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Keywords = hot stage separation

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18 pages, 3793 KB  
Article
A New Time-Based Real Driving Emission (RDE) Evaluation Method for Heavy-Duty Vehicles Focused on NOx Emissions Using Remote Monitoring Data
by Shuojin Ren, Gang Li, Fengbin Wang, Xianglin Zhong, Jianfu Zhao, Hao Zhang, Dongzhi Gao and Quanshun Yu
Atmosphere 2026, 17(5), 487; https://doi.org/10.3390/atmos17050487 - 11 May 2026
Viewed by 230
Abstract
The real driving emission (RDE) test is going to be a necessary and effective evaluation method in the next-stage heavy-duty vehicle (HDV) emission standards, the rulemaking of which is under way worldwide (e.g., EPA 2027, Euro 7 and China 7). In this work, [...] Read more.
The real driving emission (RDE) test is going to be a necessary and effective evaluation method in the next-stage heavy-duty vehicle (HDV) emission standards, the rulemaking of which is under way worldwide (e.g., EPA 2027, Euro 7 and China 7). In this work, a time-based method (TBM) was proposed for future HDV RDE calculation. In TBM, cold-start and hot-run emissions are evaluated separately with moving average windows, yet no type-approval test results are needed so that it can also be used as a remote monitoring algorithm. This study analyzes the emissions of NOx. The value of 0.1 times maximum engine power is utilized to determine the cold-start window, while a 2-bin window structure is adopted for hot-run analysis. In order to further illustrate and validate this method, 16,629.4 h of remote monitoring data with a sampling rate of 1 Hz from 36 China 6 HDVs and 4 different months were analyzed for driving and NOx emission characteristics with TBM. The average duration of the 21,466 trips analyzed in this work was found to be 0.68 h, and the average ratio of trip work to WHTC (world harmonized transient driving cycle) work was around 1.38, indicating that lower duration and work requirements are needed in future RDE test. Moreover, the average cold-start length was approximately 912.4 s (15.2 min), and long cold starts could be found in cases with low ambient temperatures, low driving speeds and frequent stops. As for hot-run analysis, the proportion of Bin 1 (low-load windows) and Bin 2 (high-load windows) is directly related to the driving scenarios. The calculation results of TBM are comparable to the 2-bin method in EPA 2027. In addition, the optimization of NOx emissions under cold start and idle conditions are challenging for future HDV updates. Full article
(This article belongs to the Special Issue Traffic Related Emission (3rd Edition))
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17 pages, 6261 KB  
Article
Coupled Simulation of Hot Stage Separation with Adaptive Mesh Refinement
by Peize Yan and Yi Jiang
Aerospace 2026, 13(5), 431; https://doi.org/10.3390/aerospace13050431 - 4 May 2026
Viewed by 306
Abstract
The stage separation process, though often completed within one second, plays a critical role in determining the overall success and safety of the launch mission. The process of host stage separation is simulated to study the flow field evolution and the impact on [...] Read more.
The stage separation process, though often completed within one second, plays a critical role in determining the overall success and safety of the launch mission. The process of host stage separation is simulated to study the flow field evolution and the impact on the lower-stage. Overset mesh is utilized together with a novel adaptive mesh refinement sensor for the purpose of adapting to the relative motion. A third-order scheme is adopted in spatial discretization, and the simulation results fit well with the experiment data. The results show that the initial shockwave oscillated back and forth in the cavity of the lower-stage, leading to sustained oscillations in the forces of the lower-stage. Based on the monitor data, the force acting on the lower-stage exhibits five phases. Compared with former research, a longer interstage results in two more obvious oscillation phases. The pressure distribution on the forward dome of the lower-stage is also studied. Full article
(This article belongs to the Section Aeronautics)
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35 pages, 9007 KB  
Article
Thermal Symmetry Breakdown in Finned Natural Convection Cavities: Band-Resolved Nusselt Statistics and Multivariate Analysis Across Conductivity Ratios
by Saleh A. Bawazeer and Mohammad S. Alsoufi
Symmetry 2026, 18(3), 496; https://doi.org/10.3390/sym18030496 - 13 Mar 2026
Viewed by 370
Abstract
This study investigates the breakdown of thermal symmetry in finned square cavities under natural convection, focusing on how the fin-to-fluid conductivity ratio governs heat-transfer redistribution and localization. A band-resolved statistical framework is employed to analyze hot- and cold-wall Nusselt number responses across conductivity [...] Read more.
This study investigates the breakdown of thermal symmetry in finned square cavities under natural convection, focusing on how the fin-to-fluid conductivity ratio governs heat-transfer redistribution and localization. A band-resolved statistical framework is employed to analyze hot- and cold-wall Nusselt number responses across conductivity ratios (kr) ranging from symmetric to highly contrasting conditions. At kr=1, the cavity exhibits a fully symmetric conduction–convection regime with complete wall-to-wall coupling and a unified thermal response. Increasing the conductivity ratio to kr=10 introduces a transitional regime marked by mild but systematic asymmetry, with convective activity beginning to favor the cold wall. At kr=100, the system undergoes a structural transition to a strongly asymmetric state, characterized by attenuation of hot-wall convection and sustained cold-wall dominance. Under extreme ratio (kr=1000), convective heat transfer becomes highly localized at the cold wall, forming a directional thermal pathway. Joint Gaussian envelopes, regression scaling, principal component analysis, and Hotelling separation collectively demonstrate that symmetry breakdown proceeds through distinct, statistically separable stages, rather than emerging as a gradual shift in mean heat-transfer intensity. The results establish cold-wall localization as the governing physical mechanism and provide a unified framework for controlling convective heat transfer in fin-assisted natural-convection systems. Full article
(This article belongs to the Section Physics)
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17 pages, 3401 KB  
Article
Interfacial Structure and Bonding Properties of Ag/Cu Through-Layered Composite Fabricated by Dual-Face Hot-Roll Inlaying Process
by Yong Wang, Quanzhen Yang, Kunshan Guo, Tianhao Liu, Xue Zhao, Lei Huang, Haiguang Ruan, Xiaorong Zhou and Yi Chen
Materials 2025, 18(24), 5580; https://doi.org/10.3390/ma18245580 - 12 Dec 2025
Cited by 1 | Viewed by 522
Abstract
A novel dual-face hot-roll inlaying technique was developed to fabricate a Ag/Cu through-layered composite for use in melt elements for fuse production, including two stages of grooving in a Cu strip followed by separate inlaying of Ag strips at the same positions on [...] Read more.
A novel dual-face hot-roll inlaying technique was developed to fabricate a Ag/Cu through-layered composite for use in melt elements for fuse production, including two stages of grooving in a Cu strip followed by separate inlaying of Ag strips at the same positions on the opposite surfaces. The microstructure was characterized using field emission scanning electron microscopy (FE-SEM), electron probe microanalysis (EPMA), X-ray diffraction (XRD), and selective area electron diffraction (SAED). The Ag/Cu interfaces are flat and well bonded, with an elemental interdiffusion layer of less than 2 μm. The same textural components—copper, brass, and S-type components—were identified in both the Ag and Cu layers. However, no well-matched crystal orientation relationship between Ag and Cu was detected at the interface. Moreover, tensile properties and electrical resistance were measured to evaluate the bonding strength and conductivity of the interface. It was found that Ag/Cu bonding strength surpassed the tensile strength of Ag, i.e., 260 MPa. While the total elongation is less than 1%, the Ag layer exhibits excellent plasticity, with a section shrinkage over 90%. Compared with the calculated resistivity with a series circuit model, the tested value of the composite sample, including six Ag/Cu interfaces, increased by only 6.6%, indicating good conductivity of the Ag/Cu interface. Therefore, the obtained composite is a promising candidate for the fabrication of melt elements. Full article
(This article belongs to the Section Advanced Composites)
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22 pages, 1891 KB  
Article
BIM-Based Life Cycle Carbon Assessment and PV Strategies for Residential Buildings in Central China
by Yifeng Guo, Yexue Li, Shanshan Xie, Wanqin Mao and Xuzhi Chen
Buildings 2025, 15(23), 4232; https://doi.org/10.3390/buildings15234232 - 24 Nov 2025
Viewed by 1160
Abstract
Aligned with China’s “Dual Carbon” goals, this study addresses carbon emissions in the building sector. Existing research predominantly focuses on single-stage carbon emission assessment or separately examines the benefits of BIM applications and photovoltaic (PV) technology. There is a notable lack of studies [...] Read more.
Aligned with China’s “Dual Carbon” goals, this study addresses carbon emissions in the building sector. Existing research predominantly focuses on single-stage carbon emission assessment or separately examines the benefits of BIM applications and photovoltaic (PV) technology. There is a notable lack of studies that deeply integrate the BIM platform with dynamic assessment of building life cycle carbon emissions and PV carbon reduction strategies, particularly under the specific context of the hot-summer/cold-winter climate in Central China and a regional grid primarily reliant on thermal power. Moreover, localized and in-depth analyses targeting residential buildings in this region remain scarce. To address this gap, this study takes a residential building in Central China as a case study and establishes a BIM-based life cycle carbon emission assessment model to systematically quantify the carbon footprint across all stages. Results show total life cycle carbon emissions of 12600 tCO2, with embodied carbon (4590 tCO2, 36.6%) and the operational phase identified as the main emission sources. Through PV system integration and multi-scenario simulations, the study demonstrates significant carbon reduction potential: systems with 40–80 kW capacity can achieve annual carbon reductions ranging from 26 to 52 tCO2. The 60 kW system shows the optimal balance with an annual reduction of 38.7 tCO2 and a payback period of 3.53 years. The primary novelty of this work lies in its development of a dynamic BIM-LCA framework that enables real-time carbon footprint tracking, and the establishment of a first-of-its-kind quantitative model for PV strategy optimization under the specific climatic and grid conditions of Central China, providing a replicable pathway for region-specific decarbonization. Full article
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19 pages, 3042 KB  
Article
Selective Oxidation Control for Synchronous Vanadium Extraction and Chromium Retention from Vanadium- and Chromium-Bearing Hot Metal
by Xin-Yu Wang, Hai-Quan Zhao, Lu-Feng Wang, Qiao-Chu Liu, Ding-Liu Yan, Feng Wang and Yuan-Hong Qi
Metals 2025, 15(11), 1275; https://doi.org/10.3390/met15111275 - 20 Nov 2025
Viewed by 626
Abstract
To address the technical challenges involved in the resource utilization of hot metal containing high levels of vanadium (V: 2–5%) and chromium (Cr: 1–5%), this study proposes a novel method based on pyrometallurgical selective oxidation for simultaneously extracting vanadium and retaining chromium. Through [...] Read more.
To address the technical challenges involved in the resource utilization of hot metal containing high levels of vanadium (V: 2–5%) and chromium (Cr: 1–5%), this study proposes a novel method based on pyrometallurgical selective oxidation for simultaneously extracting vanadium and retaining chromium. Through thermodynamic analysis and high-temperature smelting experiments, the competitive oxidation behaviors of carbon, vanadium, and chromium were revealed, and the synergistic control mechanism of temperature and oxygen partial pressure was clarified. The results indicate that within a temperature range of 1693–1753 K, adjusted over 1 h, vanadium preferentially oxidizes over carbon and chromium, while carbon effectively suppresses chromium oxidation. By optimizing ω(FeO) (10.0–15.7%), we achieved a vanadium oxidation efficiency (ηV) of 72.5–82.2% and maintained a chromium retention efficiency (100−ηCr) exceeding 57.1%. Compared to traditional methods, which rely on high-oxygen blowing (oxygen supply: 43–195 kg/tFe), multi-stage roasting, and hydrometallurgical refining, this approach eliminates roasting and hydrometallurgical steps (such as sodium/calcium roasting and the associated leaching–precipitation units), shortens the process chain, reduces oxygen consumption (>80 kg/tFe), and lowers environmental risks (Cr oxidation reduced > 40%). This study establishes a theoretical framework for achieving sustainable V/Cr separation, enhancing resource efficiency and minimizing pollution (e.g., Cr(VI)-containing wastewater, high-salinity NH4+/Na+ wastewater). Full article
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17 pages, 7152 KB  
Article
Flame Structure and Flame–Flow Interaction in a Centrally Staged Burner Featuring a Diffusion Pilot
by Weishu Mo, Te Liu, Bo Wang, Guangming Ren and Xiaohua Gan
Aerospace 2025, 12(11), 1019; https://doi.org/10.3390/aerospace12111019 - 17 Nov 2025
Cited by 1 | Viewed by 949
Abstract
The pilot flame serves as the primary anchor for global flame stabilization in a centrally staged combustor. In engineering practice, it typically operates in the diffusion mode. The fuel non-uniformity and diffusion kinetics of the pilot flame may have a significant impact on [...] Read more.
The pilot flame serves as the primary anchor for global flame stabilization in a centrally staged combustor. In engineering practice, it typically operates in the diffusion mode. The fuel non-uniformity and diffusion kinetics of the pilot flame may have a significant impact on the flow and flames within the combustor. The flame structure and flame–flow interaction in a centrally staged burner featuring a diffusion pilot flame are investigated in the present paper, using high-frequency CH2O planar laser-induced fluorescence (CH2O-PLIF), CH* chemiluminescence, and particle image velocimetry (PIV) measurements. The stratified flame (S-flame) and the lifted flame (L-flame) are identified under two-stage conditions. The S-flame and L-flame correspond to the separated flow and the merged flow of the two stages, respectively. Significant radial oscillation of the pilot stage airflow is also found. Extensive tests demonstrate that the pilot equivalence ratio (Φp) plays an important role in flame mode switching. Silicone droplets with extremely fine sizes are introduced into the pilot fuel to trace its transportation. When the oscillating pilot stage airflow rushes towards the lip in an instant, it can entrain the pilot fuel to reach the inner side of the main stage outlet. With a low pilot fuel supply and relatively low injection velocity, the pilot fuel and the hot radicals are more likely to be entrained and accumulate in larger amounts at the inner side of the main stage outlet. Consequently, the main stage premixed mixture can be ignited at the main stage outlet, forming the S-flame. The flame mode switches from S- to L-flame when the equivalence ratio increases to the point where the corresponding velocity ratio of pilot fuel to air (Vfp/Vap) approaches 1.0, with a reduced entrainment of the pilot fuel and radicals. Simultaneous CH2O-PLIF and flow field results show that when the main stage is ignited downstream, hot products cannot recirculate to the pilot stage outlet, causing the extinction of the pilot flame root. This paper reveals that the fuel diffusion characteristics of the pilot stage can dramatically change the flame structure. To achieve the ideal designed flame shape, the interaction between the pilot fuel and pilot air requires very careful treatment in practical centrally staged combustors. Full article
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20 pages, 3681 KB  
Article
Development and Performance Analysis of a Novel Multi-Stage Microchannel Separated Gravity Heat Pipe for Compressor Room Cooling
by Zhihua Li, Ying Zhang, Fanghua Ye, Juan Zi, Deji Sun, Guanglie Liu, Renqin Kuang, Weiguo Jiang and Hualiang Wu
Processes 2025, 13(11), 3609; https://doi.org/10.3390/pr13113609 - 7 Nov 2025
Viewed by 674
Abstract
Traditional multi-stage separated heat pipes (SHPs) face limitations in independently setting operation parameters for each stage. To address this issue, this paper presents a novel independent multi-stage microchannel Separated Gravity Heat Pipe (SGHP) for air compressor room cooling. The innovative structure and working [...] Read more.
Traditional multi-stage separated heat pipes (SHPs) face limitations in independently setting operation parameters for each stage. To address this issue, this paper presents a novel independent multi-stage microchannel Separated Gravity Heat Pipe (SGHP) for air compressor room cooling. The innovative structure and working principle of this novel multi-stage SGHP were introduced. Furthermore, numerical investigations on a single stage of the SGHP were then conducted to study the gas–liquid two-phase flow characteristics and phase-change heat transfer performance. Experimental research on a three-stage SGHP was carried out to further explore the impact of the filling ratio combinations and the temperature difference between the hot and cold ends on the heat transfer performance of the SGHP. The results show that the temperature difference between the hot and cold ends affects the flow pattern of the working fluid, which has a vital effect on the heat transfer performance of the SGHP. The optimum filling ratio combination of the three-stage SGHP depends on the temperature difference between the hot and cold ends. The optimum filling ratio combination is 37%/37%/30% at low temperature difference conditions and 43%/37%/37% at high temperature difference conditions, respectively. The highest heat transfer capacity of the three-stage SGHP reaches 15.3 kW, and the peak heat recovery efficiency is 74.0%. The findings provide a crucial foundation for developing novel independent multi-stage SGHP in compressor room cooling and similar industrial settings, promising high potential to reduce energy consumption and operational costs. Full article
(This article belongs to the Special Issue Multi-Phase Flow and Heat and Mass Transfer Engineering)
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14 pages, 5130 KB  
Article
Study on the Drying Characteristics of Moist Fine Lignite in a Dense Gas–Solid Separation Fluidized Bed
by Huicheng Lei, Tengfeng Wan, Tingguan Chen, Bingbing Ma, Zongxu Yao, Bao Xu, Qingfei Wang and Xuan Xu
Minerals 2025, 15(10), 1039; https://doi.org/10.3390/min15101039 - 30 Sep 2025
Cited by 1 | Viewed by 696
Abstract
Coal serves as a cornerstone and stabilizer for China’s energy security; utilizing it in a clean and efficient manner aligns with the current national energy situation. The moisture content of coal is a crucial factor affecting its calorific value and separation efficiency. Therefore, [...] Read more.
Coal serves as a cornerstone and stabilizer for China’s energy security; utilizing it in a clean and efficient manner aligns with the current national energy situation. The moisture content of coal is a crucial factor affecting its calorific value and separation efficiency. Therefore, enhancing the drying rate while simultaneously reducing the moisture content in coal is essential to improve separation efficiency. This paper primarily investigates the drying and separation characteristics of wet fine coal particles within a gas–solid fluidized bed system. A hot gas–solid fluidized bed was employed to study the particle fluidization behavior, heat–mass transfer, and agglomeration drying properties under varying airflow temperatures. The results indicate that as the airflow temperature increases, the minimum fluidization velocity tends to decrease. Additionally, with an increase in bed height, the particle temperature correspondingly decreases, leading to weakened heat exchange capability in the upper layer of the bed. Faster heating rates facilitate rapid moisture removal while minimizing agglomeration formation. The lower the proportion of moisture and magnetite powder present, the less force is required to break apart particle agglomerates. The coal drying process exhibits distinct stages. Within a temperature range of 75 °C to 100 °C, there is a significant enhancement in drying rate, while issues such as particle fragmentation or pore structure collapse are avoided at elevated temperatures. This research aims to provide foundational insights into effective drying processes for wet coal particles in gas–solid fluidized beds. Full article
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18 pages, 11004 KB  
Article
Electrical Imaging Across Eastern South China: New Insights into the Intracontinental Tectonic Process During Mesozoic
by Kun Zhang, Zhaohong Wan, Xingzhi Ma, Yufan Yang and Hao Hu
Minerals 2025, 15(10), 1035; https://doi.org/10.3390/min15101035 - 29 Sep 2025
Cited by 1 | Viewed by 623
Abstract
To further investigate the collision process and tectonic regime transition between the North China (NCB) and South China Block (SCB), two magnetotelluric profiles were arranged across the Dabie Orogeny Belt (DOB) and eastern SCB. We then obtain the lithospheric resistivity models. The prominent [...] Read more.
To further investigate the collision process and tectonic regime transition between the North China (NCB) and South China Block (SCB), two magnetotelluric profiles were arranged across the Dabie Orogeny Belt (DOB) and eastern SCB. We then obtain the lithospheric resistivity models. The prominent feature revealed by our new model is an extensive conductive arc from the lower crust to the upper mantle, across the Jiangnan orogenic belt (JNOB) and the eastern Cathaysia Block (CAB). In addition, a huge resistor beneath the conductive arc is revealed, which is separated by a conductive wedge. Combining the heat flow and seismic tomographic imaging results, the conductors are to contain a large amount of hot material that present as the detachment layers (belts) controlled by the two subduction slabs. Considering multi-phase magmatism in the study area, new models suggest an intracontinental tectonic event in eastern CAB. Therefore, we propose a reliable tectonic process that occurred in the study area, including five stages: (1) an eastward intracontinental subduction and orogen carried out in CAB before the collision between SCB and NCB; (2) an extensional structural developed in CAB, following the subduction slab wrecking/sinking; (3) after the collision with NCB, the SCB crust/lithosphere thickened following the westward subduction of the Paleo-Pacific plate; (4) following the westward Yangtze slab sinking, the regional extension developed with the asthenosphere upwelling beneath SCB; (5) afterwards, the SCB was welded into one continent in a setting of westward compression. Full article
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31 pages, 6448 KB  
Review
Review of Research on Supercritical Carbon Dioxide Axial Flow Compressors
by Yong Tian, Dexi Chen, Yuming Zhu, Peng Jiang, Bo Wang, Xiang Xu and Xiaodi Tang
Energies 2025, 18(12), 3081; https://doi.org/10.3390/en18123081 - 11 Jun 2025
Cited by 1 | Viewed by 2192
Abstract
Since the beginning of the 21st century, the supercritical carbon dioxide (sCO2) Brayton cycle has emerged as a hot topic of research in the energy field. Among its key components, the sCO2 compressor has received significant attention. In particular, axial-flow [...] Read more.
Since the beginning of the 21st century, the supercritical carbon dioxide (sCO2) Brayton cycle has emerged as a hot topic of research in the energy field. Among its key components, the sCO2 compressor has received significant attention. In particular, axial-flow sCO2 compressors are increasingly being investigated as power systems advance toward high power scaling. This paper reviews global research progress in this field. As for performance characteristics, currently, sCO2 axial-flow compressors are mostly designed with large mass flow rates (>100 kg/s), near-critical inlet conditions, multistage configurations with relatively low stage pressure ratios (1.1–1.2), and high isentropic efficiencies (87–93%). As for internal flow characteristics, although similarity laws remain applicable to sCO2 turbomachinery, the flow dynamics are strongly influenced by abrupt variations in thermophysical properties (e.g., viscosities, sound speeds, and isentropic exponents). High Reynolds numbers reduce frictional losses and enhance flow stability against separation but increase sensitivity to wall roughness. The locally reduced sound speed may induce shock waves and choke, while drastic variation in the isentropic exponent makes the multistage matching difficult and disperses normalized performance curves. Additionally, the quantitative impact of a near-critical phase change remains insufficiently understood. As for the experimental investigation, so far, it has been publicly shown that only the University of Notre Dame has conducted an axial-flow compressor experimental test, for the first stage of a 10 MW sCO2 multistage axial-flow compressor. Although the measured efficiency is higher than that of all known sCO2 centrifugal compressors, the inlet conditions evidently deviate from the critical point, limiting the applicability of the results to sCO2 power cycles. As for design and optimization, conventional design methodologies for axial-flow compressors require adaptations to incorporate real-gas property correction models, re-evaluations of maximum diffusion (e.g., the DF parameter) for sCO2 applications, and the intensification of structural constraints due to the high pressure and density of sCO2. In conclusion, further research should focus on two aspects. The first is to carry out more fundamental cascade experiments and numerical simulations to reveal the complex mechanisms for the near-critical, transonic, and two-phase flow within the sCO2 axial-flow compressor. The second is to develop loss models and design a space suitable for sCO2 multistage axial-flow compressors, thus improving the design tools for high-efficiency and wide-margin sCO2 axial-flow compressors. Full article
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11 pages, 1432 KB  
Article
Energy-Saving Design of Urea Method for Hydrazine Hydrate Process
by Zhihao Wang, Xiaojing Wang, Haibin Wu, Shengting Li and Yongjie Xu
Processes 2025, 13(5), 1585; https://doi.org/10.3390/pr13051585 - 20 May 2025
Viewed by 2179
Abstract
The conventional urea-based process for hydrazine hydrate production faces challenges including low product yield and high energy consumption. To overcome these limitations, we propose an innovative integrated approach combining jet reactor technology with membrane separation, further enhanced through heat network optimization. Through process [...] Read more.
The conventional urea-based process for hydrazine hydrate production faces challenges including low product yield and high energy consumption. To overcome these limitations, we propose an innovative integrated approach combining jet reactor technology with membrane separation, further enhanced through heat network optimization. Through process simulation and sensitivity analysis, the following optimal distillation parameters were identified: nine theoretical stages, feed entry at the fifth stage, a reflux ratio of 0.6, and a distillate flow rate of 354 kg/h. Systematic optimization of the heat exchanger network (HEN) using pinch technology achieved substantial energy savings, reducing hot utility consumption by 66.8% (to 1317 MJ/h) and cold utility usage by 62.7% (to 1503 MJ/h). The redesigned HEN prioritized temperature-cascaded heat recovery, enabling 67% energy recuperation from exothermic reaction streams. Operational costs decreased by 12%, underscoring the economic viability of coupling process intensification with thermal integration. This work establishes a sustainable framework for hydrazine hydrate synthesis, balancing industrial feasibility with reduced environmental impact in chemical manufacturing. Full article
(This article belongs to the Section Energy Systems)
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15 pages, 3644 KB  
Article
Microwave-Mediated Extraction of Critical Metals from LED E-Waste
by Athanasios B. Bourlinos, Christina Papachristodoulou, Anastasios Markou, Nikolaos Chalmpes, Emmanuel P. Giannelis, Dimitrios P. Gournis, Constantinos E. Salmas and Michael A. Karakassides
ChemEngineering 2025, 9(3), 47; https://doi.org/10.3390/chemengineering9030047 - 29 Apr 2025
Viewed by 2647
Abstract
This study introduces a microwave-assisted technique for extracting critical minerals from LED electronic waste. The process begins with microwave irradiation, which thermally decomposes the LED’s plastic lens into a brittle, charred residue. During this stage, the LED chip undergoes deflagration—being rapidly ejected from [...] Read more.
This study introduces a microwave-assisted technique for extracting critical minerals from LED electronic waste. The process begins with microwave irradiation, which thermally decomposes the LED’s plastic lens into a brittle, charred residue. During this stage, the LED chip undergoes deflagration—being rapidly ejected from the reflective cavity and becoming embedded within the decomposed lens material. Consequently, the chip is encapsulated in the resulting charred residue. This composite, consisting of the charred lens and the LED chip, can be easily separated from the metallic pins (Fe, Ni, Ag), which remain almost undamaged. Subsequent calcination of the charred material in air exposes the materials making up the LED chip, which contain critical metals (e.g., Ga, As, In, Y, Au). These metals are then extracted through a two-step acid leaching process involving aqua regia followed by hot concentrated hydrochloric acid, yielding them in potentially recoverable forms. The synergistic effect of microwave irradiation and acid treatment achieves an average extraction efficiency of 96% for critical metals. Notably, this approach enables complete and loss-free recovery of the LED chip, offering a practical and efficient solution for LED e-waste recycling. Full article
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21 pages, 3845 KB  
Article
Graphite Separation from Lithium-Ion Battery Black Mass Using Froth Flotation and Quality Evaluation for Reuse as a Secondary Raw Material Including Non-Battery Applications
by Johannes Rieger, Stephan Stuhr, Bettina Rutrecht, Stefan Morgenbesser, Thomas Nigl, Astrid Arnberger, Hartwig Kunanz and Stefanie Lesiak
Recycling 2025, 10(2), 75; https://doi.org/10.3390/recycling10020075 - 14 Apr 2025
Cited by 7 | Viewed by 7113
Abstract
This study investigates graphite separation from Lithium-Ion Battery (LIB) black mass (which is a mixture of anode and cathode materials) via froth flotation coupled with an open-loop recycling approach for the graphite (froth) product. Black mass samples originating from different LIB types were [...] Read more.
This study investigates graphite separation from Lithium-Ion Battery (LIB) black mass (which is a mixture of anode and cathode materials) via froth flotation coupled with an open-loop recycling approach for the graphite (froth) product. Black mass samples originating from different LIB types were used to produce a carbon-poor and a carbon-enriched fractions. The optimization of the flotation parameters was carried out depending on the black mass chemistry, i.e., the number of flotation stages and the dosing of flotation agents. The carbon-enriched product (with a carbon content of 92 wt.%, corresponding to a recovery of 89%) was subsequently used as a secondary carbon source for refractory material (magnesia carbon brick). Analyses of brick chemistry, as well as thermo-mechanic properties in terms of density, porosity, cold crushing strength (CCS), hot modulus of rupture (HMOR—the maximum bending stress that can be applied to a material before it breaks), and thermal conductivity showed no negative influence on brick quality. It could be demonstrated that flotation graphite can principally be used as a secondary source for non-battery applications. This is a highly valuable example that contributes to a more complete closure of a battery’s life cycle in terms of circular economy. Full article
(This article belongs to the Special Issue Lithium-Ion and Next-Generation Batteries Recycling)
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17 pages, 6014 KB  
Article
Experimental Investigation of the Effect of Seawater on Glass and Carbon Fiber Composites via Mechanical Characterization
by Senai Yalçınkaya, Dudu Mertgenç Yoldaş and Mehmet Fatih Yoldaş
J. Compos. Sci. 2025, 9(3), 107; https://doi.org/10.3390/jcs9030107 - 25 Feb 2025
Cited by 13 | Viewed by 3419
Abstract
Since composite materials are light and corrosion-resistant, they have replaced many traditional materials in the aviation and marine industries. Composite materials have the advantages of a much higher strength–weight ratio, lower maintenance requirements, and the ability to form complex shapes, such as bodies, [...] Read more.
Since composite materials are light and corrosion-resistant, they have replaced many traditional materials in the aviation and marine industries. Composite materials have the advantages of a much higher strength–weight ratio, lower maintenance requirements, and the ability to form complex shapes, such as bodies, compared to carbon steel. In this study, the mechanical properties of glass fiber reinforced (GFRP) and carbon fiber reinforced (CFRP) composite materials were investigated in marine applications in which composite materials had been used. In this study, 0/90 oriented twill weave eight-ply GFRP and eight-ply CFRP composite materials were used, incorporating the hand lay-up method and hot-pressing method. Seawater was taken from the Aegean Sea, Izmir Province (Balçova/İnciraltı), and had an average temperature of 22.43 °C. This seawater was kept in different containers for 30 days and 60 days (a total of 1440 h of keeping in seawater) with the intent to test the GFRP and CFRP composite samples separately. The produced CFRP and GFRP sheets were then cut with a wet (circular) saw in accordance with the standard procedure in the Composite Research and Testing Laboratory of the Dokuz Eylul University Department of Mechanical Engineering. Moisture retention percentages and Charpy impact tests were carried out. Then, three-point bending tests were carried out according to TS EN ISO 14125. The damage in the material was examined using a ZEISS Stereo Discovery.V12 imaging microscope (Oberkochen, Germany). The mechanical properties of CFRP- and GFRP-reinforced composite samples before and after aging were investigated using the Charpy impact test and three-point bending test. Then, the effects of the seawater environment on the mechanical properties of the CFRP and GFRP composite materials were evaluated by comparing the results. The aim was to better understand what kind of damage would occur in GFRP and CFRP composite materials given the effects of seawater and at what stages changes would occur in the mechanical properties of these materials. Moisture retention rates (%) in the tested samples after the Charpy impact test were 2.56% in GFRP and 0.47% in CFRP after 30 days. In the tested samples after the three-point bending test, these values were 1.41% in GFRP and 0.31% in CFRP after 30 days. Subsequent to the Charpy impact tests, the fracture toughness values of the CFRP samples tested at the 30 J impact energy level before aging in seawater conditions for 30 days or 60 days were found to be increased by 15.79% and 21.08%, respectively. The fracture toughness values of the GFRP tested at the 30 J impact energy level in dry conditions and kept in seawater for 30 days or 60 days were found to be 27.69% and 29.23%, respectively. The energy absorbed during the impact tests by the GFRP samples was higher than in the CFRP samples. This showed that the GFRP samples were more brittle. Subsequent to the three-point bending tests, the CFRP composite samples kept in seawater for periods of 30 days and 60 days showed changes in the modulus of elasticity of 7.48% and 7.46%, respectively, compared to the dry samples. The GFRP composite samples kept in seawater for periods of 30 days and 60 days showed changes in the modulus of elasticity of 7.015% and 11.53%, respectively, compared to the dry samples. The change in the modulus of elasticity was less in the CFRP samples than in GFRP. All of these results showed that the mechanical properties of CFRP were better than those of GFRP. Full article
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