusions and a few of gas-liquid two-phase inclusions were trapped. The SO₄²⁻, Ca²⁺ and Mg²⁺ content of fluid inclusion groups in the veins decreased from the Qinjiamiao Formation (QJM Fm.) at the bottom of Cambrian Series 3 upward and downward respectively, and the rNa⁺/rCl⁻ ratio was the lowest in the SJT Fm. and increased overall upward. The δ¹³C values of calcite veins in Tianheban Formation (THB Fm.)-Shipai Formation (SP Fm.) of the middle Cambrian Series 2 and the Loushanguan Formation (LSG Fm.) of the Cambrian Series 3 were lighter compared to the host rocks. Results indicate the later tectonic activities in this area were relatively weak, and the shale interval remained in a state of high gas saturation for a long time. The QJM Fm. was the main source of high-salinity brine, and the SJT Fm. had strong self-sealing properties and was relatively less affected by external fluids. However, the pressure evolution of high-density methane inclusions in the SJT Fm. indicated that the pressure coefficient of the shale section significantly decreased during the Indosinian uplift and erosion stage. The veins in the THB-SP and LSG Fms. were closely related to the oxidation of hydrocarbon gases by TSR (thermochemical sulfate reduction) and the infiltration of atmospheric water, respectively. Therefore, the paleo-fluid in the fractures of Well Yidi2 have integrally recorded the whole geological process including the evolution from oil to gas, the backflow of high-salinity formation water, the upward escape of shale gas, and the process of shale gas reservoirs evolving from overpressure to normal pressure. Considering that Well Yidi2 area is located in a relatively stable tectonic setting, widely distributed fracture veins probably enhance the self-sealing ability, inhibiting the rapid escape of SJT Fm. shale gas. And the rapid deposition of Cretaceous also delayed the loss of shale gas to some extent. The combination of these two factors creates favorable preservation conditions of shale gas, establishing the SJT Fm. as the primary exploration target in this area. Full article

In this article, we consider the roles of transcrustal magma- and fluid-conducting faults (TCMFCFs) in the formation of mineral deposits, showing the importance of deep sources of heat and hydrothermal solutions in the genesis and history of deposit formation. As a result of the impact on the lithosphere of mantle plumes rising along TCMFCFs, intense block deformations and tectonic movements are generated; rift systems, and volcanic–plutonic belts spatially combined with them, are formed; and intrusive bodies are introduced. These processes cause epithermal ore formation as a consequence of the impact of mantle plumes rising along TCMFCF to the lithosphere. At hydrocarbon fields, they play extremely important roles in conductive and convective heat, as well as in mass transfer to the area of hydrocarbon generation, determining the relationship between the processes of lithogenesis and tectogenesis, and activating the generation of hydrocarbons from oil and gas source rock. Detection of TCMFCFs was carried out using MMSS (the method of microseismic sounding) and MTSM (the magnetotelluric sounding method), in combination with other geological and geophysical data. Practical examples are provided for mineral deposits where subvertical transcrustal columns of increased permeability, traced to considerable depths, have been found; the nature of these unique structures is related to faults of pre-Paleozoic emplacement, which determined the fragmentation of the sub-crystalline structure of the Earth and later, while developing, inherited the conditions of volumetric fluid dynamics, where the residual forms of functioning of fluid-conducting thermohydrocolumns are granitoid batholiths and other magmatic bodies. Experimental modeling of deep processes allowed us to identify the quantum character of crystal structure interactions of minerals with “inert” gases under elevated thermobaric conditions. The roles of helium, nitrogen, and hydrogen in changing the physical properties of rocks, in accordance with their intrastructural diffusion, has been clarified; as a result of low-energy impact, stress fields are formed in the solid rock skeleton, the structures and textures of rocks are rearranged, and general porosity develops. As the pressure increases, energetic interactions intensify, leading to deformations, phase transitions, and the formation of chemical bonds under the conditions of an unstable geological environment, instability which grows with increasing gas saturation, pressure, and temperature. The processes of heat and mass transfer through TCMFCFs to the Earth’s surface occur in stages, accompanied by a release of energy that can manifest as explosions on the surface, in coal and ore mines, and during earthquakes and volcanic eruptions. Full article

Water-capped tailings technology (WCTT) is a strategy where oil sand tailings are sequestered within a mined-out pit and overlayed with a layer of water in order to sequester tailings with the aim that the resulting pit lake will support aquatic plants and organisms over time. The Base Mine Lake Demonstration (BML) is the first full-scale demonstration of a pit lake in the Athabasca Oil Sands Region (AOSR). In the BML, the release of methane from the fluid tailings influences several key processes, including the flux of greenhouse gases, microbial oxygen consumption in the water column, and ebullition-facilitated transport of organics from the fluid tailings to the lake surface. It is hypothesized that the residual low molecular weight hydrocarbons (LMWHCs) derived from diluent naphtha used during bitumen extraction processes are the carbon sources fueling ongoing microbial methanogenesis within the BML. The aims of this study were to identify the LMWHCs in the BML fluid tailings, to elucidate their sources, and to assess the extent of biogeochemical cycling affecting them. A headspace GC/MS analysis identified 84, 44, and 56 LMWHCs (C4–C10) present in naphtha, unprocessed bitumen ore, and fluid tailings, respectively. Equilibrium mass balance assessment indicated that the vast majority (>95%) of LMWHCs were absorbed within residual bitumen rather than dissolving into tailings pore water. Such absorbed compounds would not be readily available to in situ microbial communities but would represent a long-term source for methanogenesis. Chromatographic analysis revealed that most biodegradable compounds (n-alkanes and BTEX) were present in the naphtha but not in fluid tailings or bitumen ore, implying they are sourced from the naphtha and have been preferentially biodegraded after being deposited. Among the LMWHCs observed in bitumen ore, naphtha, and fluid tailings, C2-cyclohexanes had the highest relative abundance in tailings samples, implying their relatively high recalcitrance to in situ biodegradation. Full article

In recent years, frequent open biomass burning (OBB) activities such as agricultural residue burning and forest fires have led to severe air pollution and carbon emissions across South and Southeast Asia (SSEA). We selected this area as our study area and divided it into two sub-regions based on climate characteristics and geographical location: the South Asian Subcontinent (SEAS), which includes India, Laos, Thailand, Cambodia, etc., and Equatorial Asia (EQAS), which includes Indonesia, Malaysia, etc. However, existing methods—primarily emission inventories relying on burned area, fuel load, and emission factors—often lack accuracy and temporal resolution for capturing fire dynamics. Therefore, in this study, we employed high-resolution fire point data from China’s Feng Yun-4A (FY-4A) geostationary satellite and the Fire Radiative Power (FRP) method to construct a daily OBB emission inventory at a 5 km resolution in this region for 2020–2022. The results show that the average annual emissions of carbon (C), carbon dioxide (CO₂), carbon monoxide (CO), methane (CH₄), non-methane organic gases (NMOGs), hydrogen (H₂), nitrogen oxide (NO_X), sulfur dioxide (SO₂), fine particulate matter (PM_2.5), total particulate matter (TPM), total particulate carbon (TPC), organic carbon (OC), black carbon (BC), ammonia (NH₃), nitric oxide (NO), nitrogen dioxide (NO₂), non-methane hydrocarbons (NMHCs), and particulate matter ≤ 10 μm (PM₁₀) are 178.39, 598.10, 33.11, 1.44, 4.77, 0.81, 1.02, 0.28, 3.47, 5.58, 2.29, 2.34, 0.24, 0.58, 0.43, 0.99, 1.87, and 3.84 Tg/a, respectively. Taking C emission as an example, 90% of SSEA’s emissions come from SEAS, especially concentrated in Laos and western Thailand. Due to the La Niña climate anomaly in 2021, emissions surged, while EQAS showed continuous annual growth at 16.7%. Forest and woodland fires were the dominant sources, accounting for over 85% of total emissions. Compared with datasets such as the Global Fire Emissions Database (GFED) and the Global Fire Assimilation System (GFAS), FY-4A showed stronger sensitivity and regional adaptability, especially in SEAS. This work provides a robust dataset for carbon source identification, air quality modeling, and regional pollution control strategies. Full article

This review paper presents an overview of fuel cell electrochemical systems that can be used for clean large-scale power generation and energy storage as global energy concerns regarding emissions and greenhouse gases escalate. The fundamental thermochemical and operational principles of fuel cell power generation and electrolyzer technologies are discussed with a focus on high-temperature solid oxide fuel cells (SOFCs) and solid oxide electrolysis cells (SOECs) that are best suited for grid scale energy generation. SOFCs and SOECs share similar promising characteristics and have the potential to revolutionize energy conversion and storage due to improved energy efficiency and reduced carbon emissions. Electrochemical and thermodynamic foundations are presented while exploring energy conversion mechanisms, electric parameters, and efficiency in comparison with conventional power generation systems. Methods of converting hydrocarbon fuels to chemicals that can serve as fuel cell fuels are also presented. Key fuel cell challenges are also discussed, including degradation, thermal cycling, and long-term stability. The latest advancements, including in materials selection research, design, and manufacturing methods, are also presented, as they are essential for unlocking the full potential of these technologies and achieving a sustainable, near zero-emission energy future. Full article